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[3]
IONIC EQUILIBRIA A2 WS 1
[Total : 12]
(a) Methanoic acid, HCO2H, is a weak acid, with Ka = 1.77 x 104 mol dm3.
(i)
(ii)
3
Use your expression to calculate the [H+] in a 0.0500 mol dm solution of
methanoic acid.
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(iii)
Calculate the percentage of HCO2H molecules that are ionised in this solution.
(iv)
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[4]
9701/4/O/N/03
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5
(b) Calculate the pH of a 0.0500 mol dm3 solution of the strong acid HCl.
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(c) Both HCO2H and HCl react with powdered magnesium metal, giving off hydrogen gas.
For a fixed amount of magnesium, the rate equation for the reaction is as follows.
rate = k [H+(aq)]
(i)
When 20.0 cm3 of a 0.0500 mol dm3 solution of either acid is reacted with an excess of
powdered magnesium, the same volume of hydrogen is given off, but the methanoic
acid solution reacts much more slowly than the hydrochloric acid.
(ii)
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(iii)
Explain why the hydrogen is evolved more slowly from the methanoic acid solution.
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(iv)
Explain why, eventually, the methanoic acid solution produces just as much
hydrogen as the hydrochloric acid solution.
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[Total : 10]
9701/4/O/N/03
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For
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Use
reversible reaction
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(ii)
dynamic equilibrium
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[2]
(b) Water ionises to a small extent as follows.
H2O(l)
(i)
H+(aq) + OH(aq)
H = +58 kJ mol1
(ii)
Write down the expression for Kw, the ionic product of water, and explain how this
can be derived from your Kc expression in (i).
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(iii)
State and explain how the value of Kw for hot water will differ from its value for cold
water.
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[3]
(c) Kw can be used to calculate the pH of solutions of strong and weak bases.
(i)
Use the value of Kw in the Data Booklet to calculate the pH of 0.050 mol dm3
NaOH.
pH = ...........................................
Ammonia ionises slightly in water as follows.
NH3(aq) + H2O(l)
NH4+(aq) + OH(aq)
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(ii)
Calculate [OH(aq)] in a 0.050 mol dm3 solution of NH3. You may assume that only
a small fraction of the NH3 ionises, so that [NH3] at equilibrium remains at
0.050 mol dm3.
For
Examiners
Use
[OH(aq)] = .................................
(iii)
Use the value of Kw in the Data Booklet, and your answer in (ii), to calculate [H+(aq)]
in 0.050 mol dm3 NH3(aq).
8
(ii)
For
Examiners
Use
..................................................................................................................................
[H+(aq)] = ...................................
Write an equation to show how a solution of alanine, CH3CH(NH2)CO2H, behaves
as(iv)
a buffer
in thethe
presence
of an
acid such as HCl(aq).
Calculate
pH of this
solution.
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(iii)
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[Total: 11]
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(iv)
Calculate the pH of the buffer formed when 10.0 cm3 of 0.100 mol dm3 NaOH is
added to 10.0 cm3 of 0.250 mol dm3 CH3CO2H, whose pKa = 4.76.
pH = ......................................................
[7]
[Total: 19]
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42
Ibuprofen is one of the most commonly used non-steroidal anti-inflammatory drugs, used to
treat chronic arthritic pain caused by inflammation of the joints.
CH3
CH
CH3
CH
CH3
OH
CH2
ibuprofen
(a) (i)
(ii)
(iii)
Calculate the Mr of ibuprofen and use it to calculate how many grams are
needed to make 100 cm3 of a 0.15 mol dm3 solution.
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(iv)
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[7]
6
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(b) The Ka value for ibuprofen is 6.3 10 mol dm .
(i)
(ii)
Use the Ka value to calculate the pH of a 0.15 mol dm3 solution of ibuprofen.
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[3]
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(c) To avoid problems with digestive irritation over a long period of use, research is being
carried out into ways of administering ibuprofen using skin patches. For this use the
compound is dissolved in a hydrophilic gel which acts as a buffer.
(i)
For
Examiners
Use
(iii)
[5]
[Total: 15]
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1
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(c) The pH of 0.200 mol dm3 NH3(aq) is 11.3. Explain why this answer differs from your
answer in (b).
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(d) A 20.0 cm3 sample of 0.200 mol dm3 NH3(aq) was titrated with 0.100 mol dm3 HCl.
On the following axes, sketch how the pH changes during this titration. Mark clearly
where the end point occurs.
14
pH
10
20
30
volume of added
40
50
60
acid / cm3
[3]
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(e) From the following list of indicators, put a tick in the box by the side of the indicator you
consider most suitable for this titration.
indicator
For
Examiner's
Use
methyl violet
0.0 - 1.6
methyl orange
3.1 - 4.4
bromothymol blue
6.0 - 7.6
phenolphthalein
8.3 - 10.0
[1]
(f)
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(a) Explain what is meant by the Bronsted-Lowry theory of acids and bases.
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(b) The Ka values for some organic acids are listed below.
(i)
acid
Ka /mol dm3
CH3CO2H
1.7 ! 105
Cl CH2CO2H
1.3 ! 103
Cl 2CHCO2H
5.0 ! 102
(ii)
pH = ...........................................
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(iii)
Use the following axes to sketch the titration curve you would obtain when 20 cm3 of
0.10 mol dm3 NaOH is added gradually to 10 cm3 of 0.10 mol dm3 Cl CH2CO2H.
For
Examiners
Use
14
pH
10
15
20
[8]
(c) (i)
Write suitable equations to show how a mixture of ethanoic acid, CH3CO2H, and
sodium ethanoate acts as a buffer solution to control the pH when either an acid or
an alkali is added.
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(ii)
Calculate the pH of a buffer solution containing 0.10 mol dm3 ethanoic acid and
0.20 mol dm3 sodium ethanoate.
pH = ...........................................
[4]
[Total: 14]
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7 1
2H+(aq) + SO42(aq)
(a) The organic base guanidine contains carbon, nitrogen and hydrogen. Its reaction with
acids can be represented as follows.
B(aq) + H+ (aq)
BH+(aq)
10
20
30
40
50
60
Volume of guanidine
70
added / cm3
(ii)
The pH at the start of the titration was 0.70. Calculate the [H+], and hence the
concentration of sulphuric acid, at the start of the titration.
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3
(iii)
(iv)
The guanidine solution contained 8.68 g of the base per dm3. Use your answer to
(iii) calculate the Mr of guanidine.
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(b) One of the major industrial uses of sulphuric acid is to convert phosphate rock (calcium
fluorophosphate(V)) into superphosphate for use as a fertiliser. The process can be
represented by the following partially balanced equation.
2 Ca5(PO4)3F + 7H2SO4 ....... CaSO4 + ....... Ca(H2PO4)2 + ....... HF
superphosphate
(i)
(ii)
HPO42 + H+
(ii)
Calculate the pH of a buffer solution that contains 0.20 mol dm3 NaH2PO4 and
[Ka (H2PO4) = 6.3 x 108 mol dm3]
0.10 mol dm3 Na2HPO4.
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[Total: 13]
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87
pH
10
20
volume of HC (aq) added / cm3
30
[2]
[Total: 4]
UCLES 2010
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9701/43/O/N/10
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