These Y Veschetti 10 2004

Thse prsente pour obtenir le grade de Docteur de L'Universit Louis Pasteur Strasbourg I Discipline :Physique des semi-conducteurs par Yannick Veschetti
Modlisation, caractrisation et ralisation de nouvelles structures photovoltaques sur substrat de silicium mince
Soutenue publiquement le 25 Octobre 2005
Directeur de Thse : Jean-Claude Muller Rapporteur Interne : Thomas Heiser Rapporteur Externe : Santo Martinuzzi Rapporteur Externe : Anne Kaminski Examinateur : Pere Roca i Cabarrocas Examinateur : Sbastien Nol Membre invit : Nam Le Quang Membre invit : Andr Claverie
Ingnieur de recherche Professeur

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Professeur Matre de Confrence Directeur de recherche Ingnieur de recherche Ingnieur de recherche Ingnieur ADEME
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99
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10
100
Coefficient dabsorption [cm-1]
10 10 10 10 10 10 10
abs c-Si abs a-Si:H (HMI) [31] abs a-Si:H (LPICM)
80
Absorption [%]
60
Absorption du silicium amorphe (LPICM) e=5nm e=10nm e=20nm
40
20
400
600
800
1000
1200
300
400
500
600
700
Longueur donde [nm]
Longueur donde [nm]
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100
1,0
Rendement quantique interne RQI
0,9 0,8 0,7 0,6 0,5 0,4 0,3 0,2 0,1

Jcc=32mA/cm Jcc=33.3mA/cm Jcc=34.1mA/cm
a-Si:H(n)=5nm a-Si:H(n)=10nm a-Si:H(n)=20nm
0,0 250 300 350 400 450 500 550 600 650 700
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700 650 600 550
-3,6 -3,2
Dit=1E14cm
-3
Niveau d'nergie [eV]
-4,0
Dit=1E10cm
-3
Vco [mV]
500 450 400 350 300 250 1E10 1E11 1E12 1E13
-2
-4,4 -4,8 -5,2 -5,6
Structure A [c-Si(p)] Structure B [c-Si(n)]
(n) a-Si:H
(p) c-Si
1E14
1E-8
1E-7
1E-6
1E-5
1E-4
1E-3
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Distance de lorigine [cm]
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profondeur de plot dn+ [m]
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