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  • Derivation of Clausius Clapeyron Equation PDF

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    Shweta Sridhar
    200 vizualizări1 pagină
    The document derives the Clausius-Clapeyron equation, which describes the phase boundary between two phases in pressure-temperature space. It starts with the Gibbs-Duhem relation and applies it to a solid-liquid phase change, setting the chemical potentials of the two phases equal along the boundary. Rearranging and dividing by dT yields the Clausius-Clapeyron equation, where L is the latent heat of the phase change and ΔV is the difference in molar volumes between phases.

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    The document derives the Clausius-Clapeyron equation, which describes the phase boundary between two phases in pressure-temperature space. It starts with the Gibbs-Duhem relation and applies it to a solid-liquid phase change, setting the chemical potentials of the two phases equal along the boundary. Rearranging and dividing by dT yields the Clausius-Clapeyron equation, where L is the latent heat of the phase change and ΔV is the difference in molar volumes between phases.

    Drepturi de autor:

    Attribution Non-Commercial (BY-NC)
    Descărcați ca PDF, TXT sau citiți online pe Scribd
    Indicator pentru conținut neadecvat
    200 vizualizări1 pagină

    Derivation of Clausius Clapeyron Equation PDF

    Încărcat de

    Shweta Sridhar
    The document derives the Clausius-Clapeyron equation, which describes the phase boundary between two phases in pressure-temperature space. It starts with the Gibbs-Duhem relation and applies it to a solid-liquid phase change, setting the chemical potentials of the two phases equal along the boundary. Rearranging and dividing by dT yields the Clausius-Clapeyron equation, where L is the latent heat of the phase change and ΔV is the difference in molar volumes between phases.

    Drepturi de autor:

    Attribution Non-Commercial (BY-NC)
    Descărcați ca PDF, TXT sau citiți online pe Scribd
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    din 1

    KALMAN KNIZHNIK - DERIVATION OF THE CLAUSIUS-CLAPEYRON EQUATION

    The Clausius-Clapeyron equation describes the phase boundary line (in pressure-temperature phase space) between two phases. To derive it, we start with the Gibbs-Duhem relation: d = SdT + V dP (1)

    Now, along the phase boundary, the chemical potentials are equal. Lets suppose we are going from a solid to a liquid (other phase changes follow identically). Then dliquid = dsolid . Then: Sliquid dT + Vliquid dP = Ssolid dT + Vsolid dP Dividing by dT and rearranging yields: Ssolid Sliquid dP = dT Vsolid Vliquid If we now dene L = T S as the latent heat, we get the Clausius-Clapeyron equation: dP L = dT T V 2 (4) (3) (2)

    Latent heat describes the amount of heat that must be added to a substance in order to induce a phase transition.

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