Universitatea Politehnica Bucureti Facultatea de Chimie Aplicat i tiina Materialelor

Introducere
MgO prezint: Cost redus Materii prime multiple Condiii simple antibacteriene Non-toxicitate Mecanism antibacterian unic- oxigen activ

Introducere
Metode de obinere Precursori Sol-gel -Mg(NO3)26H2O -LiNO3, Zn(NO3)26H2O, Ti(OC4H9)4 -C6H8O7H2O -600C/2h -Mg(NO3)26H2O -Na2CO3 -550,750,950C/1h

Precipitare

Investigate: Efectul dopajului Efectul dimensiuni de particule

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XRD

Fig.1 Analiza XRD: a) probe dopate obtinute prin Sol-gel si b) probe prin metoda precipitari

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TEM

Fig.2 Analiza TEM a probelor obinute prin Sol-gel: a) MgO nedopat b) dopat cu Ti c) dopat cu Zn d) dopat cu Li

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TEM

Fig.3 Analiza TEM a probei obinute prin metoda precipitri

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XPS

Fig.4 Analiza XPS a nanopulberi:a)MgO,b)MgO-Ti,c)MgO-Zn,d)MgO-Li

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FT-IR

Fig.5 Analiza FT-IR a probelor cu: a)bacterie, b)MgO, c) MgO+ bacterie.

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FT-IR

Fig.6 Analiza FT-IR a probei MgO + bacterie pe un interval de timp

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Proprieti antibacteriene raportate la dopare

Fig.7 Imagini reprezentative pentru activitile antibacteriene ale nanopulberilor (a): Control pozitiv; (b): Control negativ; (c): MgO; (d): dopat cu Ti; (e): dopat cu Zn; (f): dopat cu Li

Caracterizare
Proprieti antibacteriene raportate la dimensiunea particulelor

Fig.8 Dependena dimensiune-eficacitate

Bibliografie
Z.Rao et al., Influence of different ions doping on the antibacterial properties

of MgO nanopowders, Applied Surface Science, 284(2013)726731; L.Huang, D.Q.Li, Controllable preparation of Nano-MgO and investigation of its bactericidal properties, Journal of Inorganic Biochemistry, 99(2000)986993; K.Krishnamoorthy et al., Antibacterial activity of MgO nanoparticles based on lipid peroxidation by oxygen vacancy, Journal of Nanoparticle Research, (2012) 14:1063; F.Al-Hazmi et al., A new large Scale synthesis of magnesium oxide nanowires: Structural and antibacterial properties, Superlattices and Microstructures, 52(2012)200209; S.Makhluf et al., Microwave-Assisted Synthesis of Nanocrystalline MgO and Its Use as a Bacteriocide, Advanced Functional Materials, 2005, 15, 1708-1715.