Chapter 6 Worksheet 1 1. Which would decrease the internal energy of your body? a. lying in the sun b.

sitting in an air conditioned classroom where its COLD c. taking a hot bath d. eating food e. None of these 2. What is the heat capacity of a metal slug if a temperature rise from 25 C to 54 C requires 135 J? Units are Degrees Celsius. a. 0.21 J/ C b. 4.7 J/ C c. 0.60 J/ C d. 2.5 J/ C e. -4.6 J/ C 3. A 295-g aluminum engine part at an initial temperature of 3.00C absorbs 85.0 kJ of heat. What is the final temperature of the part (C)? (c of Al = 0.900 J/gK)? a. 2.68C b. 3.32C c. 323C d. 317C

4. Data: Hf values: CH4(g), -74.8 kJ; CO2(g), -393.5 kJ; H2O(l), -285.8 kJ. Using the Hf data above, calculate Hrxn for the reaction below. Reaction: CH4(g) + 2O2(g) => CO2(g) + 2H2O(l) a. -604.2 kJ b. 890.3 kJ c. -997.7 kJ d. -890.3 kJ e. none of the above

5. A 134 g aluminum engine part at an initial temperature of 16.9C absorbs 2,389 J of heat. What is the final temperature of the part (C)? (c of Al = 0.900 J/gK)?

6. Data: 2C8H18(l) + 25O2(g) => 16CO2(g) + 18H2O(l) Standard enthalpies of formation, Hf: CO2(g), -393.5 kJ/mol; H2O(l), -285.8 kJ/mol

H = -11,200. kJ

Use the above data to calculate the standard enthalpy of formation of octane, C8H18(l). a. -120. kJ/mol b. -240. kJ/mol c. -5144 kJ/mol d. -6296 kJ/mol e. -11,440. kJ/mol

7. Data: 2Fe(s) + O2(g) => 2FeO(s) H = -544.0 kJ 4Fe(s) + 3O2(g) => 2Fe2O3(s) H = -1648.4 kJ Fe3O4(s) => 3Fe(s) + 2O2(g) H = +1118.4 kJ Given the data above, determine the heat of reaction, H, for the reaction below: Reaction: Fe2O3(s) + FeO(s) => Fe3O4(s) a. -1074.0 kJ b. -22.2 kJ c. +22.2 kJ d. +249.8 kJ e. +1074.0 kJ

8. A 2.15 g sample of benzene (C6H6) is burned in a bomb calorimeter, and the temperature rises from 22.46 C to 34.34 C. Calculate the heat capacity of the bomb calorimeter. Note the following thermochemical equation:

9. When 50. mL (50. g) of 1.00 M HCl at 22.00 C is added to 50. mL (50. g) of 1.00 M NaOH at 22.00 C in a coffee cup calorimeter, the temperature increases to 28.87 C. What is the heat (q) of the reaction between HCl and NaOH? (The specific heat of the solution produced is 4.18 J/gC.)