TIRTRARE pH-metrica a ioniilor metalici in unui exces de EDTA,cu solutie standard de NaOH

Calcul concentratie:
Cn Mn+= Cn NAOH x FNaOH x (Vs NaOH/ Vs Mn+)
30.00

Titrare:
Nr
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25

Vs NaOH (ml)
pH
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24

2.24
2.34
2.44
2.64
2.86
3.03
3.3
3.81
6.29
10.28
10.6
10.8
10.92
11.03
11.11
11.18
11.24
11.27
11.33
11.38
11.41
11.46
11.49
11.51
11.54

V' (ml)
d1pH/dV V" (ml)
0.50
0.1
1.00
1.50
0.1
2.00
2.50
0.2
3.00
3.50
0.22
4.00
4.50
0.17
5.00
5.50
0.27
6.00
6.50
0.51
7.00
7.50
2.48
8.00
8.50
3.99
9.00
9.50
0.32
10.00
10.50
0.2
11.00
11.50
0.12
12.00
12.50
0.11
13.00
13.50
0.08
14.00
14.50
0.07
15.00
15.50
0.06
16.00
16.50
0.03
17.00
17.50
0.06
18.00
18.50
0.05
19.00
19.50
0.03
20.00
20.50
0.05
21.00
21.50
0.03
22.00
22.50
0.02
23.00
23.50
0.03
23.75
24.00 0.480833
24.00

Masa=0,0997,la equivalent pH=6,8

Eg:
1000*0,0997/(0,1*1*7,3)
136.5753

d2pH/V'
4.44E-16
0.1
0.02
-0.05
0.1
0.24
1.97
1.51
-3.67
-0.12
-0.08
-0.01
-0.03
-0.01
-0.01
-0.03
0.03
-0.01
-0.02
0.02
-0.02
-0.01
0.01
0.901667
0.020035

25.00

20.00

15.00

10.00

5.00

0.00
0.00 1.00 2.00

-5.00

-10.00

Series1
Series2

Series3

1.00 2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00