8/115

CH
3
COOH + HO CH
2
CH
3
CH
3
COO CH
2
CH
3
+ H
2
O
Se calculeaza cati moli de acid acetic si de alcool etilic sunt initial.
numar de moli CH
3
CH
2
OH = 46/46 = 1
numar de moli CH
3
COOH = 48/6 = !8
CH
3
COOH + HO CH
2
CH
3
CH
3
COO CH
2
CH
3
+ H
2
O
"nitial !8 1
Consumat # #
$c%ili&ru !8 # 1 # # #
'c = (CH
3
COO CH
2
CH
3
) (H
2
O) / (CH
3
CH
2
OH) (CH
3
COOH)
4 = # * # / +!8 #, * +1-#,
4 +!8 #, * +1-#, = #
2
4 + !8 # !8# + #
2
, = #
2
3!2 -.!2 # + 4#
2
= #
2
3 #
2
.!2# + 3!2 =
#
1
= 1!81
#
2
= !/0
1in cele doua 2alori este &una a doua deoarece initial au 3ost !8 moli acid si 1 mol alcool deci nu se
4uteau trans3orma 1!81 moli
5a ec%ili&ru 2or 3i6
!8 !/0 = !21 moli acid
1 !/0 = !41 moli alcool
!/0 moli ester
!/0 moli a4a
7umarul total de moli = !21 + !41 + !/0 + !/0 = 1!8
Calculam 4rocentele de moli
1!8 moli totali ........... !21 moli acid ............. !41 moli alcool ............ !/0 moli ester
1 moli amestec ..........#....................................8......................................z
# = !21 * 1/1!8 = 11!669 acid
8 = !41 * 1/1!8 = 22!..9 alcool
z = !/0 * 1/1!8 = 32!..9 ester
32!..9 a4a
1 mol CH
3
CH
2
OH = 2 * 12 + 6 + 16 = 46 :
1 mol CH
3
COOH = 2 * 12 + 4 + 2 * 16 = 6 :