QUEEN’S COLLEGE Mock Examination, 2003-2004 Chemistry Paper 1 Secondary 5 Date: 25-3-2004 ‘Time: 10:45 a.m, ~ 11:45 a.m. (1 hour) 1, Read carefully the instructions on the Answer Sheet and insert the information required in the spaces provided, 2. When told to open this book, you should check that all the questions are there. Look for the words ‘END OF PAPER’ after the last question, ANSWER ALL QUESTIONS. You should mark all your answers on the Answer Sheet. 4, You should mark only ONE answer for each question. If you mark more than one answer, you will receive NO MARKS for that question. 5. All questions carry equal marks, No marks will be deducted for wrong answers,>) © the intermolecular forces between s & ‘There are 50 questions in this paper. Choose the best answer for each question, 1. Element P and Q react to form an ionic compound with formula PQ. If P belongs to Group I of the Periodic Table, to which group does Q belong to? AI B. IV c Vi D. VIL 2. Which of the following substances is obtained industrially by fractional distillation? A. Nitrogen B. Chlorine C. Hydrogen D. Phosphorus 3. Assuming carbon has 2 isotopes, '2C and'2C, with the relative abundances of 98.89% and 1.11% respectively, calculates the relative atomic mass of carbon, A. 12.0000 B. 12.0111 Cc. 12,1299 D. 12.3098 Silicon(LV) oxide has a very high boiling point compared to carbon dioxide hecause 1&, carbon dioxide is covalent but silicon(IV) oxide is ionic. 2X silicon(IV) oxide has a giant ionic structure while carbon dioxide has a simple molecular structure. icon(TV) oxide are stronger than those between carbon dioxide, D. carbon dioxide molecules are attracted by weak intermolecular forces, while silicon and oxygen atoms form strong covalent bonds. 5. In which of the following pairs would both particles have the same electronic arrangement? AL CIF B. Ne, Mg” Cc. Na, AP* D. $,0 04-CE-CHEM 2-1 Pat— 6. 7, 8 9. Isotopes are different atoms of same element which have pow> SAPRESR the same number of protons and electrons. the same physical and chemical properties. different relative atomic masses. different mass numbers. In which of the following pairs of substances would the oxide be reduced when heated? ® When a sample of a solid element w: calcium oxide and carbon Jead(II) oxide and carbon ‘magnesium oxide and hydrogen iron({Il) oxide and carbon monoxide y (2) and (2) only (1) and (3) only “(2)and (4) only (2), G) and (4) only yeated with copper(II) oxide in the absence of air, copper was produced and a gas was given off. The element could be ” LAS. caleium, am x B. carbon. eee eo? °C. sulphur are we Pe zine. fe z In which of the following test tubes would a blue colour appear around the iron nail after some time? pomp lta rat neato ‘eon son fron eon se (Plc Yl ane | eghheoy reine an resi" taingshn Tube (1) only Tube (HID only Tube (II) and Tube (IV) only Tube (I), Tube (11) and Tube (IV) only (04-CE-CHEM 2-2 P210. Recycling of metals is not very common in most countries because (1). most people are not accustomed to using recycled metals. 2) it may be more economical to extract metals from their ores than to recycle metal wastes. (3) metal wastes are very difficult to separate from household refuse A. (only B. (and 2) only C. @and 3) only D. (1), Q)and @) LI. The getion of gifute nitric acid on, zine is represented by the following equation: AHINOs(aq) + BZn(s) —> bZn(NOs)a(aq) + cH2O(l) + ano) The values of a, b and c in the balanced equation are 3,4and 1, Be 3, 8 and 2 C. 4,3and2. D. 83and4. 8 12. v current ion j— metal X potassium chloride solution “ Referring to the above diagram, the largest current flowing from iron to metal X in the extemal circuit can be obtained when X is A. copper. B. magnesium. 3° 0 gees : My? pede? C. potassium, low vaeclue7 i Ww" peteee 7 o Ae, aNeo4 Byid 0 Ne “he tnt 13, 35.0 em of a solution of. sulphuric acid required 30.0 em? of 0.10 M sodium hydroxide 7 for complete neutralization, The concentration of the acid was A. 003M. 13.4. $%y 2 LAOH B. 0.06M ~~ Cc, 012M D. 018M 04-CE-CHEM 23Directions: Question 14 and 15 refer to the following experiment. copper(I) sulphate x solution 14. Which of the following occurs at X? OX, Hydrogen ions are reduced, 5B. “Copper(ll) ions are reduced. Sulphate ions are oxidized. Hydroxide ions are oxidized. of 15, Which of the following are the CORRECT observations in this experiment? (1) Hydrogen gas is given off at Y. (2 Copper is deposited at ¥. (3) Oxygen is given off at X. (4) Sulphur is deposited at X. A. (1) and (3) only B. (1)and (4) only C. Q)and G3) only D. Q)and (4) only 16. Which of the following statements concerning 1 mole of QY Itcontains 6.02 x 10 Ca* ions. (2) Itcontains 2 x 6.02 x 10° Ca” ions. (3), Ithas the same number of particles as 1 mole of Ca JA, Moceupies 22.4 dm at st.p. A. (lonly B. Q)only C. (and @) only D. @)and (3) only 17. Which statement concerning the electrodes in an electrolytic cell is CORRECT? A. Oxidation always occurs at the negative electrode, © B. Electrons flow from the negative to ihe positive electrode via the external circuit.” (2° Current flows from the anode to the cathode via the external circuit. « D. The cathode is the negative electrode. ‘ * 04-CE-CHEM 2-4 pa18. Which of the following are redox reactions? (3 Ma(s) + CuSO4(ag) —> MgSO,(aq) + Cu(s) QY AM(OH),(s) + NaOH (aq) —> NaAlO2(aq) + 2H200) Q) Mn0,(s) + 4HCl(aq) —> MnCh(aq) + Che) +2H00) A. (1) and (2) only B. (1) and @) only Gs, (2) and (3) only D. (0), @) and G) 19. chromatographic paper —] — riven front « 7 e $ Q e : a pd ating penton eee eee 8 ia M (known pigments) (mixture of pigments) ‘The above diagram represents the results of a paper chromatography experiment. It can be concluded that the pigments present in mixture M are fe 6 otreer A. P.RandT. vet 2 cower, B. P.QandT. : PRL ha C.P, Rand another unknown pigment. Gh yee D. Pand two other unknown pigments. 20, A solution of a metal chloride, XCla, forms a precipitate of silver chloride with silver nitrate solution. If 20 em? of 0.15 M silver nitrate solution react completely with 30 em? of 0,05 M XC1, solution, the formula of fhe metal chloride is /K XCl. Ise B. XCh Go®KCh, D XCh, 04.CE-CHEM 2-5 BSa, Oy eae New bus nergy oO 21. How much anhydrous sodium carbonate would be required to prepare 250 cm? of 0.5 M sodium carbonate solution? (Relative atomic masses: C= 12.0, 0 = 16.0, Na = 23.0) A B. c. D. LET 22. Which combination for a zine-carbon dry cell is CORRECT? Anode Cathode Electrolyte YA. zine graphite zine chloride B. zine graphite ammonium chloride 1S: ~ graphite zine zine chloride a D. graphite zine ammonium chloride 0 os oA x Nayoap B. (1) and (3) only ©: (2) and (3) only D. (1), @) and @) 24, What is the reading on the burette shown in the following diagram? A. 10.30. cm* B, 10.50 cm? C. 11.50em* D. 11.70 em* ‘04-CE-CHEM 2-6 P625. Which statement about acids is CORRECT? A. All electrolytes that give out H” in water are acids. -Compounds that contain ionizable hydrogen ion are acids. Blectrolysis of the aqueous solution of acids always giv cathode, “JEL All acids are formed from non-metal oxides. ny hhydrogen gas at the 26. ‘The IUPAC name for ie CHs-ch—g—oH is A. butanoic acid, B. 2-methylethanoic acid, C. 2-methylpropanoie acid D. 2-methylbutanoic acid. 27. Which of the following statements about cracking are CORRECT? (1)_ Inthe process, large molecules are broken down into smaller ones. (2) The products usually contain unsaturated hydrocarbons. (8) Itis used to produce extra petrol. A. (1) and (2) only B. (1) and (3) only C. @)and 3) only D. (1), Q) and 3) 28. Which of the following statements about a homologous series is INCORRECT? 2X The boiling points of the members increase gradually down the homologous series. 0B. Amember differs from the next by a—CH;— unit. ©. They have similar chemical properties, D. They have the same structural formula. 29. Which of the following fire extinguishers is NOT used for elgctrical fires? A. Carbon dioxide type B. Water type C. BCF type D. BIMtype 04-CE-CHEM 2-7 PT30. Which of the following gases occupies the largest volume at the room temperature and pressure? A. 0.5 mole of Nz gas B. 0.6 mole of Os gas C. I mole of HCl gas D. 0.5 mole of SO) gas 31. Which of the following are natural polymers? {YF Rubber 2) Starch (3) Nylon A. (1) and (2) only B. (1) and (3) only C. Q)and (3) only D. @),@)and (3) 32. Telfon is « man-made polymer used in the coatings of non-stick frying pans. Part of its structure is as follows: F | t f E { 0-7 mon Which of the following is the monomer used in the manufacture of telfon? A. CRECR, + ee CHF-CHF, Cee CPy-CF-CF, f CF}-CF-C one Fa 33, Which of the following statements concerning soapless detergents is CORRECT? XX They are biodegradable. eee They form a scum with sea water C.. They have a hydrophilic head and a hydrophobie end. D. They are made by the sponification of vegetable oils. 34, A bottle of wine was left open. After a few days it tasted sour, Which of the following types of reaction applies to this change? A. Addition B. Oxidation C._ Esterification D. Condensation 04-CE-CHEM 2-8 Ps35. Which of the following is a common use of ammonium nitrate? A. To cue plant diseases. B. Toretard the growth of weeds. C. To increase crop yield. D. To neutralize acidic soil 36. Which of the following statements concerning alkenes is CORRECT? SAC “Alkenes ate more teactive than alkanes and usually undergo substitution redctions rather than addition reactions. ee B. Alkenes can decolorize acidified potassium permanganate solution. “ C. Alkenes can be dried by concentrated sulphuric acid. D. Allalkenes are gases. X x as a = 37. What mass of calcium contains the same number of atoms as 2 g oxygen gas? (Relative atomic masses: Ca = 40,0, O = 16.0) Me a A 2g wee wee B. 25g who « i C 48 i gn? “ D, 5S, wit thowt tthaeel Bn, Hates Boot SE] oe CO ‘compound, C#HO, reacts with propanoic acid (with a little concentrated sulphuric acid) to form a product with a fruity smell. Which statement about this compound is_ CORRECT? fey A, ‘Tt decolorizes acidified potassium dichromate solution. Gs poke B. It deoolorizes acidified potassium permaniganate solution, a ; aeuctie +E, Itliberates carbon dioxide from sodium hydrogencarbonate solution. AS. “its aqueous solution is an electrolyte. ye ra 39, Which two of the following compounds react with each other to form a conde’ polymer? oe ° 0) otitciy, to 9 = 1 >(2) CHy—CH,—C—cl (8) Ha I—(CH)¢—NHp (4) C“(CHa)s—NH, 04-CE-CHEM 2-9 PoA r —*40, 41 ra 44, A. (I)and 3) B. (I)and (4) C. Qand @) D. Q)and @) The cleaning action of soap and detergent is due to their A. wetting action. B. emulsifying action. « C. wetting and emulsifyiig action. D. hydrolysis action. Which of the following statement conceming the products formed during cigarette smoking are CORRECT? (J). Tar causes the teeth of smokers to turn brown. (2) Carbon monoxide has a pungent smell (3) Nicotine is addictive. A. (1) and @) only B. (1) and (3) only & ©. @)and G) only ma D. (1), and @) : (2), @) and (3) : yo? ‘What is the final volume when 100 cm? of hydrogen reacts with 206 cm’ of chlorine? Hite) + Ch(@— 24Ci(@) 18. ‘ (All volumes are meastired at rt.p.) A. 100m? : B, 200cm? C. 300em* D. 400cm? - Which statement about aspirin is INCORRECT? A. Aspirin may cause stomach bleeding. B. Aspirin can reduce fever. C. Aspirin can be addictive. D. ‘Soluble aspirin’ is sodium acetylsalicylate, Which is the most commen ingredient of antacids? A. Magnesium hydroxide B. Potassium hydroxide C. Calcium oxide D. Sodium carbonate (04-CE-CHEM 2-10 P10Directions: 4s. Each question below (Question Nos. 45 to 50) consists of two separate statements. Decide whether each of the two statements is truc or false; if both are true, then decide whether or not the second statement is a correct explanation of the first statement. Then sclect one option from A to D according to the following table: Both statements are true and the 2" statement is a correct explanation of the 1° statement, Both statements are true but the 2" statement is NOT a correct explanation of the 1% statement, ‘The 1* statement is false but the 2" statement is truc. _Both statements are false. eet 1* statement In the presence of sunlight, ethane reacts with chlorine , to , form 24 statement ¢ Ethane is a very-reaetive hydrocarbon. I-chloroethane only. eee rN ‘ ‘A A 46, Chlorine is a stronger reducin8 agent Chiorine displaces iodine from sodium yr ‘than iodine. ft 4. 2,° iodide solution. T g i Oa a g 47. The hydrogen and nitrogen used for The impurities can poison the catalyst, making ammonia in the Haber process aust be purified. a 48. Concentrated sulphuric acid can tum Sulphuric acid is a strong acid hydrated copper(I) sulphate crystals. ( blue. 49, Acid rain is an indication of air Acid rain is caused by the oxides of pollution, sulphur and nitrogen, 1 50. Urea-methanal can be used to make -‘Urea-methanal_ isa thermosetting heat-resistant ebject. plastic. END OF PAPER O4-CE-CHEM2-11 palCher 1 Answers: 1 c 21 c 41 B 2 A 2 B 2 c 3 B 2 B 4B c 4 D 24 B 44 A 5 B @® ¢ 45 D 6 Dia 26 c 46 c 1 c 2 D 41 A 8 B 28 D 48 c 9 D 29 B 49 A 10 c 30 c 50 A L D 31 A @®D 8B 32 A B B 33 c 4 D 34 B 15 c 35 c 16 c 36 B 7 D @ BD 18 B @® B 19 D 39 A 20 B 40 c 12> Pati toe rence 7. NaHS0y > Akt tut + Soo” CB noe scxd) Ft. Si Aeecourize Cutt change ealeel ess) conse —> green. Casts olecoloudze ) poy > coleurtess \ decolawire ) (04-CE-CHEM 2-12