Q.

1 Write the IUPAC name of the given compound :

1.
C H
3
CH
3
CH
3
2.
C H
3
CH
3


3. CH
3
-(CH=CH)
2
-CH
2
CH
3
4.
CH
2
CH
3
C H
3
CH
3



5.
C H
3
C H
3
CH
3
6.
C H
2
Br


7.
C H
3
CH
3
8.
CH
3


9.
CH
3
10.
CH
3


11.
CH
3
CH
3
C H
3
CH
3
12.
C H
3
CH
3


13.
C H
3
CH
3
C H
3
14.
Et



Prof. Pawan Babel (PKB)
Pawanbabel@gmail.com
15.
Cl
Br
16.
C H
3
CH
3
CH
2
C H
3


17.
C H
3
CH
2
CH
3
CH
3
C H
3
18.
C H
3
CH
2
CH
3
CH
3
C H
3



19.
C H
3
CH
3
20.
CH
3
C H
3



21.
C H
3
CH
22.
C H
3
CH
3



23.
C H
2
CH


24.
C H
3
CH
2



24.
CH
3
CH
3
CH
3
C H
3
26.
CH
3
CH
3


27.
C H
3
CH
3
28. (CH
3
CH
2
)
2
C=CHCH
3


Prof. Pawan Babel (PKB)
Pawanbabel@gmail.com
29.
C H
3
CH
3
CH
3
30.
C H
3
CH
2
Cl
Cl

31.
Cl
Br
32.
CH
3
C H
3

33. 34.

35.
Br
Br
Cl
36.
C H
3
F
F



37.
CH
2
Br
Br
38.
C H
2
CH
2
F
OH

Q.2 Give structure of the following IUPAC name.
(i) cyclodecane
(ii) propylcyclohexane
(iii) cyclopropylcyclopentane
(iv) 3-ethyl-1,1-dimethylcyclohexane
(v) 3-methylpentene
(vi) 3,4-dibromobut-1-ene
(vii) Cyclohexa-1,3-diene
(viii) Cycloocta-1,5-diene
(ix) Cyclopropylethene
(x) 2-methylbutan-2-ol
(xi) 3,5-dimethylhexene-1,3,5-triol
(xii) 1-ethoxypropane
(xiii) 2-ethoxy-3-methylpentane
(xiv) Cyclohexylmethanol
(xv) 3-cyclohexylpentane-3-ol
(xvi) Cyclopent-3-en-1-ol
(xvii) 3-(chloromethyl)pentan-1-ol
(xviii) 2-chloro-3-methylpentane
Prof. Pawan Babel (PKB)
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(xix) 4-tert.butyl-3-iodoheptane
(xx) 1,4-dibromobut-2-ene

Q.3 Which of the following name will be correct :
(A) 3,6-dimethyl cyclohexene
(B) 1,6-dimethyl cyclohexene
(C) 6,6-dimethyl cyclohexene
(D) 1,5-dimethyl cyclohexene
Q.4 Write IUPAC name of the following compound :
1. 2.

Cl
Br
I

Cl


3.
Cl
Br
4.
CH
3
CH
3
C H
3

5.
Cl
CH
3
C H
3
6.
Cl
Br
CH
3

7.
CH
3
CH
3
C H
3
C H
3
8.
I
Br
F
Cl

Prof. Pawan Babel (PKB)
Pawanbabel@gmail.com
9.
CH
3
CH
3
CH
3
10.
CH
3
CH
3
CH
3

11.
(CH
2
)
5
CH
3
H
3
C(H
2
C)
5
(CH
2
)
5
CH
3
12.
13. 14.
CH
3
CH
3
CH
3
C H
3

15.
C H
3
CH
3
CH
3
16.
CH
3
CH
3

17.
CH
3
CH
3
18.
CH
3
C H
3
C H
3
CH
3
CH
3
CH
3

19.
Cl
F
Br
20.
21.
Br
Cl
22.

Prof. Pawan Babel (PKB)
Pawanbabel@gmail.com
23. 24.
25.
Cl
26.
CH
3
Cl
27.
CH
3
Cl
28.
Cl
Br
CH
3
C H
3
29. 30.
Answer
Q.1
1. 5-methylhex-2-ene 2. oct-2-ene
3. Hepta-2,4-diene 4. 3,7-dimethyloctene
5. 2-methylbut-2-ene 6. 3-bromoprop-1-ene
7. Deca-3,7-diene 8. 1-methylcyclohexene
9. 3-methylcyclohexene 10. 4-methylcyclohexene
11. 2,6-dimethylocta-2,6-diene 12. hex-2-ene
13. 3-methylpent-2-ene 14. 1-ethylcyclohexene
15. 1-bromo-2-chlorocyclobutene 16. 4-ethyl-3-propylheptene
17. 4-[1,2-dimethylbutyl]hepta-1,3,5-triene 18. 5-ethyl-4,6-dimethyloctene
19. But-2-yne

20.

hex-2-yne
Prof. Pawan Babel (PKB)
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21. Octyne 22. non-3-yne
23. Hex-1-en-5-yne 24. dec-1-en-5-yne
25. 1,1-dimethyl-3-(1-methylpropyl)cyclopentane 26. 3-cyclopropyl-1,1-dimethylcyclohexane
27. 4-cyclobutylnonane 28. 3-ethylpent-2-ene
29. 4-ethylhept-3-ene 30. 6-chloro-3-[chloromethyl]octa-1,3,5-triene
31. 4-bromo-6-chloro-3-cyclobutylcyclohexene 32. 1-(1-methylethyl)cycloheptene
33. 5-cyclohexylcyclopenta-1,3-diene 34. 1,2,4-tricyclopropylcyclohexane
35. 1,1-dibromo-2-chlorocyclohexane 36. 1,1-difluoropropene
37. 2,3-dibromopropene 38. 3-cyclopropyl-5-fluorohepta-1,6-dien-4-ol
Q.2


(i) (ii)
CH
3

(iii) (iv)
(v)
C H
3
CH
2
CH
3
(vi)
CH
2
Br
Br

(vii) (viii)
(ix)
CH
2
(x)
Me
Me
Me
O H

(xi)
Me
Me Me
OH
OH OH
(xii)
Me
O
Me

(xiii)
Me Me
O
Et
Me
(xiv)
OH

(xv)
Me Me
O H
(xvi)
O H

(xvii)
Me
OH
CH
2
Cl
(xviii)
Me CH
3
Cl
CH
3

Prof. Pawan Babel (PKB)
Pawanbabel@gmail.com
(xix)
Me
Me
Me Me
Me
I
(xx)
Br
Br




Q.3 (ABD)
Q.4 Answer:
1. 1-bromo-2-chloro-4-iodocyclohexane
2. 3-chlorocyclohexene
3. 5-bromo-3-chlorocyclohexene
4. 4-ethyl-1,2-dimethylcyclohexane
5. 1-chloro-2-ethyl-4-methylcyclopentane
6. 2-bromo-1-chloro-3-methylcyclohexane
7. 1-ethyl-2-methyl-3-[methylethyl]cyclobutane
8. 2-bromo-1-chloro-3-fluoro-4-iodocyclohexane
9. 2-ethyl-1,4-dimethylcyclohexane
10. 1,1,3-trimethylcyclohexane
11. 1,3,5-trihexylcyclohexane
12. cyclohexyl cyclohexane
13. cyclopropylcyclohexane
14. 1,2,3,4-tetraethylcyclohexane
15. 2-ethyl-1,2-dimethylcyclohexane
16. 1-[3-methylbutyl]cyclohexane
17. 1,3-dimethylcyclopentane
18. 1,3-bis[1,1-dimethylethyl]cyclopentane
19. 2-bromo-1-chloro-1-fluorocyclobutane
20. 1,2-dicyclopropylcyclohexane
21. 1-bromo-2-chloro-3-cyclopropylcyclohexane
22. 1-cyclopentyl-3-cyclopropylcyclohexane
23. 1,1-dicyclopropylmethane
24. 1-cyclohexyl-5-cyclopropylpentane
25. 1[2-chloroethyl]cyclopropane
26. 2-chloro-1-cyclopropylpropane
27. 1-chloro-1-cyclopropylpropane
28. 2-bromo-1-chloro-4-ethyl-3-methylcyclohexane
29. cycloheptane
30. cyclooctane


Prof. Pawan Babel (PKB)
Pawanbabel@gmail.com