14. A.

Se Usa una clula de Mercurio para un marcapasos segn la siguiente reaccin

Zn(s) + HgO(s) ZnO + Hg (1) E = 1, 35 v
Si la potencia que necesita el marcapaso en ,1!, "#uantos $ilogramos %e HgO (&'=(1),
5*) se consumir+ en 3)5 %,as-
SOLUCION
Zn(s) + HgO(s) ZnO(s) + Hg (1) E = 1, 35 v
HgO(s) + (e
.
Hg (1) + H
(
O
,1 / = , 1 01 2
HgO(s) + ( H
+
+ ( e
.
Hg (1) + H
(
O
el volta3e %e la cel%a ser+ 1,35 2 porque to%as las activi%a%es valen 1
,1 01 2 1 4 3)5 4 (5 4 3) s 1 mol e
.
1 mol HgO (1),5* HgO
1135 2 *)565 01s ( mol e
.
1 mol HgO
= ()*,16 g HgO

14. . Calcular !" # $ de cada una de las siguientes reacciones
a%
7
(
(s) + 5 8r
(
(aq) + )H
(
O ==== (7O
.
3
+ 7O8r
.
. 7(H
+
&%
#r
(+
+ 'e(s) ===== 'e
(+
+ #r(s)
c%
&g(s) + #l
(
(g) ===== &g
(+
+ (#l
.
d%
5&nO
(
(s) + 5H
+
===== 3&n
(+
(&nO
.
5
+ (H
(
O
e%
0g
+
+ (S
(
O
(.
3
===== 0g(S
(
O
3
)
3.
(
'%
#u7 (s) ===== #u
+
+ 7
.
SOLUCION
a) 7
(
(s) + 5 8r
(
(aq) + )H
(
O ==== ( 7O
.
3
+ 1 8r
.
+ 1( H
+
E=-
7O
.
3
+)H
+
+5e
.
=====

9 7
(
(s) + 3H
(
O E= 1,(1 v
(7O
.
3
+ 1(H
+
1e
.
===== 7
(
(s) + )H
(
O E= 1,(1 v
O4i%aci:n; 7
(
(s) + )H
(
O === (7O
.
3
+ 1(H
+
+ 1e
.
E= . 1,(1 v
<e%ucci:n; 58r
(
(aq) + 1e
.
=== 18r
.


E= 1, *6 v
7
(
(s) + 58r
(
(aq) + )H
(
O ==== (7O
3
. + 18r
.
+ 1(H
+
E= .,11( v
== (1)
14 (.,11()>, 5*1)
1
==1, 1? 4 1
.1*
@) #r
(
+ + 'e(s) ===== 'e
(+
+ #r(s) E=-
<e%ucci:n; #r
(+
+ ( e
.
===== #r(s) E= . ,6* v
O4i%aci:n; 'e(s) ===== 'e
(+
+ (e
.
E= ,55v
#r
(+
+ 'e(s) ===== 'e
(+
+ #r(s) E=., 55 v
== (1)
( 4( ., 55 ) >, 5*1)
== ), 1( 4 1
.1)
c) &g(s) + #1
(
(g) === &g
(+
+ (#1
.
E=-
O4i%aci:n; &g(s) === &g
(+
+ ( e
.
E= (,3)v
<e%ucci:n; #1
(
(g) + (e
.
=== ( #1
.
E
o
= 1,3)v
&g(s) + #1
(
(g) &g
(+
+ (#1
.
E
o
= 3,?(v
== (1)
(4 3, ?(>, 5*1)
= 1
1(5, ?)
%)1 5 &nO
(
(s) + 5 H
+
=====

3&n
(+
+ ( &nO
5
.
+ (H
(
O E
o
=-
<e%ucci:n; 3&nO
(
(s) + 1(H
+
+ )e === 3&n
(+
+ )H
(
O E
o
= 1,(3v
O4i%aci:n; (&nO
(
(s) + 5H
(
O ==== (&nO
.
5 + 6H
+
+ )e
.
E
o
= .1,)*(v

5&nO
(
(s) + 5H
+
==== 3&n
(+
+ (&nO
5
.
+ (H
(
OE
o
= .,5)(v
== (1)
)4 (.,5)()>,5*1)
= 1,3* 4 1
.5?
e)1 0g
+
+ ( S
(
O
3
.(
== 0g(S
(
O
3
)
(
3.
E
o
=-
O4i%aci:n; 0g(s) + (S
(
O
3
.(
== 0g(S
(
O
3
)
3.
(
+ e. E
o
= .,1?v
<e%ucci:n; 0g
+
+ e
.
=== 0g (s) E
o
= ,?**3v
0g
+
+ (S
(
O
3
.(
==== 0g (S
(
O
3
)
3.
(
E
o
= ,?6(3v
== (1)
,?6(3>,5*1)
= 1,)? 41
13
A) #u 7 (s) ===== #u
+
+ 7
.
E
o
=-
<e%ucci:n; #u 7 (s) + e
.
=== #u(s) + 7
.
E
o
= .,165v
O4i%aci:n; #u(s) ==== #u
(+
+ e





E
o
= .,5116v
#u 7 (s) ==== #u
+
+ 7
.
E
o
= .,?3 v
== (1)
1(., ?3) > , 5*1)
= 1, 31 4 1
.1(
2
14.! Calcular el (olta)e de la clula.
Cu
*s%
+ Cu
,-
*.../.M% ++ $
-
Ag*CN%
0
,
*...1% 1CN*..1.2%3 tampon de p1 4.,1+ Ag
*s%

SOLUCION
Se necesita relacionar las siguientes reacciones;
0g(#B)
(
.

+ e. == 0g(s) + ( #B. EC = .1312
H#B == H
+
+ #B
.
p=a= *1(1
Ecuaci:n %e Berts;
0g(#B)
(
.
+ e. == 0g(s) + ( #B. EC = .1312
#u
(+
+ ( e. == #u(s) EC = 133*2

E= ( .131 . 15*1) log D#B
.
E
(
1 ) . ( 133* F 15*1) log 1 )
1 D0g(#B)
.
(
E ( D#u
(+
E
#omo D0g(#B)
.
(
E=11 G D#u
(+
E=13 G nos Aaltar,a D#B
.
E para Hallar E
Ior otro la%o
=a = 1
.p=a
= 1
.*151
DH
+
E =1
.pH
= 1
.6151
Je equili@rio i:nico %el aci%o %K@il H#B
H#B === H
+
+ #B
.
=a= 1
.*151
Je concentraciones %e especies i:nicas en Aunci:n %e su pH se tiene
L
1
=D#B
.
E = 1 =a 1 = 1
.*151
1
'
H#B
DH
+
E + =a 1
.6151
+1
.*151
D#B
.
E= 1*1
'
H#B

D#B
.
E = 1*1M '
H#B
= 1*1M11 =1*1
<eemplaNan%o en ! se o@tiene;
!5 0..441
3