Trabajo Sobre Coeficientes de Equilibrio

UNIVERSIDAD NACIONAL MAYOR DE SAN MARCOS
(Universidad del Per, DECANA DE AMRICA)
ESCUELA DE POSTGRADO
FACULTAD DE QUMICA E INGENIERA QUMICA
COEFICIENTES DE ACTIVIDAD DE LIQUIDOS
PROFESOR :
ALFREDO PALOMINO
CURSO:
INVESTIGACION 1
Elaborado por:
- Julio Peralta Pelaiza
Lima, 2014
INTRODUCCION
El presente trabajo es realizado segn la secuencia de anlisis y clculo del artculo
Coeficiente de Actividad de Lquidos entregado por el profesor Alfredo Palomino en el curso
investigacin 1
Este primer trabajo estudia tres mtodos para hallar los coeficientes de actividad.
1. Mtodo coeficientes de actividad a partir de datos azeotrpicos.
2. Mtodo coeficientes de actividad a partir de varios datos.
3. Mtodo coeficientes de actividad a partir de datos de energa libre de exceso.
La importancia de este trabajo radica, en que fue elaborado en mathcad, por lo que se
ha creado rutinas iniciales (definicin de funciones), las cuales en el desarrollo del trabajo se
usan, solo llamando por el nombre atribuido, pudiendo ser usados en cualquier momento.
El desarrollo en este programa abre la posibilidad de tan solo variando los datos
iniciales (datos experimentales en este caso) se pueda generar una data nueva de anlisis de
otro componente, haciendo ciertos ajustes de dimensionamiento de datos solamente, tanto
en las tablas como en las grficas. (Captulo aparte seria con respecto al mtodo de
coeficientes de actividad a partir de varios datos, porque el anlisis, es puramente visual y de
criterio por parte del investigador)
INDICE
1 INTRODUCCION
2 RUTINAS GENERALES-SISTEMA 1 (ACETONA-CLOROFORMO)
3 MARGULES METODO DEL AZEOTROPO SISTEMA 1
4 VAN LAAR METODO DEL AZEOTROPO SISTEMA 1
5 WILSON METODO DEL AZEOTROPO SISTEMA 1
6 MARGULES DATOS DE EQUILIBRIO SISTEMA 1
7 VAN LAAR DATOS DE EQUILIBRIO SISTEMA 1
8 MARGULES METODO DE LA ENERGIA DE GIBBS SISTEMA 1
9 VAN LAAR METODODE LA ENERGIA DE GIBBS SISTEMA 1
10 WILSON METODO DE LA ENERGIA DE GIBBS SISTEMA 1
11 SISTEMA 2 (ETANOL-n-HEPTANO)
17 WILSON METODO DE LA ENERGIA DE GIBBS SISTEMA 2
18 SISTEMA (BENCENO-CICLOHEXANO)
24 WILSON METODO DE LA ENERGIA DE GIBBSO SISTEMA 3
25 RESUMEN DE CONSTANTES HALLADAS
3
4
5
8
9
10
13
15
18
20
22
24
25
26
27
28
30
32
33
34
35
36
38
40
43
DATOS EXPERIMENTALES TOMADOS DEL ARTICULO

Acetona -Cloroformo
0.1108
0.8892
0.1375
0.8625
0.2108
0.7892
0.2660
0.7340
0.3350
0.6650
0.4771
0.5229
x1
x2
0.5750
0.4250
0.6633
0.3367
0.7388
0.2612
0.7955
0.2045
0.8590
0.1410
0.9145
0.0855
0.0650
0.1000
0.1760
0.2370
0.3350
0.5170
y1exp
0.6480
0.7505
0.8235
0.8688
0.9165
0.9522
0.9350
0.9000
0.8240
0.7630
0.6650
0.4830
y2exp
0.3520
0.2495
0.1765
0.1312
0.0835
0.0478
335.93
336.24
337.00
337.52
337.76
337.07
Texp
336.00
334.76
333.58
332.60
331.50
330.61
METODOS USANDO DATOS DE EQUILIBRIO

nd 12
rot1 ( f nd )
"rutina para los R otulos"

for j 0 5
for i 1 nd
f1
0 0
f1
0 1
f1
0 2
f1
0 3
f1
0 4
f1
0 5
f1
i j
"datos y1"
"datos y2"
"datos 1"
"datos 2"
"datos T "
" error "
f
i 1 j
constantes de antonie acetona1 -cloroformo2

a1 16.6513
b1 2940.46
c1 35. 93
a2 15.9732
b2 2696.79
c2 46. 16
p 760
y.p =.x.
Ecuacion de antoine para la presion de vapor
a1 b1
c1 Texp
1exp e
a2 b2
c2 Texp
2exp e
Entonces despejando para cada caso

y1exp p
1exp ( y1expTexpx1)

a1 b1
x1 e c1 Texp
y2exp p
2exp ( y2expTexpx2)
a2 b2
x2 e c2 Texp
MARGULES PARA LOS DATOS DE EQUILIBRIO

ENCONTRANDO LAS CONSTANTES DE MARGULES USANDO LOS DATOS DEL PUNTO
AZEOTROPICO
1equil 1exp ( y1expTexpx1) 0.7589
4

4
Dado
B1 0.5
i 4
C1 0.5
ln( 1equil )
B1 x2
ln( 2equil )
1equil 0.7589
2equil 0.9124
i2 C1x2i3
2
2
3
B1 x1 1.5 C1 x1 C1 x1
i
i
i
0.3676
0.3853
consmarg_eq_s1 Find( B1C1)
B1 consmarg_eq_s1
mar ( B1C1x1x2)
C1 consmarg_eq_s1
"rutina que halla 1 2 margules "

2
3
B1 ( x2) C1 ( x2)
w1 e

2
2
3
B1 ( x1) C1 1.5 ( x1) C1 ( x1)
w2 e
h1 augment ( w1 w2)
h1
0
1mar_eq mar ( B1C1x1x2)
2 2mar_eq
1
1 1mar_eq
itera( nd Texpx1x21 2 a1 a2 b1 b2 c1 c2 y1exp)
"rutina que halla Y1 Y21 2 T err"

for i 0 nd 1
ysu 2
inc 0.00001
while ysu 1 0.00000001
b1
a1
c1 Texp i
1 e
i
b2
a2
c2 Texp i
2 e
i
1 i
y11 1 x1
i
i i 760
i
i 760
y12 2 x2
i
ysu y11 y12

i
inc ysu 1
if ysu 1
inc ysu 1
if ysu 1
Texp inc Texp

i
err
y11i y1expi100
y1exp
w y11
i
Tmar Texp
i
h1 augment ( y11 y12 1 2 Tmarerr )

h1
mar_eq itera(nd Texpx1x21 2 a1 a2 b1 b2 c1 c2 y1exp)
0 "datos y 1" "datos y 2" "datos ?1" "datos ?2" "datos T"
rot1 ( mar_eq nd )
5
" err or "
0.0795
0.9205
0.5703
0.989 336.3195
22.2552
0.1037
0.8963
0.5941
0.9833 336.6183
3.7334
0.18
0.82
0.6581
0.9623 337.2882
2.2956
0.2457
0.7543
0.7044
0.9421 337.6115
3.6757
0.335
0.665
0.7589
0.9124
337.76
0.5275
0.4725
0.8559
0.8408
337.145
2.0268
0.6523
0.3477
0.9085
0.7871 336.1017
0.6578
0.7517
0.2483
0.9452
0.7382 334.8651
0.1639
0.825
0.175
0.9686
0.6972 333.6772
0.1807
10
0.8728
0.1272
0.9815
0.6674 332.7477
0.4562
11
0.9193
0.0807
0.9916
0.6354 331.6992
0.3067
12
0.9545
0.0455
0.9971
0.6089 330.7944
0.2415
VAN LAAR PARA LOS DATOS DE EQUILIBRIO

Dado
A1 2
ln( 1equil )
B1 2
B1
Texp
4
x14
1 A1
x24
ln( 2equil )
A1 B1
Texp
4
x24
A1
x14
1.3088
256.5592
consvan_eq_s1 Find( A1 B1)
van ( A1 B1x1x2Texp)
A1 consvan_eq_s1
B1 consvan_eq_s1
"rutina que halla 1 2 van laar "
B1

Texp
2
x1
1
A1

x2
w1 e
A1 B1

Texp
x2 2
A1
x1
w2 e
h1 augment ( w1 w2)
h1
0
1
1van_eq van ( A1 B1x1x2Texp)
2van_eq van ( A1 B1x1x2Texp)
1 1van_eq
2 2van_eq
van_eq itera(nd Texpx1x21 2 a1 a2 b1 b2 c1 c2 y1exp)

0
0 "datos y 1""datos y 2" "datos ?1" "datos ?2" "datos T"
rot1 ( van_eq nd )
5
" err or "
0.0793
0.9207
0.5686
0.9886 336.3381
21.9617
0.1036
0.8964
0.5931
0.9828 336.6375
3.6289
0.1802
0.8198
0.6584
0.9617 337.3021
2.3801
0.2459
0.7541
0.7049
0.9417 337.6169
3.7673
0.335
0.665
0.7589
0.9124
337.76
0.5266
0.4734
0.8538
0.8418 337.1692
1.8527
0.6512
0.3488
0.9053
0.788 336.1599
0.4985
0.7512
0.2488
0.9419
0.7379
334.948
0.0897
0.8251
0.1749
0.9658
0.6947 333.7667
0.1936
10
0.8733
0.1267
0.9794
0.6625 332.8313
0.5233
11
0.9202
0.0798
0.9904
0.627 331.7647
0.4049
12
0.9554
0.0446
0.9966
0.5966 330.8364
0.3314
WILSON PARA LOS DATOS DE EQUILIBRIO

Dado
12 200
ln( 1equil )
ln( 2equil )
21 300
ln x1 x2 12 x2
12
4 x1 x2 12
4
4
ln x2 x1 21 x1
12
4 x1 x2 12
4
4
21
21
x2 x1 21
4
x2 x1 21
4
0.0203
4.4083
conswilson_eq_s1 Find( 12 21)
12 conswilson_eq_s1
21 conswilson_eq_s1
wil ( 12 21 x1x2)
"rutina que halla 1 2 wilson "
12
21
ln( x1 x2 12) x2
x1 x2 12 ( x2 x1 21)
w1 e
12
21
ln( x2 x1 21) x1
x1 x2 12 ( x2 x1 21)
w2 e
h1 augment ( w1 w2)
h1
0
1wil_eq wil ( 1221x1x2)
1 1wil_eq
1
2 2wil_eq
wilson_eq itera(nd Texpx1x21 2 a1 a2 b1 b2 c1 c2 y1exp)

0
rot1 ( wilson_eq nd )
5
" err or "
0.0709
0.9291
0.5188
1.0169 335.7402
9.1373
0.0932
0.9068
0.5424
1.0104
336.131
6.7789
0.1698
0.8302
0.6248
0.9807 337.0849
3.5168
0.2395
0.7605
0.6878
0.9517 337.5524
1.0365
0.335
0.665
0.7589
0.9124
337.76
0.5346
0.4654
0.8711
0.8315 337.0154
3.4057
0.658
0.342
0.9234
0.7798 335.8727
1.545
0.7542
0.2458
0.9563
0.7369 334.6104
0.492
0.8248
0.1752
0.9757
0.7031 333.4493
0.1595
10
0.8713
0.1287
0.986
0.6793
332.561
0.2853
11
0.9173
0.0827
0.9937
0.6543
331.57
0.0836
12
0.9528
0.0472
0.9978
0.6337 330.7184
0.0591
METODOS GRAFICO
0.8
x1
0.6
y1exp
0.4
0.2
0.2
0.4
0.6
0.8
x1
METODOS GRAFICO MARGULES DATOS ELV
1gra 1exp (y1expTexpx1)
ln( 1gra )
2
x2
B C x2
ln( 2gra )
2
2gra 2exp (y2expTexpx2)
B ( 0.5 x2)
x1
0.94829
0.73265
0.69313
0.71193
0.62383
ln( 1gra ) 0.63358
mar1_gr1
2
0.54928
x2
0.48127
0.44744
0.4373
0.23891
0.12328
1.38473
0.0323
0.54714
0.63971
0.81649
ln( 2gra ) 0.65489
mar1_gr2
2
0.67729
x1
0.67102
0.63958
0.58291
0.55923
0.5269
margules c on datos VLE

1.4
1.32
1.24
1.16
1.08
1
0.92
0.84
0.76
0.68
0.6
0.52
0.44
0.36
mar1_gr1 0.28
0.2
mar1_gr2
0.12
0.04
0.04
0.12
0.2
0.28
0.36
0.44
0.52
0.6
0.68
0.76
0.84
0.92
1
0.14
0.28
0.42
0.56
0.7
0.84
0.98
1.12
1.26
1.4
x2 x2 0.5
se observa en la grafica que la intercepcion en el eje x=0 se encuentra entre -0.34 y

-0.36 aproximadamente y para sacar la pendiente usaremos dos puntos dentro de la recta
mar1_gr1 mar1_gr2
8
m1
x2 x2 0.5
8
0.4083
con es mismo datos hallemos la interseccion

x2 m1 b
mar1_gr1
B1 b
b mar1_gr1 x2 m1 0.3523
4
C1 m1
consmarg_gr_s1 B1
0
consmarg_gr_s1 C1
1
mar (B1C1)
0
1mar_gr mar ( B1C1x1x2)
2 2mar_gr
1
2mar_gr mar ( B1C1x1x2)
1 1mar_eq
mar_gr itera(nd Texpx1x21 2 a1 a2 b1 b2 c1 c2 y1exp)

0
rot1 ( mar_gr nd )
5
" error "
0.0795
0.9205
0.5703
0.9888
336.3253
22.2786
0.1038
0.8962
0.5941
0.983
336.6268
3.762
0.1801
0.8199
0.6581
0.9617
337.3046
2.35
0.2459
0.7541
0.7044
0.9412
337.6334
3.7492
0.3353
0.6647
0.7589
0.9113
337.7869
0.0869
0.5279
0.4721
0.8559
0.8392
337.1725
2.1179
0.6527
0.3473
0.9085
0.7856
336.1229
0.7275
0.7521
0.2479
0.9452
0.7369
334.8783
0.2073
0.8252
0.1748
0.9686
0.6963
333.6836
0.202
10
0.8728
0.1272
0.9815
0.667
332.7499
0.4636
11
0.9193
0.0807
0.9916
0.6357
331.6983
0.3034
12
0.9544
0.0456
0.9971
0.6098
330.7924
0.2345
METODOS GRAFICO VAN LAAR DATOS ELV

linealizando las 2 ecuaciones de van laar
Texp ln( 1exp )
Texp ln( 2exp )
0.5
1
0.5
B1
0.5
A1
B1

A1
x1
Texp ln( 1gra )
0.5 x2
B1
0.5
( B1 A1)
0.5
x2
0.5 x1
Texp ln( 1gra )
0.5
Texp ln( 2gra )
0.5
x1 x2
x2 x1
acomodemos las ecuaciones a fin de tener datos reales y no imaginarios quitando los puntos extremos
con un total de 8 puntos
reduce
"reduccion de 12 a 8 puntos"
for i 2 9
j i2
xb1 x1
j
xb2 x2
j
2bexp 2gra
j
Tbexp Texp
j
1bexp 1gra
j
h1 augment ( xb1xb21bexp 2bexp Tbexp)

h1
xb1 reduce
xb2 reduce
1bexp reduce
2bexp reduce
Tbexp reduce
Tbexp ln( 1bexp )
0.5
A1
0.5
Tbexp ln( 2bexp )
xb1
0.5 xb2
B1
B1
0.5
A1
B1

0.5
( B1 A1)
0.45
0.41
0.37
0.33
Tbexp ln( 1bexp )
0.5
Tbexp ln( 2bexp )
0.5
0.29
0.25
0.21
0.17
0.13
0.09
0.05
0.4
0.8
1.2
1.6
2.4
xb1 xb2
xb2 xb1
in2 (00.075)
Dado
A1 2
B1 3
m2
in2 0.075
A1
B1

(40.34)
( 0.34 0.075)
4
1
0.5
in2
( B1 A1)
0.5
0.0663
m2
1.1321
201.2579
consvan_gr Find( A1 B1)
in1 (00.060)
in1 0.06
(40.415)
m1
( 0.415 0.06)
4
0.0888
2.8
3.2
3.6
xb2
0.5 xb1
A1
m1
0.5
B1
0.075
0.5
B1
A1 consvan_gr
A1
B1
B1
A1 1.1577
B1 consvan_gr
consvan_gr_s1
177.7778
0.075
0.5
A1 m1B1
1.1833
B1 189.5178
A1
consvan_gr_s1
B1
van (A1 B1x1x2Texp)

0
1van_gr van ( A1 B1x1x2Texp)
1 1van_gr
1
2van_gr van ( A1 B1x1x2Texp)
2 2van_gr
van_gr itera(nd Texpx1x21 2 a1 a2 b1 b2 c1 c2 y1exp)
rot1 ( van_gr nd )
5
" err or "
0.0893
0.9107
0.6499
0.9923
335.8815
37.3447
0.1148
0.8852
0.6692
0.9883
336.073
14.7845
0.1919
0.8081
0.7203
0.9733
336.4763
9.0465
0.2558
0.7442
0.7568
0.9585
336.6441
7.9521
0.3407
0.6593
0.7994
0.9363
336.6764
1.7062
0.5217
0.4783
0.8755
0.8797
336.1102
0.9086
0.6413
0.3587
0.9179
0.834
335.2677
1.0349
0.7396
0.2604
0.9488
0.7895
334.2584
1.4478
0.8143
0.1857
0.9694
0.7498
333.26
1.1136
10
0.8642
0.1358
0.9814
0.7192
332.4563
0.5313
11
0.9136
0.0864
0.9912
0.6847
331.5251
0.3216
12
0.9512
0.0488
0.9968
0.6545
330.7015
0.1003
ECUACION DE MARGULES GIBBS

P Q(2x1 1)
G1
B
P 3 Q
4 Q
0.6898
0.6363
0.6624
0.6927
0.6884
ln( 1exp ( y1exp Texpx1) )
ln( 2exp ( y2exp Texpx2) ) 0.6437
G1
x2
x1
0.6229
0.6071
0.5894
0.5531
0.5141
0.4713
1.4497
1.5715
1.5098
1.4436
1.4527
1.5534
1
G1
1.6054
1.6471
1.6967
1.8079
1.9453
2.1217
corr (x1G1) 0.8887

m slope(x1G1) 0.2185
b intercept (x1G1) 0.7251

lineal(x1) mx1 b
G1
P Q(2x1 1)
despejando y ordenando
G1
(P Q) 2Qx1
G1_g m x1 b
0.4
0.5
G1
0.6
G1_g
0.7
0.8
0.2
0.4
0.6
x1
0.8
Dado
m 0.2185
Q
b 0.7251
B 1
C 1
P b Q
P 3 Q
4 Q
0.288
0.4371
consmarg_G_s1 Find( BC)
B1 consmarg_G_s1
C1 consmarg_G_s1
mar (B1C1)
0
1mar_G mar ( B1C1x1x2)
2 2mar_eq
1 1mar_G
1
1 1mar_eq
2 2mar_G
mar_G itera(nd Texpx1x21 2 a1 a2 b1 b2 c1 c2 y1exp)

0
rot1 ( mar_Gnd )
5
" err or "
0.0814
0.9186
0.5857
0.9891
336.2502
25.2625
0.1062
0.8938
0.6098
0.9834
336.5283
6.1562
0.1835
0.8165
0.6742
0.9629
337.1361
4.2806
0.2497
0.7503
0.7204
0.9431
337.4112
5.3425
0.3389
0.6611
0.7742
0.9144
337.5041
1.1789
0.5295
0.4705
0.8683
0.8459
336.82
2.418
0.6522
0.3478
0.918
0.7954
335.7803
0.6486
0.75
0.25
0.9519
0.7501
334.5824
0.0624
0.8224
0.1776
0.9729
0.7126
333.448
0.129
10
0.87
0.13
0.9843
0.6858
332.5669
0.14
11
0.9168
0.0832
0.9931
0.6576
331.5763
0.0368
12
0.9527
0.0473
0.9976
0.6345
330.7223
0.0523
ECUACION DE VAN LAAR GIBBS

1
C DQ ( 2x1 1)
G1
A
( D C)
( D C)
( D C)
0.6898
0.6363
0.6624
0.6927
0.6884
ln( 2exp ( y2exp Texpx2) ) 0.6437
G1
x2
x1
0.6229
0.6071
0.5894
0.5531
0.5141
0.4713
1.4497
1.5715
1.5098
1.4436
1.4527
1.5534
1
G1
1.6054
1.6471
1.6967
1.8079
1.9453
2.1217
1
corr x1 0.8644
G1
1
m slope x1 0.6325
G1
1
b intercept x1 1.3298
G1
lineal(x1) mx1 b
1
G1
C D ( 2x1 1)
G1
G1_v m x1 b
Dado
m 0.6325
A1 1
m
D1
2
A1
b 1.3298
B1 1
D1 C1
D1 C1
T 336
C1 b D1
B1
T
D1 C1
( C D) 2 D x1
1.4756
252.6762
consvan_G_s1 Find( A1 B1)
A1 consvan_G_s1
B1 consvan_G_s1
1.2
1.4
1 1.6
G1
G1_v 1.8
2.2
0.2
0.4
0.6
0.8
x1
0
1van_G van ( A1 B1x1x2Texp)
1 1van_G
1
2 2van_G
van_G itera(nd Texpx1x21 2 a1 a2 b1 b2 c1 c2 y1exp)

0
rot1 ( van_G nd )
5
" err or "
0.0814
0.9186
0.5847
0.9878
336.2918
25.223
0.1065
0.8935
0.6111
0.9817
336.5703
6.532
0.1852
0.8148
0.6799
0.9602
337.1583
5.2407
0.2521
0.7479
0.7277
0.9403
337.4029
6.391
0.3417
0.6583
0.7818
0.9119
337.4562
2.012
0.5307
0.4693
0.8727
0.846
336.7358
2.6575
0.652
0.348
0.9197
0.7975
335.7155
0.6179
0.7492
0.2508
0.9518
0.7534
334.5513
0.1763
0.8216
0.1784
0.9721
0.716
333.444
0.2282
10
0.8695
0.1305
0.9834
0.6884
332.5769
0.0795
11
0.9167
0.0833
0.9924
0.6582
331.5928
0.0235
12
0.9528
0.0472
0.9973
0.6325
330.7362
0.0658
ECUACION DE WILSON GIBBS

aqui llevaremos la GE de wison a una distribucuion cuadratica
G_w
ln( 1exp ( y1expTexpx1) )

x2

x1
x11 x1
i 0 11
X
i 0
1
X x1
2
X x11
b11
X X
T
X G_w
0.6388
b11 0.2733
0.4881
cuad ( x1) b11 b11 x1 b11 x1
2
0.4
0.5
cuad( x1)
G_w
0.6
0.7
0.2
0.4
0.6
x1
2
cuad1 ( x) b11 b11 x b11 x

0
0.8
cuad1 (0) 0.6388

cuad1 (1) 0.424
tomando los 8 mejores puntos mejores
0.2108
0.335
0.4771
0.575
xa1
0.6633
0.7388
0.7955
0.859
Ga_w
0.976
0.9124
0.8615
0.7994
2aexp
0.7444
0.7053
0.6915
0.6619
ln( 1aexp )
xa2
0.7892
0.665
0.5229
0.425
xa2
0.3367
0.2612
0.2045
0.141
0.6494
0.7589
0.8409
0.9055
1aexp
0.9469
0.9699
0.9819
0.9953
ln( 2aexp )
xa1
0.5
0.55
Ga_w
cuad( xa1)
0.6
0.65
0.7
0.2
0.4
0.6
xa1
xa111 xa1
i 0 7
Xa
i 0
1
Xa xa1
2
Xa xa111
ba11
XaTXa
Xa Ga_w
0.6335
ba11 0.2658
0.4636
0.8
cuad ( xa1) b11 b11 xa1 b11 xa1

2
cuad2 ( x) ba11 ba11 x ba11 x

0
cuad2 (0) 0.6335

cuad2 (1) 0.4357
Dado
12 2
21 3
0.6335 ln(12) 1 21
0.4357 ln(21) 1 12
0.8504
1.7956
conswilson_G_s1 Find( 12 21)
12 conswilson_G_s1
21 conswilson_G_s1
wil (1221)
0
1wil_G wil ( 1221x1x2)
1 1wil_G
1
2 2wil_G
wilson_G itera(nd Texpx1x21 2 a1 a2 b1 b2 c1 c2 y1exp)

0
rot1 ( wilson_Gnd )
5
" err or "
0.0878
0.9122
0.6362
0.9897 336.0136
35.0128
0.1138
0.8862
0.6599
0.9846 336.2247
13.7511
0.1932
0.8068
0.7211
0.9664 336.6469
9.7821
0.2593
0.7407
0.7632
0.9495 336.7965
9.4037
0.3465
0.6535
0.8106
0.9253 336.7717
3.4452
0.5289
0.4711
0.8898
0.8685
336.034
2.3083
0.6465
0.3535
0.9306
0.8266 335.0953
0.2357
0.7419
0.2581
0.9584
0.7881 334.0462
1.1469
0.8142
0.1858
0.9759
0.7553 333.0539
1.1269
10
0.8628
0.1372
0.9857
0.731 332.2763
0.6922
11
0.9115
0.0885
0.9934
0.7041 331.3917
0.5467
12
0.9494
0.0506
0.9977
0.6812 330.6187
0.2945
Analisis de otro sistema de componentes

ETHANOL--n-HEPTANE
0.094
0.240
0.482
x1 0553
eq
0.780
0.876
Dado
0.557
0.612
0.636
y1exp 0.638
eq
0.660
0.706
347.6
345.4
344.2
Texp 344.2
eq
344.2
345.0
ya 1
ya
0.638 ( ya 0.553)
( 0.660 0.638)
(0.780 0.553)
Find(ya) 0.6471
0.094
0.240
0.482
x1 0.553
0.647
0.780
0.876
0.557
0.612
0.636
y1exp 0.638
0.647
0.660
0.706
0.906
0.76
0.518
x2 0.447
0.353
0.22
0.124
347.6
345.4
344.2
Texp 344.2
344.2
344.2
345.0
0.443
0.388
0.364
y2exp 0.362
0.353
0.34
0.294
constantes de antonie ETHANOL--n-HEPTANE

a1 18.9119
b1 3803.98
c1 41. 68
a2 15.8737
b2 2911.32
c2 56. 51
x2 1 x1
y2exp 1 y1exp
p 750
En este caso el numero de datos es
nd 7

y1exp p
1exp ( y1expTexpx1)

a1 b1
x1 e c1 Texp
y2exp p
2exp ( y2expTexpx2)

b2
a2
x2 e c2 Texp
1exp (y1expTexpx1)

AZEOTROPICO
Dado
B1 0.5
i 4
C1 0.5

4

4
i2 C1x2i3
2
2
3
B1 x1 1.5 C1 x1 C1 x1
i
i
i
ln( 1equil )
B1 x2
ln( 2equil )
2.4068
0.3963
B11 consmarg_eq_s2
C11 consmarg_eq_s2
mar (B1C1x1x2)
0
2 2mar_eq
1
1 1mar_eq

0
5
" err or "
0.31
0.69
2.1864
1.0107
362.2141
44.3486
2
rot1 ( mar_eq nd ) 3
0.4878
0.5122
1.6624
1.0673
356.6426
20.2908
0.6311
0.3689
1.2259
1.2642
353.1554
0.7764
0.6672
0.3328
1.1555
1.3468
352.5805
4.5818
0.718
0.282
1.088
1.4738
351.9884
10.979
0.8024
0.1976
1.03
1.6875
351.4541
21.5686
0.8775
0.1225
1.0087
1.8647
351.311
24.2898

Dado
A1 2
B1 2
Texp
4
B1
ln( 1equil )
x14
1 A1
x24
ln( 2equil )
A1 B1
Texp
4
x24
A1
x14
0.9126
694.5223
A1 consvan_eq_s2
B1 consvan_eq_s2
van (A1 B1x1x2)

0
1
1van_eq van ( A1 B1x1x2Texp) 2van_eq van ( A1 B1x1x2Texp)
1 1van_eq
2 2van_eq
5
" err or "
0.5041
0.4959
5.2982
1.0165
351.7926
9.4963
2
rot1 ( van_eq nd ) 3
0.6319
0.3681
3.3593
1.1166
345.4579
3.2497
0.6541
0.3459
1.8042
1.594
344.4628
2.8424
0.6506
0.3494
1.5608
1.8622
344.5159
1.9772
0.6475
0.3525
1.3264
2.3774
344.5373
0.076
0.6625
0.3375
1.119
3.6337
344.6817
0.3801
0.7172
0.2828
1.037
5.224
345.6375
1.5917

Dado
12 200
ln( 1equil )
ln( 2equil )
21 300
ln x1 x2 12 x2
12
4 x1 x2 12
4
4
ln x2 x1 21 x1
12
4 x1 x2 12
4
4
21
x2 x1 21
4
x2 x1 21
21
0.1382
0.2075
12 conswilson_eq_s2
21 conswilson_eq_s2
wil ( 12 21 x1x2)
12
21
ln( x1 x2 12) x2
x1 x2 12 ( x2 x1 21)
w1 e
12
21
ln( x2 x1 21) x1
x1 x2 12 ( x2 x1 21)
w2 e
h1 augment ( w1 w2)
h1
0
1 1wil_eq
1
2 2wil_eq
5
" err or "
0.5476
0.4524
6.592
1.04 348.3984
1.6881
2
rot1 ( wilson_eq nd ) 3
0.6073
0.3927
3.2342
1.1929 345.4162
0.7658
0.6314
0.3686
1.7276
1.6867 344.6594
0.7181
0.6374
0.3626
1.5248
1.9284 344.5821
0.1
0.6475
0.3525
1.3264
2.3774 344.5373
0.076
0.6742
0.3258
1.1368
3.5028 344.7242
2.1483
0.7213
0.2787
1.0492
5.1749 345.4905
2.1715

P Q(2x1 1)
G1
B
P 3 Q
4 Q
2.4655
2.17
2.1453
G1
2.1364
x2
x1
2.1387
2.1931
2.2128
0.4056
0.4608
0.4661
1
0.4681
G1
0.4676
0.456
0.4519
corr (x1G1) 0.5594

lineal(x1) mx1 b
G1
P Q(2x1 1)
G1
(P Q) 2Qx1
G1_g m x1 b
2.5
2.4
G1
2.3
G1_g
2.2
2.1
0.2
0.4
0.6
0.8
x1
Dado
m 0.2328
b 2.3309
B 1
C 1
P b Q
P 3 Q
4 Q
1.8654
0.4656
B1 consmarg_G_s2
C1 consmarg_G_s2
mar (B1C1)
0
2 2mar_eq
1 1mar_G
1
1 1mar_eq
2 2mar_G
5
" err or "
0.5502
0.4498
6.5365
1.0225
348.7257
1.2185
2
rot1 ( mar_Gnd ) 3
0.6388
0.3612
3.6032
1.1517
344.0301
4.3861
0.6302
0.3698
1.7599
1.722
344.1657
0.9134
0.6238
0.3762
1.5133
2.0244
344.2451
2.2281
0.6214
0.3786
1.2878
2.5782
344.2597
3.9526
0.6474
0.3526
1.0999
3.8146
344.5424
1.9034
0.7158
0.2842
1.03
5.2298
345.7521
1.3873

1
G1
A
C DQ ( 2x1 1)
( D C)
( D C)
T
( D C)
2.4655
2.17
2.1453
G1
2.1364
x2
x1
2.1387
2.1931
2.2128
0.4056
0.4608
0.4661
1
0.4681
G1
0.4676
0.456
0.4519
1
corr x1 0.5435
G1
1
m slope x1 0.0428
G1
1
G1
lineal(x1) mx1 b
1
G1
C D ( 2x1 1)
G1
G1_v m x1 b
Dado
m 0.0428
A1 1
m
D1
2
A1
b 0.4313
B1 1
T 336
C1 b D1
D1 C1
B1
D1 C1
T
D1 C1
1.0992
779.0513
A1 consvan_G_s2
B1 consvan_G_s2
( C D) 2 D x1
0.48
0.46
1
G1 0.44
G1_v
0.42
0.4
0.2
0.4
0.6
0.8
x1
0
1 1van_G
1
2 2van_G
5
" err or "
0.5343
0.4657
6.0852
1.0216
349.7752
4.0744
2
rot1 ( van_G nd ) 3
0.632
0.368
3.4657
1.146
344.7073
3.2665
0.6319
0.3681
1.7388
1.6929
344.5204
0.6486
0.6275
0.3725
1.5015
1.9813
344.5768
1.6485
0.6275
0.3725
1.2828
2.5084
344.5853
3.0216
0.6556
0.3444
1.099
3.6842
344.8658
0.6656
0.7246
0.2754
1.0298
5.0147
346.0542
2.6358

aqui llevaremos la GE de wilson a una distribucuion cuadratica
G_w

x2
x12 x1

x1
i 0 6
1
i 0
1
Y x1
2
Y x12
b12
Y Y
T
Y G_w
2.5442
b12 1.4988
1.3155
cuad ( x1) b12 b12 x1 b12 x1
2
2.5
2.4
cuad( x1)
G_w
2.3
2.2
2.1
0.2
0.4
0.6
x1
cuad ( x1) b12 b12 xa1 b12 xa1
cuad ( x) b12 b12 x b12 x
cuad (0) 2.5442

cuad (1) 2.3609
Dado
12 2
21 3
cuad (0)
ln(12) 1 21
cuad (1)
ln(21) 1 12
0.172
0.2159
0.8
12 conswilson_G_s2
21 conswilson_G_s2
wil (1221)
0
1 1wil_G
1
2 2wil_G

0
5
" error "
0.5295
0.4705
6.0465
1.0343 349.7104
4.9308
2
rot1 ( wilson_Gnd ) 3
0.6046
0.3954
3.1355
1.1746 346.0594
1.215
0.6357
0.3643
1.7099
1.6435 345.0699
0.0505
0.6427
0.3573
1.5127
1.8743 344.9741
0.7302
0.654
0.346
1.3189
2.3028 344.9154
1.0814
0.6824
0.3176
1.1332
3.3711 345.0916
3.3907
0.7308
0.2692
1.0477
4.9392 345.8409
3.5065
Analisis de otro sistema de componentes

BENZENE-CICLOHEXANE (s3)
0.101
0.101
0.171
0.171
0.256
0.256
0.343
0.343
0.428
0.428
0.525
0.525
x1
0.571 x1 eq
0.665
0.571
0.759
0.665
0.810
0.759
0.863
0.810
0.945
0.863
0.945
Dado
0.131
352.7
0.131
0.211
0.211
353.1
0.293
351.6
0.293
0.376
351
0.376
350.7
0.445
0.445
0.529
350.6
0.529 Texp
y1exp
0.564 y1exp eq
350.6
0.645
350.8
0.564
0.728
351.1
0.645
0.777
351.4
0.728
0.834
351.8
0.777
0.926
352.5
0.834
0.926
ya 1
ya
0.564 ( ya 0.571)
Find(ya) 0.5417
( 0.529 0.564)
(0.525 0.571)
352.7
353.1
351.6
351
350.7
350.6
Texp eq
350.6
350.8
351.1
351.4
351.8
352.5
0.101
0.171
0.256
0.343
0.428
0.525
x1 0.5417
0.571
0.665
0.759
0.810
0.863
0.945
0.131
0.211
0.293
0.376
0.445
0.529
y1exp 0.5417
0.564
0.645
0.728
0.777
0.834
0.926
352.7
353.1
351.6
351
350.7
350.6
Texp 350.6
350.6
350.8
351.1
351.4
351.8
352.5
x2 1 x1
y2exp 1 y1exp
0.899
0.829
0.744
0.657
0.572
0.475
x2 0.4583
0.429
0.335
0.241
0.19
0.137
0.055
0.869
0.789
0.707
0.624
0.555
0.471
y2exp 0.4583
0.436
0.355
0.272
0.223
0.166
0.074
constantes de antonie acetona1 -cloroformo2
a1 15.9008
b1 2788.51
c1 52. 36
a2 15.7527
b2 2766.63
c2 50. 50
p 760
En este caso el numero de datos es
13
nd 13
y1exp p
1exp ( y1expTexpx1)

a1 b1
x1 e c1 Texp
y2exp p
2exp ( y2expTexpx2)
a2 b2
x2 e c2 Texp
1exp (y1expTexpx1)

AZEOTROPICO
Dado
B1 0.5
i 6
C1 0.5

6

6
i2 C1x2i3
2
2
3
B1 x1 1.5 C1 x1 C1 x1
i
i
i
ln( 1equil )
B1 x2
ln( 2equil )
0.4407
0.1055
B11 consmarg_eq_s3
C11 consmarg_eq_s3
mar (B1C1x1x2)
0
2 2mar_eq
1
1 1mar_eq

0
0 "datos y 1" "datos y 2" "datos ?1" "datos ?2"
"datos T"
" error "
0.1956
0.8044
2.1541
1.0123
349.8295
49.285
0.2752
0.7248
1.8748
1.0346
348.3784
30.4359
0.3447
0.6553
1.6204
1.0763
347.3545
17.6353
0.4003
0.5997
1.4299
1.1353
346.7943
6.45
5
rot1 ( mar_eq nd ) 6
0.4482
0.5518
1.2933
1.209
346.5515
0.717
0.5022
0.4978
1.181
1.3128
346.5624
5.059
0.5119
0.4881
1.1655
1.3329
346.5943
5.4975
0.5294
0.4706
1.1405
1.3695
346.6728
6.137
0.5914
0.4086
1.0778
1.5004
347.1395
8.3065
10
0.6676
0.3324
1.0367
1.6512
348.0088
8.2966
11
0.7177
0.2823
1.0217
1.7409
348.6968
7.631
12
0.7787
0.2213
1.0107
1.8397
349.6128
6.6303
13
0.8974
0.1026
1.0016
2.0024
351.5329
3.0857

Dado
A1 2
B1 2
B1
Texp
6
ln( 1equil )
x1
1 A1
x26
A1 B1
Texp
6
ln( 2equil )
x26
A1
x16

0.8655
118.2433
A1 consvan_eq_s3
B1 consvan_eq_s3
van (A1 B1x1x2)

0
1
1van_eq van ( A1 B1x1x2Texp) 2van_eq van ( A1 B1x1x2Texp)
1 1van_eq
2 2van_eq

0
5
" error "
352.6541 6.2465 10 -3
0.131
0.869
1.3211
1.003
0.2095
0.7905
1.2726
1.0089
352.0151
0.732
0.2953
0.7047
1.221
1.0207
351.4145
0.7759
0.3751
0.6249
1.1733
1.0384
350.9858
0.2368
5
rot1 ( van_eq nd ) 6
0.448
0.552
1.1322
1.062
350.7249
0.6781
0.528
0.472
1.0921
1.0976
350.6027
0.1817
0.5417
0.4583
1.0859
1.1048
350.6
0.5657
0.4343
1.0755
1.1181
350.6083
0.3018
0.6441
0.3559
1.0467
1.1684
350.7527
0.1462
10
0.7273
0.2727
1.0246
1.2315
351.0928
0.1021
11
0.776
0.224
1.0154
1.2721
351.3738
0.1315
12
0.8305
0.1695
1.0081
1.3195
351.751
0.4194
13
0.9258
0.0742
1.0013
1.4053
352.5426
0.0254

Dado
12 200
21 300
ln( 1equil )
ln( 2equil )
ln x1 x2 12 x2
12
ln x2 x1 21 x1
6 x1 x2 12
6
6
12
6 x1 x2 12
6
6
21
x2 x1 21
6
x26 x1621
21
0.9552
0.7074
12 conswilson_eq_s3
21 conswilson_eq_s3
wil ( 12 21 x1x2)
12
21
ln( x1 x2 12) x2
x1 x2 12 ( x2 x1 21)
w1 e
21
ln( x2 x1 21) x1 12
x1 x2 12 ( x2 x1 21)
w2 e
h1 augment ( w1 w2)
h1
0
1 1wil_eq
1
2 2wil_eq

0
5
" error "
0.1312
0.8688
1.3238
1.0031 352.6438
0.1643
0.2097
0.7903
1.2749
1.0091 351.9992
0.6049
0.2953
0.7047
1.2215
1.0209 351.4059
0.7934
0.3751
0.6249
1.1733
1.0386 350.9818
0.2479
0.448
0.552
1.1321
1.0622 350.7238
0.6661
rot1 ( wilson_eq nd ) 6
0.528
0.472
1.0921
1.0976 350.6027
0.1835
0.5417
0.4583
1.0859
1.1048
350.6
0.5657
0.4343
1.0756
1.1181 350.6083
0.3048
0.6441
0.3559
1.0468
1.1683 350.7507
0.1395
10
0.7273
0.2727
1.0247
1.2317 351.0882
0.101
11
0.7759
0.2241
1.0156
1.2726 351.3674
0.138
12
0.8304
0.1696
1.0082
1.3208
351.743
0.4345
13
0.9256
0.0744
1.0014
1.4087 352.5361
0.0432
P Q(2x1 1)
G1
0.3245
0.1073
0.3206
0.3507
0.3618
0.3632
G1
0.3638
x2
x1
0.3662
0.3639
0.3745
0.3736
0.3739
0.4109
B
P 3 Q
3.0817
9.3192
3.1193
2.8517
2.7637
2.7536
1
2.7491
G1
2.7308
2.7478
2.6704
2.6765
2.6745
2.4337
4 Q
corr (x1G1) 0.6414


lineal(x1) mx1 b
G1
P Q(2x1 1)
G1
(P Q) 2Qx1
G1_g m x1 b
0.5
0.4
G1
0.3
G1_g
0.2
0.1
0.2
0.4
0.6
0.8
x1
Dado
m 0.1771
b 0.2476
B 1
C 1
P b Q
P 3 Q
4 Q
0.6018
0.3543
B1 consmarg_G_s3
C1 consmarg_G_s3
mar (B1C1)
0
2 2mar_eq
1
1 1mar_eq
1 1mar_G
2 2mar_G
5
" error "
0.1257
0.8743
1.2574
1.0011 352.9194
4.0468
0.2055
0.7945
1.2359
1.0038 352.3454
2.6068
0.2948
0.7052
1.2059
1.0106 351.7611
0.6128
0.3786
0.6214
1.1727
1.0228 351.2972
0.6888
5
rot1 ( mar_Gnd ) 6
0.4545
0.5455
1.1395
1.0415 350.9772
2.1293
0.5361
0.4639
1.1028
1.0732 350.7745
1.3386
0.5498
0.4502
1.0967
1.08
350.7574
1.4948
0.5737
0.4263
1.0863
1.093
350.7404
1.7271
0.6507
0.3493
1.0557
1.1449 350.8033
0.8764
10
0.7309
0.2691
1.0305
1.2159 351.0695
0.3999
11
0.7777
0.2223
1.0195
1.2643
351.318
0.0943
12
0.8304
0.1696
1.0104
1.3234 351.6733
0.43
13
0.9243
0.0757
1.0018
1.436
352.4773
0.1845

1
G1
C DQ ( 2x1 1)
( D C)
( D C)
( D C)
0.3245
0.1073
0.3206
0.3507
0.3618
0.3632
G1
0.3638
x2
x1
0.3662
0.3639
0.3745
0.3736
0.3739
0.4109
3.0817
9.3192
3.1193
2.8517
2.7637
2.7536
1
2.7491
G1
2.7308
2.7478
2.6704
2.6765
2.6745
2.4337
1
corr x1 0.4869
G1
1
m slope x1 3.3054
G1
1
G1
lineal(x1) mx1 b
1
G1
C D ( 2x1 1)
G1
G1_v m x1 b
Dado
m 3.3054
A1 1
m
D1
2
A1
b 5.0492
B1 1
D1 C1
D1 C1
T 336
C1 b D1
B1
T
D1 C1
( C D) 2 D x1
0.3454
66.5454
A1 consvan_G_s3
B1 consvan_G_s3
10
G1
G1_v 4
0.2
0.4
0.6
0.8
x1
0
1 1van_G
1
2 2van_G

0
0 "datos y 1""datos y 2""datos ?1""datos ?2" "datos T" " error "
1
0.1199
0.8801
1.1911
1.0008 353.1482
8.4632
0.1981
0.8019
1.1785
1.0024 352.6976
6.1121
0.2883
0.7117
1.1632
1.0062 352.2057
1.6006
0.3755
0.6245
1.1458
1.0129 351.7798
0.133
5
rot1 ( van_G nd ) 6
0.4562
0.5438
1.1273
1.0234 351.4452
2.5201
0.5437
0.4563
1.1045
1.0428 351.1735
2.7747
0.5583
0.4417
1.1004
1.0473 351.1398
3.066
0.5837
0.4163
1.0932
1.056 351.0905
3.4964
0.6635
0.3365
1.069
1.0951 351.0289
2.8731
10
0.7426
0.2574
1.0444
1.1606 351.1438
1.9998
11
0.7865
0.2135
1.0315
1.2147 351.3046
1.2282
12
0.8348
0.1652
1.0189
1.2931 351.5733
13
0.9217
0.0783
1.0039
1.4923
352.317
0.095
0.4636

aqui llevaremos la GE de wilson a una distribucuion cuadratica
G_w

x2

x1
x12 x1
i 0 12
Y
i 0
1
Y x1
2
Y x12
b12
YTY
Y G_w
0.1965
b12 0.4367
0.2488
cuad ( x1) b12 b12 x1 b12 x1
0.5
0.4
cuad( x1)
G_w
0.3
0.2
0.1
0.2
0.4
0.6
x1
0.8
cuad ( x1) b12 b12 xa1 b12 xa1

2
cuad ( x) b12 b12 x b12 x

2
cuad (0) 0.1965

cuad (1) 0.3844
Dado
12 2
21 3
cuad (0)
ln(12) 1 21
cuad (1)
ln(21) 1 12
1.4414
0.4379
12 conswilson_G_s3
21 conswilson_G_s3
wil (1221)
0
1 1wil_G
1
2 2wil_G

0
5
" error "
0.12
0.88
1.1926
1.0011 353.1327
8.3862
0.1975
0.8025
1.1751
1.0035 352.6887
6.4044
0.2861
0.7139
1.1535
1.0086 352.2299
2.3521
0.3715
0.6285
1.131
1.0172 351.8526
1.2015
5
rot1 ( wilson_Gnd ) 6
0.4506
0.5494
1.1089
1.0299 351.5764
1.2577
0.537
0.463
1.0839
1.0516 351.3787
1.5051
0.5515
0.4485
1.0797
1.0563
351.358
1.8138
0.5769
0.4231
1.0724
1.0654 351.3316
2.2923
0.6579
0.3421
1.0497
10
0.7402
0.2598
11
0.7868
12
13
1.103
351.339
1.9945
1.0293
1.1585 351.5094
1.669
0.2132
1.0196
1.1991 351.6871
1.2622
0.8382
0.1618
1.011
1.252 351.9534
0.5015
0.9278
0.0722
1.002
1.364 352.5921
0.1984
RESUMEN DE CONSTANTES
ENCONTRADAS
0.288
0.4371
consmarg_eq_s1
1.4756
252.6762
consvan_eq_s1
consmarg_G_s1
consvan_G_s1
0.8504
1.7956
conswilson_G_s1
0.3676
0.3853
consmarg_gr_s1
1.3088
256.5592
consvan_gr_s1
0.0203
4.4083
conswilson_eq_s1
1.8654
0.4656
consmarg_eq_s2
1.0992
779.0513
consvan_eq_s2
consmarg_G_s2
consvan_G_s2
0.172
0.2159
conswilson_G_s2
0.6018
0.3543
consmarg_G_s3
0.3454
66.5454
consvan_G_s3
1.4414
0.4379
conswilson_G_s3
2.4068
0.3963
0.9126
694.5223
0.1382
0.2075
conswilson_eq_s2
0.4407
0.1055
consmarg_eq_s3
0.8655
118.2433
consvan_eq_s3
0.9552
0.7074
conswilson_eq_s3
0.3523
0.4083
1.1577
189.5178

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UNIVERSIDAD NACIONAL MAYOR DE SAN MARCOS

(Universidad del Per, DECANA DE AMRICA)

COEFICIENTES DE ACTIVIDAD DE LIQUIDOS

- Julio Peralta Pelaiza

DATOS EXPERIMENTALES TOMADOS DEL ARTICULO

METODOS USANDO DATOS DE EQUILIBRIO

"rutina para los R otulos"

constantes de antonie acetona1 -cloroformo2

Entonces despejando para cada caso

MARGULES PARA LOS DATOS DE EQUILIBRIO

2equil 2exp ( y2expTexpx2) 0.9124

consmarg_eq_s1 Find( B1C1)

"rutina que halla 1 2 margules "

itera( nd Texpx1x21 2 a1 a2 b1 b2 c1 c2 y1exp)

"rutina que halla Y1 Y21 2 T err"

ysu y11 y12

Texp inc Texp

h1 augment ( y11 y12 1 2 Tmarerr )

mar_eq itera(nd Texpx1x21 2 a1 a2 b1 b2 c1 c2 y1exp)

VAN LAAR PARA LOS DATOS DE EQUILIBRIO

consvan_eq_s1 Find( A1 B1)

"rutina que halla 1 2 van laar "

van_eq itera(nd Texpx1x21 2 a1 a2 b1 b2 c1 c2 y1exp)

0 "datos y 1""datos y 2" "datos ?1" "datos ?2" "datos T"

WILSON PARA LOS DATOS DE EQUILIBRIO

conswilson_eq_s1 Find( 12 21)

"rutina que halla 1 2 wilson "

wilson_eq itera(nd Texpx1x21 2 a1 a2 b1 b2 c1 c2 y1exp)

METODOS GRAFICO MARGULES DATOS ELV

1gra 1exp (y1expTexpx1)

2gra 2exp (y2expTexpx2)

margules c on datos VLE

se observa en la grafica que la intercepcion en el eje x=0 se encuentra entre -0.34 y

con es mismo datos hallemos la interseccion

mar_gr itera(nd Texpx1x21 2 a1 a2 b1 b2 c1 c2 y1exp)

METODOS GRAFICO VAN LAAR DATOS ELV

Texp ln( 1exp )

Texp ln( 2exp )

Texp ln( 1gra )

Texp ln( 1gra )

Texp ln( 2gra )

h1 augment ( xb1xb21bexp 2bexp Tbexp)

Tbexp ln( 1bexp )

Tbexp ln( 2bexp )

Tbexp ln( 1bexp )

Tbexp ln( 2bexp )

consvan_gr Find( A1 B1)

van (A1 B1x1x2Texp)

van_gr itera(nd Texpx1x21 2 a1 a2 b1 b2 c1 c2 y1exp)

ECUACION DE MARGULES GIBBS

corr (x1G1) 0.8887

b intercept (x1G1) 0.7251

consmarg_G_s1 Find( BC)

mar_G itera(nd Texpx1x21 2 a1 a2 b1 b2 c1 c2 y1exp)

ECUACION DE VAN LAAR GIBBS

consvan_G_s1 Find( A1 B1)

van_G itera(nd Texpx1x21 2 a1 a2 b1 b2 c1 c2 y1exp)

ECUACION DE WILSON GIBBS

ln( 1exp ( y1expTexpx1) )

ln( 2exp ( y2expTexpx2) )

cuad1 ( x) b11 b11 x b11 x

cuad1 (0) 0.6388

tomando los 8 mejores puntos mejores

cuad ( xa1) b11 b11 xa1 b11 xa1