Khéa_CHUYEN DE LTDH mén Héa hoc NG CAO - PHAN UNG ESTE HOA Moon.vn DIEU CHE ESTE Bg yen thi Bal hoe true tuyén Chuyén dé: ESTE - LIPIT ~ XA PHONG Hay tham gia KHOA CHUYEN DE LTDH MON HOA HQC tai www.moon.vn dé xem Dap an va Loi giai chi tiét - HOTLINE: (04) 32 99 98 98 Cau 1 [10197 chiy hoan toan 7,6 gam hin hgp gim mit axit cacboxylic no, don chite, mach hi va mét ancol don chire (c6 s6 nguyén tir cacbon trong phan tir khiéc nhau) thu duge 0,3 mol CO> va 0,4 mol HO. Thye hign phan img este héa 7,6 gam hin hop trén véi higu suit 80% thu duge m gam este. Gi tricia m A4,08, B.6,12. C816, D.2,04, Céu 2 [101977]: Bun néng 6,0 gam CH3COOH véi 6,0 gam C2HsOH (¢6 H:S0, lam xtic téc, higu sudt phan (rng este hoa bing 50%). Khoi lrgng este tao thin la ‘A.6,0 gam. B.44 gam. C.8,8 gam. D.5,2 gam Cau 3 [101978]: Hon hop X gom axit HCOOH va axit CH3COOH (ti Ié mol 1:1). Lay 5,3 gam hn hgp X tic dung v6i 5,75. gam C2HsOH (c6 xic tic HO, dic) thu duge m gam hon hgp este (higu suat cia cde phan irng este hod déu bing 80%). Gid tricia m ‘A.10,12. B.6,48. C8,10. D.16,20. CAu 4 [101979]: Cho 45 gam axit axetic phin irng wi 69 gam ancol etylic (xiic té¢ HySO¥ dc), dun néng, thu duoc 41,25 gametylaxetat. Higu suit cit phiin img este hod a A.62,50%. B. 50,00%. €.40,00%. D.31,25%. C4u 5 [101980]: Dun 12 gamaxit axetic v6i 13,8 gam etanol (cé H2SO, dc lim xtc tc) dén khi phan img dat t6i trang thai can bang, thuduge 11 gam este, Higu suat cua phan img este hod la A.55%, B. 50%. C.62,5%. D.75%. Cu 6 [101981]: Cho hén hop X gm ancol metylic va hai axit cacboxylic (no, don chitc, ké tigp nhau trong diy ding ding) tic dung hét v6i Na, giti phéng ra 6,72 lit khi Hy (dktc). Néu dun néng hon hop _X (c6 Hz8O4 die kim xéic téc) thi cc chat trong hin hop phan ing vira dit v6i nhau tao thinh 25 gam hon hop este (gii thiét phan tmg este hod dat higu suit 100%). Hai axit trong hon hgp X li ‘A.CH;COOH va C:HsCOOH B.HCOOH va CH;COOH ‘C.C)HsCOOH va C;H;COOH D.C;H;COOH va CyHyCOOH Cu 7 [101982]: Hén hop M_gdm ancol no, don chite X vi axit eacboxylic don chire Y, déu mach hé va e6 cng s6 nguyén tir C, tng s6 mol cia hai chat 14 0,5 mol (s6 mol euia Y kin hon s6 mol euia X). Néu dét chay hodn toan M thi thu duge 33,6 lit khi CO> (dkte) va 25,2 gam H20. Mat khdc, néu dun néng M véi HSOy dic dé thyrc hign phan ieng este hoa (higu suit 1a 80%) thi sé gameste thu durge fa 22,80. B.17,92. 27,36 D.18,24, C4u 8 [101983]: Fste don chite X thu durge tir phan img este héa gitta ancol Y vi axit hiru co Z. (xtc tée HO, ac, t’). Dét chay hoan toan 4,3 gam X thu duge 0,2 mol CO? va 0,15 mol HzO. $6 CTCT c6 thé cé cla XB Al B.3 C4 DS CAu 9 [101984]: Khi tin 1 mol CoHsOH va 1 mol CHsCOOH, hrgng este lin nhit thu durge 1a 2/3 mol Khi tign hanh este héa 3 mol CoHsOH va | mol CH;COOH sé thu duge sé mol este lt (biét phin ting este hhéa thyc hign 6 cing t°) AAA B.09 Cis D.0,1 www.moon.vn Tong dai tie vin (04) 32 99 98 98 Trang |Khéa_CHUYEN DE LTBH mén Héa hoc C4u 10 [101985]: Dun m6t krong dur axit axetic v6i 13,80 gam ancol etylic (c6 axit HSO, de lim xtc tic). Dén khi phan (rng dimg li thu duge 11,0 gam este, Higu suit cia phan ting este héa kt A.15,0% B.62,5% €.60,0% D.41,67% C4u 11 [101986]: Tién hinh én men gidm 100ml dung dich C2HsOH 46° v6i higu sudt 50% thi thu durge dung dich X, Dun ndng X (giai sit chi xay ra phan tg este héa) dén trang thai canbing thu duge 17,6 gam este, Tinh hing s6 cén bang cia phan tmng este héa ? (biét duzo = 1g/ml; deansou = 0,8 g/ml) Ad B.16 ci7 D.18 Cu 12 [101987]: Dét chiy a gam C2HsOH thi thu duge 0,2 mol CO>. étb gam CHsCOOH thu durge 0,2 mol CO2. Cho a gam C>H:OH tac dung véi b gam CHsCOOH eé xiic tic HoSOy dc (H = 100%). Khéi hrgng este thu dirge 1a Add gam. B.8,8 gam. C106 gam. D.12,2 gam. C4u 13 [101988]: Chia 7,8 gam hén hop ancol etylic va ancol déng ding R-OH thinh 2 phin bing nhau. Phan | tic dung vi Na (du) thu duge 1,12 lit Hz (dktc). Phin 2,cho tac dung v6i 30 gam CHsCOOH (c6 mat HeSOy dc). Tinh tong khoi krong este thu durge, biét higu suat phan img este hod déu bang 80%. A.6,48 gam. B.8,1 gam. C88 gam. D.6,24 gam. ‘Cfu 14 [101989]: Cho biét hing sé can bing cia phin tng este hod: R-COOH +R = OH & R -COOR'+H, O ; c6Ke=4. Néucho hin hop cing sé mol axit vi ancol tic dung. ‘v6i nhau thi khi phan img este hod dat ti trang thai cn bing thi cé bao nhigu % ancol va axit da bi este hod ? 4.50%, B.66,7%. 75%. D.62,5%. C4u 15 [101990]: Khi dun néng 25,8 gam hin hop ancol etylic va axit axetic 66 HoSOs dic durge 14,08 gam este. Néu dt chy hoan toan rng hin hgp dé thu durgc 23,4 ml nude. Thinh phin % hon hop ban dau va higu suat ciia phan img este héa lan lrgt la A.53,5% C2HsOH; 46,5% CHsCOOH va higu suit 80%. B.55,3% C2HsOH; 44,7% CH3COOH va higu sudt 80%. C.60,0% C2HsOH; 40,0% CH3COOH va higu suat 75%. D.A5,0% C2HsOH; 55,0% CHsCOOH vi higu suat 60%. ‘Cau 16 [101991]: Phenyl axetat duge diéu ché bang phan img gitta A.phenol véi axit axetic. B. phenol véi axetan andehit. phenol véi axeton. D. pheno! véi anhidrit axetie. C4u 17 [101992]: Hén hyp X gim HCOOH va CH;COOH (ti mol 1:1); hin hop Y gim CH3OH va CoH,OH (ti 1G mol 3 : 2). Lay 11,13 gam hén hgp X téc dung v6i 7,52 gam hin hop Y c6 xic tic H2SOy dec, dun néng. Khdi krong ca este thu durge Bi (bikt higu suit cdc phan img este déu 75%) ‘A.10,89 gam. B. 11,4345 gam. 14,52 gam. D.11,616 gam. Cau 18 [101993]: Dét chiy hoan toan 12,88 gam hén hop gom mét axit no don chite va 1 ancol no don chire duge 0,54 mol CO2 va 0,64 mol HzO. Thyc hign phan img este héa hoan toan kxgng hbn hop trén thi thu durge m gam este. Gia tricia m li A882. B. 10,20. C.12,30. D.11,08. ‘Cau 19 [101994]: Hén hop X g6m HCOOH, CH;COOH (ti & mol 1:1), hén hop Y g8m CH3OH, C2Hs;OH (ti Ig mol 2:3). Lay 16,96 gam hin hop X tic dung véi 8,08 gam hon hop Y (c6 xiic tic HzO, dic) thu duge m gameste (higu suit cde phin tng este héa déu bing 80%). Gid tricia m ‘A.12,064. B. 22,736. C.17,728, D.20,4352. C4u 20 [101995]: Ddt chiy hoan toin 7,3 gam mt axit no, da chite mgch hé thu duge 0,3 mol CO2 va 0,25 mol H2. Cho 0,2 mol axit trén tic dung v6i ancol etylic dur c6 xtc tac HSO, dic. Khdi hrgng este thu durge (gid sir higu suat phan ting dat 100%) www.moon.vn Tong dai tie vin (04) 32 99 98 98 Trang 2Khéa_CHUYEN DE LTBH mén Héa hoc ‘A375 gam. B.28,6 gam. 34,7 gam. D.40,4 gam. Cu 21 [101996]: Khi dun néng hén hop cdc dong phan ciia axit CsHy-COOH véi hin hgp céc dbng phan cia ancol CsHy-OH (¢6 mit H2SO, dic) thi s6 este toi da thu durge li Ad B.6 C8 D.10 (Cau 22 [101998]: Hdn hop X gdm 1 axit no don chite., mach ho ya mbt axit khOng no don chitc, mach hé c6 mOt lign két di & géc hidrocacbon. Khi cho a gam X tée dung hét voi CaCO; thoat ra 1,12 lit COz (aktc), Hon hgp Y gbmCHOH va CoHsOH; khi cho 7,8 gam Y tée dung hét Na thoat ra 2,24 lit Hp (dkte). Néu tron a gam X v6i 3,9 gam Y rOi dun ndng c6 H2SO4 dic xie tée thi thu duge m gam este (higu suat h%). Gia tri m theo a, ha A(a+2,Dh%. B.(a + 7,8)h%. Ca+3,yn%, D.(a+ 6)h%. C4u 23 [101999]: Cho 23 gam C2HsOH ti phan irng 60%. Khoi rong este thu durge 1 A.21,12 gam. B. 26,4 gam. C22 gam. D.23,76 gam. ‘CAu 24 [102000]: Dét hoan toan m gam ancol etylic duge 0,2 mol CO». Dét chay hon toan p gam axit axetic duge 0,2 mol CO>. Khi thie hign phin tmg este hod gita m gam ancol etylic vi p gam axit axetic (c6é H2SOz dic Lim xéc tée, higu sueit 80%) thu durge bao nhiéu gam este? dung v6i 24 gam CHsCOOH (nite tée Ho, de) v6i higu sudt A.7,04. B.8,8. C.14,08. D.17,6. ‘Cu 25 [102001]: Day hoa chat nio sau day can sir dung dé digu ché duge benzyl axetat? A.axit benzoic va ancol metylic B. phenol, axit axetic va axit sunfuric dc. Cphenol va anhidrit axetic. D.ancol benzylic va axit axetic. Cu 26 [102003]: Bun néng hin hop axit axetic va etyen glicol (sé mol bing nhau, cé H;SOs die xtc téc) thi thu duge hén hop X gdm 5 chat (trong 46 6 2 chat chira chife este Ey va Fa, Mr: y) thanh hai phan bing hau. 1: Cho tie dung véi Na dur thu duge 5,6 lit Hy (6 dk) - Phin 2; Dun néng v6i HoSO, die t6i phan tng hoan toan durge 8,8 gam es Gia sir cdc phan img xiy ra hoan toin. Gif tr) ctia x va y la Ax=04;y=01. 2. Cx=03; y= 0.2 D.x=06;y=04. C4u 36 [102024]: Dun ndng hon hop X gdm | mol ancol etylic va 1 mol axit axetic (¢6 0,1 mol H2SO, de lim xe tie), Khi phan Ging dat dén trang thai ci bing duge hin hgp Y trong dé 6 0,667 mol etyl axetat. Hang s6 cén bing Kc cia phn ting C4u 37 [102025]: Biét ring phan img este héa: CH;COOH + CaHOH + CHCOOCGHG + HO} Ke = Cho néng dé dau cita cde chat: [C:HsOH] = 1M, [CHyCOOH] = 2M. % ancoletylic bieste hod la A80% B.68%. C.75%. D.84,5%. ‘Cau 38 [102026]: Dun s n hop X gdm 9,0 gam axit axetic va 6,21 gamancoletylic v6i H>SO, dac am xtic tic dén khi két thie phan img thu duge 7,92 gam etyl axetat. Higu suat cla phan trng este héa li 460.0%, B.61,97%. €.63,31%. D.66,67%. CAu 39 [102027]: Thyc hién phin ing este hoa gitta axit adipic (HOOC-(CH2),-COOH) véi ancol don chise X thu duge hai hgp chat c6 chita chite este Yi va Ya trong d6 Yi 6 cng thie phan tir Bi CsHisOs. Céng thite etia X li A.C3HsOH. B.CHOH. C.CH;OH hoe C2H50H. D.C:HOH. Cau 40 [102028]: Tinh khdi hrgng metyl metacrylat thu duge khi dun néng 215 gam axit metacrylic véi 100 gam ancol metylic. Gii thiét phin tng este hod dat higu suit 60% AB12,5 gam. B.187,5 gam. .150 gam D.250 gam. www.moon.vn Tong dai tie vin (04) 32 99 98 98 Trang 4