Unit 8: Clicker Quiz 4

You may use a periodic table and a calculator.

8.1 Potential Energy- I can identify endothermic and exothermic reactions
8.2 Calorimetry- I can use q=mCT to heat associated with temperature change
8.3 Heat Quantities- I can use molar ratios to quantify heat from a reaction
8.4 Hess's Law- I can sum up enthalpy, entropy, and Gibbs Free Energy given
their values for a reaction.
8.5 Bond Dissociation Energy- I can calculate bond dissociation energy given
bond formation energies for a reaction.

For a given process at constant

pressure, G is negative. This means
that the process is _______.
A)
B)
C)
D)
E)

exothermic
endothermic
spontaneous
nonspontaneous
a state function

The value of H for the reaction below is -120 kJ.

How many kJ of heat are released when 3.0 mol of
HCl is formed in this reaction?
H2 (g) + Cl2 (g) 2HCl (g)

A)
B)
C)
D)
E)

180
-180
360
-360
240

The value of H for the reaction below is 210 kJ. The

amount of heat that is absorbed by the reaction of
0.250 g of water with excess (NH4)2S is __________ kJ.
(NH4)2S(s) + 2H2O(l) 2NH4OH(aq) + H2S(aq)

A)
B)
C)
D)
E)

-126
-3.50
0
27.2
1.46

35g of CaCl2 is dissolved in water. The volume of this

solution is 550mL. How much heat in kJ is released if
the temperature changed from 24.1oC to 27.9oC, the
specific heat of the solution is 4.18J/gK, and the
density of the solution is 1.10 g/cm3?

A)
B)
C)
D)
E)

92,000
9.6
8,700
8.7
5.6

NH4NO3(s) NH4+(aq) + NO3-(aq)

Hfo

So

NH4NO3(s)

-365.56 kJ/mol

151.08 J/molK

NH4+(aq)

-132.51 kJ/mol

113.4 J/molK

NO3-(aq)

-205.0 kJ/mol

146.4 J/molK

Compound

Calculate the So for the reaction.

A)
B)
C)
D)
E)

108.7 J/K
-108.7 J/K
-28,100 J/K
357 J/K
-357 J/K

For a given process at constant

pressure, G is negative. This means
that the process is _______.
A)
B)
C)
D)
E)

exothermic
endothermic
spontaneous
nonspontaneous
a state function

The value of H for the reaction below is -120 kJ.

How many kJ of heat are released when 3.0 mol of
HCl is formed in this reaction?
H2 (g) + Cl2 (g) 2HCl (g)

A)
B)
C)
D)
E)

180
-180
360
-360
240

The value of H for the reaction below is 210 kJ. The

amount of heat that is absorbed by the reaction of
0.250 g of water with excess (NH4)2S is __________ kJ.
(NH4)2S(s) + 2H2O(l) 2NH4OH(aq) + H2S(aq)

A)
B)
C)
D)
E)

-126
-3.50
0
27.2
1.46

35g of CaCl2 is dissolved in water. The volume of this

solution is 550mL. How much heat in kJ is released if
the temperature changed from 24.1oC to 27.9oC, the
specific heat of the solution is 4.18J/gK, and the
density of the solution is 1.10 g/cm3?

A)
B)
C)
D)
E)

92,000
9.6
8,700
8.7
5.6

NH4NO3(s) NH4+(aq) + NO3-(aq)

Hfo

So

NH4NO3(s)

-365.56 kJ/mol

151.08 J/molK

NH4+(aq)

-132.51 kJ/mol

113.4 J/molK

NO3-(aq)

-205.0 kJ/mol

146.4 J/molK

Compound

Calculate the So for the reaction.

A)
B)
C)
D)
E)

108.7 J/mol
-108.7 J/mol
-28,100 J/mol
357 J/mol
-357 J/mol

Past Thermdynamics AP Questions

99 MC
22. Of the following reactions, which involves
the largest decrease in entropy?
(A) CaCO3(s) CaO(s) + CO2(g)
(B) 2 CO(g) + O2(g) 2 CO2(g)
(C) Pb(NO3)2(s) + 2 KI(s) PbI2(s) + 2 KNO3(s)
(D) C3H8(g) + 5 O2(g) 3 CO2(g) + 4 H2O(g)
(E) 4 La(s) + 3 O2(g) 2 La2O3(s)
5
94

4
89

3
77

2
62

1
30

Ave.
68

94 MC
N2(g) + 3 H2(g) 2 NH3(g)
The reaction indicated above is thermodynamically
spontaneous at 298 K, but becomes nonspontaneous at
higher temperatures. Which of the following is true at
298 K?
(A) _G, _H, and _S are all positive.
(B) _G, _H. and _S are all negative.
(C) _G and _H are negative, but _S is positive.
(D) _G and _S are negative, but _H is positive.
(E) _G and _H are positive, but _S is negative.
58.

Ave.
29

2007 Part A Question 2

N2(g) + 3 F2(g) 2 NF3(g)

298
= 264 kJ mol1; 298
= 278 J K1 mol1
The following questions relate to the synthesis reaction represented by
the chemical equation in the box above.
(a)
Calculate the value of the standard free energy change, for the
reaction.

Continued
N2(g) + 3 F2(g) 2 NF3(g)

298
= 264 kJ mol1; 298
= 278 J K1 mol1
(b)
Determine the temperature at which the equilibrium constant,
Keq, for the reaction is equal to 1.00. (Assume that H and S are
independent of temperature.)

Continued
N2(g) + 3 F2(g) 2 NF3(g)

298
= 264 kJ mol1; 298
= 278 J K1 mol1
(c)
Calculate the standard enthalpy change, H, that occurs when a
0.256 mol sample of NF3(g) is formed from N2(g) and F2(g) at 1.00 atm
and 298 K.

Continued
N2(g) + 3 F2(g) 2 NF3(g)

298
= 264 kJ mol1; 298
= 278 J K1 mol1
The enthalpy change in a chemical reaction is the difference between
energy absorbed in breaking bonds in the reactants and energy released
by bond formation in the products.
(d)
How many bonds are formed when two molecules of NF3 are
produced according to the equation in the box above?

Continued
N2(g) + 3 F2(g) 2 NF3(g)

298
= 264 kJ mol1; 298
= 278 J K1 mol1
(e)
Use both the information above and the table of average bond
enthalpies below to calculate the average enthalpy of the FF bond.

Bond

Average Bond Enthalpy

(kJ mol-1)

NN
NF
FF

946
272
?