(MULTIPLE CHOICE QUESTIONS (MULTIPLE OPTIONS CORRECT )

18.

Isoelectronic species are represent by pairs.

(A) N 3 , O 2

(B) CO , CN -

(C) O 2 2 , F2

(D) O2

CN-

Sol.

Isolectronic means same number of electrons.

19.

In which of the following equilibrium, the value of Kp is less than Kc ?

(A) N2O4
2NO2
(B) N2 + O2
2NO
(C) N2 + 3H2
2NH3
(D) 2SO2 +O2
2SO3

Sol.

Kp = Kc(RT)n
Kp < Kc if n < 0
For reaction (C) the value of Dn is -2 and for reaction (D) the value of n is -1
Hence, (C) and (D) are the correct answers.

20.

H2C2O4 and NaHC2O4 behave as acids as well as reducing agent. Which are correct
statements ?
(A) Equivalent weight of H2C2O4 and NaHC2O4 are equal to their molecular weights when
behaving as reducing agent.
(B) 100ml of 1M solution of each in neutralization by equal volumes of 1M Ca(OH)2.
(C) 100ml of 1 N Solution of each is neutralized by equal volumes of 1N Ca(OH)2
(D) 100ml of 1M solution of each is oxidized by equal volumes of 1M KMnO4

Sol.

H 2 C 2 O 4 NaOH NaHC 2 O 4 H 2 O

NaHC 2 O 4 NaOH Na 2 C 2 O 4 H 2 O
21.

Which is /are correct statements?

(A) A solute will dissolve in water if hydration energy is greater than lattice energy.
(B) If the anion is large compared to the cation, the lattice energy will remain almost
constant.
(C) Solubility of II A hydroxide is in order:
Be(OH)2 < Mg (OH)2 < Ca(OH)2 < Sr (OH)2
(D) None is correct

Sol.

Down the group, solubility of hydroxides increases

22.

An acid base indicator has a ka of 3.0 x 10-5. The acid form of the
the basic form is blue. Then : (Given log3 = 0.4771)
(A) PH is 4.05 when indicator is 75 % red
(B) PH is 5.00 when indicator is 75% blue.
(C) PH is 5.00 when indicator is 75 % red
(D) PH is 4.05 when indicator is 75 % blue.

Sol:

HN
Red

H+ + lnBlue

PH pKa log

[ln ]
[ H ln]

indicator is red and