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Be Telaguinal ape ponies ogee HUES ee Vi ¥=5 oes 7 1 09st r : 1648 cu P< 10K, itor Feeitot Siw: 0,99 + 0082 «T= 648 ow T > 1140 K 082 i Aor oma 2 = 0756 2666 get In 5) Marie mdse pentru mstan st ane V = ec es oy le nls zero go fe In ponditie normale s2hg7g Sse objne din dingeamt 2 = 0,89. Atunek: n= ee 46 moll RE i - 0080-328 se explieitaat P alll iloarea raleulas ford de ees exporimentlé en 12% mrt, Dla wine wry kth kc expiment et ate aR 1.909 0,082 me ay as Ms 732 > fe SK Uitisint diograme te somprsiiitete (oncza UIT) i we cocoa @) volamalocapat de 0 gan te OPC i abn 1) mantra de reo de meta sare gn pot inrodace ture ice de 2 sd peste ts 100 atm Samperatrd de °C provianon dino bute de 10 2, ex conve 1000 g propend de 7°GH se clogs o-valare pentru Z ocaleulanst P gi apot Py te determin in diagram 9 nauk valoare posta 2 Neo procedural le) valoare aprosimatiy- constant. a tal Z 10a tabelal 42 s)nt- date rozatiatele ealeul Conform oenmfiee van der Waals, presizmen gents esto data he reagins p= PAE a oe Jn came a gi stat constante individuals earactristin penta un gtx dat, Boga a4s 4s ary ee 235 — ™ onm9 7 Pot a caleuls prs fosind dingsama goneraliaté de campresblitte petodenah eain problema 8 paaetal So ine = 165 at, S: snes et condi date, prin ambele metode my ‘bfiut protic ‘okagh ental, ‘Abtoren ee of de dale experimerle ete de Se obine P 2 20 atm {0'Se procedons ang: Po A. 30 — ss explioieonn 7: 7 EA, ue aE In tabelal 4 aint preasntate calealele. berate: Eontla va er Wass acca competacn etl Jest ‘Conantle xslt vader Waals se pot sol dia dstee enter ow ene ttn 4 Yt bie ig see al pin eal eat reeset dn Se objine 7 = 462 K. Hp Me Ne ferent Sse ote Fe A a prostine de 5.atm go t= G0. # SH dermis mane nd ems Be rvbalo8 nse Satta eat emote nee gi = tng 6 Dee clas egos ee cot a ae dc faa (bo 448 Baim -aeol™ gi 9 — 0578 Tok Rezotvare Divatia Bart he Lot serie in formes Rr, realm Bp care 6 sin. consanteearstarintien subtanjln, resin o snd Picaro a eewafici van der Waals. " i Folin eonttautak 1 ih espeimala en ajutoral parametrilr iil Noolvare Foosind datele probleme se ealenluad o vaviabilé anbttars alt ceuntia van dee Watts at cu ajuloral facloratal gensral de compl Siuiat2. Vado eafeulae se emupand cu datele experimental 16 o-2 anny ¥ 3Jn care Ps pate volun) criti malar, we abine toma ven mai Secvent fl SHUM a eeuejiei Beet belo+ (eegliind dyps renrenjons armen a favs} apr, v= nitty 2 Plats 6 pawl earn) Jolt exe volta alent 1000 posye sy 2 RACE (, 5 48 soca BB fy 4 tt 7 Soe ar aaacaa ae) 40 sn Fa teatime Sete yates tne alr oars AS. Resettele obyinate to arma soda garofick denis tris aint oe present etind me dni tint eee eet iia al trimetilamines la temperaiara de 0 e Rexolvare austin virial de stare pentru gaze reas in Uermen ca pesiue are form PVT BP LEDS ; 1n care A, B, C sink rerpctir primul, al din gia treilencoeficioat vrs fnetie oma de tomporatard [A= 1a presiuni sedzue, ecuatia poate fh redusit n dat termenis PY = 4 + BP care poate fi sorist gi <4 + BP, ia care g onte densitate Areapta,. a aivt panko | coos Siri seen ravi] tabelut 4-4 aint date valor les iat figura 2, ding iin 41492 1-mol reali, re Tinat 44 St obeat din walkie oo atin ed, representing PsP ram [om fos [open] Bette meno Ua Din graic remilté 0h B= — 0.00007 1g to, va lo ame ea ve se gre oh asm ne {Stam vata (ics). tr de wa serio enol, ay eee YR ce ‘euteiches evn at see et 10, Sa se afle pe, as ccnajice 2,300 wy save'varn Her Waals ve oy (ie ooieentoe viral Tempe vied le re primal enfiotent © oars ral ete na eepuratura 0 vo, Ty) Roxelvare ck cana ae ete ser py a na(ts ¥ a ase eat isis Ay B,C oconsttai prin, al oils, a teil. cooicent viral ‘Eeugis van dee Waals (ae t= RT, se poste serie: Valoile eofiienilon visi sink — Bom cm le coeficienjio aot ¢ vanperaa By Le real din condi 5 ser peda, :410, Se dau salorile constanteer sovgiei, Beat ti -Bridgeme entre CO, (anitti: mel, |, atm, K, tabelul 45). Febsind coat Meares Total ¢2 Bridgeman sk xe calcul solemat conpat den, mot Pade Domo) Pe) Gb, a prentnnen do 460 a dete Sa timperotra de 350°C ones | im |ouor [owas [aa-io | Retolvare Fovopiy Beattie. Bri semen, atnoa pet cleus fomta existe pe un damning de petal alts — ea 5 1-8 yy an fm core 4, B gi e sat constants definite prin rene: aaalt }: Ba nl! Se oterrs cf eoustia Beattie-Bridgeman confine pe tt Cnstanin enna nek ete B eonsants Ag a; yb her To toeme at wolomal my poate explicit, find meena" opt meta narerve (vot Cap 1) Un call aproximetiv a6 ponte face dacd In expreite a yi se eye miriam P| pe basa ccuatsi fgnmulai iol. nei ay rap ie Fa rc re maranjeankeouatin tn forma: few a set Oy, ine In paranteza mare se mai face 0 aprosimare de gas ies) pentes nj, abgise inal dupa rosmajure: (Eyes tn enre: A= “(oar} a : In ld mn: A= 5,0; B05; «= 08, (22:53 oo) —opey BE 94 (222-22 + os) om «SA — on "cata lout pentr cael poten ese mal pain acts dec eta lt (nos Bite de eotem 9 = Di 411, 905 mote amesie gas cnfinind 15% Hy sé 25% Nz sint comprimat Se peteda pereeen ‘am Sia compare aceald Tutoare ik ee resulta in eal Pebiat t Ise eee = Tos ee ME ee erates ©) legen Bat Ama gat gf coe. |S tne) aa van der Waals; tema omse | Gums | 1) combinarea constantetsr eco |__| | I aie ven den Waals Sedaw rostontelsecuatei van der Waals din thelut s) Utibitnd ecaayia easata tea, roma UT 0082 ° 29 . 238 ae, 1) S exc peice dn cia van er Waals gh male husk pentru face conrttuont yrestnen parfinla, Apot we doleind ea fet te Dalton premunes tle” Aattals pet oe vom 8 i= 25.305 — 230 molis me, 25-208 ~ 70 moi 00 ‘ 10 Pag 2H .082- 23__mIOVE- OA “932 — 20-0.00001 OR, Pee 2080-024 _ P12 oy, 2 Pa Pu + Pi =32001m, ©) Se procoeest prin aprosimatitsnccriv anf! Ge: aloge ovale entra voleamal pasta! als, %o3 — se ealeulena ou gna bad Am a gat volumul pari a om = 2822 — ae oaloueaai prosianea toll po Bast op, 31 rapootiv ayy ou ewatia Iyendor Waals, Pye) 33 Paes): ‘> eantinui pnd 30 atiogo 2, 2 Py dal 47 st date evade one esta prosinmea total, InTale 2 Decks P= 69a, 1d) Corbina Conga vander Waaleate poncnion peat un med fear fractile more st 0 face allel p Pp = XPdie + Pe = (XT ean + XE, Apoi sp procedeazd ca tn problema “5, Se obfine ? — 225 atm. tru amit dat, de mieten 31 hidrogen: [XP = 95-45,8 + 0,65 128 4 8) = 2950 au 94-1903 + 065 984 + 8) = 9339 K. venE My nears 98, om efor I Donen iar my me 1, 418, 96 aerate pone gus rome xin rele 2 (Bab 8 6 ocd we conser ecaaja de store van der Wale, REE 025 Yaa b= 075- o”apst + 0.25-03015 ~ 0; at dep, ar wt Aplieind aeeste valor in etaia van dee Waals se objine: Rexelyare eee ae jn van dee Waals pontry 1 mol gur ose: Pp t BN — ms. DATE ARTF \r py —ary bo Ae ee ee ee ie ore Gear) vo Ws fle ik punital © (rh-"(Ge)-* Penteu gost van der W ants( 482. Tn oa om volume 1M er? contine wn mot de ameste dogs me #8 hire, im proporte de 23% (procenie Pounatrce) mean se trier aoe Folosind diggrama seeraliset de comuresibiliat, sf se calaleo sion sata tn ons, dard vaorle erie ns. meta set P= 15.8 oe SOG, tor als adepinants Py OB aim #i = S20. Rezolvare Culeutul pormetilor P-T-F ponte un anvstae de gaan eu jatar sramai gencralivae de armpresibltae, ste asemiaitor eu calealul pent {substeufa. pues. Difrenje cone in Tolsin ia Joel. marimilor entra aubstantae puro,» e-aumitelor mérint peendoreidsy nk amestey Setioite pein Ala: posit a ivear ae by) Se willoast relay: ermodinamicd enon) ler) Din covapin van der Waals se objine PVs AT = PbS T rogiind_Yermonal abjV% fm cares Pip, Ty gk Va sat variables de stare psoudoredune Ci aprosimajin PY = #7, 5» objine Pry Toe 3h Fy, sink mavinile panaoevitice cate ge pot exprina ta fun de vonsinatele eritiee ale substanjelor pure asifel: vals ? aE Py EXPL: Tea BAira sunicen ars (pp + a) (aor * Mt wr) eB : Cp 4b GPP. cu PY = AP si negiind trent tn ot feasiil mare sb conattuenyior amesteoua. 4 414, Polsind couse de tare van der Waals si Berthelot, dpa daesteoe ieeiaiales htone. sipibichaihecaberich:touines, a gisninek nianNerolvare 8) Conform. prinepitor £3 11 fie wrmadinonieit suk plait ueitonrea Nome guna puntra oficial dou tert hom sont ee Bae otem consant, entra matan tm conliile = 120°C gP ents penn” haan si = OG dP 1.8 abn, i Ea ee Rerolvare Conform principe T 53 1 ale trmodionmivit gm eeuayeitormodion sie sare 96 poute aot = fe aT) Aer), Din qveast relate, difrenta (Cp — Cy) eo poate eslona dimot din exjorimantale PT! sou cu ajaloral owt eeantit de sare, Ded at ‘gle cou’ van det Wale. pentry a calcula derivate pa saalitc flosind una ain ovpatile de stare ule gizulni veal. Reprezntarea afies a datelor dia taal 48 fn figura 2. pormite 2,25 cm Kt cs pone EY 578-295 — 1130 Te fae Ded it 9288 K- 9% 1) Point cpa van der Waste (p+ S)or—9 =a7, 3 pot erie urmistoarels rela psa LS Eos (er P tae dap par MP problems 4.18), ane 3) + 2-22-00 i Tnloouind Cy ~ Cy = $967 4 22 225-9599 ah mot t= KH s Yore-am-oons °° . Qa, dab Robind ceustie Boe the lot pastra x esknla, derivatele parila AE Bt aiid erent cu presial dn embrldeptYe atoll den = Substituind Sn eounia eos ponteu ti (ERIE, roma 4 bine 8 8 ro 2a an0P. c 2 Cee A(t - 1.989(1 OS So AT tere 16 5S 3a : tr fae = 2497 eal mol 278 Kata e) Sennitenficionalat Jou LeT bom Pons Gane de acumen): santo 200A aoe Lo im evunyile sure pentra yee Jprotee.= aedvaloaren. mumaratorsa wey 9.4. igrul se rioega tn tinpul expansiuai, valour negativa a mumarstoruly fonduce lee ioeilsve @ goaului. Lag. aumitd temperaluet valour Hinsritorelgi este som, Acaath temperniuel bate tempuraura de snare Prin gaovt van der Waals Valorie ealewats on colo doa went do stay slat practic nk 415, Valoorea caeficiatai Toule-Thomson penra an ta tomporatars ds 20° gt presicnn de ala eae de AST, Compare Tare enperimentla gO tu eon otceaa ies din des BT, Zi 6 abel 68 5) foosind souyia van walt ) cletaisenperanra de | Canucn elr molar peretara did exe §1,Nenl-molK- Consanih comtet vende e Wn pinta eannise Mar ises 4 Itc pca gt gh tee GTA ope 2710 K ‘Ro ~ 0,082. 0.9873Voloaren eosficientalui Jowle-T ho mso x ealbulats eu sjutorul cow finan dee Waals concordat fore putin co valoues olhinta ox Tinton Aces fapt ev Ustangte Inptalai'ctecouaia van der Wal Ii presan ideale r-di esata aatietettonre. L1G, Sa obgind expen ergot imarne U(T,¥ Yanni mo dg vmiagh coafie de sare Batti Bridgeman, EE fpeins mit PO) Gr Pa ezrin prin aie pl C= Gy t Oud a stare te refering eink U = 0, we alge Uda 2) ‘Gate ea Voth i Rezolvare olovind eesti tomodinamit awa cnars(1(Z) - +) av, ath ‘es obj prin integere, del staron do roforing la stares 7, ¥ (le (ccar el [re] — 2] nr.Y) te rT ~ To) + rs TH +07 TH +Cl(r) 7)" Fouatin do star Boa ttieliridgemon se srl ta toma yirls Ty , HA) pp p27 AD sh tar es tune ah Vive t ve rin f{) tiadae devivatele funetiDor f(T). iar 1) (25) -3 A Ae, crran ners + nae 140+ RIT) — ATH. nee 1 —ypatrecr— 14 ar=—4ea51n—1¢m0= ‘ (TPT) — 62D. Dur eeativien}ih vial stat (Sex! proms 4.3) te HAT) = BBE TE ys ALT) tunel derivatele corespunnitaare slot ft — na, 28 pry aie 1 an = 288 Nolaile cane apar tn integrals devin: AN) — THT) T= 1450) fy — 1412) In ioal s» biae dupi afectuarea tuturor ‘lecular: oe PT) hy Enh 7) 4 1144 RY ¥ (4) a ("4 Pe bn ceil de dfn 0 fusciic F:6 = GT) RT nf Vibe MELIGT ge cattle finda: and PY > PH p= Et cat pot onl gan, bw hand © Rig r 1 Re P lide cate pena vet Ean de defnijie so poate seis Informa: HT Scisind in ainbii mambsi expresia RT (In P/8 Pe Bee a a toear Dar fl a P Antegrnd de Ia P= 0 no prsiune 2 oarecare: art Aine Vi ’ Fle su, eel Gara) cso cep cas Bos cs Slupone de seuatl de stave de forma F = V(T, Ps Vey (P) a tempsratrs cotant i tinea nti pe call Se ata p= rv inpia{ 2100) a V5: conigite tia: em, Dy orn gi) mF nl ey eum m7( R27 Be ore PR) ar "are Cwsigur-£= (vet problems 417), dar unit sutrt prefer fommuern eo mai a, ‘Tiebaie mentions eevia de mai us rel ifn unm ye (vari de varied 4 mk scot ela ea Integenla din expres do la problana 4.17. octnati n exiretiaxplimantar. Limite emiateé objimte slot deternionte romai de cae se ev ust de ai Ane iajide Beattie Heldgestan sav Haditeh wong. servest la calculi! fogeetajit in fast da ‘yepori ne count BenediotcWebb:Hubin apbeabis ait Hehidoka ct qt vapecion Foue'th uae petea ealcabalfagaitilr In fam ie repel hn cok chide eer, as ne te llanbie ind i date experimental 4.19, Uuilistud eeuayia dedast fs prodlinn 418, 94 a objind expresia Pepa tn cactd owas de stare ven dew Waa Len frm Ar a ey bat ee Poovey fad i oe Rezolvare Rezolvare Fete vorba do fapt de o echimbury de variahila. Hearanjind relia de def up toler in eeuatia obpineté in probloms 4.18, rez tigi be oY 4 : toe LY RE Ge eet ae = (Galtaancan en aml} ‘sau in toma (27) aa. Conidertnd rolayn: 420, si se cleles fugacitea wa gos 25°C, fe preside 2,10, 15 : nell She Se aera Sopra se Roxolvare Min dao, a tompentrt comnantk: 7 nf— VAP ex condi i eteind saomou en mena olginer: ‘ee P Ivbeuind Vala euatia de sore: AP anf = Az — ops LP, ft Pal 2 (2e mAh (A) at lorlae ar) Nee seat gob n> 7 a arnt Jeet PRIRT = obsicem: Gr La ((ME rhaval oft pe cing = ain P— o9nseaP; din f= — oss ap, Pentru a obfine valorea fogasitalii a 0 prsivae Ps integreask i aed - onia[’ an,t byinnduaes tn Pp P= 0002 P. 'S objin tn uraus calowlelor datele din tabelul 4.8 tex fig 1 ar Gt pete Sen, find Sielsrihelodd SS sompane ren enh roe consortia Colas kas ah nin uo Ca ret ae Terateess Post ela w obey wlth ab In yates 41% aaa we-((Gr-a ind VAT din exp Ber hoo (. proloms 4.7) «Ot au Sbouind datete: Ip Devi 9 = 0785, iar fe ‘loan Ini ae poate determina ai eu ajatorul digas general Cinictnpilor de fugectace. Dentew seaesie es ealeuleaa pareetr Pewsey ea = Pa B= nt Ba 1, entry car din diagramé reaaltt et ¢ = 078 (Amera TY), Deci f 078-50 = 39am, Cole ond renaltate aint fourte aproplate. 422, La comprimarce isotem reversibi a wnat mat de Nyy te set abjinat pene facra de compra, tn func de prestunt, Slot tebe 0 7 wo | sn | 10 SB ae arose marine enn Si, witind pentru cofcientul de Pugcitate (=) si facoral de compres siaue"(2) dsuendente de presane, VF ee consanté ponte inet de Reneleare I conditit reversible, la trapsreturh constant, variafin de entalpie Fier ete gaa on Iueral ds comprosione! MGy— Considerind defiifin fagsvtai AG, = Ramp sw objine dupa ntegeare tutre dou Hite de presuns san doomeece te Abpea = RT inf Tncmduetnd costicfontal do fugnetate 9) L —inP Vand ante nla Ain tabelal 41 fe faguttace Seecese.Confores peobleniek 4.17, exist colagia | i Represent grafic ¢ ln tunel de P > objine « dneaptt (ig. 4.4). Bown sora deepte ate Wea ms-109 P, eave este dependent camuth pontea 9. Din panta aevate dropte nena z= = 29mnr(QE2) — — 2ana- a9. 298-27,8- 10-8 oP ‘ = 15 Ben mat deci o yaloure constants, Pontra gisin dependonfet Z= 2.2) oe ul saz laa: RY 2) aw Z Ar 2 mw Za 1 8 2 ey Indocuind s» obiny dependent Tink’ 2 = 1 6 10-4 P, beat Data sao feat ta 4.28, J abet 412. ote pre tm tude elemental amu a parka molar al bilegsnetat aneta : resin fa fompesaiura de °C, pe x faa de Heed Xin ie sulle fugartate Par fe hebrsennta tn anostent tt tn Lass ras Fearn de °C gt pcan de 400 a ‘nate Se eunase vanstaiee elie ole gem TS een, le PC, Rerolvare 4) eno im armas gues dt mak malt componente) v1 posted Sopnctaton parle po*bata rasiiors © mPOMA (1 se P i. ai ‘oucondiile limit: P+ 0,f,— Py sh = ® ‘on pasta, i 9, cosfisintal de fugacitate el camponontntui i din amoung (PNP Gi a FINE olsind'o Cale similar vest din problema 4.17, se obtino oxpresin ds cole gle ot ge (ar 3) Detnin o fanetn 3 porn a caranteran devin dea comportaven Meu: aay —P= 2 p, ? 201m cure Py one presi. in dere davis Pentra. a caleula integala, se Joterming valoern a lin seuafia de Aefinitie gs» repaint grafic 4, —=/(P). Ia tabelal 4.13 slat date valor bjuaule, iar tn figurn 45 dingrame! 3 712). Pria integra peice “bling alouwea —7 000 en-mol-* tinue limite de piesiane (460) ‘dupl eXteapolares eurbel experimentaly la P 0). su et: fy —5280 20m Secon a) & [eel] ee Pee 8).0 atts meted de cic const jobsiresroguit Le WissRan da Log f ws Randall cu sit asses compos star punt ampere Dar (2 Pefy tn tare of acto cotisientnl de fogucitate 1 compogentalat ur fe tonpetature 5 Presones sisemell, = Mnct: r= Bethy Chofshntal de fuguciate }composentalai pur (2) sm poate davenaiya Dy ujutoral ditgrametoncrnting ects nvell par (97) v0 poate determina,Bak: |v care HT, este entapia partial moburéi ia amesteval real, iar HB in cal ileal Poniry neat goealuload paremetsi edust Tou ajutoral est "AUTO! Decrees Ht" 1h fata molar sanponatee pa ete Cycles ferse ae pone Ee eal Ne LE RU AL Tl eg PS era GH). ar? ee aaa 0 159 cis P= =O a a02; 7, pone a+8 ‘PROBLEME PROPUSE Din iagemns, se sere, a fay Rat 18,0 = Jae? al, het mtt pi et a ia wie a a ALBA, Viitsind relatin de aufinivio o Pagastayt partite: f= WD) + RT Inf condita ind P+ 0, fem» Bok se sabi relia, eon penton feguctt de tempera Ya prasane fu compotie conan 1. Sian oleae presiunea exoreitah de 1 yo! de apa tt star de vapor, Intesin vol dy 10, 139°G fobxinds i 4) eyuotin de lane «uni eee eal” 8) ecagiia van der Waals, Saat ntl § =e GON Tc 3 Si oe caleulan pmiunes necesar, sf se omprime 2.86 m? de ammoniae laguna da Gm emperor 0 aun wl 17285 a6 tempmraturt de SD eat 00878 mol 4. Sia calouhre comarca vain der Waals pentma CO ye bata ‘alot misilarenflees T= 109 I Pete me 4-56 eal volumal molt ee molanatuai la 300°C 4i P= 290 atm ‘unoselad velo mivimilar entice! 42406 gr Py = 487 win % Canin ta oan dn no To les ena! mole rie $3 mporaara' Hoy 10 pentru Cally comcierind cena de uae ner Waale* se celewlne vulunal molar al Ne la P= 400 atm gi = (°C pe baa ‘ound gueal ulead gf a teuaied Vann ‘ew’ Wa 47. St se galoulizo densitaten aerulst entra eu vapor de’ op8 In 26°, tn soln’, Presined do vapor) Ie acenatd temporttu exe 23? mm He, Gompoagin eral unt Tire hisil de atbon ene $82 Ny Sg 31 00% Ae [proce do oun). aslo de compile, Z pontra bes de earbon le (°C 4i 100 atm esto 02007. St se ealeiete'volumul eeupat dy Gi inh decade Jb. 100 atm gh 0 ‘1) pent un ded; 6) folosind tactral de eompresibiate 9. Pectoral ds onmpresiiate, Z, ponte Ny ln 50°C 4 900 etm exe 15, ar In 400° 91 200 aim eato 0, Dac © wanthate meters de cup wn wala de 11 la 3° Gt 800 aims sare emee de Ne ups e eoeaytenntitate de att le 100°C 20) nt, 0. Cunoscnd pm on cated van der Waals: V-— 2h, Pp (RTs si'T. — Baf2Tbl, same calnloentactoral de evmnpreintats 1a punctal eri I}. S8 se determine covficintal Joule-Tomson pentru un gue a Rerolvare Uiiitndevlagin do dsfinitie in oem: 7) staf $i aplicind-o i In conf Py +0 reouli Fig wf NT) np, ToT in gare a eso valonren potenjialuhul chine 40 coniiiletimita, 2 ote envatan Dero pani cele dd ai couporife consanil x scree oie toe da thea ln Pi com ‘a, ane), gs tn caro Y; reprint tril ole le componesir ane Bin exb dou rll gh deonrooe (2 ln Pye Dye, 0, twa occa, (0), (0) Aplictnd relay Gi bbs-H elm ho Ltx ce objine 4 - mA AV B= Rr. H2. Si se caleulere fugucitaten metanului te 0° 91 200 tm cunosetnd vee love mavimior vice Zp 1003 st Py "5.8 atm, BT de, RTE : iT18, S¥ a0 sabiemcd o couse do cael penten coniisntal de fuze tn fanote de factor compress 2a Ft, ar Si se caletes, ind arse sono fayacta szatal le — In presi dp 1091 0 clam, dack so cuneve In moeata tensor 9, [aim (22) ar, (e676) an Pies ariel ans gb le rn #4 ocala cit, Sim aes tye ne tae fila pon fi a seaeezme a eS YntruCOvte 10°C 20 am bnen eager erences Dass eae rier Se hut ah Nanded "Ee oneomed ocean coceie Waren handing? 40, Sho objskmitin d pened enue pes pine un he Melis ee, my 21. Cunoseind expreia eapetiiteaborice Cy pentru CO Tn presinnen de Fateh eaiemort eo Oe : Cy= 876 40,608. 10°7 4 0413-10-47, [78 — 2.000 K), 1 4o ealeleae eapuitatncabried molar 4 CO ln 100% fe 80 atm, presupunind « vomortare 8 gu Helot Gomuawl sitive ale GO slats f Sk ML. Pentru un gaz eal a etabiit ccunfia do staro PV = RT +P, in eam Beste 0 conranth. Si sa stabilised 4) expres de caloul a fogeitiis BJ expresia do calcula voici be fing 16, To, intervalul do tumpernturi 30—00°C THe rman ecuatin dy BY = RT-+ BP, B find practic conitunt. # — 0419 I-mol ‘SK ae calelete valoils fugieitt, eotiientulot de tumncitate gi Clnintel Tonle Phoweon We P= 1 aun git= oC 16, La tompertana de °C oxigenal vemenntecuata de star» PVP OTT 104 Pe 1s. 10 Ps penta preioni cup {1000 ate, $8 se calealote fugacitatea i cafiiental def Sog'atm, Notatile PyV, te relent lq candle noe Hath i procionsa eonfarm ecw he r= i ORC g Pros 349 atm, ‘alealeze, fugoitaton CO Us 507C 95 100 atm a) prsiyaind wo ronortare a aul eonfom cugpet vay der 2) fokxind‘iogramn generalizatk couficiontulai de fogastate. Fle aneasie T 1 = 2%. In tabelal ve urmearé este dat comporigis una amestee do gem 53 centtantee Gite. SH we nleukns fagurtaten cdr camposent anes npr tla de atm emnjertn de 0 ilosind rogue Lewinlandai] sy diagrams, Genmralestt ace centults"defogacitate ferexa ty), ems ‘at ‘iiate le P adm i 0° 17. $8 90 demonstote o dependenta fugacitiji de tempernars, Ie pre Sonsanta, pentru un fluid pur eee dtl de roast BEY cancer ath” aT inde 21 este proprintaten de gaz idea! Ia acenast gi P. SE se calealede faguititen Nib, 225°C 31 P= 100 atm, cunt ‘alone Fingal Je acreag prestune si 200°G, 7 — 82,2 atm, Secon plieabit routia de siwe Ber tho lot, Datals esti sn jaw din anoxa 18, $i co arate of devingile propriatafile termodinamice ale wei aid Ale Yaorilecoroepuntiad taut gor iden, sint date expel wom G LER (ene = nr af |r —a(2) Jar, ae Si calbalem Tugaciiaton iaobutanuhif le 37245 K ql prosiunen do 40, %5, 0 atin, coscind ‘wrmétoarele dato exforimentae: Tae aeunas crate ou 8 eh. Se cunose aomibarele date: mesa clomid ee egal 2 UBL gomol, dena mcd so iO plata a a Ale, = 2 MO cal wot, la 7, = 1 88K, Ming = 1 880 051° mor, Ia Ty = 996 K, Rezolvare 5 ECHILIBRE DE FAZE IN SISTEME CU UN SINGUR COMPONENT. + folompte ria C1ausi0%C)ap ey roa In forma apeosimat efi Mln( 11) Bo RAT, Rents Ty = 1104 95 AT — 06 K, Volumil i mol de Cl rind dpentenys teppei, presi Iii sett ae: Toes "Pe basa atten relate soe cateléseealtaa de pire ashe ta 12, a il este egal eu 112. . SEE 13 om" mob! = 018 1-mor Nezolvare ap_ an, cron: Pe Votanaul unui m6l de Ga ich ste egal cn ar 1241 22 Conform eewapei Clow siv eClap ou Tobait 31g 2007 = 1405 em mat fete i Munei din rlaia AP Atta, ar” Tar, (ERO pemre un tic onogen sav deeming temioarcle resins de an 00K. is aK. ‘drive temperate eee 9) fncia Wy P= f(T): b) previanee de enpori ta PC ©) elidare de vaperizars; 1) punetit de Frbre normal a tichiutut. Hoya APU esata ea ‘fetinfgwea 94m cary sete ee ‘Rout gai cube P= My Ponte caret ote Rorolvare Din dhatole_prezentate In tabelal A. prin interpolre. a ob Lee Ae TH cm kg’ Tnlocbind in eeuaya Clans] Gispeytoat 9) Reprsentnd dese de wai sas imiro aiagrama ig P—~4 to obtine o nee pirodvind dou preci de ate os eing sens? OT Allg 00518, yyy, on 08 bear BC i0)-40° hrm apa a ee edt eo _ mgt {It Age see 268 = A226. 10 cane rezallls A B04 5} B se cae ce it ergs eaparatra i Perey cad 2370, @ so calcutess cu elt cregic (oie aruraide sotiaificarc daceSa ve catedes: a} pune pa; 3) <@itera molurd de sdlimare gi flare “Relogn ebtatd ene: Ig P= 86 — ‘nota ds tore iC, Resolvare 73K (°C) ete: 0,608: Pag = 0285 mm 14) Presianea de sopori ta 1) Tas pune rind ede tat fas eosin ecb, ine presignen de ‘vapor a'Mahidu gt soldala ete cess. Se poste acre dec oan 12000 ig Peg = 80 — cay se) Citdora de eaporiire s¢ cleat consiaerind rela Og? Meg, teh 2970, an aamer ar 50 cal: mol Sebati a B= TD a Dac Ty = 1 206390 ig P= 5000 — 128 Pe ORT sna mane is ay Di a deter aes 1) Gonfrm ccuayicd Clausiue-Glapeyron “Wee Ags dle 10 GF aguas "ar" Fae ox datrminas experimantal urmdivarcle date priv coil sishieeapors pentr if: Pets SME ae ear hg = Tel santnd salar cant de apo 1 4°, Png = 77 a cen nie mms are formeash On ware 0 Cals deat Se Rozolvare Ueiisind ccmjie inegata Clawaiue-Clapeyron (pentru ceonstant) Siecaidura de soporizre a apet eae 10,7 koa to de °C x 103 kesl- mola SMC, Consulrand ed tx» dependent liiard tir cithary de uporiare gt semperatya also, tse eheoed dopendenie pestande de ‘cporé de omperanord. La °C presinnen de eapors we ape ete $8 ra Hg Resolyara ‘Gildora de voporinsry fina dependent lines de temperatura absolut se pote erie! Sip — ATE 2 Cole dou constante; 4B, se pot determina din sisteaal de weuthi 1070244 B 10300 = 32h A 4 Bt Aaagi no nse Doci: AMyy = BT 12884 (oat mol Avoasti funele so iatreduso Su ralifia Claneiwa-Clapey ron: ln Mle, din Siler, oP 1 (ar + 100g af ar! at RP i iin: Sty = 609 ea-mah Bias ak tune: {in stare de vapori olen de sult eoresande formulsi: Sy enews one es ta entry ohinerex fwortst P— PUT) oe ialagressd aooaatt reli. intro Fimivle Poy $i P 4h respect 273 iT. rc . Pca Hg) = 6897 A ‘ of s J Pom He) reas mp2) St 28 gy 1s he ds 4g Po Ue) = 998048) $4 se siobieusct eouatia depomenfet eildurié de vaparizare de tmpe- a i nest oi Dp ftegrure yi tsoeren Ia ogsritn speimali rez 2) St se cleus calor de ooporinre a boncits ta tmperetire normale on 4: Rerkee (S040°0, gp = m8 — 401g 2%, (pm mn Her a Rezolvare si cateess presianon de vapor a ape’ ta O%G pe basa print ts label 32. 4) Transformind ceutia deté t forma difvenputd, we obfne: MF BOR yay 04m, sree EG Lanett & Prighespeigeh os eee Ca dine Ih ye 5 Ho | ws | acme | ssa Bent ABs | 88 aioli Svar trae ez dependent de tapscebok w cMurt de veporzay tne formn= Migcerehter . aie ek te Rerolvare HO) = H.00) Seek. a ieee Dec AM D) Le panent!marmat de ferbre: Moog 15 bia — 402 T+ 0675 T= re entra ealomal ui ACH 20 flisoyte whi NG} = AM — TAS, ow fold evirimilo steno: AG} = Alta + & acuar (ase ee a 7A bead mot 5M.) Prosiunes de pert o Ve ose de 497;2 mm Thy to DPC. de 05,6 tam ig la SIO. Sa se caewise eAlurh de vaporize, “onsierid Seharee meee onaentd nnd val de tapratrd cntidaran Ci ‘roars abulard si rated edb de vaportare acd pretend Ponlen ocilbeul de mai aus roaul: Alle = (Alain — (AMa)08 — W252 eal- mot ASta = (Sbaluou — (Sen4 = 2839 nl mod * AP = i0dmm tig ar 402K. Reralvare Viiiind rileie ClaweineClayesron intogrti punta Ath cy = 7487 4 237-109 T— 18016 = —10 809 4 27-1097 “Boe ibe nloeuiaa se oboe pantra 40% an a : Presuoea de aoe Feauld Mag pete AB 14260 eal- mal 4,48 mm Hg outro ealovha erent difrentnas relat oo mai soe) dunt ele pate urbe Py Pay Ty 8h Te ‘Valouren experimental rete 558mm a, i fe sar tear, tam ae SsW@Presane de capo a benceull et at co faci de mp 7 pe coment 10. join cea: (soe Noe, amar 20m T+ Asa Pe Jn Pam = — SN 16Diferonfialele se tnlocuinse prin diferenja si deoareve AT, —AT,= LAT sf AP) = AP. SAP 3 ponte sore 578 Ig ars i P. xe) ‘say dupé tnlonini: (Alyy) = E812eal- mol. I nll 5 leprae pl ale peta depo a sein epee edd tarnd mln or mat mic pe Phe ie ical CatlingactcDevis, penn mts lee. Rexolvare Conforms metodeicelor mai miei patente, pentra a ecuaye db forma yas tb Won cap. 10) gp EadnoBerey, ¥ waa lb Sat Cleans ae: eta rermat te fete Gat v5, ar Presta de too “ges arb 1G, - Piet normal. de fibre aupenuna ete BG be faikalce tae tonpdratod ties far penta fe pre Sinmea e100 mi Tg re ‘nea de eaport a actus a0. Rezolyare li RameayYoung, sapertal tenpersturior thal de i autare, In enon pana, ale onsen Conform a fiers a Ron {n car Tyr Ty int pete de frinrorospeoty ale unel substan oar ue a fabs dotlesinp no presione dat oe 7 7k —punele le irbere le sclragicubtanie ln ¢ pregae orbithant 2 : a Pont cislipenan 9 peotea se-poste serie: Ecresin | P, mio Be 28s" = — Ae, a+ 453 ~ aaa’ 7 Interstar de spac tate este dati valberea 1 — 12,66. 7324004 22 ‘Similar 25K c net 1 Task g= ee eee, Un tabekle co exprima depene samene | ets ger | pence | dente wmunil de vapor a roi.) oi tia | cielopentana do tener Valorie caleulte pentru x ain nt prerentate tn tabelal 5.4, 12,5000; Sryy, — OT ADOT AO, Ea MSE 108; (ay Ex = Mggang7281 10-5 n= 8 Beunfin Gallingeort-Davis pontry metal ore forma 670 20 esi,or sett 10%; P= 79000 iin luni se sicegle eh he t == O60, P= 10mm Hi cate abuts’ wie acoso presiunea da vapori a penta- lui 50°C, Literature proszta velgarea P— 9,9 mii Hg peotra pintaa, Ba 8 con rigs dagrama Co x-0 thm ar pe doménl d pe He punta hevan, Yeptan, benzon flier, eve spe abn de rerun pi fos dale dim lad 3.3 137Rerolyare fee eri iclcy one ales a acct mee a ins de min pre! enero, ne Poste sae tle P Alls, tig A Poin wtp ion ig» = Mlle ge anil iy P My 29 reprints i dep, eX conn ew rap im ravine eu temponstura: Aces presapanere esto satificu fe mjistan eluuayr ou esiep\n dctenisld yon pei stanyel Qe ectevinyt one): ea ci ee ee Gad Sates Prin unin" dah pects cu Ett. penta teeane means Hf ul8 es ‘cnt pits Bu Sd pe stable «reli de cae 0 fated acniis (nara de Pitzer gi Gurl) pe ba datebr otic (P, 7.) #0 a conan feuajet oi" oime penlow prisianca de vapor” Si ae cause et Inbnlan sind cd ToS Ky Py 2,8 atm, sap cones cea Antoine 4 = 6h, Bm i538, ¢— 240, Revolyare Prin defiikn factor) acentrie @ eve dat de exprosin: aes on. iy care (PL Jran topresintpresines de vapors sedush ls 7 Beuayia tu Anitwine poninn prosiun de vapoe eate MP4 ier (40 °C. Hovalia slid po sate uaa pot te aT a8, Pagneae cs te tncoe Ptsbuexprina nn Hg. Pesta hate wobjine dup lloui eee 5 i 4214, Dlageama presitnetempraiod per carn ote dad t figura 338 1 an Or a a dct ee: 4) Ge presume ete essa peer informa grail i» diamant In a), a formes af 4) La 0 vmperatird $6. presiune de fe ei mat ‘mare: gofitad a diamaneat? 7 Dat deat te eth a 8 tenporatard 98 resins sraftal $6 ‘arlonsl mpit ox accoes dense!" #800 Pe Rerolvace a) Pe coda do obits diamante ‘aft, ta emperaiom de 2 00 hie pretinen retard transfor ‘mara: P— 8) klabar 3) Pe cub de cairn amare ‘profits 40, 46 dar eG = Var—sar, Deeis ¥,4P — 5,4 000 ee a) Abies range ate eo hh ee ‘ar Panta evrbes, 97, cate positivd in diagen oor ae Deonmeee (Sy — Sj) <0, ronultd (Fa Vy) <0 at gu > a Faz eu densitatea tea’ mai mire este ddemantal Sp he dust 9) AT 0; Ta Va>95 Va> Ye entra finele 2 yi 8 in mor! areménstor se deduce et Sethi Veo Py ta entry taste 3.911 Sy > 9) 1 Fa> Me Phin corelata relate ohtinate aaa Af Pwr o entation in do fore sity Osi coi si cu mapori, ea dermingt panels triple prosenaae im wbslal D6, Eeitoet net sat SE se masce diagrona de fa ao | 6 malt | Ee yormd ar dena on on ar ta epronimcie 100°C 4100 Rezolvare Diagrams co we obfine este prezentatt in figura 55. Deen fretioniie tension coratndfevoraeaek fore enim, Deel Fata uc ne pote Sabil presi mal Wi gee deat 1 wo daea fils tingl do. echiliba ee seg | chil SS tga ea posi Sorbet i ST. Studied opel te pres ints at a peel ei ” Romie pce pk | SRE eginc, ae Z ‘leata tA ghee UE stn! tn ech Brot ae. Ghaata eee nad dts sheaf TT, cre ste tenst dat ap Bebidas ett a) Sit se trast oproximanis désgrama de fasi provinne-teniperatirt pe do ‘menial —00"—0°G gt 0-3 D0 att, mand fitcare sre sare ean Pic cite 9 ot rl ae adel he la Dentne diagrams. 5) mova stir: shed Li gheald 1, geal 1 head 11, ghana 1 fl Magi TH sae stab care forma procs realbie rida mat! mare Rexolvare 4) Foloind dail din probomd va obi ingame dn igure 58, 35) Ray ee frit fe re Fares rai te pretense Sra ara entapie mole on tise, Del Hy > Hy My > Hyp Hay > Bae SAS, Demiie ormdarice ale si kn It ae Son ate th fw db tempat imitate Tenpercir tet widens te arbon se 10°C. St fe darmine columal crt a ea iia pr ota mora graf. (ini rr te fen oescatde madsra te Saye ser Rezolvare 4) Conform Wait Gailleter gi Machine f= ee tan in cores o, esta media avitenetios {tensa estar 2etare a tem eraturn ty gq, cantante, Foti date expesineotalo av fia pt ect, Adualndprinle pata ‘ecuatii gi urmatourele:patea, se objine un sistem de doud eouatii eaa8 determin’ « si go. S» objin fs = Osi — Ont, a tamperatara ested: p58 — OpON6G5- 31,0 = OBE gem VauimeRersic nl inaidul cation ee ek uw Me a ent mot ig ciate ; 2) In figure 5.7 ete repose bm Santen inte test ea Sa ‘tua (ahi i temper : Panelele ev ropreningh nei - cineticg 4 densa ela det a fae sat uae print inie pres ‘| aid, ne care as poate oii nae oi Ghmsitdtn Ya Semporaura et a = 1.085 ¥, = fo = 04055 Te = ote = 946m? mol ae ease tae et sit eee post wen eee Wed ‘iat afte reel ewes sad Gt ut se ek ‘ec h me i n gre Me e BEM ost PROBLEME PROPUSE /SK ae volevlere variayia (4PHIT) pentru op In temperatura de 4 ‘Gudurs de vaporiziy ape ests egal cu Si97 eal volute ol lubes cide note A808 em? mak gh vokinsl snolor al. spore BOND anor Ie ADC gh at Prsionen capoior, satura de eter ete Ia O° ete 185 0m Te ag {lira biota med de Sapte intr 0 9h 5°C eae 22 cal ge Si'mentevon preiuaeavapiriarsturft do ela temperate de 26° 3. La tamperntur: do 125°C axottal do amoniw aid sferé 0 trunfee Dre alsirop i prsiuen eT atm, sri temperature de Ice Aitca I presunen do 1000 atin. Varsha do votum co Insole formarea ate eas cu 010126 en? > qt Aa ro eleuhon fom. mol fhe ennatormare Tata 49° A, Preiunen do ve ae a ee ‘aan | maa | tah aie | ie | iz: | a, | a 8) catty eleré dl sublimare ¢)entalpn mols ‘te tani, 5. Prosumer vaporilor vaturafi de 22 te P (on Hy) = - aa 1470t Ie 4 s0 glomus 9 relokn do depundenpa w cBkdeit Stang, ld af Hichide 1 dente ante 28 Se aca fa) wunetal tipi: de topite a bom atamol este dat de ceuati 59,48, Iatente de vaporinge fle temperatura, Se caleuoap ealdura de vaporzare le IC. 6 Pogortaien epei ty sary lobids la 25°C alin tent fugactatna br 370 7. Ls temperatuza do 0°, eer Intent db opine etre tenia’ de vaperiuna 4 ape 96% sme de mm lemperaturk si sso compare cele ous Yala obliy 0 O01 gern, Cunedenind Paporeare gala eu 1480 alr mol-h sd yr etoeloe het onte 8D ox got tease oo era ft a 2) aa a ae Gai eee ee ea ene ‘dev ita nceont 8. In wecinitaten punetulai ipa 223, 0 substan ¢u iri modifica aloleope J, 2 sd peeinta SPSS STS a Ve SS traseze diagram ds ster presiane-tomperat trip. tn ja pune ‘9, Sf ae arte po baza sumault pants, o& inte diagram presione-tempo Sataed penta um sistem eu am component exe Posiil ale curbeloe de chili m dows faze tf 10. O snbstanl& axist8 tn stare do vapor, P, im tame lilt 191 ca" ot moditcahysteope * 13 4, Std ed ‘ntl prorat te ese ple arian ure S80 72Y 2a, T-P, at se completety tn tal Tole diagrams, fo tad Both moe 44, Tempera north do ferbory a aleolaol shite en 7830. Folornd rate Remaey Voounlg. sh se caloem temporatara Jo ft date frst 20 ci ig dre Soe mines de fer ape Ie 300 vam Hy ote are. A rt Opt entent orl plat aly ay caw12, Entropio polar standurd « metilciclopentannoi Hehid esta 5925 emo K-! Ginosetnd dependent de-tampartini n resus vor ‘ubotanjsi Hehile in interval 213-308 4186.00 » es # Toa st talovate ontronin mola stand » metileelopentana go Zens Rin Gino nemo 4a) comport de ge eal; 5) semortare de ee eal Contrm collet Beet he 10% Parametit critic sinks 2— S08 Ky Py Sak alin ‘Sim ealeulene enizoia mola standard « ortoslentai eatia ae sre Boyt hele i Se oun: eatapin ml Srosilnslat Weta 68,8 eal “mob, procanee Yayo ioneare 6 FECHILIBRE DE FAZE IN SISTEME CU MAI MULTI COMPONENFL ACTIVITATE TERMODINAMICK 18. G6, Pepi 9 eolaie rata Binard, poionfatbs chine ae slo doi compo= nent st fant de i vrai ig = wT, P,_XS) 4 ta tT, Py Sales wabllnsit cows earblor‘ehidrdnd ‘saps dr tn colton tih ‘por’ muitos oat tm antels fase, Sinan soe ebina cape soi ‘duns yi tichedudes tm echitibre wolidlichidl cu méocibiltate totale tr ets dowd fn. 6 80 bog 74 34,7774 si panei critic: T= 6121 Ky P= 36 atm. Rexolvare Ditereniel neon | ae, 2) are Sn ae of | ae “Ns Consider expresila pontra derivate partials gi euatis potenistlui entra conipenenfi stemulu ral, = HUT RT ag ef cui Anan pRétasy 1 ary map + Raina Bary 2 map + idk de coil Ia 7 yi Peonstante In ister bifarielchid-vaporicn 2 emponent eat: Mot 9 eo, sn pentru delesie po curbete de chibi «(2 of) (aAoloevind expresite diterentinlelor remit — ars Maps nang —— Bar ap nant, r 7 HY ary M8 gps ramet -— a7 + ap + rained ars Mays name ——ars Bans wana sav dopa rouranjre: A Ys ap obi AM _ (Atlas gp AV ay Mae \ pede (atta gp 2% AP Prin. ingens (eu limite soeritonee ls componental ur ai la ome se bine nthe aa = ee Vea gp ey T sre Ys (7 (AH coh P (AM ophy ty EE (Fond arf? Aa ap Path ae NaF Hatilaeurbelor Hehidelai si valorilor sn obtin la P= constant en 1 ‘onsant, Tn pra vx lage ma wus sil Aaa Oth ary ig BTR ler at sr ce ‘Tomporatorite 72 i TE sint punetale 05 tirbore ale componentior naive pot cbyins nua evespuneoare urbele ssi data inkios $5) 28 fll gp axe hy 8 4 tn care TY pi TY lat temperature de topine ale componentior pur. fle toll sint ccuahile Sehroider-van Laan Ponty sa ene sol ti (Ailey an dy ar GB) Preinwe a yopor 9 detent Ne SE ete 2848 mm He Prin sue i dr ise and der pra wiper a cat ard cu 8% min ie. Sm Cieals nose mar suckstanjet dizatoade, . Negolvare Conlon i foi Re ole a ee m con Exprimtnd mumaral do mali pria n= Jaf se bine ou MAP = ml PR— AP Bp Ba. fear Buta, Rémuls My = 127 g > mort Ponien idemificarea anci swdsante mcummeceis 1 sfocuato analica 9 Sementiar. iar ttn cbultomenre sx dtermiaat rtoree puncte de frtere'w staiet ot tn teratorira de carom. Folsind dati in tahela? GA S98 determine masa nord sbentt $8 forthe chad na | eam | exc | om | une | aero | sane na | exe | ; 0 | amo | amex fons | wim [eae [ase | oa oe | un | 3 Conta do taractarard de carton foestd eas de O88 g, sar contanta hahiospien jena tevacorara deri, 8. ‘Recall analse elemento ei: 10,39) ( 41 B87 Ch ezolvare ouotn generala pentru eehlibee lich vapor di problema 6.1 o¢ transom’ considerind somportam foal‘ fan lich se 1 i component (1) par in faan de vapor (of — of Y, z Atunei a abjine: : oa Soh ar Fotigrind pent (Aap) consiPPonteu solu fowete iluate v0 objine eenatix (deoweven In (tl — XQ) — pentru Xe ts (lag AT. RN APY é (Altes 2 TOO AMD, In care AT, reprint rican pnetull do fierhore a sali ‘Dn ecix ebulincrpios hata dint yoralt 000 A Reraltatalecaoullor eneespanaitoare ditelar din tabelul 0.1 My = 288; 24; 242; 240; 29591 200 mol. Bonn}in olositd ete apbieabilf slutilor dante, Valoaroa mali 9 My se pits afla prin nxtrapolamon Ik tora cue Ma = ea) (ig. Seiten diy — 257 ml Tn nnst can numa do atom de Cl esto: an- x. ints i mapeetiv do atomi de C: | ee 1098 ype 0-2 Fig O4. inte dooi vorba de CyCly, bexaclovetan, A, fn tote 02 este dad corsa panctotas de inchare al anei so eae aato im bnion,fenstie de encanta sla, 8 8 deeming ie asoier ol aridala ests in bona, daa salouroncanstaniv criaspice Aencentes ese 54 K kg -mo! Resalynre (Cu relaia simiby’ tok ebtinute pentru ebulioscopie {problema 63): 10008, : Odea = Ke re detormind man moan experinenlal (jae a nc aestie la enue, ‘naa mokek taortied, (Af, Hind cunoscui (ida rin roproentaros grtied a rportula i tinaidemelltate se «tine 0 conb specific pont eubstonilo Satie ig 2). Maan lard ‘apernontaisemple mpl i lsepa et tragtaron MOGLIRT: deter poe ‘ice emcee sree: Utsaal 9 porioe «cobs apmabe tne into asa nek sprint rae re lo rome Head pete oad fe neeet utecast Oh cent tect gad trelungoes€f pi ntereeia cua rdsstely, wolfe ene Fer Stee aeeete Die faces cai Bn : (a) Yeni er tae tune etnie ODL te std ae See Viet eae 24, Goel pare SE cine presinee We port sais te 250 ast pstancs de spore apt pw see 23,736.m We Contane “YBa 30 nomnpisd a ager ee 18 Khe e mol Fe an. Roroleare Decamyee clorura de arin dissiax tn ay, evunhia eviouopio limits gi pon at Ren uth devs " i ap AT. = ik. $=) Ph (awapm Dy eee siunea de vapori total 9 mola de? SS Gegr a ompoattie y= 040, P= 430m, ar He Ses 2) Pe deapl 3 se gisesto pesinnco parils 9 lui in fara de vapori inochi ew slain" eatin Ne "05, By 2 SO lan Hg on ols 3 pate ¢) Fobcind drapta 19: abtne eomponfinsolupvi la 6 prosiune totalt as bom fig ae opt oneal oil op u G17. $0.00 dtrmine manera de tlre tortce tm olen de rsifoare soe amesteal ction 4) ~ attr ae (ta pre tot Be 3 r ‘oloana cats atinenact on vm amvsteesehinwlar de acto 5 oleae. la shitter combos fads vegans ihe molar econ Fn bead 2 dae compere sor elon toperaiohe s een: (Pn ee & y ay] ie a | ets | y Rezolvare Numa tert dosh de dstvenesosor peatay vif un azysine dn componiie” dat foate af pre taf dguane Bo Bsn 9° tect sistema atonal ile ete atin gore A. Sai Teli dna din tbl 3" Fev teapot in arg og fn eatin de och wi gpl corpse noe tae a Tens a ida cooete Stier denteine Ses neal sa cre eb ae ape ald ens el pst Secirenet aerate aueee koe erin tes aeant Gilkey punea te nd — Radu Xe} Teal Din reat potential chimie sy = alt) | RF ka Py Bewafia DuhenMargutes ari forma: Timitaren a8 efor “por, pat flue pie usin age eaayia os apliok att slutilor idem agian mone on ( 2 Diferiols forme slo eountics Duhem-Margules se utiieas’ peat vorifctren censstonet datece psperimentale Gad) 2 sti 43 an dre earl presume cope te vt Mpc seat) foe Sites ine te at a Deir etic i) ease ole Be ere Pa ete ccna oe ud noel ate Moc Ne Rice ci abort ciate cae Beet nae rose Becerra ast cats a eee bed i Pale irene marae hea ees, feapia Henry. gts ost Henry pone avid avetie neg EW] peal alls wee cal coal” cal i 4) 98m cals eciitaie 9 efron de seiaie ak wlio 4 dad acetic netdézind componengis puri rept sture standard. : i) Si alt vir exam de eee a alla aelic hans consent fhe ey tas tn bene ward NASA ec cemesoa abe li eat te fae Pe mora kezolvaro ©) Yolo proioni tule P wa caevlet ou toe ui Dalton Po > Py Nalorile sit dete in abel ts Heprezentaen grafick ohne ilor Pui Pap) 44 PX;] eto ula atau 6 in" Drape din eco — premier penta Male con Tonntegiebe Raga reaper Bye So Pe Ue Velorle_prosuni- lor de poe le ea Prieto pork in oafoem daeloe: ome mast Lg 2138 mm He Sistenual prea iter pully rompers Drops Maney stem tend sei, de teat By — AGI ‘late iting nen a bt cunha P33) Ia Prana y+ Ter ‘oct deeptd Hw ‘sontonata la Xf Pata ee co valoure KB % 64d ES ie : ‘mon Hg re on9 O waloers mat procist a sonsantei To ary oe objine din reproontat anoetulai Bye foneyie de 2X, gk exteapolaren Ta Xz C, In figurn 64 fate dati reporsntares di care rezolta AB = 450mm Hy, Ut) Activate si sofia de eticitae uiiind component ‘inp stare sandal sau caleul a el Sse Hemultatee exteslul sin redate | tabsls 69, ©) Peru a celewla activin 20) fovficintes ae aie ys =| z fae erlic_refritoace Ia pa standard iain inns, ae alieatcnstante tai Tene Via ‘AE 460mm Hg oli: oes XA Rezaltatale sit rodaty ta tabslo. 6. 1) Pail af Ky as) $h a8(%y) ee precnare n Thgur 6.10. Drop in aceegtfgurlreprorinté comportars Sal ye pets nmin (2) (ae a Oya a nnd dr 1 Bota in no San acd Fae a ae a ee” nine (1 Sepchenlenno ane pate, 2 ata = Ge Dubem-Margutes.Pik Splee’scaie’ DubemMay gules (nwhlena 615, 10 a), Ge), ) Activites gi voaficintul de avtivitata se ealeueaad yo mails Hezulusole gateullor stat (enpuratria DProzentato in tabetul 840 (Py, = 1 ate le toate ee Stopes oument (le oe Se ee s se oa | sam | ow | oc, 2) roprorints ise ‘| am lene o(ee)o" | eae siete pcan ot ae ve a | {0 pan pons da Fg BA an Tisstoerd” schematic Sade. Bguilaten rapertebr_ pont ute etean retin Hallas consetenta st dateae Lo a “Antnd cribviad Ie tohven (weld netic) 9 composite, 204 ig obi 4 Gs), on = a LGD hee a ‘Se poate conchae ot datoleoxpesimentals stat consistent. “Temperatarate inp «Pe (8 xe RUB, ar Alyy 8 670 cal- no enue cabricda ich eto matt maredecttea a waiddaten Osea nay X53 ge rats © varatia de enalpis ibrd de opie la prvtune cone, Vointe de tempera dip rela AG} = 3.1909 Tin 7 + oss 7, a $673 Kum ems cl Fe +» FuS ce Xeu > O87 eat th scibrn on (3 sol ran te i, Calcul oeficiinnd de activitat at etn opine dal, Rerolvare Se ulllvaans reatia GibheHeImhelte 2 Pin intagrane roa Gt; Pentra o serie de aligie opte de Zo-On 0x mdsurat AG AG Allg + AAT 1 pone ir Foam | rp : man conn ow Deore Ia Ty 6, = ei ine a or ee ? z (rfetite a ompoonil nok dg ware stenard) ted ptm de Deeps (ot es ave ear ig Pt, —— 66D T!— 126g T | 12h 20 1 Pie 7 —aolg Intgeuind valor sf ranjind 0 objine relia corn, Deourete a eehi- br ak ie (Dur) piconsidertnd 9, +27 Ya ve pe — pix inns To Ye = — (ot) ~ RT dn Xp, = — 80} — RP tn Yop ten T1678 a ob 106. Reroleare inde irre s det espunstos compo date i tempuratrilo d {mae naa lo ay pests de vapor Za pur28, Sinem apt {P)-ar elem glial moms (2) formeasi on nat Sloe i Depending composts se wmperatits de frre a omesonel acai Indie stnte aapee Wn Laan corepnsinare items nonllaes ‘date tbe GA. van baer ‘Dependent. preemie de_onpori de somseatar pear consiaenit. Stare ae (aptsh te eh gitol manos ste dat de seu 1g FE = 8002 — 100010 +230), Ie R= Atte — 24840 + 250, ‘Sits diene rmpratara con mai scieu si proinnea be care sistema went bint SRG Hi mae en ae C24) Pentre siateneat eceiond a eee eas fone | fir 260 mum Hg fe eh ‘abel 612. Saarcle uotst yan zolvare i sohlerea pasion compoaiiaamastecub cot Is pseu tisbore ao tabu i crnponetal eu puacl do etry cal 43 oe Din hod tao wound psi, amesetl nesta ispare. Prbns ite git tanipertara gt posfanen le sre eompouyt eos! aa propor tile spe companeatil pur, apa i anor) ri: (") Pontra on amaves coun: Sym Ya: (2) = FE z (ys — Weadee = {ha lerdae = Ne Te Avi yi ty ol i 28 61 PE int fanopi de temperatura ‘SU bofaidorko terporatent Ie ene eumpouitia tmestoculs) nsolayp propio do eonetituental pur. La aceastl temperatrt (ora — Ny) = im (ter Renolva poate eo van Lae Deonrece netivitaist componentalsi 7 tinde epee unitate, eonstanla di oewafin ful vad Lia egult ex (vert problema 624), len Balen(t iim, ovine ta xy, B= Ie ve wor ag —ssteeareei (i Devondeaye cortivienil de oetivitate de Hin aston 6 ponebal kzeot,digpare la temperatura Ia ears hy Juwalor componenilon pus gal x Bin ecuatia (i) nes ya ee 4 Hew temp porta, nterseoyie al olor da enue pact eat a rat oot Tishiteraport dave to tro rite consantor Tomar trai eta ompeaitia eae rose ate Wspeimate desea prin celia emiempi P holifents de Carlena g Colborn: 4 len ae (4 ms 2 sin conan dgondate do taper 1 Sali aleveCConsideriad comportarea_vapueloe allul eneftelgaplor de actvitite rel YP Rorultaslsealeuolor eet dats jn tabelul 643, 50 punto uliiza pew ‘ os eta ene ae cus cere wee fe ania 7 aman were Gre Sees Te figure 5 Walon” fe 1 ‘consantelr van Laat sole 13 Jorile ag, eseulote siat date in ; oe .25."Tnuro wvufn binant a dnteriinat ermbioarea dependenta te Peseta shane sata, fy frctas molar Ee as ta 0s Oss od Pmt. teachin Totaly Oreaptt apy cont ine slit owe, ele eine cet ‘tard Mantard "component put, a8 hn lati $4 m cabal: 1) avo btn doa (0) rarest ia sere nar naz nen ae Sar epee srl FAX} 91 8) ‘cia stant sie ropa sc std nia ts it lnynt os epee eb a) Nemechek SH oe repens dpe chesare feta makrd Xe Nexolvare xt 1} Tn coal om caret sonsidrcompariars reel Gi fara de vapor ae vitnte, uportal ln sta standard de eqponent pat ste dati do Wa = ta x! toms 05 Date a= + in eine 2 nts fagawitatea componntuly pur is infin ce fee analog: ye *E 08: Gorespunsilor frase molare Xe se obfin valoile a din tabylul 64 lel ran a aca en onan dena 0) Im casa miiisiris stérét standard a soluyiek a Aiuie infiniGh, activtaten ta bel 246 lt da eal bf Se obs opt = 0 nedserainare ponte ve. Valanen Sorexpuanatare a ponte cbfioe Pr id X= 0 be al Pree cu rela + cam roauli ugar dia reaylle enterioare Determinarwa ootiiontalu dh’ aotivitas apart le sola a dite int date in tal 14 sink przentite depondentel (Xs) i 4a* R28) Penieit um amesiee topit AgC oe ‘au Termine prin needa curbeor dere 4 cle den teil 615, siemal prion a cuctis ta Xayso= 08 5) f= BHC. Sasa aleze acivite si coeficienyt de acto entre SoC gf PDC to fas edit (fi component puri dept tare sendord (OBihnem B heal = mol ta NBG, {AByp)rae,— 87 Keal- mol! a 456°C, Sens east dependent de omperaturd 0 ntalpile ie pire Rezolvare So utils eolagie generale in pocbleme 6. nla Faas Ine nthe (lle : thecty Siac ere Deoue siemal formeaat evtetie, rele se pot aplica penta cae douk Tame ile digg de fan sere fale elke aint eatoponentt eet ager Ih hey = 1 Neaijind depontent defen ern tan “Tn topive, se obxin nlagate Se haa dene an L sat a form: r, In oa i enn Re Pe teh otha Goctiionit de avtivitte a6 cule on reli ci Maga Lag yc Gc! Naty Meauliatele ealelelr st. preven Cetin tae 0, i & pisses: alga de emesoars a 1 a0) de LO) ex 1 mel de abaol ee 200 Mpg =~ 82.cal Ia tomportara de GEC. Preianile de vanort ale comeonangdr snc ns anst: onde. P= O80 1% gh Py= 0.500 DB. Siw enleatess emropia de amenecws si enopia de eae a sisemalu. Rezolvare Se pat aaeute ative coor dot umponont x sitamului dats ze 1 ay = Fem ona sia 2 Entalpic Where mostocee va Sine = Ta, seepatt Ajay = 1987 313 (ln 0.8 + 0.0) = — SA ond Bntmpn de sinter te: Man Aloe _ = 82 4 46 Peo ae: 35 atria de amestcare penta sistema ial ae AHL — RE in Xp = ABT ln 05 a 03) atria de xaos sistema el: Fe Mtoe Ah 1 409 = 2755 82%, Conic de tiie friars componemol pu dap sae sur) ie ban tai sole te dat ria Inyy TAX, ter ee 0 cman eo mati a Swot epraciaa Senin ab svlontad fencje de Ny #1 4, Sd se sublease exprecile Denora potnjaat choice ds avast ontalpia iar te exes. 1473 ca) Rezolvarc Sr ilznink usta” GibbeDu hem in forma: Xd, + Yell, = 0 Diforstind rlain dat: does = 24 %1%, fe ltin dpi Fal RX = — 2A — XX, = VK ALY cae Aeoarove y= 1X, 91 a= — aX Integra ss dlny, NG BANA,ax y Fprosile potaatslgehimioo do exse ent CHE MTSE, antxts of = RTM, — ANT XE Enalpia Tiber do exeos ote OF oe Xyih b Xyed = ARTINAAE + MEX) = ARTS 1. Uzond cafe de rtete refer ta stron stanard cong rent prs pant sae en () eed ate (2) din problema, 89, ne cs pool kama deen island component 2 et eal ihe de eee (G8) en nto so factia,motardtlacnutas (X,). SA se re inte soft ancile HA), 281%) 91 OL) Reaglvare S» ulilaeasi eenajia GibbeDu hem, Relijado cate este: ous | oa | oa nel ao | as | oe ‘ume se ponte nozolva gmtie saw momeric, Se caleuleaxh. raponetale Xy/Xy rm defiaitiorwe pate see BAP ng: PAT to yg, GE Xysh Aylioind aenste rela ea eaewla valor din abwlal O47 (7 ast * | a ae Mn w ae vl | ei > | ee eee | | | Sa | Se {fn Figura 6.16 est reperzemiotat tos | Sh sipendem X48, —/ (i gee |e | ledge (de exemplafontoy y= | Mie} $888 | fs) obit emf, nd fl : fsa | Ahn de 1 CUR enpina ate YA gh My — O42 (aria haganut Reaslvatya marin se ne face fv figura 6.15 sot mprotentate ‘ ‘ rin moda Iapeaelae : cole funeile Xn, a8) 9h PX) sor A(R) alta 030, fn sinemot apa ( propamat (2) saa obfnun pera +(e) Jost aero eefcenlel e cirts re te pala olor din tala 48 Bt far Sone a ey a rE St walt efit de ova de cls). Husa alo lie ape, th ance ope idee in tbe 69, vis 680 roped fact de compra ‘omponentit puri fa P= 1 atm { temperatira sistatnt as fost eyo tri standard re 631. Pentru daerminaren ecvivitait plumule tn agin Ph-Bi va foost voir element galoonie ox eletol wp (> POPBCl, + LiGl + KOl|Pb tn BPD)ofa cecromotore aie a 0 presi wrmdverle vii ceaporimntat Me nes ax oon 0380 Ew, 38 sit 1050. Si se caleoleze ects gt eoftetnont de aeinitate pera VD tn ai Povbi de campo date. S Rezolvare osetia eletrehiies var ane lee. pit cenit dora plumbul Wa ano [ipidepunerea Tabla cated (-+). Procaul gob este Phe (our) <> Ph (ata) PB nha de entalpe liberi x processlai ete: AG sg oe) — Hn PH) ob ve obtie re 2-000 R awe AF — 3 p0s- 8544-700 tye th = BT Ina, Doouroe 1p keen 92 AG = Lay = 632. Yn clone saloon: CAT | C4804 CH Ha (ec dectoci snd salt (amalzome) de eadmiu tn mreur cs facia molard adit, rvpeisr X90 Ng Mercoral ae conser int ig) SA wy taubae forte sltromotoare a cementalié galvenio te pant Tee ge Xe LS 40" preanpentnd’ et eae corka. de folui iate, 1) Stind cf fviaeecromotoare dtr mina experimental este de 0,20¥, ssc elitece raprtl sufioogor de atte in sie dan whi. Rezolvare TEkanentud glvsaie propos este 9 pls formats din di eletrosi de oxen Tp solafen nat poncentata | in Deoaeoe Xr > Xi posi formind slut de concentra dle hijo an deeeaed, iar fn Gea duals metal so Gx) — OI +26 foot) abt GALAY (ond +) HAP HON) eae tm ps nr x4) 00605 x IT 510 5 y An) USM (yr 5g He) eee) ee a) Ponort solapt ate 1 Bo 05015 Me aE vB aoe oe ge 00615. ie AUR 2 — 1 ona 6.38, fy clement patonie ened) P| PHBH! Co Bred, OL aN| Cs ( Phis) + Gullniag, NOL M, eleeouit are) + PbBegs) + Cuts) ) Canossind Ia tamperaaara de 25°C, B = OOWRY gi eefcenat median Ute autvtate ponte CuBr tate 4 — O01, of we calles: ‘hy Sa be dettrmine saloaren prodewabai de soluble at Bromnrié de plumb ‘in 2G [BD Rerolvare a) Fora elctramotoare ete ald e0 5 te Powe — He RT a BT a wae = ess ayes = Boer Se f Set Chon + AE ne BE towing = doe + AE in PSE tn eon ME in SE eoarce P,{produmol de slublitat esta oxal cu: P, = ares ahen ar oe eget — Erinn oy — Sb SE I [ace the)sare: a. ote ntiitatn mie ond a edie de etiote Gath PTE (re nt 4 humdra) de Tank pole, nape “neg fia sn ua wolul de etry ound toil de reaulat pin dcore {cant ee ioe ta ln cate me veto aaitaten soli Alun: Gna)? = (mg? (J = fm (my (mOsm = An hme = Pim Pan — 0.0 #5, Meoareee =A, = Day = “ igen aL le mm mee mB SEE tum) = w+ 2 089) 0420—1 0) PO si b+ 047) = 42 4 0475 — date 2) Rapria tut Beate: ae Ba dy sd = deo — tame — fn, ae 28 0 rn wee ‘ Ue P= ae [ean 5 SEP = 72010 (Pentru ets gi chines veal snes VID. G31, 0. cabnive EP pom ebmenal pala () PUB, jg, atm) | Mig. Ae Br] ABC) euros sorte rie ckemooars, E, a ifr comers Se om eine hgca tieitd De hy o-M ee Rexolvare noha ont are bc fn pil ete + Aw Be (A) == Agteh + He Be 1 ing Beton @ _2ar ? Aroarer WS Ev mem Dur in va = — INGE (conform ait tinisd a ti Debs 0-H Oe keal) vw cane HE Gte u oanatakd earinteritieb Tie! solu: Oepeonta tt "eipeatur Amo 4 28 tai ELL t + nar rire ye ste se. Ginn 0, e Det A no [4 2BE a 4 F Reeriniod grafic Pee G +i cslempag Iain obine By. Din gues 17 a ohswrvd of son 65. Diagrams de fase empe anomie porn en de component te a prune eT at ene den’ fier 18, ncaa do 0c Pre dual wluempuratera de °C, eat divas pint ee recital Lihidall flebe Fer, Sim ratte i) Comgwsiia reselaatal, cy 8} compwsitie madi a sida: cin tata ah te dt, 92 soso de rst, Roaalyare Digan datd rprocin we sto innans ert ol romponen}s As Tt ‘St total mscliatitn fea8 eh tah in fee vapor Gye ‘apotike QV) sieht (24) Tin dete ecunfilegeineao dit enn 2) wonpeaiia seciuatus exe ot as neta : #5) oman mi iat ‘inal enalatape bom. vampe fife initise si finwe «vapor ithnvsal 32 onto my = 1208 + 85)—785% ime© onsierind ap masa de resid gp masa de amvsie infin de cope sep = TheG.A punstal ) oe pok serbia sy gy — zp lary 1e6e + ee = Mr fe (bilan penis A). Anind in counted lang rol feta = MD, Of ge-+ 0705 gy = 078 +400, = 286,00: = 1506, G67, Aral 9% aba formeash un comps chimio AuShy. Toate re stant cnt vovipit ain fook-ehit, dare frre § sla Fah ‘etudd Comowcd se date din tel 621 90: osolvind fy usb | Ava 1) sf sr wus diagramed fn, omprratnrcomposiie entra sea by pero sete leh ce comme 20% Shy 80% Ay ret tnt de de 1100'C in TAC, te trans care de orate a ongrants In tiny pen roves de rice 6 0 sxplie fare paral acartes fond drama Roxolvare 14) Cau proton obtine Aap de tate A ty 6.1, rao O a an By Ave das — gf Aa dig rh u a it eo 30 a 30 8D 70 wo oO Too Tia? ° ee, ‘ Canoeing tomperaturla de lop la endo dow metaln pure 9 note ys sndonmidpunetels gi. Temperarile de tpive ae elo dean eatetion ‘oezinraaime ave fe vepeesnth prin tater #95 21 (sobs aol Vila Panetele 8 2 afl la interna nee eriomtala tee in fy rogmstiv Len vertisle RC rides fx pune eurespunaator romping ‘pumice Aust (de par Se pert) ped in puncte core yunaitor tempetatat de toe coxipunu. Paget €esle vn fame ‘earaleraty formar op camper nia verticals KE impart dicgrems de Save In. dood prt ientiowen| ‘oom rsprenetd fieate in perc digreml ie ose a Weal sate lot eozapag total suse tare Hehiay ot 'vn sigur eutectic reels Au 2 Au, Ansty ~ Sb Catoseiad compote priului euletic se otfine puaetul 2 Weel ql wre 95 (ened eli frau snansnor se predens pentey puatol 1) Payar solaie eu eamposiie 20% Sh #1 80% Aw; ema do eBlee ve heptane gues 6, Segnalo tsnaly eee npredint 1 athe solaieh belo: 2 — racine mo nut a slot ti tore ae ‘onto de Re pr is wxeen ft de comport vtoctir al) aural mls stibrtn-g eontlate ae edlduet edt ew elu lut latent top, ton \Gnutal dal fue! chide seede pad atigezvacampoaite enterica HHT punctal eatetios perature #omign conan pina ee rid. ‘elite pamteu a objae AM emcee do AN gt SuSby tae. HU) 1a amesteeut ahd 622, Folorind date mtendul 82 sp sro diagramed fast penn sistem NaCLHS-A) Se prope of a farmed ide Reralvare otal ¢20 Go gjutorl deter din label prvind comporitia s- Inge # puncte de lngbelare Soreeponttoirs, as ota furiele aE, BC gf CD tin Figo 8.8, Se nteant str 6 ‘coneapnnstoate peta to tap a ately fi pools! fy pnotel until marchetes compo: age hit poe care apa my esi | 184 cite dies Gen ub form deapt deren | "30 | alin (S28 609i, 209%4). | 8 ztesma CF intenerieash | 38° | vervenla din in punetut é, | 360 impintind diame n dome: |e tilincar stem ete format | A oe din feat indieate Sn igus 1 teriporstue punetulil pertetio Cy jaferioar temperatur potatien de tape mcompusulit S24, acortadin ura me eseempune neonateBik 7a tes ee 4 Jn rola e armies wai tu tip tm oid por 838 wlai ones empl uncut ¢ Pe a ‘te we poate sere so eepar soli Mg eee lar pe amare CB 20 Si TaTaRt ard sai n= anpuna gmat ae frontal Mass 1) Conforms wate tiaras probe 838. In tion Sint presente date rat pr ane f fnpiturlr ds mage a et) nts sg ii as ropontta ste fu Suna dp eee waa at a ey St fall ex raponl BEAL Shee orl esa chi fret oe frie do swdatuo BOS 2) 98 9 caller q 7 ‘im par obi pe Feira 100 hee a (ard ce contin "3 tn 000 °C coma Resolrare 2) Analsn te ta ni inte oT iat eet liebe" tase al Sie to ipa Tete eta Inl poeaturi Carbele ob 199, cmos nro ows di aba 62, ‘Shinde wisn A Brio espwzetargoaied wemperatnh in Tones ae ae presi uti sunelocar de dir compen ae mance care Meche? Wiehe Pb. GG rs needo turk, exile. unor palure indice penle de topre Ni by gt ea no sa fermenter par, le amesecerton, to omgonen. Orie sehinbare pant indies einbarn mamane de fa rin roprezentaen gnick in lurior ce indiot schmidt pacts sé plies pc Siagrane dy fae sate 4h cual sisemula gy folosind tele din Fornarea une ecmbinati chimien, ou Aird de ev kompo nan fuay prnteun maim al wutbei do 190 ce 1 ale computor form funetie de composite 9 tnturr lempen or puri oso pusé tn eviena po degra Hh nibea. Tn Figur maxima eoespand ethane fai faa te tromse dia yeni Jac temp frm. Sat notte ficare pore aterm, fat preiree nba decir, ob labelul 62 ae obpial Usd pune 2, 10413 9h rapt, de te ae ig igus 22. lum amentae ce cuntine 6% Ma.Tikad eont do magle atm reste dai dl petal coeapeneiar doe i tpitur bo °C dt ied sek, ponete £2 Me Me tripe ounoseuih 3.6, B's obtioe8.10. In coset emai nar Sy, fe care Sf i dae ad omits oct etabh ita uemiioarels ar woh Asean . al x ae Pewee OR ew fiate te i ine sare so ing ‘Sia store splnamiare ane Sane per iterming ‘mld ¢ dingremet fuss os Rezolvare In figura 6221 praca diagran Toe Pooeiae Bg, 20 we lk Ean aS seme 8, Pinel serespe Me elt 625 Farol In sch stot as dag oplinea slat aetesre penn taunt ale hn fetta 77 aay ‘Rae date ree rete de enor Timatsi Acta ate, BETO 55-240 Lesyneavseeh ( ‘ind dose tie austin oto tome pits (lin 77) s0cepe Sphere i HD. tn woe ‘iugto teebuie trad Tinie 11, Ser tale hg emu tl (8, TS i stn (5) (9) -F (Sy =D) ee Stuaiainveret apa dad prions de vapor pote (S44 Se 2,0), vie mal te dest tes pests ere 8, “HO ioe dpm beth Trial ti 17, lat tale ty oxlibva detmpre ucenein ‘af 1S," 140) BHO} —'sp mapect va aoe) (Se Sy “Hkh I0)-F ()), Sub Hint 2 fazele AL. Bomar sitet vrmar format de Uchida A,B $i. 98 exo, urd nie date to antrnia Hrpiratara gi pesiane: — Bi 30°C si partake i ea te at ee rut ah Sibsanta Aste teat miocilt ee B91 Sib oe apres schemes ngrama fas. sistent eae nape ec oa iad hig ene ect wnt Oy alee ay oop cesar el ‘rll erate enue ces do aurel hala ste Ree Soa ieerarate alma aie tin, LEE 1ale =. is eee eran are inelioahg al eg PROBLEME PROPUSE 1, Prowinnee de vapor «unl sagi de meaite 5m evte ou 0.158 mm Tig ‘mei acdmati det postinen ape pure Ie tenperature de 20,86", Sh Caleleae Prositen de apo &apel ue I acest emperatard 3. O aoluie'ce confine un gram do mvbstant@ (. — 882) In 100 em, pro in 0 pasion osm de 560 er, ln OFC, wv ‘i se calcubze raportal = i i we comentene portal Eg 8, Si se ealcuete prsionnsosmtic a une slut cn un volum én 50 en ce confine 2 sahdr. Masa mule «sabia eto 2¢ “mel 4. Care este masa mola x dinitrbenrenli,daok a denlvarea yn gram in eos in 60 de benzen sida teperstute de feeb Brenna 4 020°C; constanta ebuloscopicta benznui este 281 ky = K-!= mol, 5, Si eo edleuloe constanta etalioeopicl ape dect ee slic «3 o saluie 8 euatine 0450 wren in 225 wd apt ie I confi normale de pre. ‘inne, fe tomporaturn de 100, °C, Sie company renutatul én valonren woreticl a constantel ebuloseopivn a apei (0518 kg =} = molbop eulealae ebldurs abot do apie « aa ylvent fiero te 127°, eonsabant Ta 2°, gh ore Alloy ule eetah solvent fierbe le HETATC pl eohgelauet la 2553 ai el oe opel a, a ea s Prsnma deport Remtemaok pu uealul 20°C ete 7h 2 Fig rspeety 22 tn Lg, Sas alesis presi prtigh ale buxazoul Uiblugmalar gc peesunes ala evap on sha petra once uch sin banal ato 09 9. Doni lise nemisibile A 95 B slot diatilate in amoaton in presi Mauss, he tamperatara de BI-C. Lea goa toorathd resus de Sapa eonponsntalr 8 nt 2 = 355 He ‘Si betdutoritinesisee marin component B, ae dstilatal conti ‘Sieg mle Ay far mea mularé a componentalss A ese Aly = 82. 0. Prsiunsn total, Pty cau! unui anstee ideals poate termina oon foom tiger tet OWI: 4 PoP SMM, iy cares PP oh Ph ata psc ds sapon aleTicideee pure, ae Py 1, a Frio peas de vapor le Canpanenelr Ix Fomor Px, Nvamentcniue Gontorm fei fei Dalton, fenfile molire a Thmonenior ass eens snk ‘Shap anata 8 ponte 1 eaalat eu rola pb en A= yA A {1 Activites commponentolul J tro solute him este dats de eouapi Riva =P hn Xy + ANE BM, la care Ny Np sntfeaofile molare, iar A, B, constant. Boustia este vilabil i fret denen de crumponigi Sire davroine oxprosia pentru activin comments 2 e 12, La deternicaren,aotvitayi Gu tn oliajol Cu-Aus eau mavens la 77 snvmtoaels date Xa 0 01 02 04 068 08 09 4, tm 9 0015 O08 0102 03 O71 09 10° ‘4 wo ealoulezeactiitatan Aw I ales rt mone 5. Dow fuze lihide formato de oubsiontale patil m inte solujie biowR eu doterminet fugusitttes substanjet danlvate 1 fonote db race molar Xo 02 4 oe 19 ho 8 DAS Gad Gas eA Si se saloutere aclivtiile dimteate ulieind eunpote ieceaeke ceveaeriel as wince ior imp sane stn La pao # tn aaa i il mens a "mesteeemetrop con{iniad 894% malar in pal cespononts Tepe ‘atin de foro w azenopui sin TSC. 9 ge der 4) constantolb A gi B din eeunide van Lea ay 2) compozitie aaeocpulol 2) preionet total corespanzstaaee temp um le flerbore de DOC duct 4 si B au sa media, Poorivaie Co ‘pri filer prs In ag att ible A gh sat th oatunt In ella. Se insiders pe oetielenit de acti su standard de component por femora sprit sito (Couvenfia inetrieay in pn in faze Ha eawfeuethe molec vamp Tentolat Acate Ny Useh Vegi. ant event de activilate cones iri fn celal fad de fence molar iq wo ara existe eli Xalvsre — vive) — 2s — 1: . Pentro un stom Dinas sa ebjiaut wcsltoatele date exporientale te ful ei 2): ork te temperaturd constants (resiune total-comse‘Se neuter: ©) presiunie partial $i vorticiei de activitate vy y95 1) etal ber de exien: ) Sabie Hit ae oefivinntlor do eoivitate Sie vevilioe consistent dstlarexperimontaty wild éenatia Du he mis Margules {In sstesmal dimatiltormamé (2) -benzen (2) sau determina’ urmtoarelah Aina de eclins Tiettt-vapint ba terpeatara Te] ee [oor [es [oe [osm orm [om [ow | $4 te valeuleas: 1) prsiunlsparfisl #coeficontil de ativitate wy ei 5) exmsianen Ini Henry KE si coetvient de wetivitate Si ve rofirerint gation ty $i Ino faneja do Ku Sse ealcauy tomperatura i ene ae lon antrenaren cx vapor de ithtame) 4 byneulus tolenhal, -tisut 9 airabennet a (rE pam ig Ge eats spa ean cesar pent. dst 1 tn g din ticeare din esate vobatano? iam Fa Sisemul benzen (Z}-toluen (2) se omport tel je un deni leg mera Solniad dates din tbe a oe alle t) prestunle de"veqn ab compen pus 1) Aira do faut presiiwesorpostie a 30°C 3 90°C: 4) dagsnn dh. fae Uenprratuet-omportie a P= 0) mun Mes ‘) tomseb Tosco 9h componjie acetoek Ia eciibra a t= 00° Beynon pentew un antertnc iif de 200 gen 4% molare. bonzeny 10 fol ee] =] ereamane | var [aa | ame, | sao | aise Yea | en | recite | wa | we a Vea | remmne [aaa [oar | om [oma |e | oe | | me 2, Capoacind vemitoarsls dats. esperimentale ks ealeulea eqordonatele ponetulad gutoet reaultatala cw varie mmolare Ey vac = 0,095: tis we compare ‘periontsle: ‘etnpeature —OE. gi tree a — OD tian digs de fave tempernturd Paden mens unontad ee 045 cal aot, Toad an 220 8 (Allan Si determine coondensteiapunctalu nuentic tsa nec topa 11 eg de amesneeuteetiefrmuidonataresiae idol Sedan emporatee fe ncopat de eratalizans ifort composi «1 [ali] an] ana] ar] a0) an] a9) nae] on ee ee eee : [-4 Bl] a] a va 22. Contra HIgh _ ar tn cae (Cpt 3 (Gt sat mfsurate In vecfodtaton punctlui de toi, oe» obfing pe basa esuayiet Schroderean Laan Tehticn 2 (aghor (44), (WC RT USCA 1 nan d A 4), ae op, TE ae yee ie, Kise ealeuleye concentraia slain wtarate da it jenn (ay) = 5 Sten sump {alba abil dai ae sda lag = eon mpere Mamata (Cp) = (Ci = (AC = ens,42. Comporifia wor stoate do fnulopa 9 apttenot ele uaa eB or oe eee 1 tae peti sie a seaman oe ats Ste trata eurbol de Faery pentea on stem compra Iedieaa de" ssenia (2) (98 Diageama de fasn 2 wo stom fort dia dot tomponenti Beste de pul poveontat $0 ort 62, Si aids ceules 1 Sie construed diagnos de fe terupermtor-tomporife alse deter 4) lee temporaturt va tnoepe aa AA 2 ‘nine comport punetull crite do diaclvarepunteu iy = 2G, oli tee Farha ut ammuiee de ASCE de eo toda devpiek mois vw prob 5.18) composite 73 molars A a cn i 4) vate oto competi reziunla deck anestanl ds ln punetat (x) fast ila pd n'y Temperatura et 15°C mai recat dei ew fearon neo inrbonel cnr ea camponitin meaie » ditiatuli obfnut le purctul (8) 21, Curbole de new puntra aliajy GiLSH pivzintl in functio de. procatal In grutate de Ca unmitomels puncte de echinbors pantet (bell 1620), Ske sehifow ogre ie fe gis we stableasc fran exilonta tn teoare damental aati, [os owe [a |e 18 |e [oa | a s a each e 8} non DiS racers sire] — [a |e Jaw | — [om | =| = ol [oe [an [om [ow [ue [em [ef - “ pa | % iy al 25, Si sues diagram nium 25 i eo ontaeerie apall eae Finare diag nine oan nn la reals 4 4 s #) cave este tamperators initia de fisbere i rompesiti prime ete gente mie eer ey 8045) + 1220548) = $04 0) sited gh -vabaran coal Stamey Hur rane lel fim '# ss bine ain L es Pan 3 jumperatura dv SAFC, constanta de eckitibra, Ky are saloarea 8 peniew i (Me sin paaie expednate Op leery Er pe cme Fee, 1) Soe bat Ky ox ta Ne 1 Soo ete: ln OTC 1 Para recta on aa Sa ae 280,10) + Oe) = 28048). eee - a, evap temporary, SOFC, sto sri expresilepodra Ky. eB #8 ae u-8 lr Prin vok}e we posta seis gi tn forma pavivare y ay Seat 40.238 k= — am oe Ton Cod De unt rem: 8) (Rehm sag ~ 800 ton Har" ah ge ake Yh AKT ath aaa YBa ee 76 m0". * es = On ve Forma cuit MA ete doirmiat deal duilentormen din vla.a a ee 8, ropewnlanes fue (aye) ar fy deapta FA a) Wea petty = Hate Valle feneies ¢g— 248) In punctele E= 0 ¢ & = wi : (Ky = 2 — y= 485 10701 ee ee Aylin aia abs: Sete igr REPS! selewtectecs conara ds sehttre Ky pemrn raciat pica Be orp Wien = a te tempts de 18159 i pein tl 10 etm, So om pes sepeleg red eet oma te ste ate de ecilbra, tn procence de mana: Tha%, Nig) 1128S ce 7980 a eke = 72 + 1308, ezolyare : Bi, Cf nt Coortanta de ebiidra Kp wate ext cu 6))s0 s¢ fatale trporaioa’ ts ce a ofie aitod pda set 2 ‘ bad aera ve ioe eisai ties einer ep nee ke Bp ge a eee m= [N) 26h) -+.04e) = 2004s); (AGR, —s9400 — a4,9 7, () CaSi0(s) = 200) + Si) + Oe); (ACR), = 267 400 — 476 7, Si considera 8 prosanen eid de carton resale din rodacre le vit wT atm, ta homperture carat Nomssele dno din tieare component: me = 3,48 race mar conrpunaitoue tN hes OB) oe Oa Alamoit Kp = 1 A AIEEE mn ins te cote in Gis On cody aa Me ro lvare in dunaoe eslor dud aot chim (2) (2) x0 ebyine Mi) CeSiOfe) = Bais) Sif} BOG) gi tarspunadioe 4 AG} = 194300 —a85 7 fo =1, timpoutara tort objine pero MG = — AT In Kym 0. 19450 Rezolvare Prin adunares color dov8 ret dato we bine: 2eag040) + 9) = 5Ca(s) + C04); AG = 28. onstanin ds ech 9 regi esl: p= Po Dia lain ental Hire stand 86} = ATK, Drone, ty 247K. 194800 WS T—0 gi 7 Bs Presi vepordor de apa je ehira cu on ameste de CaCl 58K gi reapertes C000 at Go 8 Gal MYO (0) cae 132 ten tn 3 aK. ) Si oe serie expresia eonsiaick de clbr® Ky ) Sa me ede ware content de ocitbrin Ky te eve dowd tom 1) Saw dbrmine dace CCye 2440) ura cnr pssild wit Pla te tna de porta ape fe 2M Kae 13 mn, obtine: fn Peo = =! = BS Pon 390-100 Monn Pam GE ik Wh Poy = 3,85 10a ¥ x qty, eke ‘ stabi te 291% tm contact 8 Siebtoed dojohtnte de temper a lpi fa consancl ewer penta roe i‘ ) MnO(e) + ate) = Ming) + ,0fe) crass variate emalpier Whee sunderd ts foto de 2) Made) = vem + 120K @) Me) + 12040) = 104 se) Bebilibret pote (8 sens 211,069) < CuCl HOG + H,O18) cut Ke= Pao. La tempera de 38 Ki Ky ~ 032, We sompernura de 204K | Re = 04 ) 4 ray He — 0185 ater ‘tats Rezolvare Prin adunavea reacilor (2) + (2) sb obfice rae (1). Corespunsitor: (AG, = (AGH, + (AGE), = 96.400 — 194Drouroce 0.049 atm > 0.0148 atm, CuCly:211,0 mu evto stail le 2 Ee o Pim its cosa ninin de manga Hn for nies seamed ape ae , rea din fi. i fons 9 volte tral et memtennl) ce tte Lapabild 68 080, ‘> simatan ea 1%" (nat) sieve i fer, a 1EIL Ky pera 9 forme an Wet SE entra constants de ection tu 1873 K pena eo i pir. St de cual there sanded. ponrn rea chine are tot in Be pit 7 Uy (0+ 04( atm) == S04); AGF = —217 570-4 470 7, 2A + 107 = nays) 2) 2M0] + 05am) = Mino); S6R = — 19940 + 2925 7, in cre paramere mahi (| ramified. amstotedtote (eh Fo). Se thgandntte ae prac enfant dink vs Parameste dene somifcdeubnant diaste (in Fe) Nagas ane Cocfiviennad de activivata al sidieiatai dizolvat in fier ta 1873 K este ALOys) = (A) AO} = 06 250 — wd 7 + = 0176 Ab = 240) 30) = 25 40 — 1407 15 Ode) = 910); 6 ~ 29 38 — 1907. Rexolvare Penance miei semis fah lishide pur. Pn aati depute Reser 2M, (ata) = 230 (a) vain enti libeer de wartie, AOne entra eosin do oxidare a eluminivtal din Wat ta tie, conmianty de E rae Ming = 36} RP ly the oe ito, Rye Po, —1 sie = (io enn format wna oid in stare, Axe i) me Tone ar ostre AO, ete oh prt ax Ming A68 + OT ly 364 2H may, tunel: A =— 1 . 4g ts foe ‘sci in cam oxi a 1% silica conginut in ip vrai ental! Hoge Eilon steve due Sami cu (ae ain i «lite Coromuaritee mena. Aas = “Zak daz nil coe Nieto ania atin odin ig Ky = 51000. Pent 10 $b digWvat in tes Xu — td se oe me ae LaBare: (AG 86600 ea Ta 187K renulls = 2.10%, ce: Se | ae eas map 9 Mea ‘wate sti ia a vo ae a 2M lat I) +30 eit Fg aN, In com oxidit mangnls, dim dates problemi ee ioe ene — Ane (Spr = 100800 $9625 T— ORT In Naw ‘Sia 4 mangamil se yor oxide simultan dae ANNs < ALO au (8Gr, = (SGrz)_ = 90900 en fn nee nat he nee Deol: Ig Nig = —1417 si Nw = 0,067, oven ov repretintd 0 concentnatn for snes a Wea de" 6745 Mn tn tie Inveonclarie » pba ip lia) de fir eu mingan ce contine ass) 1% Si ovidesza tn'1872 K de Tu'un continit avai mare de Os, Mie tat Se bey male po ae tract tate anze si wlide < AMO: <= 2c A> = 2 ‘oct ene Yeas segs coun ach sunita partihe eect pent Petia ct cae sn tat mate dma at 2 wn + 4 Bini = Bit He +m) zed» + ry 3 ere 196
Sp he dust 9) AT 0; Ta Va>95 Va> Ye entra finele 2 yi 8 in mor! areménstor se deduce et Sethi Veo Py ta entry taste 3.911 Sy > 9) 1 Fa> Me Phin corelata relate ohtinate aaa Af Pwr o entation in do fore sity Osi coi si cu mapori, ea dermingt panels triple prosenaae im wbslal D6, Eeitoet net sat SE se masce diagrona de fa ao | 6 malt | Ee yormd ar dena on on ar ta epronimcie 100°C 4100 Rezolvare Diagrams co we obfine este prezentatt in figura 55. Deen fretioniie tension coratndfevoraeaek fore enim, Deel Fata uc ne pote Sabil presi mal Wi gee deat 1 wo daea fils tingl do. echiliba ee seg | chil SS tga ea posi Sorbet i ST. Studied opel te pres ints at a peel ei ” Romie pce pk | SRE eginc, ae Z ‘leata tA ghee UE stn! tn ech Brot ae. Ghaata eee nad dts sheaf TT, cre ste tenst dat ap Bebidas ett a) Sit se trast oproximanis désgrama de fasi provinne-teniperatirt pe do ‘menial —00"—0°G gt 0-3 D0 att, mand fitcare sre sare ean Pic cite 9 ot rl ae adel he la Dentne diagrams. 5) mova stir: shed Li gheald 1, geal 1 head 11, ghana 1 fl Magi TH sae stab care forma procs realbie rida mat! mare Rexolvare 4) Foloind dail din probomd va obi ingame dn igure 58, 35) Ray ee frit fe re Fares rai te pretense Sra ara entapie mole on tise, Del Hy > Hy My > Hyp Hay > Bae SAS, Demiie ormdarice ale si kn It ae Son ate th fw db tempat imitate Tenpercir tet widens te arbon se 10°C. St fe darmine columal crt a ea iia pr ota mora graf. (ini rr te fen oescatde madsra te Saye ser Rezolvare 4) Conform Wait Gailleter gi Machine f= ee tan in cores o, esta media avitenetios {tensa estar 2etare a tem eraturn ty gq, cantante, Foti date expesineotalo av fia pt ect, Adualndprinle pata ‘ecuatii gi urmatourele:patea, se objine un sistem de doud eouatii eaa8 determin’ « si go. S» objin fs = Osi — Ont, a tamperatara ested: p58 — OpON6G5- 31,0 = OBE gem VauimeRersic nl inaidul cation ee ek uw Me a ent mot ig ciate ; 2) In figure 5.7 ete repose bm Santen inte test ea Sa ‘tua (ahi i temper : Panelele ev ropreningh nei - cineticg 4 densa ela det a fae sat uae print inie pres ‘| aid, ne care as poate oii nae oi Ghmsitdtn Ya Semporaura et a = 1.085 ¥, = fo = 04055 Te = ote = 946m? mol ae ease tae et sit eee post wen eee Wed ‘iat afte reel ewes sad Gt ut se ek ‘ec h me i n gre Me e BEM ost PROBLEME PROPUSE /SK ae volevlere variayia (4PHIT) pentru op In temperatura de 4 ‘Gudurs de vaporiziy ape ests egal cu Si97 eal volute ol lubes cide note A808 em? mak gh vokinsl snolor al. spore BOND anor Ie ADC gh at Prsionen capoior, satura de eter ete Ia O° ete 185 0m Te ag {lira biota med de Sapte intr 0 9h 5°C eae 22 cal ge Si'mentevon preiuaeavapiriarsturft do ela temperate de 26° 3. La tamperntur: do 125°C axottal do amoniw aid sferé 0 trunfee Dre alsirop i prsiuen eT atm, sri temperature de Ice Aitca I presunen do 1000 atin. Varsha do votum co Insole formarea ate eas cu 010126 en? > qt Aa ro eleuhon fom. mol fhe ennatormare Tata 49° A, Preiunen do ve ae a ee ‘aan | maa | tah aie | ie | iz: | a, | a 8) catty eleré dl sublimare ¢)entalpn mols ‘te tani, 5. Prosumer vaporilor vaturafi de 22 te P (on Hy) = - aa 1470t Ie 4 s0 glomus 9 relokn do depundenpa w cBkdeit Stang, ld af Hichide 1 dente ante 28 Se aca fa) wunetal tipi: de topite a bom atamol este dat de ceuati 59,48, Iatente de vaporinge fle temperatura, Se caleuoap ealdura de vaporzare le IC. 6 Pogortaien epei ty sary lobids la 25°C alin tent fugactatna br 370 7. Ls temperatuza do 0°, eer Intent db opine etre tenia’ de vaperiuna 4 ape 96% sme de mm lemperaturk si sso compare cele ous Yala obliy 0 O01 gern, Cunedenind Paporeare gala eu 1480 alr mol-h sd yr etoeloe het onte 8D ox got tease oo era ft a 2) aa a ae Gai eee ee ea ene ‘dev ita nceont 8. In wecinitaten punetulai ipa 223, 0 substan ¢u iri modifica aloleope J, 2 sd peeinta SPSS STS a Ve SS traseze diagram ds ster presiane-tomperat trip. tn ja pune ‘9, Sf ae arte po baza sumault pants, o& inte diagram presione-tempo Sataed penta um sistem eu am component exe Posiil ale curbeloe de chili m dows faze tf 10. O snbstanl& axist8 tn stare do vapor, P, im tame lilt 191 ca" ot moditcahysteope * 13 4, Std ed ‘ntl prorat te ese ple arian ure S80 72Y 2a, T-P, at se completety tn tal Tole diagrams, fo tad Both moe 44, Tempera north do ferbory a aleolaol shite en 7830. Folornd rate Remaey Voounlg. sh se caloem temporatara Jo ft date frst 20 ci ig dre Soe mines de fer ape Ie 300 vam Hy ote are. A rt Opt entent orl plat aly ay caw12, Entropio polar standurd « metilciclopentannoi Hehid esta 5925 emo K-! Ginosetnd dependent de-tampartini n resus vor ‘ubotanjsi Hehile in interval 213-308 4186.00 » es # Toa st talovate ontronin mola stand » metileelopentana go Zens Rin Gino nemo 4a) comport de ge eal; 5) semortare de ee eal Contrm collet Beet he 10% Parametit critic sinks 2— S08 Ky Py Sak alin ‘Sim ealeulene enizoia mola standard « ortoslentai eatia ae sre Boyt hele i Se oun: eatapin ml Srosilnslat Weta 68,8 eal “mob, procanee Yayo ioneare 6 FECHILIBRE DE FAZE IN SISTEME CU MAI MULTI COMPONENFL ACTIVITATE TERMODINAMICK 18. G6, Pepi 9 eolaie rata Binard, poionfatbs chine ae slo doi compo= nent st fant de i vrai ig = wT, P,_XS) 4 ta tT, Py Sales wabllnsit cows earblor‘ehidrdnd ‘saps dr tn colton tih ‘por’ muitos oat tm antels fase, Sinan soe ebina cape soi ‘duns yi tichedudes tm echitibre wolidlichidl cu méocibiltate totale tr ets dowd fn. 6 80 bog 74 34,7774 si panei critic: T= 6121 Ky P= 36 atm. Rexolvare Ditereniel neon | ae, 2) are Sn ae of | ae “Ns Consider expresila pontra derivate partials gi euatis potenistlui entra conipenenfi stemulu ral, = HUT RT ag ef cui Anan pRétasy 1 ary map + Raina Bary 2 map + idk de coil Ia 7 yi Peonstante In ister bifarielchid-vaporicn 2 emponent eat: Mot 9 eo, sn pentru delesie po curbete de chibi «(2 of) (aAoloevind expresite diterentinlelor remit — ars Maps nang —— Bar ap nant, r 7 HY ary M8 gps ramet -— a7 + ap + rained ars Mays name ——ars Bans wana sav dopa rouranjre: A Ys ap obi AM _ (Atlas gp AV ay Mae \ pede (atta gp 2% AP Prin. ingens (eu limite soeritonee ls componental ur ai la ome se bine nthe aa = ee Vea gp ey T sre Ys (7 (AH coh P (AM ophy ty EE (Fond arf? Aa ap Path ae NaF Hatilaeurbelor Hehidelai si valorilor sn obtin la P= constant en 1 ‘onsant, Tn pra vx lage ma wus sil Aaa Oth ary ig BTR ler at sr ce ‘Tomporatorite 72 i TE sint punetale 05 tirbore ale componentior naive pot cbyins nua evespuneoare urbele ssi data inkios $5) 28 fll gp axe hy 8 4 tn care TY pi TY lat temperature de topine ale componentior pur. fle toll sint ccuahile Sehroider-van Laan Ponty sa ene sol ti (Ailey an dy ar GB) Preinwe a yopor 9 detent Ne SE ete 2848 mm He Prin sue i dr ise and der pra wiper a cat ard cu 8% min ie. Sm Cieals nose mar suckstanjet dizatoade, . Negolvare Conlon i foi Re ole a ee m con Exprimtnd mumaral do mali pria n= Jaf se bine ou MAP = ml PR— AP Bp Ba. fear Buta, Rémuls My = 127 g > mort Ponien idemificarea anci swdsante mcummeceis 1 sfocuato analica 9 Sementiar. iar ttn cbultomenre sx dtermiaat rtoree puncte de frtere'w staiet ot tn teratorira de carom. Folsind dati in tahela? GA S98 determine masa nord sbentt $8 forthe chad na | eam | exc | om | une | aero | sane na | exe | ; 0 | amo | amex fons | wim [eae [ase | oa oe | un | 3 Conta do taractarard de carton foestd eas de O88 g, sar contanta hahiospien jena tevacorara deri, 8. ‘Recall analse elemento ei: 10,39) ( 41 B87 Ch ezolvare ouotn generala pentru eehlibee lich vapor di problema 6.1 o¢ transom’ considerind somportam foal‘ fan lich se 1 i component (1) par in faan de vapor (of — of Y, z Atunei a abjine: : oa Soh ar Fotigrind pent (Aap) consiPPonteu solu fowete iluate v0 objine eenatix (deoweven In (tl — XQ) — pentru Xe ts (lag AT. RN APY é (Altes 2 TOO AMD, In care AT, reprint rican pnetull do fierhore a sali ‘Dn ecix ebulincrpios hata dint yoralt 000 A Reraltatalecaoullor eneespanaitoare ditelar din tabelul 0.1 My = 288; 24; 242; 240; 29591 200 mol. Bonn}in olositd ete apbieabilf slutilor dante, Valoaroa mali 9 My se pits afla prin nxtrapolamon Ik tora cue Ma = ea) (ig. Seiten diy — 257 ml Tn nnst can numa do atom de Cl esto: an- x. ints i mapeetiv do atomi de C: | ee 1098 ype 0-2 Fig O4. inte dooi vorba de CyCly, bexaclovetan, A, fn tote 02 este dad corsa panctotas de inchare al anei so eae aato im bnion,fenstie de encanta sla, 8 8 deeming ie asoier ol aridala ests in bona, daa salouroncanstaniv criaspice Aencentes ese 54 K kg -mo! Resalynre (Cu relaia simiby’ tok ebtinute pentru ebulioscopie {problema 63): 10008, : Odea = Ke re detormind man moan experinenlal (jae a nc aestie la enue, ‘naa mokek taortied, (Af, Hind cunoscui (ida rin roproentaros grtied a rportula i tinaidemelltate se «tine 0 conb specific pont eubstonilo Satie ig 2). Maan lard ‘apernontaisemple mpl i lsepa et tragtaron MOGLIRT: deter poe ‘ice emcee sree: Utsaal 9 porioe «cobs apmabe tne into asa nek sprint rae re lo rome Head pete oad fe neeet utecast Oh cent tect gad trelungoes€f pi ntereeia cua rdsstely, wolfe ene Fer Stee aeeete Die faces cai Bn : (a) Yeni er tae tune etnie ODL te std ae See Viet eae 24, Goel pare SE cine presinee We port sais te 250 ast pstancs de spore apt pw see 23,736.m We Contane “YBa 30 nomnpisd a ager ee 18 Khe e mol Fe an. Roroleare Decamyee clorura de arin dissiax tn ay, evunhia eviouopio limits gi pon at Ren uth devs " i ap AT. = ik. $=) Ph (awapm Dy eee siunea de vapori total 9 mola de? SS Gegr a ompoattie y= 040, P= 430m, ar He Ses 2) Pe deapl 3 se gisesto pesinnco parils 9 lui in fara de vapori inochi ew slain" eatin Ne "05, By 2 SO lan Hg on ols 3 pate ¢) Fobcind drapta 19: abtne eomponfinsolupvi la 6 prosiune totalt as bom fig ae opt oneal oil op u G17. $0.00 dtrmine manera de tlre tortce tm olen de rsifoare soe amesteal ction 4) ~ attr ae (ta pre tot Be 3 r ‘oloana cats atinenact on vm amvsteesehinwlar de acto 5 oleae. la shitter combos fads vegans ihe molar econ Fn bead 2 dae compere sor elon toperaiohe s een: (Pn ee & y ay] ie a | ets | y Rezolvare Numa tert dosh de dstvenesosor peatay vif un azysine dn componiie” dat foate af pre taf dguane Bo Bsn 9° tect sistema atonal ile ete atin gore A. Sai Teli dna din tbl 3" Fev teapot in arg og fn eatin de och wi gpl corpse noe tae a Tens a ida cooete Stier denteine Ses neal sa cre eb ae ape ald ens el pst Secirenet aerate aueee koe erin tes aeant Gilkey punea te nd — Radu Xe} Teal Din reat potential chimie sy = alt) | RF ka Py Bewafia DuhenMargutes ari forma: Timitaren a8 efor “por, pat flue pie usin age eaayia os apliok att slutilor idem agian mone on ( 2 Diferiols forme slo eountics Duhem-Margules se utiieas’ peat vorifctren censstonet datece psperimentale Gad) 2 sti 43 an dre earl presume cope te vt Mpc seat) foe Sites ine te at a Deir etic i) ease ole Be ere Pa ete ccna oe ud noel ate Moc Ne Rice ci abort ciate cae Beet nae rose Becerra ast cats a eee bed i Pale irene marae hea ees, feapia Henry. gts ost Henry pone avid avetie neg EW] peal alls wee cal coal” cal i 4) 98m cals eciitaie 9 efron de seiaie ak wlio 4 dad acetic netdézind componengis puri rept sture standard. : i) Si alt vir exam de eee a alla aelic hans consent fhe ey tas tn bene ward NASA ec cemesoa abe li eat te fae Pe mora kezolvaro ©) Yolo proioni tule P wa caevlet ou toe ui Dalton Po > Py Nalorile sit dete in abel ts Heprezentaen grafick ohne ilor Pui Pap) 44 PX;] eto ula atau 6 in" Drape din eco — premier penta Male con Tonntegiebe Raga reaper Bye So Pe Ue Velorle_prosuni- lor de poe le ea Prieto pork in oafoem daeloe: ome mast Lg 2138 mm He Sistenual prea iter pully rompers Drops Maney stem tend sei, de teat By — AGI ‘late iting nen a bt cunha P33) Ia Prana y+ Ter ‘oct deeptd Hw ‘sontonata la Xf Pata ee co valoure KB % 64d ES ie : ‘mon Hg re on9 O waloers mat procist a sonsantei To ary oe objine din reproontat anoetulai Bye foneyie de 2X, gk exteapolaren Ta Xz C, In figurn 64 fate dati reporsntares di care rezolta AB = 450mm Hy, Ut) Activate si sofia de eticitae uiiind component ‘inp stare sandal sau caleul a el Sse Hemultatee exteslul sin redate | tabsls 69, ©) Peru a celewla activin 20) fovficintes ae aie ys =| z fae erlic_refritoace Ia pa standard iain inns, ae alieatcnstante tai Tene Via ‘AE 460mm Hg oli: oes XA Rezaltatale sit rodaty ta tabslo. 6. 1) Pail af Ky as) $h a8(%y) ee precnare n Thgur 6.10. Drop in aceegtfgurlreprorinté comportars Sal ye pets nmin (2) (ae a Oya a nnd dr 1 Bota in no San acd Fae a ae a ee” nine (1 Sepchenlenno ane pate, 2 ata = Ge Dubem-Margutes.Pik Splee’scaie’ DubemMay gules (nwhlena 615, 10 a), Ge), ) Activites gi voaficintul de avtivitata se ealeueaad yo mails Hezulusole gateullor stat (enpuratria DProzentato in tabetul 840 (Py, = 1 ate le toate ee Stopes oument (le oe Se ee s se oa | sam | ow | oc, 2) roprorints ise ‘| am lene o(ee)o" | eae siete pcan ot ae ve a | {0 pan pons da Fg BA an Tisstoerd” schematic Sade. Bguilaten rapertebr_ pont ute etean retin Hallas consetenta st dateae Lo a “Antnd cribviad Ie tohven (weld netic) 9 composite, 204 ig obi 4 Gs), on = a LGD hee a ‘Se poate conchae ot datoleoxpesimentals stat consistent. “Temperatarate inp «Pe (8 xe RUB, ar Alyy 8 670 cal- no enue cabricda ich eto matt maredecttea a waiddaten Osea nay X53 ge rats © varatia de enalpis ibrd de opie la prvtune cone, Vointe de tempera dip rela AG} = 3.1909 Tin 7 + oss 7, a $673 Kum ems cl Fe +» FuS ce Xeu > O87 eat th scibrn on (3 sol ran te i, Calcul oeficiinnd de activitat at etn opine dal, Rerolvare Se ulllvaans reatia GibheHeImhelte 2 Pin intagrane roa Gt; Pentra o serie de aligie opte de Zo-On 0x mdsurat AG AG Allg + AAT 1 pone ir Foam | rp : man conn ow Deore Ia Ty 6, = ei ine a or ee ? z (rfetite a ompoonil nok dg ware stenard) ted ptm de Deeps (ot es ave ear ig Pt, —— 66D T!— 126g T | 12h 20 1 Pie 7 —aolg Intgeuind valor sf ranjind 0 objine relia corn, Deourete a eehi- br ak ie (Dur) piconsidertnd 9, +27 Ya ve pe — pix inns To Ye = — (ot) ~ RT dn Xp, = — 80} — RP tn Yop ten T1678 a ob 106. Reroleare inde irre s det espunstos compo date i tempuratrilo d {mae naa lo ay pests de vapor Za pur28, Sinem apt {P)-ar elem glial moms (2) formeasi on nat Sloe i Depending composts se wmperatits de frre a omesonel acai Indie stnte aapee Wn Laan corepnsinare items nonllaes ‘date tbe GA. van baer ‘Dependent. preemie de_onpori de somseatar pear consiaenit. Stare ae (aptsh te eh gitol manos ste dat de seu 1g FE = 8002 — 100010 +230), Ie R= Atte — 24840 + 250, ‘Sits diene rmpratara con mai scieu si proinnea be care sistema went bint SRG Hi mae en ae C24) Pentre siateneat eceiond a eee eas fone | fir 260 mum Hg fe eh ‘abel 612. Saarcle uotst yan zolvare i sohlerea pasion compoaiiaamastecub cot Is pseu tisbore ao tabu i crnponetal eu puacl do etry cal 43 oe Din hod tao wound psi, amesetl nesta ispare. Prbns ite git tanipertara gt posfanen le sre eompouyt eos! aa propor tile spe companeatil pur, apa i anor) ri: (") Pontra on amaves coun: Sym Ya: (2) = FE z (ys — Weadee = {ha lerdae = Ne Te Avi yi ty ol i 28 61 PE int fanopi de temperatura ‘SU bofaidorko terporatent Ie ene eumpouitia tmestoculs) nsolayp propio do eonetituental pur. La aceastl temperatrt (ora — Ny) = im (ter Renolva poate eo van Lae Deonrece netivitaist componentalsi 7 tinde epee unitate, eonstanla di oewafin ful vad Lia egult ex (vert problema 624), len Balen(t iim, ovine ta xy, B= Ie ve wor ag —ssteeareei (i Devondeaye cortivienil de oetivitate de Hin aston 6 ponebal kzeot,digpare la temperatura Ia ears hy Juwalor componenilon pus gal x Bin ecuatia (i) nes ya ee 4 Hew temp porta, nterseoyie al olor da enue pact eat a rat oot Tishiteraport dave to tro rite consantor Tomar trai eta ompeaitia eae rose ate Wspeimate desea prin celia emiempi P holifents de Carlena g Colborn: 4 len ae (4 ms 2 sin conan dgondate do taper 1 Sali aleveCConsideriad comportarea_vapueloe allul eneftelgaplor de actvitite rel YP Rorultaslsealeuolor eet dats jn tabelul 643, 50 punto uliiza pew ‘ os eta ene ae cus cere wee fe ania 7 aman were Gre Sees Te figure 5 Walon” fe 1 ‘consantelr van Laat sole 13 Jorile ag, eseulote siat date in ; oe .25."Tnuro wvufn binant a dnteriinat ermbioarea dependenta te Peseta shane sata, fy frctas molar Ee as ta 0s Oss od Pmt. teachin Totaly Oreaptt apy cont ine slit owe, ele eine cet ‘tard Mantard "component put, a8 hn lati $4 m cabal: 1) avo btn doa (0) rarest ia sere nar naz nen ae Sar epee srl FAX} 91 8) ‘cia stant sie ropa sc std nia ts it lnynt os epee eb a) Nemechek SH oe repens dpe chesare feta makrd Xe Nexolvare xt 1} Tn coal om caret sonsidrcompariars reel Gi fara de vapor ae vitnte, uportal ln sta standard de eqponent pat ste dati do Wa = ta x! toms 05 Date a= + in eine 2 nts fagawitatea componntuly pur is infin ce fee analog: ye *E 08: Gorespunsilor frase molare Xe se obfin valoile a din tabylul 64 lel ran a aca en onan dena 0) Im casa miiisiris stérét standard a soluyiek a Aiuie infiniGh, activtaten ta bel 246 lt da eal bf Se obs opt = 0 nedserainare ponte ve. Valanen Sorexpuanatare a ponte cbfioe Pr id X= 0 be al Pree cu rela + cam roauli ugar dia reaylle enterioare Determinarwa ootiiontalu dh’ aotivitas apart le sola a dite int date in tal 14 sink przentite depondentel (Xs) i 4a* R28) Penieit um amesiee topit AgC oe ‘au Termine prin needa curbeor dere 4 cle den teil 615, siemal prion a cuctis ta Xayso= 08 5) f= BHC. Sasa aleze acivite si coeficienyt de acto entre SoC gf PDC to fas edit (fi component puri dept tare sendord (OBihnem B heal = mol ta NBG, {AByp)rae,— 87 Keal- mol! a 456°C, Sens east dependent de omperaturd 0 ntalpile ie pire Rezolvare So utils eolagie generale in pocbleme 6. nla Faas Ine nthe (lle : thecty Siac ere Deoue siemal formeaat evtetie, rele se pot aplica penta cae douk Tame ile digg de fan sere fale elke aint eatoponentt eet ager Ih hey = 1 Neaijind depontent defen ern tan “Tn topive, se obxin nlagate Se haa dene an L sat a form: r, In oa i enn Re Pe teh otha Goctiionit de avtivitte a6 cule on reli ci Maga Lag yc Gc! Naty Meauliatele ealelelr st. preven Cetin tae 0, i & pisses: alga de emesoars a 1 a0) de LO) ex 1 mel de abaol ee 200 Mpg =~ 82.cal Ia tomportara de GEC. Preianile de vanort ale comeonangdr snc ns anst: onde. P= O80 1% gh Py= 0.500 DB. Siw enleatess emropia de amenecws si enopia de eae a sisemalu. Rezolvare Se pat aaeute ative coor dot umponont x sitamului dats ze 1 ay = Fem ona sia 2 Entalpic Where mostocee va Sine = Ta, seepatt Ajay = 1987 313 (ln 0.8 + 0.0) = — SA ond Bntmpn de sinter te: Man Aloe _ = 82 4 46 Peo ae: 35 atria de amestcare penta sistema ial ae AHL — RE in Xp = ABT ln 05 a 03) atria de xaos sistema el: Fe Mtoe Ah 1 409 = 2755 82%, Conic de tiie friars componemol pu dap sae sur) ie ban tai sole te dat ria Inyy TAX, ter ee 0 cman eo mati a Swot epraciaa Senin ab svlontad fencje de Ny #1 4, Sd se sublease exprecile Denora potnjaat choice ds avast ontalpia iar te exes. 1473 ca) Rezolvarc Sr ilznink usta” GibbeDu hem in forma: Xd, + Yell, = 0 Diforstind rlain dat: does = 24 %1%, fe ltin dpi Fal RX = — 2A — XX, = VK ALY cae Aeoarove y= 1X, 91 a= — aX Integra ss dlny, NG BANA,ax y Fprosile potaatslgehimioo do exse ent CHE MTSE, antxts of = RTM, — ANT XE Enalpia Tiber do exeos ote OF oe Xyih b Xyed = ARTINAAE + MEX) = ARTS 1. Uzond cafe de rtete refer ta stron stanard cong rent prs pant sae en () eed ate (2) din problema, 89, ne cs pool kama deen island component 2 et eal ihe de eee (G8) en nto so factia,motardtlacnutas (X,). SA se re inte soft ancile HA), 281%) 91 OL) Reaglvare S» ulilaeasi eenajia GibbeDu hem, Relijado cate este: ous | oa | oa nel ao | as | oe ‘ume se ponte nozolva gmtie saw momeric, Se caleuleaxh. raponetale Xy/Xy rm defiaitiorwe pate see BAP ng: PAT to yg, GE Xysh Aylioind aenste rela ea eaewla valor din abwlal O47 (7 ast * | a ae Mn w ae vl | ei > | ee eee | | | Sa | Se {fn Figura 6.16 est reperzemiotat tos | Sh sipendem X48, —/ (i gee |e | ledge (de exemplafontoy y= | Mie} $888 | fs) obit emf, nd fl : fsa | Ahn de 1 CUR enpina ate YA gh My — O42 (aria haganut Reaslvatya marin se ne face fv figura 6.15 sot mprotentate ‘ ‘ rin moda Iapeaelae : cole funeile Xn, a8) 9h PX) sor A(R) alta 030, fn sinemot apa ( propamat (2) saa obfnun pera +(e) Jost aero eefcenlel e cirts re te pala olor din tala 48 Bt far Sone a ey a rE St walt efit de ova de cls). Husa alo lie ape, th ance ope idee in tbe 69, vis 680 roped fact de compra ‘omponentit puri fa P= 1 atm { temperatira sistatnt as fost eyo tri standard re 631. Pentru daerminaren ecvivitait plumule tn agin Ph-Bi va foost voir element galoonie ox eletol wp (> POPBCl, + LiGl + KOl|Pb tn BPD)ofa cecromotore aie a 0 presi wrmdverle vii ceaporimntat Me nes ax oon 0380 Ew, 38 sit 1050. Si se caleoleze ects gt eoftetnont de aeinitate pera VD tn ai Povbi de campo date. S Rezolvare osetia eletrehiies var ane lee. pit cenit dora plumbul Wa ano [ipidepunerea Tabla cated (-+). Procaul gob este Phe (our) <> Ph (ata) PB nha de entalpe liberi x processlai ete: AG sg oe) — Hn PH) ob ve obtie re 2-000 R awe AF — 3 p0s- 8544-700 tye th = BT Ina, Doouroe 1p keen 92 AG = Lay = 632. Yn clone saloon: CAT | C4804 CH Ha (ec dectoci snd salt (amalzome) de eadmiu tn mreur cs facia molard adit, rvpeisr X90 Ng Mercoral ae conser int ig) SA wy taubae forte sltromotoare a cementalié galvenio te pant Tee ge Xe LS 40" preanpentnd’ et eae corka. de folui iate, 1) Stind cf fviaeecromotoare dtr mina experimental este de 0,20¥, ssc elitece raprtl sufioogor de atte in sie dan whi. Rezolvare TEkanentud glvsaie propos este 9 pls formats din di eletrosi de oxen Tp solafen nat poncentata | in Deoaeoe Xr > Xi posi formind slut de concentra dle hijo an deeeaed, iar fn Gea duals metal so Gx) — OI +26 foot) abt GALAY (ond +) HAP HON) eae tm ps nr x4) 00605 x IT 510 5 y An) USM (yr 5g He) eee) ee a) Ponort solapt ate 1 Bo 05015 Me aE vB aoe oe ge 00615. ie AUR 2 — 1 ona 6.38, fy clement patonie ened) P| PHBH! Co Bred, OL aN| Cs ( Phis) + Gullniag, NOL M, eleeouit are) + PbBegs) + Cuts) ) Canossind Ia tamperaaara de 25°C, B = OOWRY gi eefcenat median Ute autvtate ponte CuBr tate 4 — O01, of we calles: ‘hy Sa be dettrmine saloaren prodewabai de soluble at Bromnrié de plumb ‘in 2G [BD Rerolvare a) Fora elctramotoare ete ald e0 5 te Powe — He RT a BT a wae = ess ayes = Boer Se f Set Chon + AE ne BE towing = doe + AE in PSE tn eon ME in SE eoarce P,{produmol de slublitat esta oxal cu: P, = ares ahen ar oe eget — Erinn oy — Sb SE I [ace the)sare: a. ote ntiitatn mie ond a edie de etiote Gath PTE (re nt 4 humdra) de Tank pole, nape “neg fia sn ua wolul de etry ound toil de reaulat pin dcore {cant ee ioe ta ln cate me veto aaitaten soli Alun: Gna)? = (mg? (J = fm (my (mOsm = An hme = Pim Pan — 0.0 #5, Meoareee =A, = Day = “ igen aL le mm mee mB SEE tum) = w+ 2 089) 0420—1 0) PO si b+ 047) = 42 4 0475 — date 2) Rapria tut Beate: ae Ba dy sd = deo — tame — fn, ae 28 0 rn wee ‘ Ue P= ae [ean 5 SEP = 72010 (Pentru ets gi chines veal snes VID. G31, 0. cabnive EP pom ebmenal pala () PUB, jg, atm) | Mig. Ae Br] ABC) euros sorte rie ckemooars, E, a ifr comers Se om eine hgca tieitd De hy o-M ee Rexolvare noha ont are bc fn pil ete + Aw Be (A) == Agteh + He Be 1 ing Beton @ _2ar ? Aroarer WS Ev mem Dur in va = — INGE (conform ait tinisd a ti Debs 0-H Oe keal) vw cane HE Gte u oanatakd earinteritieb Tie! solu: Oepeonta tt "eipeatur Amo 4 28 tai ELL t + nar rire ye ste se. Ginn 0, e Det A no [4 2BE a 4 F Reeriniod grafic Pee G +i cslempag Iain obine By. Din gues 17 a ohswrvd of son 65. Diagrams de fase empe anomie porn en de component te a prune eT at ene den’ fier 18, ncaa do 0c Pre dual wluempuratera de °C, eat divas pint ee recital Lihidall flebe Fer, Sim ratte i) Comgwsiia reselaatal, cy 8} compwsitie madi a sida: cin tata ah te dt, 92 soso de rst, Roaalyare Digan datd rprocin we sto innans ert ol romponen}s As Tt ‘St total mscliatitn fea8 eh tah in fee vapor Gye ‘apotike QV) sieht (24) Tin dete ecunfilegeineao dit enn 2) wonpeaiia seciuatus exe ot as neta : #5) oman mi iat ‘inal enalatape bom. vampe fife initise si finwe «vapor ithnvsal 32 onto my = 1208 + 85)—785% ime© onsierind ap masa de resid gp masa de amvsie infin de cope sep = TheG.A punstal ) oe pok serbia sy gy — zp lary 1e6e + ee = Mr fe (bilan penis A). Anind in counted lang rol feta = MD, Of ge-+ 0705 gy = 078 +400, = 286,00: = 1506, G67, Aral 9% aba formeash un comps chimio AuShy. Toate re stant cnt vovipit ain fook-ehit, dare frre § sla Fah ‘etudd Comowcd se date din tel 621 90: osolvind fy usb | Ava 1) sf sr wus diagramed fn, omprratnrcomposiie entra sea by pero sete leh ce comme 20% Shy 80% Ay ret tnt de de 1100'C in TAC, te trans care de orate a ongrants In tiny pen roves de rice 6 0 sxplie fare paral acartes fond drama Roxolvare 14) Cau proton obtine Aap de tate A ty 6.1, rao O a an By Ave das — gf Aa dig rh u a it eo 30 a 30 8D 70 wo oO Too Tia? ° ee, ‘ Canoeing tomperaturla de lop la endo dow metaln pure 9 note ys sndonmidpunetels gi. Temperarile de tpive ae elo dean eatetion ‘oezinraaime ave fe vepeesnth prin tater #95 21 (sobs aol Vila Panetele 8 2 afl la interna nee eriomtala tee in fy rogmstiv Len vertisle RC rides fx pune eurespunaator romping ‘pumice Aust (de par Se pert) ped in puncte core yunaitor tempetatat de toe coxipunu. Paget €esle vn fame ‘earaleraty formar op camper nia verticals KE impart dicgrems de Save In. dood prt ientiowen| ‘oom rsprenetd fieate in perc digreml ie ose a Weal sate lot eozapag total suse tare Hehiay ot 'vn sigur eutectic reels Au 2 Au, Ansty ~ Sb Catoseiad compote priului euletic se otfine puaetul 2 Weel ql wre 95 (ened eli frau snansnor se predens pentey puatol 1) Payar solaie eu eamposiie 20% Sh #1 80% Aw; ema do eBlee ve heptane gues 6, Segnalo tsnaly eee npredint 1 athe solaieh belo: 2 — racine mo nut a slot ti tore ae ‘onto de Re pr is wxeen ft de comport vtoctir al) aural mls stibrtn-g eontlate ae edlduet edt ew elu lut latent top, ton \Gnutal dal fue! chide seede pad atigezvacampoaite enterica HHT punctal eatetios perature #omign conan pina ee rid. ‘elite pamteu a objae AM emcee do AN gt SuSby tae. HU) 1a amesteeut ahd 622, Folorind date mtendul 82 sp sro diagramed fast penn sistem NaCLHS-A) Se prope of a farmed ide Reralvare otal ¢20 Go gjutorl deter din label prvind comporitia s- Inge # puncte de lngbelare Soreeponttoirs, as ota furiele aE, BC gf CD tin Figo 8.8, Se nteant str 6 ‘coneapnnstoate peta to tap a ately fi pools! fy pnotel until marchetes compo: age hit poe care apa my esi | 184 cite dies Gen ub form deapt deren | "30 | alin (S28 609i, 209%4). | 8 ztesma CF intenerieash | 38° | vervenla din in punetut é, | 360 impintind diame n dome: |e tilincar stem ete format | A oe din feat indieate Sn igus 1 teriporstue punetulil pertetio Cy jaferioar temperatur potatien de tape mcompusulit S24, acortadin ura me eseempune neonateBik 7a tes ee 4 Jn rola e armies wai tu tip tm oid por 838 wlai ones empl uncut ¢ Pe a ‘te we poate sere so eepar soli Mg eee lar pe amare CB 20 Si TaTaRt ard sai n= anpuna gmat ae frontal Mass 1) Conforms wate tiaras probe 838. In tion Sint presente date rat pr ane f fnpiturlr ds mage a et) nts sg ii as ropontta ste fu Suna dp eee waa at a ey St fall ex raponl BEAL Shee orl esa chi fret oe frie do swdatuo BOS 2) 98 9 caller q 7 ‘im par obi pe Feira 100 hee a (ard ce contin "3 tn 000 °C coma Resolrare 2) Analsn te ta ni inte oT iat eet liebe" tase al Sie to ipa Tete eta Inl poeaturi Carbele ob 199, cmos nro ows di aba 62, ‘Shinde wisn A Brio espwzetargoaied wemperatnh in Tones ae ae presi uti sunelocar de dir compen ae mance care Meche? Wiehe Pb. GG rs needo turk, exile. unor palure indice penle de topre Ni by gt ea no sa fermenter par, le amesecerton, to omgonen. Orie sehinbare pant indies einbarn mamane de fa rin roprezentaen gnick in lurior ce indiot schmidt pacts sé plies pc Siagrane dy fae sate 4h cual sisemula gy folosind tele din Fornarea une ecmbinati chimien, ou Aird de ev kompo nan fuay prnteun maim al wutbei do 190 ce 1 ale computor form funetie de composite 9 tnturr lempen or puri oso pusé tn eviena po degra Hh nibea. Tn Figur maxima eoespand ethane fai faa te tromse dia yeni Jac temp frm. Sat notte ficare pore aterm, fat preiree nba decir, ob labelul 62 ae obpial Usd pune 2, 10413 9h rapt, de te ae ig igus 22. lum amentae ce cuntine 6% Ma.Tikad eont do magle atm reste dai dl petal coeapeneiar doe i tpitur bo °C dt ied sek, ponete £2 Me Me tripe ounoseuih 3.6, B's obtioe8.10. In coset emai nar Sy, fe care Sf i dae ad omits oct etabh ita uemiioarels ar woh Asean . al x ae Pewee OR ew fiate te i ine sare so ing ‘Sia store splnamiare ane Sane per iterming ‘mld ¢ dingremet fuss os Rezolvare In figura 6221 praca diagran Toe Pooeiae Bg, 20 we lk Ean aS seme 8, Pinel serespe Me elt 625 Farol In sch stot as dag oplinea slat aetesre penn taunt ale hn fetta 77 aay ‘Rae date ree rete de enor Timatsi Acta ate, BETO 55-240 Lesyneavseeh ( ‘ind dose tie austin oto tome pits (lin 77) s0cepe Sphere i HD. tn woe ‘iugto teebuie trad Tinie 11, Ser tale hg emu tl (8, TS i stn (5) (9) -F (Sy =D) ee Stuaiainveret apa dad prions de vapor pote (S44 Se 2,0), vie mal te dest tes pests ere 8, “HO ioe dpm beth Trial ti 17, lat tale ty oxlibva detmpre ucenein ‘af 1S," 140) BHO} —'sp mapect va aoe) (Se Sy “Hkh I0)-F ()), Sub Hint 2 fazele AL. Bomar sitet vrmar format de Uchida A,B $i. 98 exo, urd nie date to antrnia Hrpiratara gi pesiane: — Bi 30°C si partake i ea te at ee rut ah Sibsanta Aste teat miocilt ee B91 Sib oe apres schemes ngrama fas. sistent eae nape ec oa iad hig ene ect wnt Oy alee ay oop cesar el ‘rll erate enue ces do aurel hala ste Ree Soa ieerarate alma aie tin, LEE 1ale =. is eee eran are inelioahg al eg PROBLEME PROPUSE 1, Prowinnee de vapor «unl sagi de meaite 5m evte ou 0.158 mm Tig ‘mei acdmati det postinen ape pure Ie tenperature de 20,86", Sh Caleleae Prositen de apo &apel ue I acest emperatard 3. O aoluie'ce confine un gram do mvbstant@ (. — 882) In 100 em, pro in 0 pasion osm de 560 er, ln OFC, wv ‘i se calcubze raportal = i i we comentene portal Eg 8, Si se ealcuete prsionnsosmtic a une slut cn un volum én 50 en ce confine 2 sahdr. Masa mule «sabia eto 2¢ “mel 4. Care este masa mola x dinitrbenrenli,daok a denlvarea yn gram in eos in 60 de benzen sida teperstute de feeb Brenna 4 020°C; constanta ebuloscopicta benznui este 281 ky = K-!= mol, 5, Si eo edleuloe constanta etalioeopicl ape dect ee slic «3 o saluie 8 euatine 0450 wren in 225 wd apt ie I confi normale de pre. ‘inne, fe tomporaturn de 100, °C, Sie company renutatul én valonren woreticl a constantel ebuloseopivn a apei (0518 kg =} = molbop eulealae ebldurs abot do apie « aa ylvent fiero te 127°, eonsabant Ta 2°, gh ore Alloy ule eetah solvent fierbe le HETATC pl eohgelauet la 2553 ai el oe opel a, a ea s Prsnma deport Remtemaok pu uealul 20°C ete 7h 2 Fig rspeety 22 tn Lg, Sas alesis presi prtigh ale buxazoul Uiblugmalar gc peesunes ala evap on sha petra once uch sin banal ato 09 9. Doni lise nemisibile A 95 B slot diatilate in amoaton in presi Mauss, he tamperatara de BI-C. Lea goa toorathd resus de Sapa eonponsntalr 8 nt 2 = 355 He ‘Si betdutoritinesisee marin component B, ae dstilatal conti ‘Sieg mle Ay far mea mularé a componentalss A ese Aly = 82. 0. Prsiunsn total, Pty cau! unui anstee ideals poate termina oon foom tiger tet OWI: 4 PoP SMM, iy cares PP oh Ph ata psc ds sapon aleTicideee pure, ae Py 1, a Frio peas de vapor le Canpanenelr Ix Fomor Px, Nvamentcniue Gontorm fei fei Dalton, fenfile molire a Thmonenior ass eens snk ‘Shap anata 8 ponte 1 eaalat eu rola pb en A= yA A {1 Activites commponentolul J tro solute him este dats de eouapi Riva =P hn Xy + ANE BM, la care Ny Np sntfeaofile molare, iar A, B, constant. Boustia este vilabil i fret denen de crumponigi Sire davroine oxprosia pentru activin comments 2 e 12, La deternicaren,aotvitayi Gu tn oliajol Cu-Aus eau mavens la 77 snvmtoaels date Xa 0 01 02 04 068 08 09 4, tm 9 0015 O08 0102 03 O71 09 10° ‘4 wo ealoulezeactiitatan Aw I ales rt mone 5. Dow fuze lihide formato de oubsiontale patil m inte solujie biowR eu doterminet fugusitttes substanjet danlvate 1 fonote db race molar Xo 02 4 oe 19 ho 8 DAS Gad Gas eA Si se saloutere aclivtiile dimteate ulieind eunpote ieceaeke ceveaeriel as wince ior imp sane stn La pao # tn aaa i il mens a "mesteeemetrop con{iniad 894% malar in pal cespononts Tepe ‘atin de foro w azenopui sin TSC. 9 ge der 4) constantolb A gi B din eeunide van Lea ay 2) compozitie aaeocpulol 2) preionet total corespanzstaaee temp um le flerbore de DOC duct 4 si B au sa media, Poorivaie Co ‘pri filer prs In ag att ible A gh sat th oatunt In ella. Se insiders pe oetielenit de acti su standard de component por femora sprit sito (Couvenfia inetrieay in pn in faze Ha eawfeuethe molec vamp Tentolat Acate Ny Useh Vegi. ant event de activilate cones iri fn celal fad de fence molar iq wo ara existe eli Xalvsre — vive) — 2s — 1: . Pentro un stom Dinas sa ebjiaut wcsltoatele date exporientale te ful ei 2): ork te temperaturd constants (resiune total-comse‘Se neuter: ©) presiunie partial $i vorticiei de activitate vy y95 1) etal ber de exien: ) Sabie Hit ae oefivinntlor do eoivitate Sie vevilioe consistent dstlarexperimontaty wild éenatia Du he mis Margules {In sstesmal dimatiltormamé (2) -benzen (2) sau determina’ urmtoarelah Aina de eclins Tiettt-vapint ba terpeatara Te] ee [oor [es [oe [osm orm [om [ow | $4 te valeuleas: 1) prsiunlsparfisl #coeficontil de ativitate wy ei 5) exmsianen Ini Henry KE si coetvient de wetivitate Si ve rofirerint gation ty $i Ino faneja do Ku Sse ealcauy tomperatura i ene ae lon antrenaren cx vapor de ithtame) 4 byneulus tolenhal, -tisut 9 airabennet a (rE pam ig Ge eats spa ean cesar pent. dst 1 tn g din ticeare din esate vobatano? iam Fa Sisemul benzen (Z}-toluen (2) se omport tel je un deni leg mera Solniad dates din tbe a oe alle t) prestunle de"veqn ab compen pus 1) Aira do faut presiiwesorpostie a 30°C 3 90°C: 4) dagsnn dh. fae Uenprratuet-omportie a P= 0) mun Mes ‘) tomseb Tosco 9h componjie acetoek Ia eciibra a t= 00° Beynon pentew un antertnc iif de 200 gen 4% molare. bonzeny 10 fol ee] =] ereamane | var [aa | ame, | sao | aise Yea | en | recite | wa | we a Vea | remmne [aaa [oar | om [oma |e | oe | | me 2, Capoacind vemitoarsls dats. esperimentale ks ealeulea eqordonatele ponetulad gutoet reaultatala cw varie mmolare Ey vac = 0,095: tis we compare ‘periontsle: ‘etnpeature —OE. gi tree a — OD tian digs de fave tempernturd Paden mens unontad ee 045 cal aot, Toad an 220 8 (Allan Si determine coondensteiapunctalu nuentic tsa nec topa 11 eg de amesneeuteetiefrmuidonataresiae idol Sedan emporatee fe ncopat de eratalizans ifort composi «1 [ali] an] ana] ar] a0) an] a9) nae] on ee ee eee : [-4 Bl] a] a va 22. Contra HIgh _ ar tn cae (Cpt 3 (Gt sat mfsurate In vecfodtaton punctlui de toi, oe» obfing pe basa esuayiet Schroderean Laan Tehticn 2 (aghor (44), (WC RT USCA 1 nan d A 4), ae op, TE ae yee ie, Kise ealeuleye concentraia slain wtarate da it jenn (ay) = 5 Sten sump {alba abil dai ae sda lag = eon mpere Mamata (Cp) = (Ci = (AC = ens,42. Comporifia wor stoate do fnulopa 9 apttenot ele uaa eB or oe eee 1 tae peti sie a seaman oe ats Ste trata eurbol de Faery pentea on stem compra Iedieaa de" ssenia (2) (98 Diageama de fasn 2 wo stom fort dia dot tomponenti Beste de pul poveontat $0 ort 62, Si aids ceules 1 Sie construed diagnos de fe terupermtor-tomporife alse deter 4) lee temporaturt va tnoepe aa AA 2 ‘nine comport punetull crite do diaclvarepunteu iy = 2G, oli tee Farha ut ammuiee de ASCE de eo toda devpiek mois vw prob 5.18) composite 73 molars A a cn i 4) vate oto competi reziunla deck anestanl ds ln punetat (x) fast ila pd n'y Temperatura et 15°C mai recat dei ew fearon neo inrbonel cnr ea camponitin meaie » ditiatuli obfnut le purctul (8) 21, Curbole de new puntra aliajy GiLSH pivzintl in functio de. procatal In grutate de Ca unmitomels puncte de echinbors pantet (bell 1620), Ske sehifow ogre ie fe gis we stableasc fran exilonta tn teoare damental aati, [os owe [a |e 18 |e [oa | a s a each e 8} non DiS racers sire] — [a |e Jaw | — [om | =| = ol [oe [an [om [ow [ue [em [ef - “ pa | % iy al 25, Si sues diagram nium 25 i eo ontaeerie apall eae Finare diag nine oan nn la reals 4 4 s #) cave este tamperators initia de fisbere i rompesiti prime ete gente mie eer ey 8045) + 1220548) = $04 0) sited gh -vabaran coal Stamey Hur rane lel fim '# ss bine ain L es Pan 3 jumperatura dv SAFC, constanta de eckitibra, Ky are saloarea 8 peniew i (Me sin paaie expednate Op leery Er pe cme Fee, 1) Soe bat Ky ox ta Ne 1 Soo ete: ln OTC 1 Para recta on aa Sa ae 280,10) + Oe) = 28048). eee - a, evap temporary, SOFC, sto sri expresilepodra Ky. eB #8 ae u-8 lr Prin vok}e we posta seis gi tn forma pavivare y ay Seat 40.238 k= — am oe Ton Cod De unt rem: 8) (Rehm sag ~ 800 ton Har" ah ge ake Yh AKT ath aaa YBa ee 76 m0". * es = On ve Forma cuit MA ete doirmiat deal duilentormen din vla.a a ee 8, ropewnlanes fue (aye) ar fy deapta FA a) Wea petty = Hate Valle feneies ¢g— 248) In punctele E= 0 ¢ & = wi : (Ky = 2 — y= 485 10701 ee ee Aylin aia abs: Sete igr REPS! selewtectecs conara ds sehttre Ky pemrn raciat pica Be orp Wien = a te tempts de 18159 i pein tl 10 etm, So om pes sepeleg red eet oma te ste ate de ecilbra, tn procence de mana: Tha%, Nig) 1128S ce 7980 a eke = 72 + 1308, ezolyare : Bi, Cf nt Coortanta de ebiidra Kp wate ext cu 6))s0 s¢ fatale trporaioa’ ts ce a ofie aitod pda set 2 ‘ bad aera ve ioe eisai ties einer ep nee ke Bp ge a eee m= [N) 26h) -+.04e) = 2004s); (AGR, —s9400 — a4,9 7, () CaSi0(s) = 200) + Si) + Oe); (ACR), = 267 400 — 476 7, Si considera 8 prosanen eid de carton resale din rodacre le vit wT atm, ta homperture carat Nomssele dno din tieare component: me = 3,48 race mar conrpunaitoue tN hes OB) oe Oa Alamoit Kp = 1 A AIEEE mn ins te cote in Gis On cody aa Me ro lvare in dunaoe eslor dud aot chim (2) (2) x0 ebyine Mi) CeSiOfe) = Bais) Sif} BOG) gi tarspunadioe 4 AG} = 194300 —a85 7 fo =1, timpoutara tort objine pero MG = — AT In Kym 0. 19450 Rezolvare Prin adunares color dov8 ret dato we bine: 2eag040) + 9) = 5Ca(s) + C04); AG = 28. onstanin ds ech 9 regi esl: p= Po Dia lain ental Hire stand 86} = ATK, Drone, ty 247K. 194800 WS T—0 gi 7 Bs Presi vepordor de apa je ehira cu on ameste de CaCl 58K gi reapertes C000 at Go 8 Gal MYO (0) cae 132 ten tn 3 aK. ) Si oe serie expresia eonsiaick de clbr® Ky ) Sa me ede ware content de ocitbrin Ky te eve dowd tom 1) Saw dbrmine dace CCye 2440) ura cnr pssild wit Pla te tna de porta ape fe 2M Kae 13 mn, obtine: fn Peo = =! = BS Pon 390-100 Monn Pam GE ik Wh Poy = 3,85 10a ¥ x qty, eke ‘ stabi te 291% tm contact 8 Siebtoed dojohtnte de temper a lpi fa consancl ewer penta roe i‘ ) MnO(e) + ate) = Ming) + ,0fe) crass variate emalpier Whee sunderd ts foto de 2) Made) = vem + 120K @) Me) + 12040) = 104 se) Bebilibret pote (8 sens 211,069) < CuCl HOG + H,O18) cut Ke= Pao. La tempera de 38 Ki Ky ~ 032, We sompernura de 204K | Re = 04 ) 4 ray He — 0185 ater ‘tats Rezolvare Prin adunavea reacilor (2) + (2) sb obfice rae (1). Corespunsitor: (AG, = (AGH, + (AGE), = 96.400 — 194Drouroce 0.049 atm > 0.0148 atm, CuCly:211,0 mu evto stail le 2 Ee o Pim its cosa ninin de manga Hn for nies seamed ape ae , rea din fi. i fons 9 volte tral et memtennl) ce tte Lapabild 68 080, ‘> simatan ea 1%" (nat) sieve i fer, a 1EIL Ky pera 9 forme an Wet SE entra constants de ection tu 1873 K pena eo i pir. St de cual there sanded. ponrn rea chine are tot in Be pit 7 Uy (0+ 04( atm) == S04); AGF = —217 570-4 470 7, 2A + 107 = nays) 2) 2M0] + 05am) = Mino); S6R = — 19940 + 2925 7, in cre paramere mahi (| ramified. amstotedtote (eh Fo). Se thgandntte ae prac enfant dink vs Parameste dene somifcdeubnant diaste (in Fe) Nagas ane Cocfiviennad de activivata al sidieiatai dizolvat in fier ta 1873 K este ALOys) = (A) AO} = 06 250 — wd 7 + = 0176 Ab = 240) 30) = 25 40 — 1407 15 Ode) = 910); 6 ~ 29 38 — 1907. Rexolvare Penance miei semis fah lishide pur. Pn aati depute Reser 2M, (ata) = 230 (a) vain enti libeer de wartie, AOne entra eosin do oxidare a eluminivtal din Wat ta tie, conmianty de E rae Ming = 36} RP ly the oe ito, Rye Po, —1 sie = (io enn format wna oid in stare, Axe i) me Tone ar ostre AO, ete oh prt ax Ming A68 + OT ly 364 2H may, tunel: A =— 1 . 4g ts foe ‘sci in cam oxi a 1% silica conginut in ip vrai ental! Hoge Eilon steve due Sami cu (ae ain i «lite Coromuaritee mena. Aas = “Zak daz nil coe Nieto ania atin odin ig Ky = 51000. Pent 10 $b digWvat in tes Xu — td se oe me ae LaBare: (AG 86600 ea Ta 187K renulls = 2.10%, ce: Se | ae eas map 9 Mea ‘wate sti ia a vo ae a 2M lat I) +30 eit Fg aN, In com oxidit mangnls, dim dates problemi ee ioe ene — Ane (Spr = 100800 $9625 T— ORT In Naw ‘Sia 4 mangamil se yor oxide simultan dae ANNs < ALO au (8Gr, = (SGrz)_ = 90900 en fn nee nat he nee Deol: Ig Nig = —1417 si Nw = 0,067, oven ov repretintd 0 concentnatn for snes a Wea de" 6745 Mn tn tie Inveonclarie » pba ip lia) de fir eu mingan ce contine ass) 1% Si ovidesza tn'1872 K de Tu'un continit avai mare de Os, Mie tat Se bey male po ae tract tate anze si wlide < AMO: <= 2c A> = 2 ‘oct ene Yeas segs coun ach sunita partihe eect pent Petia ct cae sn tat mate dma at 2 wn + 4 Bini = Bit He +m) zed» + ry 3 ere 196