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  • Carbon Dioxide Gas Absorbent Containing Lithium Silicate

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    Carbon Dioxide Gas Absorbent Containing Lithium Silicate

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    Carbon Dioxide Gas Absorbent Containing Lithium Silicate

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    © All Rights Reserved
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    22 vizualizări18 pagini

    Carbon Dioxide Gas Absorbent Containing Lithium Silicate

    Încărcat de

    Seyit Avcu
    Carbon Dioxide Gas Absorbent Containing Lithium Silicate

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    © All Rights Reserved
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    2) United States Patent Masahiro et al. 06387845B1 US 6,387,845 BL May 14, 2002 a0) Patent No.: (45) Date of Patent: (54) CARBON DIOXD CONTAINING L GAS ABSORBENT THIUM SILICATI (75) Inventors: Kato Masahiro, Naka-gun; Kazuaki Nakagawa, Yokohama; Toshiyuki Ohashi, Kawasaki Sawako Yoshikawa; Kenji Essaki, both of Yokohama, all of (JP) (73) Assignee: Kabushiki Kaisha Toshiba, Kawasaki oP) (+). Notice: Subject to any disclaimer, the term of this patent is extended or adjusted under 35 USC. 154(b) by 0 days, (21) Appl. No. 09/527,229 (22) Filed: Mar. 16, 2000 (30) Foreign Application Priority Data Mar. 23, 1999 GP) 1.97199 Sep. 30, 1999 GP) 11-280667 Dee. 17, 1999 GP) (1) In. cl? (52) US. Cl (58) Field of Seareh 11-358956, BOLJ 20/10; CO1B 33/32 ‘302/407; 423/230, 423/332 423/332, 333, “423/334, 265, 275, 230; 502/407 56) References Cited USS, PATENT DOCUMENTS 3084712 A * 3932140 A. 81972 Bovard 1976. Jayawant ot al. 44042482 A + 8/1977 Shannon et a. 2oveaz SO7SSIS A * 12/1991 Ueno tl 361/321 5.298475 A * 3/1904. Shibata et al. ‘A * 12/1996 Donne eta S01/33 5755940 A * 5/1998. Shindo owns 5.866,000 A 2/1909 Nakagawa et 5,925,180 A * 7/1999 Frank et al. 106/35 6.085015 A * 7/2000 Armand eta 385/140, FOREIGN PATENT DOCUMENTS DE 198 42 298 3/1999 oB 2154222. * 9/1985 cB 2.159.805 12/1985 OTHER PUBLICATIONS. Derwent Publications, AN 1999-584169, JP LL Sep. 21, 1999, Kazraki Nakagawa, et al, “A Novel CO. Absorbent Using Lithium Zirconate Ceramics”, Chemisiry and Chemical Industry, 52, 1998, pp. 285-287, no month, 3746, K. Nakagawa, et al, “Chemical Absorption of Carbon Dioxide Using Lithium Zieconate (1)", Proc. Ana, Meet. of Electrochem. Soc. Jpn., 1997, No. 3F1, no month, Ryuji Matsuhashi, etal, “A Study on the Efficient Removal of CO, from a Coal Gasification Combined Cycle Plant”, T IBE Japan, vol. 112-B, No, 6, 1992, pp. 531-537, no month, A.M. Wolsky, et al., “Technologies for CO_-Capture from ‘Advanced Power-Generation Systems”, U.S. Department of Energy Report, ANL/ES/CP/S80346, 1993, pp. 1-19 with cover page, Aug Norio Miura, etal, “Stabilized Zirconia Based CO, Sensors Combined with Carbonate Auxiliary Phase”, Chemistry Letters, The Chemical Society of Japan, 1994, pp. 393-396, ‘no month, T. Ohashi, et al., “Acceleration Effect of Potassium Carbon- ate on CO, Absorption in Lithium Ziteonate Powder", Proc Foll. Meet. Elect. Soe. Jpn., 1997, No. 2G31, no month, K. Nakagawa, et al, “High Temperature COs Absorption Using Lithium Transition Metal Oxide (1)", Pro. Foll. Meet Elect. Soe. Jpn., 1997, No. 2G32, no month, K, Nakagawa, etal, “A Novel Method of CO. Capture from High Temperature Gases”, J. Electrochem. Soe. , vol. 145, No. 4, Apr. 1998, pp. 1344-1346, J, Tsubaki, “Current Inorganic Membrane ‘Technology for Gas Separation and Is Application to Carbone Dioxide Separation”, Membrane, vol. 19, No. 3, 1994, p. 146-154, ‘no month, T. Yoshida, et al., “Development of Molten Carbonate Fuel Cell (MCFC) Power Generation Technology”, Ishikawaji- ‘ma-Harima Engineering Rev., vol. 27, No. 4, Oct, 1994, pp. 125-134, K, Shoji ef al., Proc. of MCFC Seminar, 1993, pp. 45-54, ‘a9 month, * cited by examiner Primary Examiner—Steven Bos (74) Aitorney, Agent, or Firm—Oblon, Spivak, MeClelland, Maier & Neustadt, PC. 67) ABSTRACT Disclosed is a carbon dioxide gas absorbent coataining lithium silicate reacting with a carbon dioxide gas to form lithium carbonate and represented by the general formula, Li,Si,O,, where x, y,7 are integers meeting the requirement of x+4y-22=0, The lithium content x in the general formula should desirably be at least 4, 28 Claims, 2 Drawing Sheets U.S. Patent May 14, 2002 Sheet 1 of 2 US 6,387,845 BL FIG.2 U.S. Patent May 14, 2002 Sheet 2 of 2 US 6,387,845 BL US 6,387,845 BL 1 CARBON DIOXIDE GAS ABSORBENT ‘CONTAINING LITHIUM SILICATE CROSS-REFERENCE TO RELATED APPLICATIONS ‘This application is based upon and claims the benefit of priority from the prior Japanese Patent Applications No. 11-077199, filed Mar. 23, 1999; No. 11-280667, filed Sep. 30, 1999; and No. 11-358956, filed Dec. 17, 1999, the entire ‘contents of which are incorporated herein by reference. BACKGROUND OF THE INVENTION ‘The present invention relates to a earbon dioxide gas absorbent, particulary, 1 a carbon dioxide gas absorbent ‘employed in an energy plant ora chemical plant that utilizes a hydrocarbon-based fuel, in a system for separating and recovering carbon dioxide gas from an exhaust gas of motor ‘ars, of in a refining system of gas supplied into a fuel supply section In an apparatus in which a hydrocarbon-based fuel is ‘combusted such as an engine, the exhaust gas release portion adapted for recovery of a carbon dioxide gas is heated to a high temperature not lower than 300° C. ‘A methosl using cellulose acetate, a chemical absorption method using an alkanol amine-based solvent, ete. are knowin to the at as methods of separating a carbon dioxide gas. However, it is necessary 10 suppress the inlet gas temperature to level not higher than 200° C-in any ofthese ‘conventional methods. Therefore, for processing an exhaust ‘gas requiring a gas recycle at high temperatures, the exhaust gas must be cooled once to temperatures not higher than 200" C. by usin, for example, a heat exchanger. Inthe case ‘of employing these conventional methods, 3 problem is brought about thatthe energy consumption for separating a carbon dioxide gas is increase. (On the other hand, Japanese Patent Disclesure (Kokal) No, 9.99214 diseloses a carbon dioxide gas absorbent con- sisting of lithium zirconate that performs its funetion under high temperatures exceeding about 500° C. The method

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