Breakup of silica agglomerates in corotating twin screw
extruder Modeling and experiment
Extensive experimental studies in silica agglomerate breakup during compounding with polymer melts of various viscosities and polarities in a modular corotating twin-screw extruder were conducted. To avoid a subjectivity of the full total result, due to small size particles involved, silica agglomerates were seen as a measuring their mass typical values. Increasing the screw quickness, melt viscosity, and silica concentration were found to increase the silica agglomerate breakup. The effect of these parameters on agglomerate breakup was ranked as follows: silica focus > polymer viscosity screw revolutions per minute (rpm). An excellent correlation between silica agglomerate breakage and power source was also found. In line with the experimental info and dispersion process, a composite modular kinetic style for analyzing silica agglomerate breakup during compounding in a corotating twin-screw extruder was analyzed. The kinetic constants of breakup and reagglomeration of silica agglomerates were calculated using the stresses applied to the agglomerates and their cohesive power. These constants for silica agglomerates were found to be not distinctive at increased concentrations significantly. The latter was in contrast to experimental info from available literature on compounding of calcium carbonate with polypropylene where the excessive reagglomeration kinetic constants of calcium carbonate in comparison with those of breakup enjoyed a major part in the agglomerate breakup. Evaluation of the experimental and plastic compounding machines calculated outcomes on the silica agglomerate size development during compounding with polymer melts indicated an acceptable arrangement between them at increased rotational speeds.