Problema 10

a) PFR (isotrmico) y CSTR (adiabtico)

Balance de materia PFR
d F A
=r A
dV

r A=
v

dF A d [ F A 0X A F A 0 ] F A 0 dX A
=
=
dV
dV
dV
XA

dX

dv =F A 0 r A
0

XA

dX A
dX A
= F A 0
r A
0 k C A 0 ( 1X A )
XA

V =F A 0
0

XA

V =C A 0 v 0
0

dX A
k C A 0 ( 1 X A )
XA

0.3
V=
8
9.736 x 10 0

dX A
e

7000
(
)
T

XA
10

V =3.0813 x 10

( 1X A )
dX A

7000
)
T

( 1X A )
T=313 K

XA

V =3.0813 x 10

10

dX A
7000
(
)
313

( 1X A )

XA

V =1.59
0

dX A
( 1X A )

Balance de materia reactor CSTR

F A 1F A 2+ r A V 2=0
F A 0 ( 1X A 1 ) F A 0 ( 1X A 2) =r A V 2
F A 0F A 0 X A 1F A 0 + F A 0 X A 2 =r A V 2
F A 0 ( X A 2 X A 1 )=r A V 2

V 2 X A 2X A 1
=
F A0
r A

V 2=C A 0 v 0

X A 2 X A 1
r A

V 2=C A 0 v 0

X A 2X A 1
X X A1
=C A 0 v 0 A 2
k C A 0 ( 1X A 2 )
k ( 1 X A 2 )

V 2=v 0

V 2=

X A 2X A 1
7000
(
)
9.736 x 10 e T 1X
8

A2

(0.3) ( 0.5 X A 1 )
7000
(
)
9.736 x 10 e T 1 X
8

V 2=

A2

(6.1626 x 1010) ( 0.5 X A 1 )

e

(7000
T )
T=363

10

V 2=

(6.1626 x 10

) ( 0.5 X A 1 )

7000
(
)
e 363

V 2=0.14172( 0.5 X A 1 )
V 2=0.0730860.14172 X A 1
Balance de energa:
m

T0

i=1

F A 0 CpdT =

F A 0 ( X A 2X A 1 ) H R (T )
a

i=1

i=1

Cp i= v i Cp i productos v i Cp i reactivos

Cpi=( 2 ) 0.6

MJ
MJ
1.2
=0
Kmol K
Kmol K

H R ( T )=17

MJ
Kmol

)(

F A 0 Cp A ( T 0T )=F A 0 ( X A 2X A 1 ) H R (T )
1.2 ( T 0T ) =( X A 2X A 1) (170)
1.2T 01.2 T =( X A 2X A 1 ) (170)

T=

( X A 2 X A 1 ) ( 170 ) +1.2T 0
1.2

T =T 0 +141.667 ( X A 2 X A 1 )
T=363

T 0 =313

363=313+141.667 ( 0.5 X A 1 )
363=313+70.8335141.667 X A 1
X A 1=
0.14705

V =1.59

20.8335
=0.14705
141.667

dX A
=0.253069m3=253.069 L
( 1 X A )

V 2=0.14172( 0.50.14705 )=0.05159 m3=51.59 L

b) PFR
Balance de energa
m

T0

F i 0 Cpi dT =
i=1

Q=

F A 0 X A H R (T )
Q
a

F A 0 X A H R (T )
[ F A 0 Cp A ] ( T 0T )=F A 0 X A H R (T )[ F A 0 Cp A ] ( T 0T )
a

F A 0=C A 0 v 0=3

Kmol
m3
Kmol
0.3
=0.9
3
s
s
m

Kmol
0.9
1.2 MJ
(
s )
Kmol 0.14705170 MJ
Q=(0.9
) Kmol K ( 313313)
s )(
Kmol

Q=22.5

MJ
s

c) Sustituyendo el reactor
Balance de materia:

r A=

dF A d [ F A 0X A F A 0 ] F A 0 dX A
=
=
dV
dV
dV
X A2

dX

dv =F A 0 r A
0

X A1

XA 2

XA 2

A2

A1

dX A
dX A
= F A 0
=0.9
r A
X k C A 0 ( 1X A )
X

dX A
8

9.736 x 10 e

7000
)
T

3 ( 1X A )

XA 2

V 2=F A 0
XA 2

X A2

V 2=0.9

X A1

dX A

9.736 x 10 8e

7000
1.2 ( 313 ) +170 X A
1.2

)3 (1 X )
A

=0.060842m3=60.842 L