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COMBUSTIBILI,
LUBRIFIANTI ~I
ALMA MATER
Cluj.,NAPOCA,200~
PRof.dR.iNq.
NicolAE BArAGA
Poof.dR.iNG. NicolAE BURNETE
* ~Ef IUCR.iNG.ISTVANBARABAS *
Pnof.dR.iNG.AURiCAcAZII..A
CoNf.dR.iNG.
NicolAEFILIP* PRof.dR.iNG.
AIEXANdRU
NAGHIU * iNG.floRiANDAN
COMBUSTIBILI, LUBRIFIANTI~I
MATERIALESPECIALEPENTRU
AUTOMOBILE
ECONOMICITATESI
, POLUARE
.
ALMAMATER
Cluj...NApOCA,
200}
PftF~'A
#
ultrasanareaaeestora.
Lubrifiantii se trateaza sub aspectul proprietatilor fizice, reologice, tensioactive~i termice precum $i a aditivilor folosifi pentru sporirea eficienfei uleiurilor In
funclionareamotoarelor.
Se face clasificarea uleiurilor dupa viscozitate $i tipul serviciului # se precizeaziiuleiurile multigrade cu durata lunga de utilizare.
Uleiurile pentru tran.fmisii mecanice $i automate precum $i unsorile eonsistentesuntcore/ate cu particularitatilefunctionale
ale motoarelor.
$i la electrolitiipentru acumulatoare.
-.
\,
ale
injluenta dozajului
Reducerea poluanti/or se face prin intermediul combustibilului, prin neutra/izare in reactori termici $i eatalitici.
Geneza, masurarea $i redueerea fumu/ui este exemp/ifieata pentru motoare/e
de putere mica, mij/oeie $I mare.
Parametrii de control ai emisiilor poluante sunt corelati eu norme/e reeente
eare limiteaza po/uarea produsa de motoare/e cu ardere interna.
Se trateaza'ciclurile de incercare la poluare: ciclul Federal, ciclul Europa $i
ciclul eu 13 punete de testare. Se prezinta sistemu/ de pre/evare a probelor $i masurarea poluanti/or.
Poluarea sonora euprinde: sursele de zgomot, reglementari/e $i unele tehnici
de reducere a zgomotului la motoarele pentru autovehicule rutiere. Se face calcuful unor atenuatoare de zgomot $I apoi se prezinta traductoarele, analizoarele de
zgomot $i unele rezultate ale masurarii zgomotului.
Lucrarea se adreseaza studenti/or de fa specializari/e de Autovehicu/e rutiere
$i Automobi/e, putand fi consultata $I de a/ti studenti sau speciali$ti care au tangen/a eu motoare/e eu ardere interna respeetiv eu autovehicule/e rutiere.
Autoni
CUPRINS
3.2.].StareafizicAa amesteculuicombustibil-aer
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38
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40
42
...46
47
47
54
55
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60
62
64
65
~TECUL
COMBUSTIBIL-AER
5.2. IONIZAREACOMBUSTIBILULUI
5.3. IONIZAREAAMESTECULUICOMBUSTIBIL-AER
65
66
71
5.4. ULTRASONAREACOMBUSTIBILULUI
5.4.1. Principalele efecte ale ultrasunetelor
5.4.2. Dispozitivede ultrasonare a amesteculuicombustibil-aer
5.5. ALIMENTAREA MOTOARELORCU ARDEREINTERNA cu
EMULSn DE COMBUSTffiIL ~I APA
"
BffiLIOGRAFIE
6. ULEIURI LUBRIFIANTE
6.1. ULEIURIDE BAZA
6.2. PROPRIETATILE ULEIURILORLUBRIFIANTE
6.2.1. Puritatea fIzica
...
6.2.2. Proprietap reologice...
6.2.3. Proprietap tensioaetive
6.2.4. Proprietati termiee..
6.2.5. Alte proprietap ale uleiurilor
6.3. ADITIVIPENTRU ULEIURI LUBRlFIANTE
6.4. ULEIURIPENTRU MOTOARECU ARDEREINTERNA
6.4.1. Clasifieareauleiurilor dupa viseozitate~itipul servieiului
6.4.2. Specifieapi ~ievaluari de uleiuri pentru diferitesolicitari
6.4.3. Vleiuri multigrade ~ieu durataiunga de utilizare
6.5. ULEIURIPENTRUTRANSMISn
6.5.1. Uleiuri pentru transmisii mecanice
6.5.2. Uleiuri pentru transmisii automate
6.6. UNSOR! CONSISTENTE
0.6.1. Proprietatiale unsorilor consistente
6.6.2. Unsori eonsistente lubrifiante ~ide protecpe antieorosiva
6.6.3. Lubrifiantisolizi ~ipaste lubrifiante
6.7. ASPECTETEHNICO-ECONOMICEPRIVIND
UTILIZAREALUBRIFIANTILOR
6.7.1. Consumul de ulei in motoarele eu ardere intema
6.7.2. Degradareauleiului in motoareleeu ardere intema
6.7.3. Regenerareauleiurilor
6.7.4. Apreciereadegradarii ~ia sehimbariiuleiurilor
BffiLIOGRAFIE
7. ECONOMICITA TEA MOTOARELOR CU ARDERE INTERNA
7.1. NOTIUNIGENERALE
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85
...85
85
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91
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94
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99
103
105
7.2. ECONOMICITATEAMOTOARELORCU
APRINDEREPRIN SCANTEIE
7.2.1. Posibilitatifundamentalede marire a eeonomicitatiila MAS
7.2.2. Alte mijloaee de marire a economicitatiiMAS
7.3. ECONOMICITATEAMOTOARELORCU APRINDERE
PRIN COMPRIMARE
7.4. OPTIMIZAREACONSUMULUIDE COMBUSTmIL iN CONDITIILE
LA LIMITA DEFINITE DE NORMELE ANTIPOLUANTE
BffiUOGRAFIE
:
8. LICHIDE SPECIALE PENTRU EXPLOATAREA AUTOVEHICULELOR
8.1. UCHIDE (FLUIDE)PENTRU RACIREAMOTOARELOR
105
109
110
114
132
139
140
142
142
12.1.4.Utilizareaceramiciiin perspectivii
D9
10
14
32
12.2. MATERIALECOMPOZITE
12.2.1.ProprietAplematerialelorcompozite
12.2.2.Utilizareamaterialelor compozite la motoarelecu ardere interna
BIBLIOGRAFlE
13. POLUAREACHIMICA A MOTOARELOR CU ARDERE INTERNA
13.1. ASPECTEGENERAlE
13.2. PRODUCEREA~I COMBATEREA POLUANTILORLA
GENEZAiN MAS
13.2.1.Geneza CO ~iNO
13.2.2.Geneza hidrocarburilor(CmHn)
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162
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166
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]97
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228
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247
248
250
262
263
263
263
267
276
280
282
283
286
295
298
298
308
312
314
TABLE OF CONTENTS
16
17
.18
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21
22
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32
33
38
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40
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46
...47
47
54
55
56
60
62
64
65
65
66
71
75
6. LUBRICATINGOILS
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103
105
105
109
ll0
114
132
139
140
142
142
144
I
803.BATTERYELECTROLYTES
Literature
9. PLASTICMATERIALS AND SYNTHETIC ADHESIVES IN THE
AUTOMOTIVESCONSTRUCTION
9.1.THEPLASTICMATERIALS
9.1.1. The plastic materials classificationand composition
9.1.2. The plastic materials main characteristics
9.1.3. Automotivepieces made of plastic materials
9.2. SYNTHETICADHESIVES
Literature
10.TIREMATERIALS AND OTHER RUBBER PIECES
10.1.PHYSICALAND MECHANICALPROPERTIESOF THE RUBBER
10.2.AUTOMOTIVETIRES
10.3.OTHERPIECES MADE OF RUBBER
.
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147
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162
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166
174
10.3.1.Tubes,sleevesandrubberelbowsforthe
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12
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228
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298
298
308
312
314
ABSTRACT
The fuels and the lubricants. as well as the problems concerning the
economicityand the pollution of internal combustion engines regard a great numberof users, which prefer performant vehicles from this point of view.
The classic fuels (gasoline and diesel oil) and those non-conventionals (organic-oxidecomplexes, natural gases, hydrogen, vegetable oils, etc.) are treated
regardingthe aspects of mixture formation and burning, at the spark ignition engine as well as
at the Diesel engine. There are presented the physical state of the
The oils are grouped accordingly to their viscosity and the type of service and
therearepresentedthe multigrade oils, with a
The oils used in the hydraulic and mechanical transmissions and the consistentgreases are correlated with the functioning parameters of the engines.
The oil consumption, its degradation, the degree of this degradation and the
oil's regeneration are presented under the aspects concerning the directions of
laterresearches.
The economicity of internal combustion engines is pointed on the basic methods
for improving the spark ignition engine and the compression ignition engine
economicity.
There are presented the conditions
atthe limits of anti-pollution norms.
of the optimization
The special liquids used in the vehicles engines cover the area of the cooling
andbraking fluids. and ,the electrolyte for the batteries.
13
-The plastic materials and synthetic adhesives are treated under the aspect of
their structure and their main characteristics. There are given some examples for
pieces made of plastic materials.
At the materials for the tires there are presented the physical and mechanical
properties of the rubber and some of its characteristics and shapes.
There are treated the ceramic materials and their use in some parts of the engines and automotive vehicles.
The pollution of the internal combustion engines includes the chemical and
acoustic pollution.
The chemical pollution refers to the pollutants production and elimination.
There are treated the carbon oxide, the nitrogen oxide and the hydrocarbons
genesys as well as their dependence with the airjuel ratio.
The pollutants are reduced using fuels with special characteristics and using
thennal and catalytic converters.
The origin, the measurement and the diminution of the smoke is illustrated for
The pollutants control parameters are correlated with the recent nonns,
which limit the pollution of the internal combustion engines.
There are treated the pollution test cycles: the Federal cycle, the European
cycle and the cycle with 13 test points. There are presented the drawing-off of the
specimens and the measurement of the pollutants.
.
The acoustic pollution includes: the noise sources, the regulations and some
noise reduction methods for the automotive vehicle's engines. There are made calculations for some silencers. Also, the transducers, the sound analyzers and some
results in noise measurement there are presented.
This book is dedicated to the students from the Automotive Engineering Department. It could be used also by other students and specialists, whom work is
related to the internal combustion engines or the automobiles.
14
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aria suprafetei,,~g,
tr~e de gaze;atenuare
viteza sunetului;p
ciUduraspecific1i
eonsumspecific efectiv
de eombustibil
"~
concentratie
(]a
eonsumde aer~"
~,
'~,
I-
',w
.~
consumorarde
,gr
eombustibil~,
c1ildurapierdutAprin
"'!#,,
hidrocarburi
sistemul de rncire
1-
rk'
gradient de vitez1i
saureopanta
t()
oxid de carbon
bioxid de carbon
D'
t
'F
diametrulcilindrului
tTeeventa
deoscilatie
fortA
In
M~C
I-
IS:'
nominal1i
ciildur1i
latenta
de
,,-
capacitate a electric1i
L. ,IiI
M,
"F&
ft.
vapori~e
'
"
num1iru1
Mach
cursapistonului
temperatura,in K
temperatura, in C
'.'f
tensiuneaelectric1i
'
,I!
raza
rezistentaintem1i
.,
,~
masa~,
't'
unitati
Bosch
,
~I '
u~itap Hartridge
. -
Ylteza
volum
comprimare
MASI -
motoreuaprindereprin.ki~
scanteie
; ",1;
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vitezadeinaintareaa
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viteza de reactie
indicele de viscozitate
energiaacustic1i
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.
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viscozitate cinematicA
densitate
;;1f,J%~,
';,au;
-.
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arbore cotit
tensiune, timp
sarcina
15
16
pressure
upper dead center
lower dead center
heat
heat lost in the
cooling system
velocity gradient
radius
internal resistance
stroke
temperature, K
temperature, C
voltage
Bosch units
Hartridge units
speed
volume
vehicle's speed
reaction speed
acoustic energy
viscosity number
compression ratio
dynamic viscosity
crankshaft
rotation angle
kinetic viscosity
density
strain, time
load
crankshaftangular speed
CAPITOLUL
1
SIS'fEJ\AUt
'rEHi'UCCOMPLEX
AU'fOVEa-UtUl- COJ\AaUS'flBll- MAJERIAtE
Problemele ehimotologiee" prineipale se analizeaza prin intermediul unui
sistem<,:U
trei elemente: motor (autovehieul) - eombustibil
materiale (Iubrifiant
etc.) sau a unui sistem eu patru elemente: motor (autovehieul) - eombustibil lubrifiant- exploatare [1, 2, 3].
Problemele chimotologice secundare se refera la necesitatea modificarii eali!Apimaterialelor de exploatare auto, datorita urmatoarelor cauze:
. tehnice- legatede imbunatatireafiabilitiitii~idurabilitiipiautovehiculelor;
economice
.
.
.
- in scopulscaderiicosturilorproduselorpetroliere;
Bibliografie
1. BATAGA,N., BURNETE, N.: Motoare cu ardere intern". Vol. I ~i II. Cluj-Napoca,
UTCN,1995.
2. MARlNCA~,D. ~.a.: Combustibili, lubrifianfi # materiale speciale pentru automobile.Bucure~ti,Editura Didacticii~iPedagogica, 1983.
3. AADULESCU, G.A., PETRE, I.: Combustibili. uleiuri ~i exploatarea autovehiculelor.Bucure~ti,Editura Tehnica, 1986.
, Chimotologiaeste tiinta care studiaza teoria ~i practica utilizarii rationale a combustibililor ~imaterialelor lubrifiante la motoare, in stransii dependentii cu producpa materialelor
deexplpatare auto.
17
.....
CAPITOLUL 2
REZERVE
DE COJ'i\BUS'f8aat
tPE'fROU
- 1,4 %;
- 5,7 %;
- 11 %.
La nivelul anilor '90 producpa ~i consumul mondial de petrol erau de 3,1 miliarde de tone pe an.
Petrolul provine din unnatoarele zone geografice:
tfu'ile din OPEC - 37% (Irak 7%, Kuweit, Algeria, Arabia Saudita,
Emiratele Arabe Unite, Venezuela);
tacile fostei URSS, China ~iEuropa de Est - 25%;
tarile occidentale industrializate - 23%;
alte tan in curs de dezvoltare - 15%.
Evolutia necesarului de petrol pe plan mondial rezulta din tabelul 2.1.
1 baril de petrol
= 158,98 litri.