Rl 20ly Series OSR ais. 56/3 Code No. vai. aitandi ae at sacgfern : BE Roll No. | W aay fer | Candidates must write the Code on the title page of the answer-book. «pra ata a at ff a eu a ae ye 15 2 + eer 2 of wa A ok fe me ais ae a on RYT} Ge fer 1 « persia a a fh ga yee i some ge | ° BIA es ar Te ferern YE we a Vee, Wea aT aT aterea feral | °F seer at vet fae 15 fae a are Ree 8 |. wea ar Rae ata # 10.15 aa frat SET 1 10.15 7 8 10.90 79 ow om daa We a ST ait ee aati % dir 3 sacaftren 1 aid sat aa * _ Please check that this question paper contains 15 printed pages. * Code number given on the right hand side of the question paper should be written on the title page of the answer-book by the candidate. * Please check that this question paper contains 30 questions. * Please write down the Serial Number of the question before attempting it. * 15 minutes time has been allotted to read this question paper. The question paper will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 am., the students will read the question paper only and will not write any answer on the answer-book during this period. warn fas (dar) CHEMISTRY (Theory) c Hie rs . Ruth waa: 3 ae [eNets RTA HB: 70 Time allowed : 3- hours Maximum Marks : 70 56/3. P.T.O.are Fader: PONT Cir ry @ wit yer shart e) . ca (i) WR-HOT 1B we oiler cag-sea We & | ede METH fer 1 awe | (ii) WT-WeT 9 4 18 aH ag-seA Were | Neo Te H fee 2 HH FI (iv) We-WET 19 H27 TH Hh eI-Teea Were | ew WET eres aie F | (v) Were 28 330 Te Ael-seria were | ele TH fee 5 ate F | (vi) amrerveraseregear atin read ar weit ae | Heaclend & seal AH argale Tee | General Instructions : @ — All questions are compulsory. (ii) Questions number 1 to 8 are very short-answer questions and carry 1 mark each, (iii) Questions number 9 to 18 are short-answer questions and carry 2 marks each. (iv) Questions. number 19 to 27 are also short-answer questions and carry 3 marks each. (») Questions number 28 to 30 are long-answer questions and carry 5 marks each. , (vi) Use Log Tables, if necessary. Use of caleulators is not allowed. 1. qa a oRftra waeen ait cea mean aan & 2 1 What are the dispersed phase and dispersion medium in milk ? 2° Beier eng & sihert & fre saw FAA ar are fafa | 1 Name the method used for refining of copper metal. 3. NH, aga ans} wt wel aan Gea 8? 1 Why does NH; act as a Lewis base ? 4, weft Wifes wisi sehen vant a ahead wt fee ae a Sear TAT a? 1 The conversion of primary aromatic amines into diazonium salts is known as : h 56/3 25. 7. 10. 56/3 fad oan a I we 2? aged, Asia, pvc Which of the following is a fibre ? Nylon, Neoprene, PVC ‘cada & Fe-srraes % Ferg ferfiay | Write the products of hydrolysis of lactose. fi aig 8 Pater orgy at een : Identify the chiral molecule in the following pair : cl cl QeRgian tales ara A deer fafa 4 Write the structure of 2-hydrexybenzoic acid. fr antec at ag sAifae : @ C+ H,S0, > (i) XeF,+H,0 > Complete the following equations : () — C+eone. HyS0, > (i) XeF,+H,0 > fret At acer wag : @) — XeO, (i) 80, Draw the structures of the following : ® Ke, TOR Cres Gi) H,SO, lta) lei1. 12, 13, 14, 56/3 fe agent Bt srr Set & fre wae Gert are fafa : @ eae Gi) FN Write the name of monomers used for getting the following polymers : @ ~~ Teflon (i) Buna-N WHS 2-8 g om? Sl Uh Ted Heh HAT AMHR (Lec) THR Hl Aas Aa art @ fiat Peat At weg 4x 10% em 2 1 we Te wT IR Ubeeiea sifare | (feat 7H 8 : Ny = 6-022 x 10° Ha) An element with density 2-8 g cm forms a fc.c. unit cell with edge length 4 x10" cm. Calculate the molar mass of the element. Given : Nq = 6-022 x 10” mol“) @® wea gate anpt sem densi Fae ait seamen femneit F (Raa ad 2 at fre wear Gerais Ger Gar a, ferftaq | (i) Bear aetna ahs aa eeeet HI Aa HA A STAT ? @ Write the type of magnetism observed when the magnetic moments are aligned in parallel and anti-parallel directions in unequal numbers. Gi) Which stoichiometric defect decreases the density of the crystal ? res val ft afemerd aif : @ = Wet aera (A,,) Gi) Agee SeRet Define the following terms : @) — Molar conductivity (An) ates Gi) Secondary batteries CTT ello16. 16. 17. 56/3 Fira saftisoar i firerfatt ferfiac : 2 CH,CH,OH —"", CH,CH,Br+H,0 Write the mechanism of the following reaction : cH,CH,oH —, CH,CH,Br+H,0 HH TeRhe afi, Ro Pe fee, ara () % wie aga (R) F ahaa a wa are # fear rae | 2 t B)! t— @) —- aiBeaT H H (order) Gearee | Gi) HA Fae (Sera) wT ett ? For a chemical reaction R - P, the variation in the concentration (R) vs. time (t) plot is given as t ®) t— @ Predict the order of the reaction. (i) What is the slope of the curve ? a ere apH a ore feria ferfiae | ga wena HH cere oer eer ars sta a? 2 Write the principle behind the froth floatation process. What is the role of collectors in this process ? ATs oe Question el el-1918, fier aftifeensit @ arate antec fetter : 19. 20. 56/3 @ @) Tan - dm aftifien faferanaa dxT (synthesis) Write the equations involved in the following reactions : @ Gi) ® Gi) Gi) ® Gi) ii) (@) ) Reimer ~ Tiemann reaction Williamson synthesis ‘et (Cr(NH,), Cl,]Cl #1 TUPAC 7a ferftae | PR [Colen),]* fra wa Al ara Rearat 8 2 (en = $9F-1,2-s1gt47) INiCLJ et saga diet 8 sal (Ni(CO),) wfrqraehta ater 3 2 (FET HAT : Cr= 24, Co=27, Ni=28) Write the IUPAC name of the complex [Cr(NH,)4 Cl,JC1. What type of isomerism is exhibited by the complex [Co(en)s]** ? (en = ethane-1,2-diamine) Why is [NiCl,]?" paramagnetic but [Ni(CO),] is diamagnetic ? (At. nos. : Cr = 24, Co=27, Ni= 28) Fir Ha odes aie & aye Cae sere A ace ae : @ {> CH,OH POs, Gi) €» CH, - CH = CH, + HBr ——> fet gai a a stam ech afte 8,2 afin F afte dam a after ae : @) CH,Br 4yat CHI Ce Cr Gi) (CH;)3 C-Cl sat CH;-Cl Creat al e\—i9 621. 56/3 (a) Draw the structures of major monohalo products in each of the following reactions : PCI, @ (> CHO —> Th ea Cetin La lol-ig Gi) (p> Ci, CH= CH, + HBr ——> P (») Which halogen compound in each of the following pairs will react faster in Sy2 reaction : @ CH;Br or CH,I Gi) (CH,)3 C- Cl or CH; - Cl Rreafefsd & oro faftar : 3 @ Glas St RQ) A get 4 wate Gl (RNH,) % Feri Fe MEI i). Uefa sheer — serge oafteftren wat At (ii) eta Rear 4 CH,),N Geet 4 (CH,).NH siftrs ants eth 3 1 wet fra aftiraaii # a,B ait c At dent afc: 3 . Sn +HCl NaNO, + HCl HO @ C.H;NO. —————> A ——_____, B ——> © 273K H,0/H* NH, Br, + KOH (i) CH,N —~—> a ~., p —“"—_5,¢ Account for the following : (@) Primary amines (R-NH,) have higher boiling point than tertiary amines (R3N). (i) __ Aniline does not undergo Friedel — Crafts reaction. (ii) (CHg)2NH is more basic than (CHg)3N in an aqueous solution. OR u P.T.O.56/3 Give the structures of A, B and C in the following reactions : : Sn+HCl NaNO» + HCl H,0 @ . GiHNO; ———> A —— 5 B_—* € goon 2H, y Nib, y Bm tKOH fara care tae & wat H, Si. aaa Awa} aia FS aa ad Reardt & fore we ‘carer ey waren | ats 3 are, wa ae de a TERT wT fs aan sreaerat % weré Harts sar Phar Ha afrst st ban a a a oT | Sa a agai aes A oT | Se Se ea attofral stg 1 Si. wane 3 ea ara FH EAT AHI A BEA eee She (NHRC) # @ 1 NHRC & garat % Been 7 Pola fern A sleet wera ait fart ware chit Bt at ore ait aa & BA wal A ores Tet wea st TA fore areaftrs afer aret tera Get STE | @ — @) i. aaa aX >) NERC ae alg 8 ar ard ff | Gi) afaa han A dig a war & fee gerd a-at dterers aisftat ‘Wa et are S 2 Gi) Wate APTS fore Gare ae Phir aya FB Pee eH a seIECT afi | On the occasion of World Health Day, Dr. Satpal organized a ‘health camp’ for the poor farmers living in a nearby village. After check-up, he was shocked to see that most of the farmers suffered from cancer due to regular exposure to pesticides and many were diabetic. They distributed free medicines to them. Dr. Satpal immediately reported the matter to the National Human Rights Commission (NHRC). On the suggestions of NHRC, the government decided. to :provide medical -care, financial AS Cretnd lel23. 56/3 assistance, setting up of super-speciality -hospitals for treatment and prevention of the deadly disease in the affected villages all over India. (@) _ Write the values shown by (a) Dr. Satpal (>) NHRC. (i) What type of analgesics are chiefly used for the relief of pains of terminal cancer ? (ii) Give an example of artificial sweetener that could have been recommended to diabetic patients. fre val Ht oiereme Afra - 3 @ afrastags Gi) ter Gi) afar Bieta Define the following terms : () — Nucleotide Gi) Anomers (ii) Essential amino acids @) afta Mg (s) + Cu (aiefla) > Mg?* (aiefla) + Cu(s) & fa A,6° afenfera Fie | fen mH : BY =+271V, 1F = 96500 Cita >) ate (Apollo) sfaher stoma % fore eq wits saree aH fae sae Ger & year ar are ferfag | 10 Years Ciera) 9 [eres P.T.O.(a) Calculate A,G° for the reaction Mg (6) + Cu* (aq) > Mg (aq) + Cu (9) aa ta Given : E°,y=+2:71V, 1 F=96500 C mol (b) Name the type of cell which was used in Apollo space programme for providing electrical power. 25. fen ae saeT F SOC], & yam aife & anta-faaer & dhe Prafeifad aes WH RE : S0,Cl, (447) —+ SOp (4#) + Clp (4a), 0 0-4 in was! | aaa Tas 1 2 100 0-7 an Pract oftatera Afr | (fea 7H % : log 4 = 0-6021, log 2 = 0-3010) The following data were obtained during the first order thermal decomposition of SO,Cl, at a constant volume : S02Cly (g) —> S02 (g) + Cly(g) ‘Experiment | Time/s | Total pressure/atm 1 0 0-4 2 100 07 Calculate the rate constant. (Given : log 4 = 0-6021, log 2 = 0-3010) 26. Fea FT aa 22 ee fafa wen aT 2 es ER HH ERT “aia What are emulsions ? What are their different types ? Give one example of each type. 56/3 1027, 56/3 Freafeifiad & spre dif : 3 @ @) iii) (CH)s P= 0 @t tat Sa 8 WY (CHy)s N= O7E fea | ag we we A se fee arch Ge A weRe A aT station & fore a Sten 8 | : HPO, # afte H;PO, afte vat arraren 8 | Give reasons for the following : @ Gi) (ii) @) ) @ Gi) (CH)y P= O exists but (CH,)3 N = O does not. Oxygen has less electron gain enthalpy with negative sign than sulphur. HPO; is a stronger reducing agent than HP03. fra wisi a yg fifa : @ Cr0;> + 20H —> Gi) MnOg + 4H* + 3° —5 FS are fafa ; @ ZnB aaa we ae AT TT | Gi) Sr ag ag aaa a | (ii) Mn*/Mn®* a, Cr*/Cr** gm a aa afte E° a Tact 3 | 28 wat Hea oferta ott caries atfiantteer % deal gatest aikt ftetiagi & ate 8 fefaw 1 werigs Fue & se weet at am ferfay, G4 afar aracer fear & fac wftg 81 aS 1 Pires) P:T.O. els29. 56/3 ii) 1) (@) (b) @ @ Gi Gv) (a) Fre attr at ye Fifi : MnO, + 8H* + 5e= —> Ma* aft CO 3 a ar after agaeaita 3 ak at 2 (TEN HHI : Mn = 25, Cr = 24) Complete the following equations : @ Cr,0,% + 20H —> (i) MnO, + 4H* + 3° —> Account for the following : @_ Znis not considered as a transition element. Gi) Transition metals form a large number of complexes. . (iii) ‘The E” value for the Mn®+/Mn2* couple is much more positive » than that for Cr®"/Cr™* couple. OR With reference to structural variability and chemical reactivity, write the differences between lanthanoids and actinoids. Name a member of the lanthanoid series which is well known to exhibit +4 oxidation state, Complete the following equation : - MnO + 8H* + 5& —> Out of Mn* and Cr**, which is more paramagnetic and why ? (Atomic nos, : Mn = 25, Cr = 24) fr afterat 3 CH,CHO A afiien ean ser a fafa: @ HCN ee ee 10 Years Gi) NaOH 4 safeafa F CH,CHO Question elelag 12) (b) © (@) 0) 56/3 fra ais gat # sex Rar & fae aa Taras wha afer: @ dais ora otk Grier @) The ak th 38 fae & are fatter : @ CH,COOH ft geet # Cl- CH,COOH aftrm saci aa 2 | Gi) arelfaates ara araitia ayy A aaltiispend aa 2A | fie a afte afters % fee carts aioe fafa ; @ WR ae Gi) Rist afiiear CH,CH, — CO - CH, - CH; 3it CHyCH, - CH, - CO - CH; #8 or aetteteid adam tat 8 2 2,2,1 Write the products formed when CH;CHO reacts with the following reagents : @ HON @) H,N-OH (ii) CH CHO in the presence of dilute NaOH Give simple chemical tests to distinguish between the following pairs of compounds : @ —_Benzoic acid and Phenol Gi) Propanal and Propanone OR 10 Years Question Paper 13 P.T.O.30. 56/3 (a) ) © () (a) () Account for the following : SON ela Cet) Paper (@ Cl-CH,COOH is a stronger acid than CH;COOH. (i) Carboxylic acids do not give reactions of carbonyl group. Write the chemical equations to illustrate the following name reactions : @) = Rosenmund reduction. i). Cannizzaro’s reaction Out of CHjCH,- CO - CH, - CH and CHsCH,- CH,~ CO-CHs, which gives iodoform test ? fier val At often afi : @ teat Gi) Alaa srr feats K,) we acta facet Ht wfa feet fea #15 g afm (ate goon = 60 g Aer) ule & 1 se ees TE aa ae A gH (te 32H = 180 g tet) & ww een & aM (saree) 2 1 Uw feet freee 4 sofa apts ar gor ahefera Fife | 2,8 aaa Ghia ak Waa a fem fa ven a fae farts? aT She ae Hh reals (Alen FOTN = 180 g Her) & Uw ear T Gar wT 8, 10% (GOTH BGAN) 1 ge Para A Hterere aie tecaT ea eA 2 (fern I BA = 1.2 g mL) 23 14(@) (b) @ (b) 56/3 Define the following terms : @) — Molarity . Gi) Molal elevation constant (K,) A solution containing 15 g urea (molar mass = 60 g mol’) per litre of solution in water has the same osmotic pressure (isotonic) as a solution of glucose (molar mass = 180 g mol”) in water. Calculate the mass of glucose present in one litre of its solution. ‘OR What type of deviation is shown by.a mixture of ethanol and acetone ? Give reason. A solution of glucose (molar mass = 180 g mol”) in water is labelled as 10% (by mass). What would be the molality and molarity of the solution ? ensity of solution = 1-2 g mL“) te Cr Question Paper 15