CHEM 1311: General Chemistry 1, Fall 2008

Exam #4, December 2, 2008

Class section:
Instructor

Section #

Dieckmann

001

Sibert

002

Class time
11:30 am to 12:20 pm
1:30 to 2:20 pm

EXAM TYPE: A
_________________________________________________________________________________
Potentially Useful Information
1amu(u)=1.66054x1024g
1mole=6.022x1023
2 2
1J=1kgm s
1 calorie = 4.184 J
1 Newton (N) = 1 kg m s

1 2

1 Pa = 1 N m = 1 kg m s
1 atm
= 760 mm Hg
= 760 torr
= 101,325 Pa
= 1.01325 bar
= 14.7 psi (pounds per sq. in)
R = 0.08206 L atm mol

= 8.314 J mol

CHEM 1311: Exam #4

December 2, 2008

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CHEM 1311: Exam #4

December 2, 2008

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1. WhatisthetemperatureinCelsiusat77.0K,whichisthetemperatureofliquidnitrogen?
A.
350C
B.
196C
C.
3.55C
D.
196C
E.
350C
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2. Calculatethestandardenthalpyofreactionforthefollowingreaction:

C(graphite)+2H2(g)+O2(g)CH3OH(l)
usingthefollowinginformation:
C(graph)+O2(g)CO2(g)

H=393.5kJ/mol

H(g)+1/

H=285.8kJ/mol

HO(l)
2

CH3OH(l)+3/2O2(g)CO2(g)+2H2O(l)

A.
B.
C.
D.
E.

H=726.4kJ/mol

1691.5kJ/mol

47.1kJ/mol
238.7kJ/mol
1,691.5kJ/mol
47.1kJ/mol

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3. Whichofthelinesonthefigurebelowisthebestrepresentationoftherelationshipbetweenthevolumeofagasandits
pressure,otherfactorsremainingconstant?

A.
B.
C.
D.
E.

b
c
e
d

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4. For a substance thatremains a gas under the conditionslisted, deviation from theideal gas law wouldbe most
pronouncedat:

A.
100Cand2.0atm
B.
100Cand2.0atm
C.
100Cand4.0atm
D.
100Cand4.0atm
E.
0Cand2.0atm
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CHEM 1311: Exam #4

December 2, 2008

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5. Glycine,C2H5O2N,isimportantforbiologicalenergy.Thecombustionreactionofglycineisgivenbytheequation:

4C2H5O2N(s)+9O2(g)8CO2(g)+10H2O(l)+2N2(g)

Hrxn=3857kJ

GiventhatHf[CO2(g)]=393.5kJ/molandHf[H2O(l)]=285.8kJ/mol,calculatetheenthalpyof
formationofglycine:

A.
B.
C.
D.
E.

2,149kJ/mol

3,178
964kJ/mol
537.2kJ/mol
268.2kJ/mol

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6. Agasevolvedduringthefermentationofsugarwascollectedat22.5Cand702mmHg.Afterpurification,its
volumewasfoundtobe25.0L.Howmanymolesofgaswerecollected?

A.
B.
C.
D.
E.

12.5mol

724mol
1.05mol
22.4mol
0.95mol

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7. Calciumoxideandwaterreactinanexothermicreaction:

CaO(s)+H2O(l)Ca(OH)2(s)

Hrxn=64.8kJ/mol.

Howmuchheatwouldbeliberatedwhen7.15gCaO(s)isdroppedintoabeakercontaining152gH 2O?

A.
1.97103kJ
B.
8.26kJ
C.
555kJ
D.
547kJ
E.
508kJ
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8. NitrogenandhydrogencombinetoformammoniaintheHaberprocess.Calculate(inkJ)the

standardenthalpychange Hforthereactionwrittenbelow,usingthebondenergiesgiven:
N2(g)+3H2(g)2NH3(g)
Bondenergy(kJ/mol):
N N,945; H H,432; N H,391
A.
105kJ
B.
C.
D.
E.

969kJ
204kJ
204kJ
595kJ

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CHEM 1311: Exam #4

December 2, 2008

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9. Inwhichofthefollowingcompounds willthemolecules notformhydrogenbondswitheach

other?A.H F
B.
C.
D.
E.
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10. Selectthegaswiththehighestaveragekineticenergypermoleat298K.

A.
B.
C.
D.
E.

CO2
H2O
H2
O2
Allhavethesameaveragekineticenergy.

__________________________________________________________________________________
11. Asampleofpropane,acomponentofLPgas,hasavolumeof35.3Lat315Kand922torr.Whatisitsvolumeat
STP?

A.
49.2L
B.
37.1L
C.
33.6L
D.
25.2L
E.
30.6L
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12. Whichisnotapropertyofagas?

A.
densityislargerthanthatofaliquid
B.
formshomogeneousmixtureswithoneanother
C.
densityvarieswithtemperature
D.
assumestheshapeandvolumeofitscontainer
E.
iscompressible
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13. Forwhichofthefollowingspeciesarethedispersionforcesstrongest?

A.
C7H16
B.
C6H14
C.
C5H12
D.
C8H18
E.
C4H10
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CHEM 1311: Exam #4

December 2, 2008

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14. Hydrogenperoxidewascatalyticallydecomposedand75.3mLofoxygengaswascollectedoverwaterat25Cand
742torr.Whatmassofoxygenwascollected?(Pwater=24torrat25C)?
A.
B.
C.
D.
E.

0.0993g

0.0931g
0.00291g
0.0962g
0.962g

__________________________________________________________________________________
15. Whichoneofthefollowingsubstanceswillhavebothdispersionforcesanddipoledipoleforces?
A.
B.
C.
D.
E.

HCl
H2
BCl3
CO2
Br2

__________________________________________________________________________________
16. Asampleofcarbondioxidegasat125Cand248torroccupiesavolumeof275L.Whatwillthegaspressure
beifthevolumeisincreasedto321Lat125C?
A.
B.
C.
D.
E.

356torr
359torr
441torr
289torr
212torr

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17. ApressurethatwillsupportacolumnofHgtoaheightof256mmwouldsupportacolumnofwatertowhat
height?Thedensityofmercuryis13.6g/cm3;thedensityofwateris1.00g/cm3.
A.
B.
C.
D.
E.

1.00102ft
76.0cm

348cm
18.8mm
33.8ft

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18. Whichstatementisfalse?
A. Moleculesofagasundergomanycollisionswitheachotherandthecontainerwalls.
B. Themoleculesofanidealgasarerelativelyfarapart.
C. Theaveragekineticenergiesofmoleculesfromsamplesofdifferent"ideal"gasesisthesameatthe
sametemperature.
D. Moleculesofgreatermasshavealoweraveragespeedthanthoseoflessmassatthesametemperature.
E. Allmoleculesofanidealgashavethesamekineticenergyatconstanttemperature.

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CHEM 1311: Exam #4

December 2, 2008

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19. Asampleofagasoccupies1.40 103 mLat25.0 Cand760.mmHg.Whatvolumewillitoccupyatthesame

temperatureand380.mmHg?

A.
2.80x103mL
B.
1.05x103mL
C.
2.10x103mL
D.
700.mL
E.
1.40x103mL
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20. Howmanylitersofchlorinegasat25.0Cand0.950atmcanbeproducedbythereactionof12.0gofMnO2?

MnO2(s)+4HCl(aq)MnCl2(aq)+2H2O(l)+Cl2(g)
0.282L

A.
B.
3.09L
C.
5.36103L
D.
0.138L
E.
3.55L
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21. Whatisthefinaltemperatureofagasthatexpandsfromavolumeof22.4Lat278Ktoavolumeof38.3L?
A.
B.
C.
D.
E.

162.6K

475.3K
217.3K
293.9K
3.09K

__________________________________________________________________________________

22. Whichofthefollowingsubstancesshouldhavethehighestboilingpoint?
A.
Kr
B.
CH4
C.
N2
D.
CH3Cl
E.
Cl2

__________________________________________________________________________________

23. Giventhat:

CaO(s)+H2O(l)Ca(OH)2(s)
Hrxn=64.8kJ/mol
howmanygramsofCaOmustreactinordertoliberate525kJofheat?

A.
56.1g
B.
6.92g
C.
3.40104g
D.
606g
E.
455g
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CHEM 1311: Exam #4

December 2, 2008

Page 8 of 11

24. Aflaskwithavolumeof3.16Lcontains9.33gramsofanunknowngasat32.0Cand1.00atm.Whatisthemolar
massofthegas?

A.
B.
C.
D.
E.

81.4g/mol

144g/mol
7.76g/mol
74.0g/mol
66.1g/mol

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25. When0.560gofNa(s)reactswithexcessF 2(g)toformNaF(s),13.8kJofheatisevolvedatstandardstate
conditions.Whatisthestandardenthalpyofformation(Hf)ofNaF(s)?

A.
B.
C.
D.
E.

24.8kJ/mol

567kJ/mol
7.8kJ/mol
24.8kJ/mol
567kJ/mol

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26. Arrangethefollowinggasesinorderofincreasingrateofeffusion.

C2H6,Ar,HCl,andPH3
Ar<PH3<HCl<C2H6

A.
B.
C2H6<PH3<HCl<Ar
C.
C2H6<HCl<PH3<Ar
D.
Ar<HCl<PH3<C2H6
E.
Ar<PH3<C2H6<HCl
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27. Whichoneofthefollowinginvolveshydrogenbonding?

A.
CHCl3
B.
H2O
C.
H2C CH2
D.
CF3OH
E.
CH4
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28. Aflaskcontainingneongasisconnectedtoanopenendedmercurymanometer.Theopenendisexposedto
theatmosphere,wheretheprevailingpressureis745torr.Themercurylevelintheopenarmis50.0mm
belowthatinthearmconnectedtotheflaskofneon.Whatistheneonpressure,intorr?

A.
50.torr
B.
50.torr
C.
795torr
D.
Noneofthesechoicesiscorrect
E.
695torr
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CHEM 1311: Exam #4

29.Given:

December 2, 2008
3

2Al(s)+

O(g)AlO (s)

Page 9 of 11

H f =1,670kJ/molforAlO (s)

determine

2Al2O3(s) 4Al(s)+
A.
B.
C.
D.
E.

Hforthereaction:
3O2(g).

3,340kJ/mol

3,340kJ/mol
835kJ/mol
1,670kJ/mol
1,670kJ/mol

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30. Thestrongestintermolecularinteractionsbetweenhydrogensulfide(H 2S)moleculesarisefrom:

A.
B.
C.
D.
E.

iondipoleinteractions.

disulfulfidelinkages.
hydrogenbonding.
Londondispersionforces.
dipoledipoleforces.

__________________________________________________________________________________
1
31. Agasmixture,withatotalpressureof300.torr,consistsofequalmassesofNe(atomicweight20.Gmol
)andAr(atomic
1

weight40.Gmol ).WhatisthepartialpressureofAr,intorr?

A.

100.torr

B.
150.torr
C.
200.torr
D.
75torr
E. noneofthesechoicesiscorrect

__________________________________________________________________________________
32. WhatisthevolumeofNH3producedinthefollowingreactionwhen3.0LofN2reactswith4.0L
ofH2?

A.
B.
C.
D.
E.

2.66L
2.0L
1.5L
0.66L
0.5L

N2(g)+3H2(g)2NH3(g)

__________________________________________________________________________________

continuedonnextpage

CHEM 1311: Exam #4

December 2, 2008

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33.Calculatethe Hrxnforthefollowingreaction.
SiO2(s)+4HCl(g)SiCl4(g)+2H2O(g)
Hf[SiO2(s)]=910.9kJ/mol; Hf[SiCl4(g)]=657.0kJ/mol; Hf[HCl(g)]=92.3kJ/mol;
Hf[H2O(g)]=241.8kJ/mol;

A.
B.
C.
D.
E.

139.5kJ

139.5kJ
104.4kJ
104.4kJ
137.4kJ

__________________________________________________________________________________
34. Selectthepairofsubstancesinwhichtheonewiththelowervaporpressureatagiventemperatureislistedfirst.

A.
B.

C3H8,C4H10
F2,Cl2

C.
D.
E.

,CH3CH2CH2OH
CF4,CBr4
PH3,NH3

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CHEM 1311: Exam #4

December 2, 2008

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