Max Marks:360

KEY SHEET

Physics:
1) a

2)

3)

4)

5)

6)

7)

8)

9)

10) a

11) c

12) c

13) d

14) d

15) a

16) c

17) b

18) c

19) b

20) d

21) a

22) a

23) c

24) b

25) a

26) a

27) a

28) d

29) b

30) b

33) c

34) a

35) d

36) d

37) c

38) b

39) b

40) a

47) d

48) a

49) a

50) b

58) b

59) b

60) d

42) d

43) a

44) a

45) b

46) a

51) b

52) b

53) b

54) a

55) b

56) c

61) d 62) b

63) c

64) a

65) a

71) d

72) d

73) a

74) b

75) d

81) a

82) b

83) d

84) a

.s
t

ud

ys

te

Chemistry:

67) d

68) a

69) a

70) a

76) c

77) c

78) d

79) b

80) b

86) d

87) b

88) b

89) c

90) a

ww
w

85) b

66) b

SOLUTIONS
-:PHYSICS:1.

(a)

57) a

ps

41) d

.i

31) a 32) b

Mathematics:

4.

ps

(d)
The charge of the capacitor means the charge appearing on the facing surface of the capacitor.
So,
2Q CV
2Q
.

V
C
(a)
In steady state, capacitor can be treated as open circuit and hence circuit diagram would be as
follows:
Apply Kirchhoffs voltage law to two loops 1 and 2
E1 V1 0 V1 E1
E2 V1 V2 0 V2 V1 E2
E1 E2 .
Charge on C1 ,
Q1 V1C1 C1 E1
Q2 C2V2 C2 E1 E2 .
Charge on C2 ,

ww
w

.s
t

ud

6.

ys

te

5.

dq
towards dl
4 0 R 2

dl
dl
2

2
.
2
4 0 R
8 0 R 3

3.

(b)
As we move away from the origin along X-axis, the area under p-V curve is continuously increasing
and hence work done by the system during the process is continuously increasing. As temperature is
constant the internal energy remains constant. From 1st law, we can say that as W is continuously
increasing, the heat supplied is also continuously increasing as V is constant.
(a)
The slope of x t graph at t 0 is +ve i.e., initial velocity of the particle is +ve and x t graph is
concave down, so it means acceleration is ve but whether it is constant or not it cant be predicted
from given information. As v and acceleration are in opposite directions, the motion is the retarded
one and finally particle stops.
(a)
Here to solve this question we can use principle of superposition. The given structure can be
considered as combination of two as shown in figure.

E at 0 (due to given structure)

Eat 0 due to I Eat 0 due to II

.i

2.

7.

(d)
As battery is connected across the resistor, thermal power developed in the circuit is, H

E2
.
R

1
. As time increases, temperature of the resistor increases and therefore
R
its resistance and hence rate of production of thermal energy decreases.

Here, E is constant, so H

8.

(c)
For refraction at the spherical surface,
1 1, 2 , R R, u , v 2 R
2 1 2 1

v
u
R

or

9.

1
1
2.
2R
R

(c)
This is a direct question based on concept of pure rolling. For no slipping relative velocity of point of
contact has to be zero.
Here velocity of the bottom-most point on cylinder is v0 R , and velocity of platform is v. So,
from definition of pure rolling, v0 R v 0

(c)
As medium remains same, the wave-speed remains same, but as frequency changes, new wavelength
is given by,

(d)

ud

13.

v
1 v
.
2f 2 f 2

ys

te

ps

12.

2h h
h

1.05 1034 J s .
2 2 2

11.

.i

10.

v v0 R .
(a)
The circuit is steady state is shown in the figure. Capacitor would be open circuited while inductor
would be short-circuited.
Two 2R resistors have no role, whatever current is coming that goes to the inductor branch.
(c)
For Li 2 ion, ground state energy is 13.6 9 122.4 eV and on absorbing 91.8 eV energy electron
transits from 1st energy level to 2nd energy level.
So, increase in angular momentum,

v 2
m.
f 5
Frequency as received by person in boat is,
velocity of wave relative to the person
f

14.

ww
w

.s
t

Wavelength of the water waves is

10 2 12 5

30 Hz .

(d)
Draw the free body diagram of block and platform. As M m , the acceleration of the platform,
mg
can be taken as zero and hence its velocity remains constant as 4m/s. Acceleration of the
a
M
block is, ablock , ground g 2 m / s 2 towards right.
Let velocity of block wrt ground at time t be v (towards right), then v 2t .
Solve the question wrt platform frame of reference.

ablock , platform 2m / s 2
(towards right)

vblock , platform 2t 4 m / s
(towards right)
Initial velocity of block wrt platform is 4 m/s towards left.

Let s be the required distance, then v 2 u 2 2a.s

0 4 2 2 s s 4 m .
2

15.

(a)


U U
F VU
i
j
y
x
7i 24 j .

F 7 2 242 25 units .

16.

(c)
Let a be the acceleration of the centre of mass and be the angular acceleration about an axis
passing through the centre of mass.
2
F Ma, F h R MR 2
5
For pure rolling a R
F 5F h R
or

M
2 MR
or
5h 7 R

(b)
1st method: Let us assume that the spheres are moving with velocities v1 and v2 when they are at a
separation of d.
Then from momentum conservation, mv1 Mv2 .
From energy conservation,
mv12 Mv22
GMm

0 .

0
2
d

2
After solving above equation, we get

ys

te

ps

.i

17.

h 1.4 R .

2G M m
.
d
2nd method: Using C frame or reduced mass concept.
Let v, be the relative when they are at a separation of d,
2
mM vT
GMm
then
0

d
mM 2

18.

vT

ww
w

.s
t

ud

v1 v2

2G M m
.
d

(c)
Elongation in the spring in equilibrium position is given by mg ky0

y0 10 cm .
The point mass is released from the location where elongation in spring is 15 cm.
So, amplitude of oscillation of point mass is 15 10 5cm .
As Hookes law is valid, the point mass performs simple harmonic motion, let equation of simple
harmonic motion be,
y A sin t

20
1
.
2000 10
At t 0, y 5 cm so, 5 5sin
where A 5 cm and

.
2

19.

t
So, equation of motion is, y 5 cm sin where t is in sec.
10 2
(b)
T/A
Al
From, Y
where l0 is the length or natural length of string.
T YA
l / l0
l0

YA l1 l0
k l l0
l0
where l1 is the length of string when tension in string is T.

T1 4 N k a l0
T

T2 5 N k b l0
T3 3N k l l0
where l is the required length.
Solving above equations, we get l 5b 4a .

(d)

(d)
Time period is same so A B
v
r
r
Linear velocity v r so A A A A .
vB rBB rB

.i

20.
21.

ps

Force required is, F mr 2 .

ys

.s
t

ww
w

23.

V V 1000 V 900

or

V
0.1V .
10

So, fraction of ice piece outside the water is, f

24.

25.

rA
.
rB

(a)
T cos mg
T sin component would be balanced by force exerted on mirror by light.
2 IA
T sin
c
2 IA
So, tan
for small angle tan .
cmg
(c)
Let V be the total volume of ice piece and V is the volume of ice piece which is outside the water,
then
V V water g V ice g

ud

22.

te

Now, masses of two particles can be different and hence ratio of the force required may not be,

V
0.1 .
V

(b)
dx
db dc
da
100 3 2 100 .
x
db c
a
For % age error we consider the worst case --% age error is x 3 % in a 2 % error in b % error in c.
(a)
The force acting on the ball are buoyancy force and gravitational force.

Net force on the ball will be zero when

BF mg
v axg v 0 g

x 0 , i.e., mean position is at a depth of 0 from free surface.

But, it moves down from this mean position due to acquired speed. When it is at a depth of

from the free surface, net force acting on ball is F v 0 x g v 0 g v0 xg .

[Towards mean position]

F x so simple harmonic motion.
2
Velocity of ball becomes zero when x 0 from free surface,

i.e., amplitude of simple harmonic motion become 0 .

(a)
At a distance y from bottom end consider a string element of length dy.
m
Tension at this height is, T yg
l
T
dy
So,
velocity of wave
gy
dt

2.45 dy
t

0 gy 0 dt
or
t 1s .
(a)
y

For proper resolution,

1.22
D
d
where y 1 mm, 500 nm, d 3 mm .
D 5m
Dmax 5m .
(a)
When multimeter shows the conduction on its connection with two legs of diode, it means the leg
which is connected to positive leads of multimeter is p-side of diode.
(d)
Option (A) tells that transistor is not working, as there is no connection between base and collector
means there is some fault in this part of the transistor.
Option (B) tells that transistor is having no open circuit fault, i.e., it is having the continuity.
Transistor is faulty.
(b)
Taking moments about the mid-point.
2 g 0.5 mg 0.2

m 5 kg .

28.
29.

30.

31.

ww
w

.s
t

ud

27.

ys

te

ps

.i

26.

0
x

-:Mathematics:-

(a)
Since the planes are all parallel planes,
26
4
4
p1

4 9 16
29
22 32 42
Equation of the plane 4 x 6 y 8 z 3 0 can be written as 2 x 3 y 4 z 3 / 2 0

2 3/ 2

So p2

2 3 4
26
2

and p3

2 3 4
p1 8 p2 p3 0

32.

1
2 29

8
29

(b)
The equation of a line which passes through 2, 1 is y 1 m x 2 ....... i
The equation (i) will touches the circle x 2 y 2 1 if

2m 1
1 m2

1 m 0,

4
3

4
x 2 4x 3 y 5 0
3
Now 5, 5 is a point on the above line. Its image by the line y 1 is 5,3

i becomes y 1

The equation of the incident ray is

(c)
We have to find the number of integral solutions if x1 x2 x3 x4 x5 6 and that equals

.i

33.

y 1
x2

4 x 3 y 11 0
1 3 2 5

5 6 1

.s
t

34.

ud

ys

te

ps

C51 10 C4
Thus Statement-1 is false.
Number of different ways of arranging 6As and 4Bs in a row
10 10

C4 = Number of different way the child can buy the six ice-creams.
6 4
Statement-2 is true
So, Statement-1 is false, Statement-2 is true.
(a)
Mean x x ny

xx
n
ny n 1
=
2n 1

35.

ww
w

Mean deviation =

(d)
2
2
2
Here OP OQ PQ

a2 2 2
a2 2 2
2
b

b l 4l 2
b2
b2
a 2b 2
l2 2
0 3b 2 a 2 0 3b 2 a 2
2
3b a
2
3a e 2 1 a 2 e 2 1 b 2 / a 2

e2
36.

4
2
e
3
3

(d)

let C x i y j 3 k

c 1 x 2 y 2 z 2 1........ 1

c a c.a 0
x y z 0........... 2

a b c 0
1 1 1

1 1

1 0

1 z y 1 z x 1 y x 0
z y z x y x 0
2 y z 0
x 2z
y z
2
1
1
,y
,z
6
6
6

c
2 i j k

.i

(c)
Let the sequence of 3n consecutive integers begins with m. Then 3n consecutive integers are m, m+2,
..,m + (3n 1)
3 integers from 3n can be selected in 3n C3 ...... i
Now 3n integers can be divided into 3 groups.
G1 : n numbers of from 3p
G2 : n numbers of from 3 p 2
The sum of 3integers chosen from 3n integers will be divisible by 3 if either all the three are from
same group or one integer from each group. The number of ways that the three integers are from
same group is n C3 n C3 n C3 and number of ways that the integers are from different groups is

C1 n C1 n C1

.s
t

ud

ys

te

ps

37.

favourable cases n C3 n C3 n C3 n C1 n C1 n C1

38.

(b)

ww
w

Required probability

3.n C3 n C1
3n

C3

3n 3n 2
3n 1 3n 2
2

3x 4
3x 4
3x 4
1
z 1 3x 4
3x 4 3x 4

z 1 3x 4 1 3x 4 3x 4
3x 4
Let z

6 x 6 x 3

x
8
8
4
4 z 1
4 z 4 6 6 z 10 2 z
f z

2
3 1 z
3 1 z
3 1 z

10 2 1 z 2
8
2

3 1 z
3 1 z 3

f x

8
2

3 1 x 3
8
2
dx dx
3 1 x
3

f x dx

2
2
log 1 x x c
3
3
(b)

Let A
We have

39.

2

A

2
1
2
A I

.i

ps

0
1

te

giving 2 1 2

ys

and 0

1 0

1 0 1

.s
t

det A

ud

As A 1, A I , we have

ww
w

giving 2 1 2
and 0

As A I , A I , we have

1 1

1
Statement-1 is therefore true.
tr A 0
det A

Statement-2 is false because tr A 0

40.

(a)

adj adjA A

adj adjA A

41.

(d)

n 12

A A5
0

0 2 3 1 5 1

Statement 1:
y 2 16 3 x, y mx

4 3
m

x2 y 2

1, x m1 y 4m12 2
2
4
x
2
1
y
4 2 ,m
m1
m1
m1
2

4 3
2
Now,
4 2
m1
m
48
2
24
2 4 2 4 2m 2 2 2 m 2
m
m1
m
m 4 2m 2 24 0 (1)
m 2 6 m 2 4 0 m 2

4 3
is a common tangent to y 2 16 3 x and ellipse 2 x 2 y 2 4 , then
m
4
2
m satisfies m 2m 24 0
From (1), statement 2 is a correct explanation for statement 1.

(d)
n

r 1 nCr r. nCr
r 0

r 0

r 0

Cr

r 1
r 0

ud
.s
t

Again

ys

n
n
n
r. . n 1Cr 1 nCr
r
r 0
r 0
n 1
n
n 1
= n.2 2 2 n 2
Thus Statement-1 is true.

te

Cr x r r . n Cr x r n Cr x r
r 0

= n r 1 nCr x r r. nCr x r nCr x r

r 0

r 0

n n 1 Cr 1 x r nCr x r
r 0

= nx 1 x

r 0

n 1

1 x

ww
w

42.

ps

.i

Statement 2: If y mx

43.

(a)

2
1
0
2
2

4
At x , f
0
2 2
2
4
Equation has at least one root in 0,
0
2
2
(a)
dx y sin y x
dx x

sin y
dy
y
dy y

At x 0, f x sin x

44.

I .F . e

y dy

elog y y

yx y sin ydy y cos y 1 cos y dy c

yx y cos y sin y c

y x cos y sin y c

(b)
If the two A.P.s are a a d a 2d ..... and A A D A 2 D ..., then

.i

45.

ww
w

.s
t

ud

ys

te

ps

n
2a n 1 d
3n 8
2

n
2 A n 1 D 7 n 15
2
n 1
a
d
3n 8
2

7 n 15
n 1
A
D
2
n 1
Substituting
11 i.e. n = 23, we get
2
a 11d
3n 8

A 11D 7 n 15
n 1
a
d
3n 8
2

7 n 15
n 1
A
D
2
n 1
Substituting
11 i.e. n=23, we get
2
a 11d
77
7

ratio of 12th terms

A 11D 176
16
(a)
Since, the person is allowed to select at most n coins out of 2n 1 coins, therefore he can select
one, two, three, ., n coins. Thus, if T is the total number of ways of selecting at least one coin,
then T 2 n 1 C1 2 n 1 C2 ..... 2 n 1 Cn 255 . (i)

46.

Using the bionomial thermo

2 n 1

C0 2 n 1 C1 2 n 1 C2 ..... 2 n 1 Cn 2 n 1 Cn 1 2 n 1 Cn 2 ...... 2 n 1 C2 n 1 1 1

2 n 1 C0 2 2 n 1 C1 2 n 1 C2 ..... 2 n 1 Cn 2 n 1 C2 n 1 22 n 1

1 2 T 1 22 n 1

2 n 1

22 n 1

22 n 1
22 n
2
1 255 22 n 22 n 28 n 4

1 T

47.

(d)

48.

(a)

q
p q
~ q ~ p q (By Commutative law)
(~ q q ~ p (By Commutative law)
~ q q ~ q ~ p (By Distributive law)
~ q p ~ p q
1

In ABC , Given 1
1

a 0

ps

a b b c c a 0

.i

a 2 b 2 c 2 ab bc ca 0
2a 2 2b 2 2c 2 2ab 2bc 2ca 0
a 2 b 2 2ab b 2 c 2 2bc c 2 a 2 2ca 0

1 c 2 ab a c a b b c 0

(a)

ln f x ln x 1 ln x 2 ..... ln x 100
Differentiating
f ' x
1
1
1

.......
f x x 1 x 2
100

ww
w

49.

.s
t

ud

ys

te

Here, sum of squares of three numbers can be zero, if an only if a b c .

ABC is an equilateral triangle.
A B C 600
sin 2 A sin 2 B sin 2 C sin 2 600 sin 2 600 sin 2 600
3 3 3 9

4 4 4 4

Again differentiating

f x f " x f ' x

......

f x
1

x 1 x 2
x 100
2
f x f " x f ' x 0 g x 0
g x 0 has no solution
2

50.

(b)
Applying Leibnitz rule, we get
f x x x2 f x f x
1

f x dx

1/ 2

51.

x
1 x2

x
x
1 8
dx
dx ln
2
2

1 x
1 x
2 5
1/ 2
1/ 2

(b)

3 i k , i 3 j and i 2 sin j k

2 sin

0 0

2 sin 3 6 0

(b)
Let z rei . Then we have

ps

52.

.i

7 3 2 sin 0 0

ys
ud
.s
t

(b)
S.D. between the lines

x y z

l
m
n
'
x
y ' z '
and

is given by
l'
m'
n'
'
' '
2
S.D. = l
m
n mn ' m ' n

ww
w

53.

te

2
r 2 i
1
e e i 1 r 2

12
3
2
2
2
r cos
r

1
3
3
3
r2
3
2
cos 1
max r 3 i.e., max z 3

m'

n'

2
2
2
mn ' m' n 1 2 1 6

1 2 2
1
S .D. 2 3 4 6
6
3 4 5
2

54.

(a)
log e a is defined for a>0

log

4 x / 1 x is defined for
2

4 x / 1 x 0
Now 4 x 2 x 2 x is real
2

If 2 x 2 and x 2

4 x 0 when
2

x 2

2 x 2 and x 1 2 x 1
Thus the domain of f x is 2, 1

To find the range

Let

4 x / 1 x u
2

f x sin log u, 2 x 1

.i

du
4 x

0
2
dx 1 x 4 x 2

ps

Also,

The function f x is continuous for 2 x 1

ud

when 2 x 1, 1 f x sin log u 1

ys

te

If 2 x 1
Thus in the interval 2 x 1 , u is an increasing function
At x 2, u 0 and at x 1, u
0 u when 2 x 1
when 2 x 1, log u

56.

.s
t

(c)
Given curve is y

ww
w

55.

Thus the range of f x is 1,1

(b)
x2 x4


1
x3
x 2 x3
1 1
L lim 3 1 x .... 1 ..... x ... = L lim +terms
x 0
x 0 x
6
2 24
2 3
6 3

containing positive powers of x 1/ 2

x sin x

Let at P x1 , y1 , tangent be parallel to x-axis, so dy / dx x , y 0

1

. 1 cos x 0
2 x sin x

i.e., cos x1 1, so sin x1 0 .

From (1) and (2), we have
y12 x1 sin x1 x1

Hence P x1 , y1 lies on y 2 x , which is a parabola.

57.

(a)
Odd prime on a dice are 3 and 5.
Let even A = one of the dice shows odd prime
And event B = remaining dice also shows odd prime
n A B
p B / A
n A
A { 3,1 , 3, 2 , 3,3 , 3, 4 , 3,5 , 3, 6 , 1,3 , 2,3 , 2,3 , 4,3 , 5,3 , 6,3 ,

5,1 , 5, 2 , 5, 4 , 5,5 , 5, 6 , 1,5 , 2,5 , 4,5 , 6,5 }

A B 3,3 , 5,5 , 3,5 , 5,3
p B / A 4 / 20 1/ 5
58.

(d)
n M 47, n C 45

n T 53 ,
n M C T 80
n M C T 100 80 20
(b)
Required area

2x 2x

.i

x log x dx

ps

59.

'

2x

dy
1
2 1 x2
2

dx
1 x2 x 1 x2
1
1
2

2
1 x
1 x2

2 2 x2 1 1 x2
=
1 x2
1 2 x2 1 x2
0x R
1 x2
Hence y increases in ,
=

te

ud

.s
t

y 2 x tan 1 x log x 1 x 2

ww
w

60.

ys

2 2 x3 x 2
x2
log x
= x
3 0 2
4 0

1 1 7

log x 2 log x 0

3 4 12
x 0

(d)

:Chemistry :
61.

(d)
H
ka 1
C

62.

(b)
(i) AB S aq AB aq ; H 21 J
(ii) AB S xH 2O AB.xH 2O s ; H 29.4 J

AB.xH 2O S aq AB aq ; H ?
Equation (i) is equivalent to
AB S xH 2O AB.xH 2O s ; H H1

AB.xH 2O S aq AB aq ; H H 2

(c)

.i

63.

H1 H 2 21
29.4 H 2 21
H 2 21 29.4 8.4 J mol 1

ps

It is MA3 B3 type complex therefore it shows fac. & mer. isomers

&

ud

CH

.s
t

CH 2 O

ys

te

64.

ww
w

Number of resonance less stable less acidic nature

||

S O
||

More stable more acidity

65.
66.
67.

(a)
Conceptual
(b)
Conceptual
(d)
1
(i) CO2 CO O2 K1 9.1 1013
2
1
(ii) H 2O H 2 O2 K 2 7.1 1012
2
object CO2 H 2 CO H 2O
equation (i) (ii)
K1
K 1 2 1.28
K

68.

(a)

d O2
1 d NO2
1 d NO

2 dt
2 dt
dt
NO2 is reactant so (Z)
Rate of disappearance of NO2 rate of formation of NO
So NO is (X)
(a)
r

OH

OH

H 2O

H Br

CH 2 Br

CH 2 OH

OH

OH

CH 3 Br

.i

H Br

69.

OH

CH 3

CH 3
Br2

H 3C

CH 3

CH 3

Br

CH 3

Br

H 3C
H 3C

Br2
CH 2

ww
w

.s
t

CH 3

Br

CH 2

CH 3
Chiral center present

71.

72.

(d)
At equation G 0 0
H 7.5 1000
T

300 K
S
25
(d)
MgCl2 Mg 2 2Cl
?
0.01 M

K sp Q Mg 2 OH
1012 0.01 OH

Br

CH 3

Meso
(Not enantiomers)

CH 3
C

CH 3

Br

ys

H 3C

te

(a)

ud

70.

ps

O C H3

CH 2

OH 1010
OH 105

73.

pOH 5 pH 9
(a)
H O H 2O
(1) 2
H 44 kJ
(l )
(g)
1
(2) 2 B O2 B2O3 1273kJ
3
(3) B2 H 6 3O2 B2O3 3H 2O
(g)
H 2035 kJ
(4) H 2 1 / 2 O2 H 2O
H 286 kJ
l

ww
w

78.

.s
t

77.

ud

ys

76.

79.

.i

ps

75.

te

74.

H 1273 286 3 44 3 2035 36 kJ

(b)
Conceptual
(d)
P = 2, Q = 3, R = 0, S = 1
(c)
Zn Cu 2 Zn 2 Cu
2 Zn 2Cu 2 2 Zn 2 2Cu
For 2 moles of Zn, n =4
0
G 0 nFECell
4 96500 1.1 424.6 kJ
(c)
conceptual
(d)
According to Lagmuir curve
ap
x
1 bp
a
p
x
b
p0
x p
(b)

Equation 2 4 3 1 3 3

X e F6
X eO3
3 H 2O
6HF

Sp 3 d 3 Hybridisation
(distorted octahedral)

Sp 3 Hybridisation
(Pyramidal)

MnO4 : HCl 2 :16 1: 8

(a)
1

87.
88.
89.
90.

ps

(b)
Conceptual
(d)
Lyophobic colloids have charge of adsorbed ions on surface whose repulsion stabilizes them.
Higher the zeta potential between fixed and diffused layers, higher is the stability.
(b)
Conceptual
(b)
Conceptual
(c)
It is octahedral void
(a)
Conceptual

te

86.

ys

85.

ud

84.

.s
t

83.

ww
w

82.

1 1
E13 12 3 2 32
E 13.6 2 2 eV / atom ;

1
1
n
n

E
27
1
2
1 2

12 22
(b)
Conceptual
(d)
15 mL 0.1 N NaOH = 15 mL 0.1 N HCl
Vol. of HCl used with NH3 = 20-15 = 5 mL
1.4 NV 1.4 0.1 5
%N=

w
29.5 103
700

23.7
29.5
(a)
Conceptual

81.

(b)
16 H 2 MnO4 5C2O42 2 Mn 2 10CO2 8 H 2O
MnO4 : C2O42 2 : 5
2 K MnO4 16 HCl 2 KCl 2MnCl2 5Cl2 8H 2O

.i

80.