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BS ChE 5
03/31/2016
MA2
Y
Ymax
equation [1.5]
C
1
C
=
+
Y KadsYmax Ymax
equation
[1.6]
This is the form of the isotherm we will use for our CharcoalAcetic Acid system.
At lower concentrations, an alternate isotherm
developed by Herbert F. Freundlich frequently describes the
data better. The Freundlich Isotherm is:
Figure 1.1 General Form of Langmuir Isotherms
If we define Y as the amount of adsorption in units of
moles adsorbate per mass adsorbant, and Ymax and the
maximal adsorption, then:
DESIGN AND METHODOLOGY
A. Preparation of Solutions
First 1000 mL of a 0.100N sodium hydroxide
(NaOH) solution was prepared. To prepare the solution,
about four grams of sodium hydroxide pellets were
weighed in the analytical balance. The pellets were then
dissolved in a small quantity of water and were
transferred to a 1000 mL volumetric flask. Sufficient
water was added until the mark to make up 1000 mL of
the solution. The solution was mixed thoroughly and was
transferred to a reagent bottle and was labeled.
Next 500 mL of 0.500N acetic acid (HAc) solution
was prepared. To prepare the solution, about 18 mL of
glacial acetic acid was pipetted carefully into a 500 mL
volumetric flask and enough water was added to reach the
mark. The solution was mixed thoroughly and was
transferred to a reagent bottle and was labeled.
The titrant solution, which was the NaOH solution,
was standardized using potassium phthalate (KHP). The
amount needed for standardizing the solution was
weighed using the analytical balance and was placed in an
Erlenmeyer flask. This amount of KHP was dissolved
with a small amount of water. A few drops of
phenolphthalein were added to the flask and was titrated
with the NaOH solution. A second standardization was
done.
The normality of the titrant solution was
determined up to four digits.
B. Preparation of Adsorption Solutions
For the preparation of the adsorption solutions, 100
mL each of N/4, N/8, N/16, N/32 and N/64 HAc
solutions. The volume of N/2 or 0.500N HAc solution
required in the preparation of these solution was
computed. The computed volumes were pipetted into
different 100 mL volumetric flasks and enough water was
added to these flasks until the mark. These solutions were
mixed thoroughly and 80 mL of these solutions were
transferred to properly labeled Erlenmeyer flasks and
corks were placed as stoppers. A second set of these
solutions were made for the second trial.
Approximately one gram of activated carbon was
weighed using an analytical balance and was transferred
Y =k C
ln
equation [1.7]
wt. of HAc =
(N)(MW)(L solution)
f
equation
[2.2]
where N is the calculated normality of the equilibrium
solution, MW is the molar mass of acetic acid, L solution is
the volume of acetic acid solution equilibrated with about 1
gram of activated carbon, and f is the equivalence per mole of
a substance. By deducting the weight of acetic acid in the
equilibrium solution from that in the original solution, the
Pressure: 24.96 in Hg
TRIAL 1
TABLE 3.1 Original Concentration of Acetic Acid Solution and Weight of Acetic Acid in the Original Solution
Original
Volume of
Weight of HAc in the
Volume of
Volume of
Concentration
Solution
Original Solution
HAc in
NaOH Used
Titration
N/2
0.4841 N
80 mL
2.3237 g
10 mL
45.7 mL
N/4
0.2421 N
80 mL
1.1621 g
10 mL
22.5 mL
N/8
0.1210 N
80 mL
0.5808 g
10 mL
10.8 mL
N/16
0.0605 N
80 mL
0.2904 g
20 mL
9.9 mL
N/32
0.0303 N
80 mL
0.1454 g
20 mL
4.3 mL
N/64
0.0151 N
80 mL
0.0725 g
40 mL
4.7 mL
TABLE 3.2 Equilibrium Concentrations, Weight of Acetic Acid Adsorbed per gram Activated Carbon
Equilibrium
Weight of HAc
Weight of
Weight of
Weight of HAc per
Concentration
at Equilibrium
HAc
Activated
gram of Activated
Adsorbed
Carbon
Carbon
N/2
0.4515 N
2.1672 g
0.1565 g
1.0 g
0.1565 g HAc/ g AC
N/4
0.2223 N
1.0670 g
0.0951 g
1.0 g
0.0951 g HAc/ g AC
N/8
0.1067 N
0.5112 g
0.0686 g
1.0 g
0.0686 g HAc/ g AC
N/16
0.0489 N
0.2347 g
0.0557 g
1.0 g
0.0557 g HAc/ g AC
N/32
0.0212 N
0.1018 g
0.0436 g
1.0 g
0.0436 g HAc/ g AC
N/64
0.0116 N
0.0557 g
0.0168 g
1.0 g
0.0168 g HAc/ g AC
Freundlich constants: k = 0.2323 n = 1.9262
Langmuir constants: a = 1.4449 b = 7.8429
r = 0.9572
r = 0.9504
TRIAL 2
TABLE 3.3 Original Concentration of Acetic Acid Solution and Weight of Acetic Acid in the Original Solution
Original
Volume of
Weight of HAc in the
Volume of
Volume of
Concentration
Solution
Original Solution
HAc in
NaOH Used
Titration
N/2
0.4841 N
80 mL
2.3237 g
10 mL
46 mL
N/4
0.2421 N
80 mL
1.1621 g
10 mL
22.7 mL
N/8
0.1210 N
80 mL
0.5808 g
10 mL
10.8 mL
N/16
0.0605 N
80 mL
0.2904 g
20 mL
10 mL
N/32
0.0303 N
80 mL
0.1454 g
20 mL
4.3 mL
N/64
0.0151 N
80 mL
0.0725 g
40 mL
4.3 mL
TABLE 3.4 Equilibrium Concentrations, Weight of Acetic Acid Adsorbed per gram Activated Carbon
Equilibrium
Weight of HAc
Weight of
Weight of
Weight of HAc per
Concentration
at Equilibrium
HAc
Activated
gram of Activated
Adsorbed
Carbon
Carbon
N/2
0.4545 N
2.1816 g
0.1421 g
1.0 g
0.1421 g HAc/ g AC
N/4
0.2243 N
1.0766 g
0.0855 g
1.0 g
0.0855 g HAc/ g AC
N/8
0.1067 N
0.5122 g
0.0686 g
1.0 g
0.0686 g HAc/ g AC
N/16
0.0494 N
0.2371 g
0.0533 g
1.0 g
0.0533 g HAc/ g AC
N/32
0.0212 N
0.1018 g
0.0436 g
1.0 g
0.0436 g HAc/ g AC
N/64
0.0106 N
0.0509 g
0.0216 g
1.0 g
0.0216 g HAc/ g AC
r = 0.9734
r = 0.9523
ln y
Linear (y, ln y)
ln C
C/ y
y, ln y
-3
Linear (y, ln y)
-4
-5
-0.78859999999999997
-3.0078
ln C
y, C/y
C/ y
C
y
1
n
ln C
1
b
+
C
a
a
equation [3.2]
CONCLUSION AND RECOMMENDATION
The adsorption of acetic acid on activated carbon at
an approximately constant temperature 24C obeys the
Freundlich equation and Langmuir equation as can be seen by
the evaluated r or the closeness of the points to a curve, but the
best fit isotherm for the experiment was the Freundlich
isotherm which has lesser deviance of points to its curve.
Possible sources of error in this experiment can be
accounted mainly in inaccuracy of reading the measurements.
Failure to titrate or standardize the solutions also increases the
probability of obtaining values that are less likely to obey the
above mentioned equations. The preparation, especially the
transfer of exact amount of solutions, has a great impact on the
concentration the solution will have. Any excess or