hoahocphothong.vn Pham Nooo Diing BAI TAP TRAC NGHIEM TONG ON ESTE VA LIPIT Este X khéng no, mach hé, cé ti khéi so véi oxi bing 3,125 va khi tham gia phan tng xa phong hod tgo ra mét andehit va mot mudi ctia axit hiu ca. Cé bao nhiéu céng thite cu tao phi hgp véi X. A3 B.4 C5 D.2 Cau 2. ‘Hén hop X gém 2 este don chirc hon kém nhau mét nhém -CH-. Cho 6,6 gam hén hop X the dung vita di voi 100m! dung dich NaOH 1M thu duge 7,4gam hn hop 2 mudi. Cong thie cu tgo cia 2 este li: A. HCOOCH; vi CH;COOCH; B. CH;COOC3Hs va CH;COOCH C. CH;COOCH=CH vi HCOOCH=CH) D. CHsCOOC:Hs va HCOOC3H ° : : hs R Lam bay hoi 10,2 gam mét este A 6 dp sudt p, thu duge mot thé ticktyobbang thé tich ca 6,4 gam Oz Cing mhiét dO ap sudt po (biét po = 2 pr). Cong thite phi aA la: A. CsHeOr B. CsHiO2 CCH, C D. CHO; Cu 4, XA phong hod hoan toan 1,99 gam hdn hgp hai este vik ie dich NaOH thu duge 2,05 gam mudi cia mét axit cacboxylic va 0,94 gam hén hi ol 1a ding dang ké tiép nhau. Cong thire cua hai este dé la: A. CxHsCOOCH; vi CzHsCOOC;Hs C. CH;COOCH; va CH;COOC;Hs ICOOCH; via HCOOCHs SD. CHsCOOC;Hs vi CH;COOCSH ‘Xa phong hoa hoan toan 17,24 gai dich sau phan img thu duge khi luong xa pM A. 18,38 gam. B, 18,24 gan C. 17,80 gam, D. 16,68 gam. Cau 6. 7 Este X c6 céng thite phan ¢F G20, khi cho a gam X tac dung vita di voi 300 gam dung dich NaOH 4% thi thu ancol hai chite Y va 26,7 gam hén hop hai mudi. Céng thite cau tao thu gon ctia X A. CH3;COO-(CH)) C. CH;COO-(CH2);. Cau. : ‘Cho cot (hay triolein) lan hot vao mdi éng nghiém chia rié can vira di 0,06 mol NaOH. Cé can dung B, HCOO-(CH;),-OOCCH; D. CHsCOO-(CH3);-OOCH ‘. Cu(OH, CI dung dich Brs, dung dich NaOH. Trong diéu kign thich hgp, xay ra li: , 4 ALS Ae mh B.3. C.2. D4. Cau ‘4 phong héa hoan toan | mol este X thu duge 1 mol mudi va x (x > 2) mol rugu. Vay este X duge tao thanh tir A. axit don chite va rugu don chic B. axit da chite va rugu da chite C. axit don chire va rugu da chire D. axit da chite va rugu don chire Cau 9. Dét chay hoan toan 1a mGt este X don chic, mach hé cé mét néi ddi C = C thu duge 1,12 lit CO, (dktc) va 0,72 gam HO. Céng thite phan tir cua X la: A. CyHs02 B. CsH1902 C. CyHgO, D. CsHs02Cho chét httu co A chi chita mot loi nhém chite tée dung v6i 1 lit dung dich NaOH 0,75M thu dugc 0,45 mol mudi va 0,15 mol rugu. Lugng NaOH du cé thé trung hoa hét 0,75 lit dung dich HCl 0,4M. Cong thite tng quat tia A 14: A. (RCOO)R' B. RCOOR' C.R(COOR’); D.(RCOO);R' Cau 11. Cho 32,7 gam chat hitu co X chi chira mét logi nhom chite tée dung voi 1,5 lit dung dich NaOH 0,5M thu duge 36,9 gam mudi va 0,15 mol rugu, Lugng NaOH du cé thé trung hoa hét 0,5 lit dung dich HCI 0,6M. Céng thitc cau tao thu gon ciia X Ia: A. C3H(COOCH:)3 B, CH;COOCHs C. (CH)COO),CHy D. (CHCOO)sCsHs » Cau 12. Dun néng 65 gam axit arte véi 88 gam ancol isoamylic (CHACH gy aHLOH 6 H,SO, dc xiie tac kh6i lugng este thu duge ld (Biét H = 68%) ‘A. 95,77 gam B. 88,40 gam C. 98,76 gam Oo D. 85,60 gam Cau 13, M@t este cong thte phn ti 1 Cal khi thy phn trong méidrng ext thu duoc andehit axetic. Cong thite cau tao thu gon este dé la: A. CH;COOCH=CH; iets ‘CHCH3 C. CH;=CHCOOCH; \COOC(CH3)=CHy, 4. XA phong héa hoan toan 14,55 gam hén ho te dom chite X, Y cin 150 ml dung dich NaOH 1,5M. Sau phan img c6 dung dich 1 ‘hop chat hai ancol déng ding ké tiép va mbt mudi duy nhat. Céng thite cu tao thu goAgy) ha este li: ‘A. HCOOCH va HCOOC3Hs N B. CsH/COOCHL va CsHyCOOCiH C. CHsCOOCHL vi CHsCOOCH, 0) ._D,CHsCOOCH; va CH;COOC3Hs Cau 15. ‘Thuy phan este Y trong dung djeh KOH theo phan tmg; Y+ KOS axetat + axeton Céng thite cdu tao ctiaX. A. CH)=C(CH)C B. CH;COOCH;C! C. CH;COOCH: D. CH;COOC(CH; Cau 16, Tron 13,6 gan» phenyl axetat véi 250 ml dung dich NaOH 1M. Sau khi phan ing xay ra hoan toan c4 ean dung dich sau phan img thu duge m gam chat rin khan. Gia trj ca m la: 8.2 C. 10,2 D. 21,8 “eHlén hop X gém 2 este don chite mach hé la déng phan ciia nhau. Cho m gam X téc dyng-vira di véi 100 ml dung dich NaOH IM thu duge mét mudi cia axit cacboxylic va hon hgp hai ancol. Mat khéc, néu dét chéy m gam X thu duge 8,96 gam CO; va 7,2 gam H,0. Céng thitc cau tao cia 2 este 1a: A. CH;COOCH(CH3)CH;CH, va CHs;COOCH(CH,CH3): B, CH;COOCH;CH3CH; va HCOOCH(CH)2 C. CH;COOCH,CH,CH2CH; va CH;COOCH(CHs)CH,CH; D. HCOOCH(CHs): va HCOOCH,CH:CHs Cau 18, $6 hgp chat la déng phan cu tao, cé cling cng thire phn tli CyHsO, tic dung duge véi 2O hoahoophothong.vn Pham Nooo Ding dung dich NaOH nhung khéng tac dung duge véi Na la: _ ad A2 B.4, Ca: D1. Chu 19, : : : XA phong héa 1 kg lipit c6 chi sé axit ld 2,8 ngudi ta cin ding 350 ml KOH IM. Khéi lugng glixerol thu duge 1a: A. 32,2 gam B. 16,1 gam C.9,2 gam D.18,4 gam Cau 20, Thyc hién phan img este héa hén hop gdm 322,5 gam axit metacry metylic véi higu suat dat 60%. Khoi lrgng metyl metacrylat thu duge li: A. 262,5 gam B. 225 gam C. 300 gam D. 187,5 gam Cau 21. Dun néng 18 gam axit axetic véi 9,2 gam ancol etylic c6 mat HSO, dic fanPic tae Sau phan img thu duge 12,32 gam este. Higu suat phan tng este hod la: A. 92,35% B. 35,42% C. 70,00% 46,67% Cu 22: Dé thi tuyén sinh DH khdi B- 2011 Phat biéu nao sau day ding? y “ A. Trong phan img este hod gia CH\COOH véi CHOH, 1:0 5 Neff tir OH trong nhém ic va 150 gam ancol ~ COOH ciia axit vi H trong nhém ~ OH cia ancol. B. Phan tng gitta axit axetic vi ancol benzylic (6 diéu kién th mui thom ciia chudi chin. =’ C. Bé phan biét benzen, toluen va stiren (6 diéu as ‘bang phuong phap hoa hoc, chi can aug {ao thanh benzyl axetat c6 diing thude thir la nude brom. D. Tat ca cdc este déu tan tét trong nudc, khong d6c, nghiép thyc pham, my pham. Cfu 23. X la mét este don chite, 66 ti kh voi dung dich NaOH dur, thu duge 4,1 uh A. CH;COOC:Hs C. HCOOCH,CH;CH;, Cau 24, 7 Hai este don chite xO dng phan ciia nhau. Khi héa hoi 3,7 gam X thu duge thé tich hoi ding bing thé tictr'gde 1,4 gam No (do cing digu kign nhigt d). Cong thite edu tao thu 1g lam chat tgo hyong trong cng véi CH, ld 5,5. Néu dem dun 4,4 gam este X i. COng thire cu tao thu gon cia X la: B, HCOOCH(CHs)2 D. CHsCOOCH; gon cia X va Y Ia: A. HCOOGHs Mrcooen, B, CHsCOOCH; va HCOOCH(CH3) C. CoHsCOOS D. HCOOCH,CH2CH; va CH;COOC:Hs X la,b6n hyp 2 este cd cing mét ancol no, don chite va hai axit no, don chtte dong ding ké tiép, Bok chay hoan toan 0,1 mol X cdn 6,16 lit Op (dktc). Dun néng 0,1 mol X véi 50 gam d h NaOH 20% dén phan tig hon toan, ri c6 can dung dich sau phan img duge chat ran. Gid tri cua m 1a: A.37,5 gam B. 15 gam C.7,5 gam D. 13,5 gam Ciu 26, : : Thuy phan chat X cd CTPT CsH;4Qs thu duge rugu etylic va chat hiru co Y. Cho biét Sé mol X : sé mol C;HsOH = % sé mol Y. Y duge diéu ché tryc tiép tir glucozo bang phan Gg lén men, tring ngung Y thu duge mét loai polime. CTCT thu gon ciia X la: ‘A. CxHs0COCH(OH)CH,COOC;Hs B. CHsOCOCH-COOCHs C. CH)(OH)CH,COOCH,CH,COOCHs D. CH;CH(OH)COOCH(CH3)COOC;HsPe ae . Nyoo Ding “htop chat hitu cv X don chite chita C, H, O. Bét chdy hoan toan X thu duge sé mol CO = 1,5 s6 mol H,0 = 1,5 s6 mol 02. Biét X tée dung duge voi NaOH va tham gia phan img trang guong. CTCT thu gon cia X la A. HCOOCH; B. HCOOCH,CH; (C, HCOOCH;CH=CH) D. HCOOCH=CH; Cau 28, Xa phong hod 8,8 gam etyl axetat bing 200 ml dung dich NaOH 0,2 M. Sau khi phan mg xay ra hoan toan, c6 can dung dich thu duge chat rn khan c6 khéi lugng la: A.3,2 gam B. 5,12 gam C. 8,56 gam D. Dn Cau 29. ; Thiy phan este X trong moi trudng axit thu durgc hai chat hitu co A va B Oxi hoa A tg0 ra sin phdm 1a chat B. Chat X khong thé 1a: . A. Etylen glicol oxalat B. Isopropyl at C. Vinyl axetat D. etyl axe Cau 30. “ cin dung 150 ml dung dich NaOH x (mol/!). Gia tri ca x Ia ALLS B.1 C.2 % Cau 31, | Xa phong héa hoan toin 0,1 mol m6t chat hife,¢6,Schira C,H, O) cdn vita dit 300 ml Xa phong héa hoan toan 13,2 gam hdn hgp 2 este oe va CHyCOOC;Hs D.0,5 dung dich NaOH 1M cé can dung dich sau phan imikgyedice 24,6 gam musi khan. Cong thire cia X la: A. C3Hs(COOCH3)3 ~ B. (CHCOO);CsHs C. (HCOO);C3Hs Ny D. (CH3COO):C:Hy Clu 32: Dé thi tuyén sinh DH khéi B ‘Cho day cac chat: phenyl axetat: Iaxetat, metyl axetat, ety! fomat, tripanmitin. $d chat trong day khi thay phan trong dung di¢h NaOH (du), dun néng sinh ra ancol 1a : BM C5 D.3 Hop chat thom A Ethie phan tir CyH,O>. Khi phan img véi dung dich NaOH thu duge a mudi. $6 oy pain cu tao ctia A phi hgp voi gia thiét trén 1a: ar 5 C4 D.2 ae 34. Hén aap m 2 chat httu co A, B chi chtra mt loai nhom chite. Cho m gam X téc dyng hét ygiNNaDH thu duge mot mudi cua axit hiru co don chire va hén hgp hai ancol, tach nude hpan fin hai ancol nay é diéu kign thich hgp chi thu duge m6t anken lam mat mau 24 Biét A, B chita khéng qua 4 nguyén tu C trong phan ti. Gia trj ctia m la: B, 22,2 eqs D. 26.4 Cau 38: Dé thi tuyén sinh DH khéi B- 2011 Cho 200 gam mét loai chat béo c6 chi s6 axit bing 7 tic dung vira dii véi mét lugng NaOH, thu duge 207,55 gam hén hp muéi khan, Khéi lugng NaOH da tham gia phan ting la: A. 31,45 gam. B. 31 gam, C. 32,36 gam D. 30 gam. Cau 36. Cho glixerol tac dung véi hén hgp ba axit béo gdm: axit oleic, axit stearic va axit panmitic thi sé este thu durge tdi da la: ALI8 B.12 c.21 D.15hoahocphothong.vn Pham Ngoc Ding Céu 37. ee X 1a m6t este no don chite cé ti khéi so véi metan bing 5,5. Néu dun 2,2 gam este X véi dung dich NaOH dung dich thu dugc 2,05 gam mudi. Céng thite cau tao cita X 1a: A. CH;COOC3Hs B, HCOOCH(CHS)2 C. HCOOCH,CH;CH; D. CzHsCOOCH; Cau 38, Mt loai m& chtra 40% olein, 20% panmitin va 40% stearin. Xa phong héa hoan toan m gam md trén thu duge 138 gam glixerol. Gid tr) ciia m 1A A. 1326,00 B. 1209,00 C. 1304,27 D. 133,01 Cau 39, t X thu Hén hgp A gdm hidrocacbon X va 1,16 gam este sec-butyl axetat. Dét chayehi duge 5,28 gam CO; va 2,52 gam HzO. Hidrocacbon X la: A. GH B. CiHio C. G3Hs ‘D"CsH, Cau 40. oo MOt logi ma chita 70% olein (glixeryl trioleat) va 30% stearin (glgr)I stearat) vé khdi lugng. Khdi lugng xa phong Na thu duge khi xa phong h6a hoan toan (0Qkg mo dé Ia: A. 103,16 kg. B. 68,0 kg Se, 7 D. 90,8 kg, Ciu4l. | A ___Détchdy hodn ton a mol hén hgp X gdm 2 mudi ni ding lign tiép can 9,52 lit O; (6 0°C, 2 atm), phan chat Ri 10,6 gam, CTPT ciia hai mudi la: ‘A. CH;COONa va C3HsCOONa CsHyCOONa va C,HoCOONa C. CsHsCOONa va CsH;COONa HCOONa va CHsCOONa Cau 42, M6t este tao bai axit don chite va oe chitc ¢6 ti khdi hoi so v6i khi CO; bing 2. mi Khi dun néng este véi dung dich NaO) 1u6i c6 khdi lugng 1én hon Iugng este da phan mg, Céng thite cdu tao thu gon ctia ¢ . A. HCOOC3H;, Coit no don chic la ding n lai sau khi dét edn nang B. C;HsCOOCHs C. CH;COOCH " D, CH;COOC;Hs Clu 43: Dé thi tuyén sinh DEN B-2011 Triolein khong tac demgvoi chat (hodc dung dich) nao sau day? : 4A. FO (xt téc HS , dun néng). B. Cu(OH): (6 digu kign thuéng). C. Dung dich NaOWi (din néng). D, Ha (xi tée Ni, dun néng). Cau 44, Ae Hop cg X tde dung duge véi dung dich NaOH dun néng va véi dung dich AgNOs ty Thé tich cua 3,7 gam hoi chat X bing thé tich ca 1,6 gam khi O2 (cing dieu ki ihigt 4 va dp sudt). Khi dét chay hoan toin 1 gam X thi thé tich khi CO, thu duc qua 0,7 lit (6 dkte). Céng thite cau tao ctia X 1a: ]OC-CHO. B. HCOOCHs C. HCOOCH; D. O=CH-CH,-CH;0H. Céiu 45: Dé thi tuyén sinh DH khéi B- 2011 : Hn hop X gém vinyl axetat, metyl axetat va etyl fomat. Dét chdy hodn ton 3,08 gam X, thu duc 2,16 gam H20. Phan tram sé mol cia vinyl axetat trong X 1a A. 75% B, 72,08% C. 27,92% D.25% CAu 46: Dé thi tuyén sinh DH khdi A - 2011 ‘Bat chay hodn toan 3,42 gam hén hop gdm axit acrylic, vinyl axetat, metyl acrylat va axit oleic, r8i hap thy toan bé sin phim chay vao dung dich Ca(OH)» (du). Sau phan img thu duge 18 gam© presse két tia va dung fe Kh6fluong X so véi khéi Iueng dung dich Ca(OH): ban dau da thay di nhur thé nao? A. Giam 7,38 gam. B. Tang 2.70 gam. C. Tang 7,92 gam. —_D. Gidm 7,74 gam. Cau 47, 7 ‘Dat chay hoan toan 0,1 mol mot este X rdi cho san phim chdy vio dung dich Ca(OH), du thu duge 20 gam két tia, Céng thite phan ti cia X la: A. HCOOCH; B, CH;COOCH; C. HCOOC;Hs D. CH;COOC;Hs Céu 48, ‘Dun mét lugng dur axit axetic véi 20,7 gam ancol etylic (cd axit HS, dic lamxtic tac). Dén khi phan tng dimg lai thu duge 16,5 gam este. Higu sudt cla phan tmg mci A. 62,5% B.41,67% C. 75% % Cau 49, Cho 0,15 mol hén hop hai este don chite phan ting vira di véi 0,25 mol. on thu duge hn hop hai mudi va mét ancol c6 khdi hrong twong tg 14 21,8 gam Bim. Hai este da cho 1a: A. CH;COOC(Hs va CH;COOC)Hs B. CH;COOCgi#%a CH;COOCH; C, HCOOC,Hs va CH;COOCH; D. HCOOC(Hs va HCOOCHs Cau $0, t Dét chay hoan toan 0,1 mol este X thu duge 0,3 Hf) YO, va 0,3 mol H,0. Néu cho 0,1 mol X tac dung hét voi NaOH tao ra 8,2 gam mi te cfu tao cia X la A.HCOOCH; —_B. HCOOC:Hs ie! D. CH;COOC2Hs Cau 51. 7 Cho axit axetic tic dung vira di voi, m@Mencol trong day ding ding cita ancol etylic (xtic tic H)SO, dic dun néng, H = 100%), lay ancol nao dé cé s6 mol bing sé mol axit axit axetic va kh6i lugng ciing bing khdjAgodg axit d6. A. CoHsOH B.CH;OH _\. C. CHoOH D. C;H,0H Cfu 52. Cho 8,6 gam este X bay*o? durge 4.48 lit hoi X & 273°C va 1 atm. Mat khéc, cho 8.6 gam X téc dung vira dit ayn dich NaOH thi thu duge 8,2 gam mudi. Cong thite cdu tao diing ciia X La: A. HCOOCH)=CHy, B. CH;COOCH;CH; C. CH;COOCH=CH3" D, HCOOCH,CH;CH3 Cau 5: ° Dét chay foan toan 4,4 gam chit hitu co X don chic thu duge san pham V gém 4,48 lit CO) (dkt 6 gam HO. Néu cho 4,4 gam X téc dung vira dit voi dung dich NaOH thu duge 4, 1udi cita axit hiru co Y va hgp chat hitu co’ Z. Tén goi cia X la: A.dsopropyl axetat B. Etyl propinat Coty! axetat D. Mety! propionat Cau 54. Day thudc thir thich hop dé phan bigt 4 chat Ing riéng biét: ancol etylic, andehit axetic, axit axetic, metylfomiat dung trong 4 19 mat nhan la: ‘A.Na, dung dich AgNO3/NH3 B. Gidy quy tim, NaOH C. Gidy quy tim, dung dich AgNOy/NHy, D. Cu(OH):, NaOH Cau 5 Lan lugt cho cae chat vinyl axetat; 2,2-diclopropan; phenyl axetat va 1,1,1-tricloetan tac dung hoan toan véi dung dich NaOH du. Trudng hgp nao sau day phan tg khéng viet ding? 6Omens Pham Nooo Di A. CHsCHCI; + 4NaOH — CH;COONa + 3NaCI + 2H,0. (sat B. CH;COOC,Hs + NaOH -> CH;COONa + CsHsOH C. CH;COOCH=CH + NaOH > CH;COONa + CH;CHO D. CHsCHCI;CH; + NaOH + CHsCOCH; + NaCl + H20 Cau 56, Phat biéu nao sau day khdng diing vé xi phong va chat ty rita tng hop? ‘A. Xa phdng va chat tay rita téng hop duge san xuét bing céch dun néng chat béo véi dung dich kiém B. Xa phong 14 hén hop mudi natri (hod kali) cla cde axit béo, khong nén ding xa phong trong nue cig vi tao ra 1 mudi két tia clia canxi va magic C. XA phong va chit ty nia tng hgp c6 kha nang hoat dong bé mat cao, c6 igduris fam gidm site cang bé mat chat ban D. Chat tay riza tng hop khéng phai la mudi natri cia axit cacboxylic khry tua trong nude cig Cau 57. Dét chay hoan toan 20,1 gam hén hop X gdm 2 este don cl tiép can 46,16 lit Mig khi. Cong thite cia khéng khi (dkte) thu duge 46,2 gam CO). Biét O» chiém X% thé oe este 1a; A. CsHig02 Va CoH 202 geo, va H,02 C. CqHOp va CsHyO2 oO CHO va Col i902 Cau 58. H6n hop X gém 2 axit HCOOH va CHsCOG sé mat bing nhau. Lay 5.3 gam X tac dung vdi 5,75 gam C7HsOH (c6 H;SO, dic xiicQae) thu duge m gam hén hop este (higu suat cdc phan tmg este ho déu bing 80%). Gid tri nica tim la: A648 B. 16,20 % C. 10,12 D. 8,10 Cau 59, S 2 14 gam mét mau chat béo cAn 15m] dung dich Dé trung hoa luong axit ty KOH 0,1M. Chi sé axit cia mat 20 trén 1a: ASS B80" C48 D.72 Cau 60. Dy’ M6t este c6 céng,thite*phan tir 1a CyH,O2 khi thy phan trong méi trudng it thu duge andehit acrylic. C edu tao ctia CyHyO> 1a: A. HCOOCH: B, CHyCOOCH=CH) C. CH= igo D. HCOOCH=CHCH; Ciusl. ¢ chi gam este X thanh hai phan bing nhau. Dét chay hoan toan phan 1 thu dug 4,48 (dktc) va 3,6 gam HO. Phin 2 téc dung vira di voi 100 ml dung dich NaOH nage rj cia m 1a: ADS B.44. C88 D.2,2 ‘Thuy phan hoan toan hén hgp gdm 2 este don chite X, Y 1a dong | phan cu tao cla nhau cin 100 mi dung dich NaOH 1M thu duge 7,85 gam hén hop hai mu6i ciia hai axit 1a ddng dang ké tiép va 4,95 gam hai ancol béc I. Céng thite cdu tao va % khdi lugng cua 2 este la A. HCOOCH,CH; 55%; CH;COOCH; 45% B, HCOOCH;CH; 45%; CHsCOOCH; 55% C. HCOOCHCH;CHs 25%; CHsCOOC Hs 75% D. HCOOCH,CH,CH; 75%; CHsCOOC;Hs 25% 7/hoahocphothong.vn Pham Noe Dis Cau 63. * taslet / Cho 0,1 mol mét este X tac dung vira di voi dung dich chita 0,2 mol NaOH thu duge hn hop 2 muéi cia hai axit hitu co déu don chite va 6,2 gam m6t ancol Y. Ancol Y la: A. CHyCH;CH,OH B. CoH(OH)2 C. CH(OH)s D. CH(CH,OH)2 Cfu 64, X 1a mot este cua m6t axit hu co don chire va ancol don chite. Thuy phén hoan toan 7,04 gam X ngudi ta ding 100 ml dung dich NaOH 1M lay dur 25%. Sé céng thite cdu tao thoa man cia X la: A3 B.2 C4 D.S Cau 65. Khi dét chy m6t este cho s6 mol CO) va H;O bing nhau. Thuy phan hodn i6an 6 gam. este nay thi cin dung dich chira 0,1 mol NaOH. Céng thite phan tir cia este la: “Oy A. CsHio02 B. CH,O, C. C3H(O2 CyH,02 Cau 66. Cho este X c6 céng thire cdu tao thu gon cla CH;COOCH: day la sai? ‘A. X laeste khong no don chite B, X c6 thé lam mat mau nuéc brom C. X duge diéu ché tir phan img gitta ancol va axit tuons D. Xa phong hoa X san phdm 1a mudi va andehit inh nao sau ‘au 67, Thuy phan este E c6 cong thi i sie mit H,SO, lofing) thu durge hai san pham hitu co X va Y. Tir X c6 thé diéu cl Ip ra Y bang mét phan img duy nhét. Tén goi cia E la: A. propyl fomiat C. etyl axetat ‘ Cau 68. © Mét hén hop X gm gthitu co don chite, Cho X phan img vira du voi 500ml dung dich KOH 1M. Sau phan oa Sie hén hop Y gdm 2 mudi ctia 2 axit cacboxylic va mot ancol. Cho toin bé lugng angol thu duge 6 trén tac dung véi Na du, thu duge 3,36 lit Hy (d.k.tc). Hin hgp X gi me) Ahaieste B. mét axit va mdt este CC. mét axit va mét ancol D. mét este va mét ancol Cau 69. ‘Xa phOMAhod hoan todn 0,2 mol metyl axetat bing dung dich NaOH du 20% so véi long phatraing thu duzge dung dich X. C6 can dung dich X thu durge bao nhiéu gam chat rin? AJ&k0™ B. 18.4 C.244 D.16,4 mn B. metyl propionat D. ancol etylic huy phan 4,3 gam este X don chite, mach hé (xtc tée axit) dén khi phan tng hoan toan thu duge hén hgp hai chét httu co Y va Z. Cho Y va Z phan img véi lugng dur dung dich AgNOs/NH; thu duge 21,6 g Ag. Céng thite edu tgo ca X la: A. HCOOC(CH3)=CH, B, HCOOCH=CHCH C. CH;COOCH=CH) Cau 71, Dun 20,4 gam mét chat hitu co A don chire véi 300 ml dung dich NaOH IM thu durge mudi B va hgp chat hitu co C. Cho C tac dung voi Na dur thoat ra 2,24 lit khi Hz (d.k.t.c). Biét khi nung B vai NaOH rin duge khi K 06 ti khéi so véi O2 bang 0,5. Hop chat hiu co C don 8chite khi bj oxi hoa béi CuO dun néng tao ra sin phim D khong tham gia phan img trang bac. Cong thite edu tao cua A 1a: A. Két qua khde B. CH;COOCH,CH,CH; C. CH;CH;COOCH(CHs): D. CHsCOOCH(CH3), Cau 72. Cée déng phan tg véi cong thire phan tir CgHgO> (déu 1a din xudt benzen) tac dung véi NaOH tao ra mudi va rugu la: A3 B.4 C.2 D.7 Cau 73. Cau nao sau day khéng ding? x» A. Chat béo nhe hon nuée va khong tan trong nude B, Hidro héa dau thye vat long sé tgo thanh cdc mo dong vat rin CC. M@ dong vat chi yéu céu thanh tir cde axit béo, no tén tai 6 trang thai rin “S. @ D. Dau thye vat chi yéu ehtta ec axit béo khOng no tn ta 6 trang thai long“. Cau 74, Bé xa phong hod hon todn 1,51 gam chit béo cin ding 45 ml Chi s6 xa phing hod chat béo la: 7 ASI B.167 €.252 0) D. 126 Cau 75, Este X c6 céng thirc don gian nhat la C,H,O. Dun NaOH 3% dén khi phan img xay ra hoan toan. 8,1 gam chat ran khan. Cong thite cu tao ciia X 1a: ME dich KOH 0,1M. ‘gam X véi 200 gam dung dich ng dich sau phan ing thu duge A. CH;CH,COOCH oO B. HCOOCH(CH): C. CH;COOCHCH3 D. HCOOCH;CH3CH; C4u 76. Cho 2,64 gam mét este ciia axijgcacboxylic don chire va rugu don chite phan img vira hét véi 60 ml dung dich NaOH 0,5 dirc chat X va chat Y. Dét chay hoan toan m gam chat Y cho 3,96 gam CO; va 2,16 gam'H,O. Cong thite céu tao clia este la: A. HCOOCH;CH,CH3 NY : B, CH\COOCH;CH;CHs C.CH:=CHCOOCH; D. CH;COOCH=CH) Cau 77. Xa phong héa he mét trieste X bang dung dich NaOH thu duge 9,2 gam glixerol va 83,4 gam mudi clint axit béo no B. Chat B la: A. axit ane eB. axit axetic C. axit oleic D, axit stearic 1H; tae dyng duge véi dung dich Br, 1H, cing day ding ding voi CHjOCOCH=CH,-CH D. CH,CH,COOCH=CH, tée dung duge véi dung dich NaOH thu durge andehit va muéi Cau 79. . ‘Xa phong héa 4,4 gam etyl axetat bing 100 ml dung dich NaOH 1M. Sau phan img xay ra hoan toan, cd can dung dich thu duge chat rin khan c6 khéi lugng a: A. 41 gam B. 4,1 gam C. 6,1 gam D.61 gam CAu 80, X 1a este tao duge glixerol ‘va hai axit (fomic va axetic). X tac dung duge voi Na giai phéong Hp. Téng sé céng thitc cau tao théa man diéu kign cita X la: 9© geese eee CAu 81: Bé thi tuyén sinh Cao ding khéi A - 2011 . ‘Dé xa phong hoa hoan toan 52,8 gam hdn hop hai este no, don chic, mach ho 1a dng phiin cia nhau can vita dit 600 ml dung dich KOH 1M. Bist ca hai este nay déu khéng tham gia phan img trang bac. Céng thite ca hai este 1a sCOOC:Hs va C3HrCOOCH: B. C:HsCOOCHS va CHsCOOC:Hs. HCOOC:Hb va CHsCOOC3EP. D. CHiCOOG:Hs va HCOOC:Hh. 8: Cho 20 gam mét este X (c6 phén tir khéi la 100 d.v.C) tae dung véi 300 ml dung dich NaOH IM. Sau phan tmg, c6 can dung dich thu duge 23,2 gam chat rin khan, Cong inesgle tao ctia X la: A. C)HsCOOCH=CH, B. Ck rcuca,coosd, » C. CHy=CHCOOC;Hs D. CH;COOCH: Cau 83. a Hidro hod hoan toan m gam triolein thu duge 89 gam tristearin. Gi A488 B. 88,9 C. 88,4 cS D. 84,8 Cau 84, © Thuy phan hoan toan este A ciia mét axit hitu co don chtteva mét ancol don chite bing lugng dung dich NaOH vira di. Lam bay hoi hoan toan dupadieH’ sau thuy phn. Phan hoi duge dan qua binh (1) dyng CuSO, khan dur. Hoi khé oon UR tu hét vao binh (2) dng Na du, thdy ¢6 khi G bay ra va khoi long binh 2 ting them 6,2 gam. Dan khi G qua binh (3) dyng CuO du, dun néng thu duge 6,4 gam Cu. iy ‘A ban dau téc dung véi dung dich brém dur thi c6 32 gam brém phan tmg thu duge samphin trong dé brom chiém 65,04% khdi lugng phan tit. Tén goi A la A. vinyl axetat WN B. metyl metacrylat C. metyl acrylat D. metyl axetat Cau 85, - . Khéi lugng NaOH cén dé tryag'hod Yam chat béo ¢6 chi A.7 mg B,9 C.5mg D.3 mg Cau 86: Dé thi tuyén sinh Cag tang khéi A - 2011 Cho m gam chat hitu chite X tac dung vira di véi SO gam dung dich NaOH 8%, sau khi phan tng hoan toan thu dyge 9,8 gam mudi ciia mét axit hiru co va 3,2 gam mot ancol. Céng thire cla Xa . 4. CHsCOOCH: B. CHsCOOG:Hs, ©. CHsCOOCHD. D. CH=CHCOOCES. Cau 87 mY }a hodn toan 66,6 gam hén hop hai este HCOOC;H; va CH;COOCH; bing dung ighior thu duge hén hop X gdm hai ancol. Bun néng hén hgp X vi H,SO, dye & 140°C-Sat%hi phan img xay ra hoan toan thu duge m gam nude. Gia trj ctia m la: A. 18}00. B. 8,10. C.4,05. D. 16,20. Céu 88, Thuy phan hoan toan 0,1 mol este (RCOO);R’ bing dung dich NaOH thu duge 28,2 gam mudi va 9,2 gam ancol. Céng thire phan tir ciia este La: A. (CxH;COO);C4Hy B, (C:HsCOO);C3Hs C. (C3H;COO);C3Hs D. (CpH3COO);CsHs Cau 89. 1uy phan este X trong dung dich NaOH theo phan img: X + 2NaOH > mudi Y + ancol Z + HzO Céng thie cau tao ca X 1a: 10© mesyseee “ee ig A. CHy;COOCH=CH) B. C3H;00C-COOC! C. HOOC-COOC)Hs D. HOOC-COOCH=CH) Cau 90. Dun néng hén hop hai axit béo R\COOH va R,COOH véi glixerol sé thu duge bao nhigu este? A8 B.9 cs D.17 31, Bun néng hén hop ba axit béo R\COOH, RxCOOH va R;COOH véi etandiol sé thu duge bao nhigu este khang téc dung durgc voi Na? A3 B.S C9 D.6 Cau 92. A Dun hgp chat hiru co X (CsHigO,) voi dung dich NaOH du thu duge mudi va ancol B Nung A véi NaOH rin thu duge hidrocacbon C c6 ti khéi so véi hidro bang chat hitw co B khi bj oxi hos boi CuO dun néng thu duge sin phim D c6 phan tng gj Cu(OH),/OH” tao két tia d6 gach. Cong thite edu tao cia X la: A. CH;COOCH(CHs)2 5 cus (OOCH,CH; ra tdi da bao nhiéu sin phdm este? C. CH;=CHCOOCH,CH; Gpooen CH) Cau 93. . Cho glixerol tac dung véi hén hgp ba axit béo Ri oo OH va R;COOH thi tao Al2 B.S D.18 Cc. cine oe \ Cho m gam hon hgp gom hai chat hitu code chite, mach ho tac dung vita di voi dung dich chtta 11,2 gam KOH, thu duge mudi if axit cacboxylic va mét ancol X. Cho toan 6 X tic dung hét voi Na thu duge 3,36 livkhNi (6 d.k.t.c). Hai chat hau co d6 1a: A. hai axit. 7 B. mét este va mét ancol. C. mt este va mgt axit, © D. hai este Cau 95, ~~ Hai hgp chat hou co XY 86 cing céng thite phan tir CsHsQ>. Ca X va Y déu tac dung véi Na; X tac dung duge va NGHCO; con Y c6 kha nang tham gia phan tng trang bac. Cong thite cdu tgo cua X va Y Jdinjbet la: ‘A. HCOOC)Hs eHCOCH; B. CsHsCOOH Npbocin C. CH;CO 1;CH(OH)CHO. D. HCOO@ MMA HOCH,CH,CHO. Cau 96, 4 ng X c6 chi sé axit bing 7. Xa phong hod 20 kg chat béo trén ngudi ta dun né voi di h chia 71 mol NaOH. Sau phan ting két thie muén trung hoa hén hgp ean 1 lit dung, ICl 1M. Lugng glixerol thu duge a: A. 3,070 kg B. 4,070 kg C. 2,070 kg D. 1,070 kg Cfu 97: Dé thi uyén sink Cao ding khdi A - 2011 Bé phan img hét véi mét lugng hén hop gdm hai chat hitu co dom chite X va Y (Mx < My) edn vvita di 300 ml dung dich NaOH IM. Sau khi phan tmg xdy ra hoan toan thu duge 24,6 gam mudi ciia mt axit hitu co va m gam mot ancol. Dét chay hoan toan long ancol trén thu duge 4,48 lit COe (dktc) va 5,4 gam Ha0. Céng thite ctia Y 1a A. CHsCOOCH:. B. C2HsCOOC:Hs. (C, CH»=CHCOOCHS. D. CHsCOOC:Hs. Cau 98, Khi phan huy hoan toan 0,05 mol este cia mét axit da chite véi mét ancol don chite cin uhoal hothong.vn Pham Nove Dio : ding 5,6 gam KOM. Mat Pha khi phn huy 5.475 gam este dé thi can 4,2 gam KOH va thu durge 6,225 gam mubi. Cong thite cia este la: A. (COOC:Hs)2 B. (COOCH;CH3CH3), C. (COOCHS), D, CH{COOC}Hs)z Céu 99. Mét este c6 céng thite phan ti C3H,O2 c6 phan img trang guong véi dung dich AgNOs trong NH3. Céng thite cau tao cua este la: A. C:HsCOOH B. HCOOC;H;, C. CH;COOCH; D. HCOOC;Hs Cau 100. ‘Muén phan biét diu nhét béi tron may véi dau nhot thyc vai 1, Dun néng voi dung dich NaOH, dé ngugi cho san pl chuyén sang dung dich mau xanh thim la dau thyc vat |, ngudi ta dé xudt 3 tac dung voi Cu(Ok))S 2. Chat nao tan trong dung dich HCI la dau nhét RSs 3. Cho vio nude chat ndo nhe n6i trén bé mat la dau thye vat Phuong an ding La: oO A.lva2 B.1,2va3 C.Chieé 1 D.2va3 Cau 101: Dé thi tuyén sinh Cao ding khéi A - 2011 3 Este X no, don chite, mach hé, khéng cé phan ting trang bac. Dat effdy 0,1 mol X rdi cho sin phim chay hép thy hoan ton, vio dung djch nude véi trong c6 gimig (22 mol Ca(OH): thi van thu duge két tua. Thuy phan X bing dung dich NaOH thu dugc ftni"co co s6 nguyén tir cacbon trong phan tt bing nhau. Phan trim khdi lung ca oxi trong (129 A.37,21%. B. 36,36%, Céu 102: Dé thi tuyén sinh Cao ding khéi A- 201%) ‘ng thie cia triolein la A. (CHa{CH2]wCOO)1CHs NY B. (CH:{CH:];CH=CH[CH2}sCOO)CsHs. 4%, D. 53,33%. ©. (CHs[CH2}1COO)C3Hs. D, (CHs[CH2};CH=CH[CH:}COO)sCsHs, Cau 103. NY Cho $2,8 gam hén hop gém hai Gjo'son chite 1a déng phan cia nhau cé ty khéi hoi so voi Hp bang 44, té dung(dith NaOH 0,6M, réi c6 can dung dich vira thu duge cdn’ lai 66,9 gam chi BFeste la. A. HCOOC;Hs va CH;COO¢ B. C:HsCOOCH; va CH;COOC;Hs C, HCOOC3H; va CHsCQOC:Hs D. HCOOCHy va CHsCOOCH3 Cau 104, XA phong héa hoa t6an 19,4 gam hdn hgp 2 este don chite can 200 ml dung dich NaOH 1,5M. Sau khi phan tmg hoan toan thu duoc hin hop 2 ancol déng dang ké tiép nhau va m gam mét mudi khan X duy nhataCéng*thite 2 ancol va gid tri m la. A. CHOI GsH50H va 20,4 gam B. C3HsOH, C3H,OH va 20,4 gam omen CsHsOH va 24,4 gam D. CH;OH, CoHsOH va 24,4 gam Cau 106 “Hon hop X gém hai este no, don chic, mach hé. Dét ch4y hoan toan mét Iugng X cdn ding via tr'3,976 lit khi Oo (6 d.k.t.c), thu duge 6.38 gam CO. Mat khae, X tac dung voi dung dich NaOH, thu duge mt mudi va hai ancol ld déng dang ké tiép. Cong thife phan t ctia hai este trong X 1. A. CoH4O) va CsHipO2 B. C2H4Q» va C3H602 C. CsHiO> va CaHeO2 D. C3H602 va CsHs02 CAu 106. Cho hén hop X gém hai este A, B don chite mach hé. Dét chy hoan toan m gam hn hop X cdn 8.4 lit Oz (6 d.k.t.c) va thu duge 6,72 lit COz (6 d.k.t.c) va 5,4gam HO. Cho biét Mg lon hon My 28 dvC. Xac dinh céng thite cia A va B. A. HCOOCH; va CH3;COOCHs B. HCOOCHS va HCOOC3H; C. HCOOC>Hs va CH\COOC3H; D. CHsCOOC3Hs va C2HsCOOC3Hy 12