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Solution Stoichiometry
1. Silver nitrate and sodium chromate solutions react as follows:
2AgNO3(aq) + Na2CrO4(aq) Ag2CrO4(s) + 2NaNO3(aq)
(a) How many moles of silver chromate form when 0.200 mol of silver nitrate react?

(b) How many moles of sodium nitrate form when 500 mL of 0.300 mol/L sodium chromate
react with silver nitrate?

(c) How many grams of precipitate will form if 200 mL of 0.500 mol/L silver nitrate react with
sodium chromate?

2. Write the balanced equation for the reaction of sulfuric acid with a solution of sodium hydroxide.

(a) What volume of 0.320 mol/L sulfuric acid reacts with 47.3 mL of 0.224 mol/L sodium
hydroxide?

(b) If 50.0 mL of 0.540 mol/L sodium hydroxide reacts with 85.6 mL of sulfuric acid, calculate
the concentration of the sulfuric acid.

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3. Write the balanced reaction between barium nitrate and sodium carbonate.

(a) How many grams of sodium carbonate would be needed to react with 120 mL of
0.0500 mol/L barium nitrate to entirely remove the barium ions from the solution?

(b) How many grams of precipitate would form if this was done?

4. A student adds 5.77 g of zinc to 100 mL of HCl(aq) . Write the reaction which occurs.

(a) How many moles of HCl(aq) react with the zinc?

(b) What would the concentration of zinc chloride be in the 100 mL solution when all the zinc
had reacted?

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SOLUTION STOICH ANSWER KEY


1. 2AgNO3(aq) + Na2CrO4(aq) Ag2CrO4(s) + 2NaNO3(aq)

(a)

(b)

nAg 2CrO4 0.200 mol AgNO3

nNaNO3 0.500 L 0.300

mAg2 CrO4 0.200 L 0.500

1mol Ag 2CrO 4
0.100 mol Ag 2 CrO4 (s)
2 mol AgNO 3

2 mol NaNO3
mol
Na 2CrO 4
0.300 mol NaNO3 (aq)
L
1mol Na 2CrO 4

mol
1mol Ag 2 CrO 4
g
AgNO3
331.74
Ag 2 CrO 4
L
2 mol AgNO3
mol

mAg2 CrO4 16.6 g Ag 2 CrO 4 (s)


(c)

2. H2SO4(aq) + 2NaOH(aq) Na2SO4(aq) + 2H2O()


mol
1mol H 2SO 4
L
VH2SO4 0.0473L 0.224
NaOH

H 2SO 4
L
2 mol NaOH 0.320 mol
VH2SO4 0.0166 L 16.6 mL H 2SO 4 (aq)
(a)

cH2SO4 0.0500 L NaOH 0.540


cH2SO4 0.158

1mol H 2SO 4
mol
1
NaOH

L
2 mol NaOH 0.0856 L H 2SO 4

mol
H 2SO 4 (aq)
L

(b)

3. Ba(NO3)2(aq) + Na2CO3(aq) BaCO3(s) + 2NaNO3(aq)


1mol Na 2 CO3
mol
g
mNa 2CO3 0.120 L Ba(NO3 ) 2 0.0500
Ba(NO3 ) 2
105.99
Na 2CO3
L
1mol Ba(NO3 ) 2
mol
mNa 2CO3 0.636 g Na 2 CO3 (aq)
(a)

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mBaCO3 0.120 L Ba(NO3 ) 2 0.0500

1mol BaCO3
mol
g
Ba(NO3 )2
197.34
BaCO3
L
1mol Ba(NO3 ) 2
mol

mBaCO3 1.18 g BaCO3 (s)


(b)

4. Zn(s) + 2HCl ZnCl2(aq) + H2(g)

(a)

(b)

nHCl 5.77 g Zn

mol
2 mol HCl
Zn
0.176 mol HCl(aq)
65.41g
1mol Zn

cZnCl2 0.176 mol HCl

1mol ZnCl 2
1
mol

ZnCl 2 0.880
ZnCl 2 (aq)
2 mol HCl 0.100 L
L

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This page may be reproduced for classroom use by the purchaser of this book without the written permission of the publisher.

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