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Atomic Structure
Atoms are made up of protons, neutrons and electrons.
Protons are positively charged. Electrons are negatively charged. Neutrons dont have a
charge.
An atom consists of a nucleus, which contains protons and neutrons; and some electron shells
which surround the nucleus and contain electrons. The neutrons however, are different. The
number of protons and the number of neutrons add up to make the mass number of an
element.
complicated periodic table. In IGCSE level however, the atomic mass should read 12. Anyways,
the atomic number is the number of protons (and electrons), so to find the number of
neutrons, if asked to, simply subtract the atomic mass by the atomic number.
Each shell can only hold a certain number of electrons. The very first shell can hold only two
electrons. The second shell can hold eight. The third sometimes appear full with eight but can
expand to a total of eighteen. However, this is beyond GCSE level, and for now, the shells only
hold eight.
So how do you find the electron configuration? Well lets use potassium (K) as an example.
Look up the atomic number of potassium. It should say 19. This tells you the number of
protons, which is equal to the number of electrons so we can use that.
Arrange the electrons in shells, always filling up the inner shell before you go to the outer one.
Remember the first, innermost shell can only take 2 electrons, the second one can take 8, and
the third one, 8. You will find that you have one electron left. That goes on the fourth shell.
Your electron configuration should look like this: 2, 8, 8, 1.
Example: Work out the electron configuration of chlorine.
Chlorine has an atomic number of 17 so 17 electrons.
17 2 (as the innermost shell only holds two electrons) = 15
15 8 (as the second shell only holds eight electrons) = 7 (This number is the number
of electrons Chlorine has on its outer shell).
7 electrons does not fill up the third shell so we are left with the configuration: 2, 8, 7.
Isotopes
The number of neutrons in an atom can vary slightly. For example, there are three kinds of
carbon atom, called carbon-12, carbon-13 and carbon-14. They all have the same number of
protons, but the number of neutrons vary. These different atoms of carbon are called isotopes.
Isotopes are atoms that have the same atomic number, but different mass numbers. They
have the same number of protons, but different numbers of neutrons. The fact that they have
varying numbers of neutrons makes no difference whatsoever to their chemical reactions. The
chemical properties are governed by the number and arrangement of the electrons.
Metals
Metals tend to be shiny. They tend to have high melting and boiling points because of powerful
attractions. Metals conduct heat and electricity because delocalized electrons are free to move
throughout the structure. Metals are usually easy to shape due to their regular packed
molecules. Metals react with water to form bases, and their oxides are also bases. They are
good reducing agents because they lose electron.
Non-Metals
Non-metals tend to be brittle. They are poor conductors of heat and electricity. They form
acidic oxides and are good oxydising agents because they gain electrons.
Aluminium Oxide
Aluminium oxide is amphoteric. It can neutralize both an acid and a base.
In this (and similar reactions with other acids), aluminium oxide is showing the basic side of its
amphoteric nature.
Density (g/cm3)
0.53
0.97
0.86
1.53
1.88
You can see that as reactivity increases, the melting and boiling points decreases; however,
density increases. These points are very low for metals. Remember that potassium, sodium
and lithium would float on water due to their densities. But why are they so reactive? Well they
only have one electron to lose!
The metals are also very soft and easy to cut, becoming softer as you go down the group. They
are shiny and silver when cut, but tarnish within seconds on exposure to air.
brick red
-crimson
-apple-green
Gas
Yellow
Chlorine
Gas
Green
Bromine
Liquid
Iodine
Solid
These vapours and gases are poisonous. All these elements need to be handled in a fume
cupboard.
Halogen
Flourine
Chlorine
Potassium
Chloride
Bromine
Brown
Iodine
Brown
Potassium
Bromide
Yellow to
Brown
Potassium Iodide
Yellow to Brown
Brown to Dark
Brown
Brown
Note: Colour changes are due to the element being displaced. For example, the colour
change from yellow to brown when chlorine reacted with potassium bromide was due to the
fact that the bromine was displace. It was the brown of the Bromine that turned the solution
brown.
Potassium is only a spectator ion. It does not change.
But now we have a problem. To distinguish whether bromine or iodine has been displaced is
difficult, as both elements produce very similar shades of brown. What do we do? We add an
organic solvent such as Volasil. When Volasil is added, the iodine turns pink while the bromine
stays brown. Pretty neat huh?
These reactions are known as redox reactions, where oxidation and reduction are occurring
(not just one of them).
Explaining the Trend in Reactivity of Halogens
As you go down the group, the oxidizing ability of the halogens falls due to the decreasing
reactivity. When a halogen oxidizes something, it does so by removing electrons from it.
Chlorine is a strong oxidizing agent because its atoms readily attract an extra electron to make
chloride ions. Bromine is less successful. Why? This relates to electron shells again. In Chlorine,
there are three shells which shield the nucleus attraction force from attracting another
electron to gain a full outer electron shell. Bromine however, has a lot more shells to shield the
attraction, therefore, the force is much weaker.
Halogens: Quick Notes
Diatomic molecules
Seven electrons on outer shell
Highly reactive only need one electron to fill outer shell
Form hydrogen halides when reacting with hydrogen
Reaction increases as you go up the group
Halogens can displace each other
Volasil turns iodine pink
Equation:
(2.17)Making Oxygen in the Lab
Oxygen is most easily made in the lab from hydrogen peroxide solution using manganese(IV)
oxide as a catalyst. The reaction is known as the catalytic decomposition (splitting up using a
catalyst) of hydrogen peroxide.
2H2O2(aq) 2H2O(l) + O2(g)
With Sulfur
With Carbon
Carbon Dioxide
Preparing It in the Lab
Carbon dioxide is made by the reaction between dilute hydrochloric acid and calcium
carbonate in the form of marble chips.
CaCO3(s) + 2HCl(aq) CaCl2(aq) + CO2(g) + H2O(l)
Sulphur Dioxide
The solution to acid rain involves removing sulfur from fuels, using catalytic converters in cars
and scrubbing the gases from power stations to remove the oxides. The catalyst helps convert
nitrogen oxides into harmless nitrogen gas but has no effect on sulfur dioxide.
Methods of Separation
Filtration: For separating an insoluble solid from a liquid, or a soluble solid from an insoluble
one.
Sand can be separated from water by pouring the mixture down a funnel with filter paper. The
sand will collect at the filter paper.
It can also be used to separate sand from something like salt by dissolving salt in water (which
leaves you with sand mixed with salt water). The mixture can then be poured down a funnel.
The sand that collects at the top should can be rinsed and dried. The water can be evaporated
from the salt by heating with a Bunsen burner. 38Back
An example would be separating ink colours or plant dyes. A dot of the ink/dye would be drawn
onto a piece of paper. It would then be left in water, which acts as a solvent. Because different
colours have different solubility levels, some colours would travel up further on the paper.
Fractional Distillation:
Fractional Distillation is used to separate two liquids based on their boiling points.
An example would be separating ethanol from water. Ethanol has a lower boiling water than
water (at about 780C), therefore, the heating is monitored (using the thermometer) to ensure
that the temperature does not reach 1000C (the boiling point of water). Anyways, the ethanol
would turn into a vapour and travel out of the flask. It would then condense into its liquid form
with the help of the cooling water and fall into the beaker.
You can find the charge of an ion by looking at the group it belongs to. If it belongs to groups 14, it has a charge of 1-4+ (they are positive), whereas, if it belongs to groups 5-0, it has a
charge of 30. Below is a table containing charges of common ionic compounds and transition
metals.
Ion
Symbol
Silver
Copper (I)
Ammonium
Copper (II)
Cobalt
Nickel
Zinc
Iron (II)
Chromium
Iron (III)
Ion
Ag
Cu
NH4
Cu
Co
Ni
Zn
Fe
Cr
Fe
Symbol
Hydroxide
Nitrate
Hydrogen
Carbonate
Carbonate
Sulphate
Phosphide
Phosphate
Nitride
OH
NO3
HCO3
Charg
e
1+
1+
1+
2+
2+
2+
2+
2+
3+
3+
Charg
e
111-
CO3
SO4
P
PO4
N
22333-
As ionic charge increases, so does the melting/boiling points. Ions with 2 + and 2- would
have stronger attraction because their charges a stronger, whereas, ions with 1 + and 1would still have a strong attraction, but less stronger than 2+- compounds.
Covalent Bonding
Covalent bonding is formed by sharing a pair of electrons between two atoms. This is so that
both atoms can achieve a full outer shell. It is a strong attraction between the bonding pair of
electrons and the nuclei of the atoms involved. Covalent compounds are only formed when the
reactants are non-metals.
Diagram
Eleme
nt
CH4
NH3
Diagram
Elemen
t
CO2
Ethane
Diagram
HCl(g)
H2O
O2
N2
Ethene
These are gases, liquids or solids with low melting points. Examples include water,
chlorine, oxygenetc
The covalent bonds between the atoms in a molecule are strong.
However, the forces of attraction between these molecules (inter-molecular forces) are
weak.
They have low melting points, since not a lot of heat is needed to provide the energy
for the molecules to move away from each other, hence, overcome the intermolecular
forces between them.
They tend to be insoluble in water.
They are often soluble in organic solvents.
They do not conduct electricity because the molecules have no overall charge and
there are no electrons mobile enough to move from molecule to molecule.
Diamond
The diamond is the hardest natural substance. It is a form of pure carbon.
Each carbon atom forms four covalent bonds to the other carbon atoms. They are arranged in
a tetrahedral arrangement. Diamond has a very high melting point, obviously due to very
strong carbon-carbon bonds. It does not conduct electricity because all the electrons in the
outer levels of the carbon atoms are tightly bonded between the atoms. None of them are free
to move around. Diamond is insoluble like, to both water and other solvents.
Use of Diamond
Saw blades can be tipped with diamonds in high-speed cutting tools used on stone and
concrete. The strong tetrahedral structure makes the diamond hard, making it suitable
for this purpose.
Graphite
Graphite is arranged differently it has a layer structure. Each graphite
layer is strong, but it is easy to separate individual graphite layers. Each carbon atom only
forms three covalent bonds. Graphite conducts electricity because the fourth electron is free to
move around.
Use of Graphite
Because of the layered structure, graphite can be used as a dry lubricant to lubricate
locks.
Metallic Crystals
Metals are giant structures which consist of a regular array of
positive ions in a sea of delocalized electrons. When metal atoms bond together to form solid,
visible metal, their outer electrons are no longer attached to particular electrons and are free
to move around the whole structure.
Metals are able to conduct electricity because the delocalized electrons are free to move
throughout the structure. The energy is picked up by the electrons and moved around the
metals, transferring the electricity throughout the whole structure. The same goes to heat
energy.
Metals are easy to shape because their regular packing makes it simple for atoms to slide over
each other. Metals are said to be malleable.
Introduction to Electrolysis
In metals and carbon, electricity and electric current is simply a flow of
electrons or ions. Electrolysis is the chemical change caused by passing an electric current
through a compound which is either molten or in a solution. An electrolyte is a substance that
undergoes electrolysis. It contains ions. It is the movement of the ions, which are responsible
for both the conduction of electricity and the chemical changes that take place. Covalent
compounds are not electrolytes and dont conduct electricity because they have no free
moving electrons. Ionic compounds only conduct electricity when molten or in a solution
because the ions separate and are free to move. These particles can then carry the electric
current.
Diffusion
Diffusion happens when particles spread from higher to lower concentration. It requires a
concentration gradient).
Potassium Manganate (VII) Experiment
Diffusion through liquids is very slow if the liquid is totally still. This can be shown but dropping
a piece of potassium manganate (VII) into water. It can take days for the colour to spread
because the gap between each particle is small.
The Bromine Experiment
Showing diffusion in gases can be done by filling a lower gas jar with bromine gas and topping
it with a gas jar filled with air. The bromine particles and air particles will eventually bounce
around to give an even mixture.
The Ammonium Chloride Experiment
This experiment is used to show that particles in different gases travel at different speeds. It
relies on the reaction between ammonia and hydrogen chloride gases to give white solid
ammonium chloride.
A white ring of ammonium chloride would form near the hydrochloric acid. This shows that
ammonia particles have travelled further to reach the hydrogen chloride gas, showing that it
travels faster.
Dilution
Dilution is the reduction of concentration in a solution.
Showing Dilution and Leading to the Idea of Small Sized Particles
Suppose you dissolve 0.1g of potassium manganate (VII) in 10cm 3 of water to give a deep
purple solution. Assume the smallest drop you can see is 1/1000cm 3. The whole solution will be
made up of 10000 drops, each drop containing 0.00001g of potassium manganate (VII).
Suppose you dilute this down 10 times by taking 1cm 3 of the solution and making it up to
10cm3 with more water. Continue doing this until the colour is too faint to see. By the time of
the fifth dilution, each drop will only contain a billionth of a gram of potassium manganate
(VII). If you only needed one particle of potassium manganate (VII) per drop in order to see
the colour, the particle cant weigh more than a billionth of a gram.
IS this a good answer? Nowhere near it! A potassium manganate (VII) particle actually weighs
about 0.00000000000000000000026g! In reality, you need huge numbers of particles in each
drop in order to see the colour.
Dont worry I dont get this either
Code
Meth
Eth
Prop
But
Pent
Hex
Hept
Oct
Non
Dec
Number of
Carbons
1
2
3
4
5
6
7
8
9
10
Do you have to remember the formula for propane, butane, ethane? No! You can work it out
yourself! The first part of the name tells you how many carbons there are in the longest chain
(not necessarily in total). By the way you have to learn these at least the first five. It helps.
For example: propane (left) has three carbons. Butane (right) has four carbons.
Meaning?
All carbon bonds
are filled with
hydrogen i.e.
they are saturated
hydrocarbons.
ene
There is a double
carbon-carbon
bond they are
unsaturated
hydrocarbons.
Alkanes and Alkenes are two homologous series.
Pentene has a five carbon chain with a double bond.
Isomers
We know what isomers are.
Pent-2-ene means pentene with the double bond on the second carbon-carbon bond and so
on
But wait! What about pent-4-ene and pent-5-ene? Those dont exist. Why? Because pent-4-ene
is pent-2-ene flipped over, and pent-5-ene is pent-1-ene flipped over!
Flip: C-C-C=C-C and you get C-C=C-C-C!
Meaning
Has a branch of
CH3 coming off
one of the bonds.
Ethyl
Has a branch of
CH3CH2 coming
off.
If the hydrocarbon has a methyl or ethyl group, these two come first, before the coding for the
number of carbons in the chain. But before even the methyl or the ethyl there is a number
and hyphen to show which carbon has the methyl or ethyl branch.
For example, this is 2-methylbutane
As you can see, there is a methyl group branching off the second
carbon. The rules are similar to double bonds though, there is no such thing as 3-methylbutane
because that is basically 2-methylbutane flipped over.
But wait! There are five carbons! Why isnt it 2-methylpentane? Because remember, these
names are based on the longest carbon chain in the hydrocarbon and the longest carbon chain
there is 4, hence, butane. This means that 2-methylbutane is an isomer of pentane C5H12.
Alkanes
Alkanes are a homologous series of saturated hydrocarbons. The first five are methane,
ethane, propane, butane and pentane.
The general formula for alkanes is: CnH2n + 2
= C2H6.
Incomplete Combustion
If there isnt enough oxygen, you get incomplete combustion, in which carbon monoxide and
water are produced instead. Carbon monoxide is a colourless, odourless and poisonous gas. It
is dangerous because it can combine to our haemoglobin and stop it from carrying oxygen. As
a result, you get ill or even die because oxygen cannot travel to all parts of your body.
Alkenes
Alkenes have double bonds, making them unsaturated hydrocarbons.
Alkenes have the general formula of CnH2n the first four being ethene, propene, butene and
pentene.
Combustion
Like alkanes, alkenes burn in oxygen or air to give carbon dioxide and water.
Alkenes undergo addition reactions, in which part of the double bond breaks and is used to join
other atoms onto the two carbon atoms. When added to alkenes, and the test tube is shook,
the brown of the bromine would be decolourised, making it suitable as a test for alkenes.
The product of reacting ethene to bromine gives 1, 2-dibromoethane and is a colourless liquid.
CH2=CH2(g) + Br2(aq) CH2BrCH2Br(l)
Ethanol
What is Needed:
Production of Ethanol
Hydration of Ethene
Ethanol can be made by reacting ethene with steam (because it contains more energy) a
process known as hydration.
CH2=CH2(g) + H2O(g) CH3CH2OH(g)
Only a small portion of ethene reacts. The ethanol is condensed as a liquid and the unreacted
ethene is recycled.
Explaining the Choice of Temperature
Reversible reactions happen in two ways while ethene is being converted into ethanol,
ethanol is also being converted back into ethene. Reversible reactions can also shift the
equilibrium or alter the reaction. Since the reaction is exothermic the reaction produces
lots of heat. If you increase the temperature, the reaction wont like it because it is already
producing heat, therefore, it would adapt to the conditions by making more ethene so less
heat will be produced. On the contrary, if you decrease the temperature, the reaction would
adapt to this by increasing back the temperature; by producing more ethanol in other
words, push the equilibrium to the favourable/forward reaction. However, making the
temperature too low would mean super slow reaction, although more ethanol would be
produced. 300 degrees is therefore, a compromise temperature producing an acceptable yield
of ethanol in a short time.
Explaining High Pressure
In the equation, you have two moles (one mole of ethene and one mole of water) on the left,
and one mole (of ethanol) on the right. Increasing the pressure would mean the equilibrium
would be shifted forwards. Why? The reaction would adapt to the conditions by producing
more ethanol because you only get one mole of ethanol which takes less space than two
moles of ethene and water.
Also, theres the collision theory. Increasing the pressure means that thered be less space for
the atoms to move. The atoms would also move with more force. This increases the frequency
of collisions.
The problem: its expensive and ethene might polymerise and turn into polyethene.
Fermentation
Yeast is added to a sugar or starch solution at 300C for several days in the absence of air for
anaerobic respiration. Enzymes in the yeast lower the activation energy, increasing the rate of
conversion of the sugar into ethanol and carbon dioxide. However, they first have to break the
sugars into smaller sugars like glucose. In fact, ethanoic acid is produced and then converted
into ethanol.
For example, sucrose:
C12H22O11(aq) + H20 C6H12O6(aq) + C6H12O6(aq)
The yeast then gets killed in the mixture, which means that the ethanol produced is impure. To
purify it, the alcohol must undergo fractional distillation.
Use of Resources
Type of Process
Rate of Reaction
Quality of Product
Reaction Conditions
Fermentation
Uses renewable resources sugar
beet or sugar cane, corn and other
starchy materials.
A batch process everything is mixed
and left for several days. It is then
removed and a new reaction is set up
quite inefficient.
Slow, takes several days.
Produces impure ethanol that needs
further processing.
Uses gentle temperatures and
ordinary pressure relying on
anaerobic respiration of yeast.
Hydration
Uses non-renewable resources once
oil gets used up, theyre screwed.
A continuous flow process a stream
of reactants is constantly passed over
the catalyst more efficient.
Rapid
Produces much purer ethanol.
Uses high temperatures and
pressures, needing a high input of
energy expensive.
Common Question: Which method would poorer places like Brazil use and why? [3 marks]
Answer: Fermentation, because Brazil has the weather conditions to grow large yields of sugar
cane and they dont have access to crude oil.
Crude Oil
Crude oil is a mixture of hydrocarbons. These chains can be super long or super short.
As the number of carbon atoms in molecules increases and gets bigger, intermolecular
attractions also increase, making it more difficult to pull one molecule away from neighbouring
ones. As they get bigger, these changes occur:
Boiling point increases the larger the molecule, the higher the boiling point due to
stronger intermolecular attractions.
Liquids become less volatile the bigger the hydrocarbon, the more slowly it
evaporates in room temperature. This is again, due to strong intermolecular
attractions.
Liquids become more viscous (flow less easily) Small hydrocarbons are runny, but
large ones are much stickier and gooey (and viscous) because of intermolecular
attractions.
Bigger hydrocarbons do not burn as easily, meaning they are less useful.
Uses
Gasoline
Kerosene
Diesel oil
Fuel oil
Bitumen
In car engines, the temperature reached is high enough to allow nitrogen and oxygen from the
air to react, forming nitrogen oxides. This contributes to smog and causes irritation to human
mucus membranes. As well as that, nitrogen oxides can react with water in the atmosphere
and from nitric acid or acid rain.
Cracking
The Crude Oil Problem
Amounts of each fraction you get depend on the proportions of various hydrocarbons in the
original crude oil. Far more petrol is needed, than something like bitumen. In other words,
fractional distillation of crude oil produces more long-chain hydrocarbons than can be used
directly, and fewer short-chain hydrocarbons than required.
The solution? Cracking! Cracking is a useful process in which large hydrocarbon molecules are
broken into smaller ones. Most of the hydrocarbons found in crude oil are long-chain alkanes.
Cracking can convert these into alkenes and shorter alkanes. It is an example of thermal
decomposition.
How it Works
What is Needed:
Alumina/Silica as catalyst
600-7000C
The fraction is heated to give a gas and is passed over a catalyst of silica or alumina with a
temperature of 600-700oC.
Long alkane alkene + alkane
C6H14
Polymers
Alkenes can be used to make polymers. Polymers are big long molecules of single units called
monomers. Molecules containing carbon-carbon double bonds can be joined together. Part of
the double bond is broken and used to join to other monomers. Joining up lots of monomers to
make a polymer is called addition polymerisation.
Polymers to Know
Polymer
Polyethene
Repeating Unit
Uses
Polypropene
Polychloroethen
e
Plastic bags
Plastic
bottles
Ropes
Crates
PVC for
drainpipes or
windows
Electrical
insulation
As a block diagram (where the (CH2)6 and (CH2)4 become blocks to make it look easier)
End Note: Sometimes you may be given ClOCCH2 CH2 CH2 CH2COCl instead of hexanedioic acid.
In this case, just do the same thing, with the lost of hydrogen chloride HCl.
Colour
Li
Crimson red
Na+
Yellow orange
Lilac
Ca2+
Colour of Precipitate
Cu
Blue
2+
Fe2+
Fe
3+
Colour of Precipitate
Cl
White
Br-
Pale Cream
Yellow
Test
Result
Hydrogen
Oxygen
Carbon
Dioxide
Ammonia
Chlorine
Solubility Patterns
Zinc
Iron
Reaction to Acid
Rapid fizzing, mixture gets very hot, colourless magnesium sulphate/chloride
solution forms.
Is slow due to its coat of aluminium oxide which prevents aluminium from
contacting the acid. On heating, this layer is removed, aluminium will start fizzing
rapidly abit like Mg.
Zinc reacts slowly with cold dilute acid and may produce some effervescence. On
heating however, it fizzes more.
Iron also reacts slowly with cold dilute acid and will produce abit of effervescence
when heated.
Combustion of Hydrogen
Bonds are broken in the hydrogen and oxygen molecules. These form new bonds of water
molecules. This reaction is exothermic, and gives out water in the form of steam, before it
condenses into a liquid. The reaction is:
2H2(g) + O2(g) 2H2O(l)
Rates of Reactions
Experiment Setup
To measure the effects of changes in surface area, concentration
of solutions, temperature and use of catalyst, you can react calcium carbonate marble chips
with dilute hydrochloric acid and measure the mass of CO 2 produced by weighing the
difference in mass of the reactants and the mass of the products (there wont be any change in
mass produced, because the initial mass of reaction will equal the final mass, however, since
carbon dioxide gas is formed, this will escape from the flask, and therefore, the amount of
mass lost will be the mass of carbon dioxide produced. Plot the results on a graph with mass
against time and youll get an upward curve.
For the reaction to occur, acid particles must collide with the surface of the marble chips. As
the acid particles get used up, the collision rate decreases, so the reaction slows down.
Hx2
(1 x Ca) + (2 x O) + (2 x
H)
Straightforward stuff.
2x1=2
40 + (2 x 16) + (2 x 1) =
74
The equation says that 2 moles of Na and 1 mole of Cl (1 mole of a diatomic molecule is
always X2) is needed to produce 2 moles of NaCl, so if 0.1 mol of Na is used, then half of that is
the amount of chlorine used in the reaction in moles.
So moles of Cl used = 0.1 / 2 = 0.05 mol
One mole of any gas has a volume of 24 dm3 (24000cm3) at room temperature and
pressure. This is also called the molar volume.
Cl2 is a gas and the moles used in the reaction = 0.05 mol
So the volume of Cl2 gas used = 0.05 x 24000 = 1200cm3
The moles of NaCl produced is 0.1 mol (if 2 moles of Na gives 2 moles of NaCl, then 0.1
mole of Na will give 0.1 mole of NaCl). So all you do is:
Find the RFM of NaCl (58.5)
Multiply that by 0.1 (5.85g)
Mol/dm3 means moles per litre (e.g. a salt solution of 0.5 mol/dm 3 means 0.5 moles (or
58.5/2 = 29.25g) of salt was dissolved in a litre of water
Its all about proportion
20 cm3 of 0.5 mol dm3 sodium hydroxide solution was dissolved with 25cm 3 of hydrochloric acid
to form a sodium chloride solution. Calculate the concentration of HCl needed to react with the
NaOH
NaOH + HCl H2O + NaCl
RFM of NaOH = 40g = 1 mole of NaOH
0.5 mol dm3 of NaOH means (40 x 0.5) 20g of NaOH was dissolved in 1000cm 3 of water
The amount of moles in 20cm3 of NaOH solution:
20cm3/1000cm3 x 0.5 moles = 1/50 x 0.5 = 0.01 moles of NaOH
The equation says that 1 mole of NaOH + 1 mole of HCl gives 1 mole of NaCl
So 0.01 moles of NaOH + 0.01 moles of HCl gives 0.01 moles of NaCl
So 0.01 moles of HCl was present in 25cm3 of HCl solution! However, concentration is
measured in mol dm3 so:
1000cm3/25cm3 x 0.01 mol = 0.4 mol dm3 of HCl used.
Combining
Masses
Number of moles
=
Ratio of Moles
Empirical
Formula
Mg
2.4
2.4/24
0.10
O
1.6
1.6/16
0.10
1:1
MgO
The empirical formula is the simplest formula and only tells you the ratio of the various atoms.
Suppose 2.4g of magnesium combined with 1.6g of oxygen, you can use a table to work out
the empirical formula. (Mg = 24 O = 16)
Percentage
Combining
Masses
Number of moles
=
Ratio of Moles
Empirical
Formula
C
87.5
87.5
85.7/12
7.14
H
14.3
14.3
14.3/1
14.3
1:2
CH2
However, you know that CH2 does not exist. Remember this is only the ratio. To find the
molecular formulae, you need to know the relative formula mass of the compound. Suppose it
was 56g for the above question.
Firstly, find out the RFM of CH2 = 12 + 2 = 14g
Find out how many times 14 goes into 56, so 56/14 = 4 times
Which means the molecular formula is C4H8!
52.2g
66.6g
65.0
66.6 65.0 = 1.6g
65.0 52.2 =
12.8g
Combining
Masses
Number of
moles
=
Ratio of Moles
Empirical
Formula
Cu
12.8
O
1.6
12.8/64
1.6/16
0.20
0.10
2:1
Cu2O
Endothermic
Exothermic
Heat energy is
taken in
Breaking of
bonds
Heat energy is
given out
Making of
bonds
H = + N kJ mol-1
H = - N kJ mol-1
H represents the molar enthalpy change for exothermic and endothermic reactions
Energy Calculations
The general formula:
Bonds of all the reactants Bonds of all the products = Energy change
Example: Methane reacts with chlorine to produce chloromethane and hydrogen chloride. The
equation:
CH4 + Cl2 CH3Cl + HCl
Bond
C-H
C - Cl
H - Cl
Cl Cl
243
Total: 2017 kJ
(Carbon can form 4 bonds. In this case, 3 of them bonds with 3 hydrogen and the last one
bonds with chlorine)
Energy Change = 1895 2017 = -122 kJ
Celsius).
Heat Given Out = Mass x Specific Heat x Temperature Rise
Pour an excess of sulphuric acid into a polystyrene cup and measure the temperature
of the acid.
Pour some magnesium powder into a weighing bottle and weight it.
Pour the powder into the acid and record the highest temperature.
Weigh the empty weighing bottle.
H = -412 kJ mol-1
This is actually smaller than the accepted value, which is around -417 kJ mol -1. A reason for this
could be that heat was lost too quickly. Using a mercury thermometer may give better results.
Combustion
Put 100cm3 of water into a conical flask and record the temperature.
Fill the spirit burner with alcohol (lets say ethanol) and weight.
Light the spirit burner and record the temperature of water until there is say, a 40 0C
increase.
Reweigh the spirit burner.
100
100
37.355
36.575
0.780
21.5
62.8
41.3
So what happens?
Molten lead is found at the bottom of the cathode.
Bromine gas comes out of the anode.
When the power supply is switched off, no more bubbles are produced and everything else
stops.
What the hell happened?
The bromide ions are attracted to the positive electrode. The extra electron which
makes the bromide ion negatively charged is deposited into the anode, thus, turning
them back into neutral bromine atoms. These then covalently bond to join bromine
atoms (i.e. bromine gas).
On the other hand, the lead ions gain back to electrons (it has a 2 + charge) and
become normal lead atoms. These fall to the bottom of the container as molten lead.
The half-equation at the anode would be:
2Br- Br2 + 2eWhat it basically means is that, two bromine ions are formed when one bromine molecule
receives two electrons (to fill its shell). This is the format for all anions (ions that are negatively
charged).
If the metal is more reactive than hydrogen, then hydrogen ions from water is
discharged instead. These pair up to form hydrogen gas that escapes as bubbles.
If you have solutions of halides (chlorides, bromides or iodides), you get the halogen
(chlorine, bromine or iodine) produced.
The electrolysis of sodium chloride solution (brine) does not give sodium and chlorine! Heres
the electrolysis:
Sodium is higher than hydrogen in the reactivity series, so hydrogen ions from the
water in the sodium chloride solution is discharged instead at the cathode.
2H+ + 2e- H2
Chloride ions give up one electron each (chloride ion = 1- charge) and become chlorine
atoms. These covalently bond to form chlorine gas and bubbles out of the solution at
the anode.
2Cl- Cl2 + 2e
When all the chlorine has been removed from the solution, only hydroxide (OH -) ions
and sodium (Na+) ions are left, as well as some water. These combine to form sodium
hydroxide solution (NaOH).
The electrolysis of sodium chloride solution is used to manufacture sodium hydroxide solution.
The process is slightly different it is electrolysed in a diaphragm cell:
The products are kept separated by the diaphragm.
If the chlorine produced were to react to hydrogen, it would cause an explosion on exposure to
sunlight or heat to give hydrogen chloride. Furthermore, if the chlorine were to react with the
sodium hydroxide solution formed, it would form bleach. Uses of sodium hydroxide include:
Making bleach
Making soap
Making paper NaOH breaks the wood down
Uses of chlorine include:
Sterilising water
Making hydrochloric acid
Making bleach
And the electrolysis of copper sulphate solution:
Copper is lower than hydrogen and therefore, a coat of it forms at the cathode.
Cu2+ + 2e- Cu
Oxygen gas is discharged from the hydroxide ions in the water because the sulphate
ions are more stable.
4OH- 2H2O + O2 + 4eIf you electrolyse the solution for longer, something else happens. The hydrogen ions are being
discharged and remains in the solution. Similarly, sulphate ions are being discharged either. As
a result, the solution turns into sulphuric acid (H2SO4) and it begins electrolysing:
Sulphate ions are being discharged from the acid so oxygen is discharged from the
hydroxide ions instead.
4OH- 2H2O + O2 + 4e-
There are only hydrogen ions arriving at the cathode so they discharge as hydrogen
gas.
2H++ 2e- H2
Common Exam Question: Why is twice as much hydrogen produced than oxygen? For every
four electrons that flow around the circuit, one molecule of oxygen and two molecules of
hydrogen are produced.
Electrolysis Calculations
Back to moles! Here are some things to know:
One faraday means one mole of electrons passing around the circuit.
One faraday = 96000 coulombs.
Charge (coulombs) = Current (amps) x Time (seconds)
Example: What mass of copper is deposited on the cathode during the electrolysis of copper
(II) sulphate solution if 0.15A flows for 10mins?
The electrode equation is:
Cu2+ + 2e- Cu
Calculate the coulombs involved:
10mins x 60 = 600 seconds
Charge = 0.15 x 600 = 90 coulombs
The equation says that 1 mole of copper ions + 2 moles of electrons give 1 mole of copper
atoms
1 mole of electrons = 96000 coulombs
2 moles of electrons = 192 000 coulombs
2 moles of electrons (192 000 coulombs) give 1 mole of copper (RFM = 64g), so 90 coulombs
give:
(90/192 000)
x 64g = 0.03g
and oxygen at the anode. Calculate the volumes of hydrogen and oxygen produced if 1.0A
flows for 20mins
The electrode equations are:
2H++ 2e- H2
4OH- 2H2O + O2 + 4eAssume the molar volume of gas to be 24000 cm3
For hydrogen:
2H++ 2e- H2
2 hydrogen ions + 2 moles of electrons give 1 mole of hydrogen molecule
20mins x 60 = 1200 seconds
1200 x 1A = 1200 coulombs
2 x 96 000 coulombs (2 moles of electrons) = 192 000 coulombs
1 mole of hydrogen gas = 24000 cm3
192 000 coulombs give 1 mole of hydrogen gas (or 24000 cm 3 of hydrogen gas)
So 1200 coulombs give: (1200/192 000)
x 24000 = 150 cm3 of hydrogen produced
For oxygen:
4OH- 2H2O + O2 + 4e20mins x 60 = 1200 seconds
1200 x 1A = 1200 coulombs
4 moles of hydroxide ions give 2 moles of water + 1 mole of oxygen gas + 4 moles of electrons
(4 x 96000 = 384 000 coulombs)
1 mole of oxygen gas = 24000 cm3
384 000 coulombs give 1 mole of oxygen gas (or 24000 cm 3 of oxygen gas)
So 1200 coulombs give: (1200/384 000)
x 24000 = 75 cm3 of oxygen produced
The equation:
(Calculated coulombs/moles of electrons) x (mole of gas x 24000) = amount of gas produced in
cm3
Heating the blue hydrated copper (II) sulphate crystals causes them to lose their water of
crystallisation, making them turn from blue to white the white copper (II) sulphate crystals
are described as anhydrous meaning without water:
CuSO45H2O CuSO4 + 5H2O
However, this reaction can be reversed by simply adding water to the crystals. The crystals will
become hydrated again:
CuSO4 + 5H2O CuSO45H2O
When ammonium chloride is heated in a test tube, the white crystals decompose into
hydrogen chloride gas and ammonia gas. These flow upwards and recombine again further up
the test tube:
NH4Cl HCl + NH3
This later recombines:
HCl + NH3 NH4Cl
C+D
When you have a reaction like the above, A + 2B (forward reaction) is reacting to produce C +
D (back reaction). At the same time, C + D is reacting to produce A +2B. In the end, you have
equal amounts of products and reactants. Another way to think of is, is to imagining walking
down an elevator that goes up, making sure youre walking at the same speed as the elevator.
You would be going down, but everytime you take one step down, the elevator goes one step
up. In the end, you remain where you are.
So how would you produce more of substance C in a reversible reaction such as the above? You
can do this by altering the position of the equilibrium by either:
C+D
C+D
H = -100 kJ mol -1
This would mean that the back reaction would be endothermic by the same amount (-100 kJ
mol-1).
Suppose the temperature was decreased, the reaction would respond by increasing the
temperature back up again. This can only be done by producing more C and D because the
forward reaction is exothermic. Increasing the temperature will of course, have the opposite
effect.
Adding a Catalyst
Adding a catalyst speeds up the forward and back reactions by the same proportion. This
means that there is no change in the position of the equilibrium.
Methods of Extraction
The extraction of metals depend alot on its position in the reactivity series. Costs are also
factors to take into account. For metals up to zinc, the cheapest method is usually heating the
ore with carbon or carbon monoxide to reduce it. For metals more reactive than zinc,
electrolysis is usually used.
Aluminium is extracted from an ore called bauxite, which is impure aluminium oxide.
Aluminium ions are attracted to the cathode and are reduced to aluminium:
Al3+ + 3e- Al
Oxide ions are attracted to the anode and lose electrons to form oxygen gas:
2O2- O2 + 4e-
Because of high temperatures, the carbon anodes will burn with oxygen to form carbon
dioxide. This means the anodes have to be replaced regularly.
The cost of electricity is also a major factor the cell has currents up to 100 000A so it
is expensive.
Saucepans
Iron is extracted from an ore that contains iron (III) oxide called haematite.
Coke is impure carbon. It burns to form carbon dioxide. This is a strongly exothermic reaction.
C + O2 CO2
At high temperatures, the carbon dioxide is reduced by more carbon to give carbon monoxide.
C + CO2 2CO
Carbon monoxide is the main reducing agent:
Fe2O3 + 3CO 2Fe + 3CO2
Carbon may also reduce the iron (III) oxide:
Fe2O3 + 3C 2Fe + 3CO
The heat of the furnace causes the limestone to thermally decompose to form calcium oxide
and carbon dioxide:
CaCO3 CaO + CO2
The calcium oxide reacts with silicon dioxide (one of the impurities found in haematite) to form
calcium silicate, which melts and trickles to the bottom of the furnace as molten slag:
SiO2 + CaO CaSiO3
Types of Iron
Wrought Iron
Mild Steel
High Carbon Steel
Cast Iron
Stainless Steel
Preventing the Rusting of Iron (in which iron oxidises into iron oxide Fe2O3)
Using Barriers
Keep water/oxygen away from the iron by painting, coating with oiletc.
Alloying the Iron
Such as allowing it with chromium and nickel to produce stainless steel
Using Sacrificial
Galvanising iron by coating it with a layer of zinc. Zinc is more reactive than
Anodes
iron and will corrode instead. During the process it loses electrons to form
ions. These electrons flow into the iron so any iron atom which has lost
electrons immediately regains them. These means even if the zinc is
scratched, the iron wont rust.
The Haber
Process
The Haber process is used to make ammonia NH3
Uses of ammonia include:
Making fertilisers
Making nitric acid
Making nylon
2NH3
H = -92 kJ mol-1
The forward reaction would be favoured by a low temperature because the forward
reaction is exothermic (so lowering the temperature would cause the reaction to make
more NH3 to heat things up abit more). 450C isnt a low temperature. It is however, a
compromise temperature, because if the temperature was made to be low, the
reaction would be so slow that it would take a very long time to produce much
ammonia.
Pressure is also another compromised. Because the forward reaction has less
molecules than the back reaction (2 molecules of NH3 as opposed to 1 N2 and 3 H2
molecules), the forward reaction would be favoured by a high pressure. 200 atm is
high, but anything higher would be extremely expensive.
The iron catalyst speeds the reaction up but has no effect on the equilibrium. However,
if the catalyst wasnt used, the reaction would be too slow.
Use an excess of air to react sulphur dioxide to more oxygen to form sulphur trioxide
2SO2 + O2
2SO3
H = -196 kJ mol-1
Reacting sulphur trioxide with water will give an uncontrollable fog of concentrated
sulphuric acid. Instead, sulphur trioxide is absorbed in concentrated sulphuric acid to
give fuming sulphuric acid (oleum):
SO3 + H2SO4 H2S2O7
This is converted into twice as much concentrated sulphuric acid by careful addition of
water:
H2S2O7 + H2O 2H2SO4
2SO3
H = -196 kJ mol-1
Because the forward reaction is exothermic, a low temperature has to be used. Again,
if a low temperature is used, the rate of reaction would be too slow, so 450C is a
compromise.
As for the pressure, a low pressure is needed because the forward reaction contains
fewer molecules than the back reaction.
The catalyst, vanadium (V) oxide (V2O5) speeds up the rate of reaction but has no
effect on the equilibrium. Again, without a catalyst, the rate of reaction would be
extremely slow.
colourless in
acid
red in acid
pink in alkali
yellow in alkali
Indicator Solutions
Note: Methyl orange is orange in neutral solutions, however, these two indicator solutions are
both yes no indicators meaning, if there is a reaction, the methyl orange (for example) would
turn from red to yellow (or vice versa depending on whether the solution it has been dropped
into is acidic or alkaline). It will not turn orange.
The acidity or alkalinity of something is measured in pH. Universal indicator cam be used to
measure the approximate pH of a solution.
Hydrochloric acid reacts with metals and metal compounds to form a metal chloride
Sulphuric acid reacts with metals and metal compounds to form a metal sulphate
When enough acid has been added to neutralise the alkali, the
indicator changes from pink to colourless. This is the end point of the titration.
The titration can be repeated using the same amounts of acid and alkali
but without the indicator.
Pure salt crystals which are free from indicator can then be crystallised from
the neutral solution.
Precipitation Reactions
The process of making a solid come from a solution is called precipitation. The solid itself is
called a precipitate. An insoluble salt (one that doesn't dissolve) can be made by reacting the
appropriate soluble salt with an 1acid or alkali or another salt.
STATE SYMBOLS
(s)
(l)
(g)
(aq)
solid
liquid
gas
aqueous solution
(dissolved in water)
You are normally asked to prepare a solid from two soluble solutions so know your solubility
rules:
Calcium
Magnesium
Zinc or Iron
Anything Below
Rusting of Iron
Oxygen
Water
Preventing
Using Barriers
Alloying the Iron
Using Sacrificial
Anodes
the Rusting of Iron (in which iron oxidises into iron oxide Fe2O3)
Keep water/oxygen away from the iron by painting, coating with oiletc.
Such as allowing it with chromium and nickel to produce stainless steel
Galvanising iron by coating it with a layer of zinc. Zinc is more reactive than
iron and will corrode instead. During the process it loses electrons to form
ions. These electrons flow into the iron so any iron atom which has lost
electrons immediately regains them. These means even if the zinc is
scratched, the iron wont rust.
More on sacrificial anodes if the iron has already rusted, it can still be displaced by the more
reactive zinc:
Fe2O3 + 3Zn 2Fe + 3ZnO
And this is the end.
Good luck!