Series ONS SET-2 cotene. 56/2/C wend ais a sr-Gferat & Fe-Ts ora fora | Candidates must write the Code on the title page of the-answer-book. a [ © FT ate ar a fr wa we F fe YS 6 FI © Weare oft ara at atk fu Te SS TERR I OMA SR-eal & Ya-Ts Tr fer © HT at a fe ga erga F 26 wee © BUT ar sar forant YS EAB Yee, WET car a stave ford | ©) Fes a yea & fer 15 fre a ae fen en Swear faa Gate F 10.15 FS feat STEM! 10.15 FHF 10.30 As TH BA hae WRIT HY TSA sie Fa arafy & chr 2 sa-aferat Wt aE Sat eT fers | « Please check that this question paper contains 16 printed pages. * Code number given on the right hand side of the question paper should be written on the title page of the answer-book by the candidate. * Please check that this question paper contains 26 questions. * Please write down the Serial Number of the question before attempting it, * 15minute time has been allotted to read this question paper. The question paper will be distributed at 10.15 a.m, From 10.15 a.m, to 10.30 a.m., the students will read the question paper only and will not write any answer on the answer-book during this period. tare fara ( taathte ) CHEMISTRY (Theory) frettta wre : 3 Wr TRA AE : 70 Time allowed : 3 hours Maximum Marks : 70 10 56/2/C 1 YEARS P.T.O. QUESTION PAPER.COM Iara FET : @ wait wer oifrard Fr Gi) we den1 85 we ale agai wer & ait aed ged & fore 1 ote 21 (ii) WRT WET 6 8 10 Te y-SHT Wer & ait Wee WET fea 2 art (jy) We Wem 11 H 22 7H it gama yer & oink eles WT 3 Hee) (y) 9 We 23 aecrentta wer 8 afte gate fea air 8) (oi) WT Ten 24 8 26 aH a-seia e7 & ait wee eT & fore 5 ate Bi (vit) We orerar B, at cir dacit wr weir at) Hep & sear wt arqate we 21 General Instructions : () All questions are compulsory. (ii) Questions number I to & are very short answer questions and carry I mark each. iit) Questions number 6 to 10 are short answer questions and carry.2 marks each. (iv) Questions number 11 to 22 are also short answer questions and carry 3 marks each. (v) Question number 23 is a value based question pad carry 4 marks. (vi) Questions number 24 to 26 are long answer questions and carry.5 marks each. (vii) Use log tables, if necessary. Use of calculators is not allowed. YEARS. 56/2/C 2 QUESTION PAPER.COM1. fee aie ar anata. am df: it Si CH-CH»)- OH Write the IUPAC name of the given compound : Cy CH)-CH,-OH 2, afte C,HyBr & wa We wraaet at Wer fefae A sy1 afte vfs 1 vaifre fraia 1 Write the structure of an isomer of compound C,HBr which is most reactive towards Syl reaction. 3. wlenget diet aa fea aT RN NTT eT? 1 What is the reason for the stability of colloidal sols ? 4. Te amtap ote ait Ue arate sta & sere die 1 Give an example each of a molecular solid and an ionic solid. 5. PL(NO,), ST FER UH Ro at te Pmentt F frre Sal ae feria awe 2) Ae at yes aif Pb(NO,)2 on heating gives a brown gas which undergoes dimerization on * cooling ? Identity the gas. ‘AR: 56/2/C 3 auesnon BS ccs P.T.O.6 afifen : Hy + Cl, > 2Hel % fet W=k @ 4 afin at aie sik srofena feafar Gi) k wt afte feafers For a reaction : Hp + Clp —%5 2HC1 Rate=k @ @) Write the order and molecularity of this reaction. Write the unit of k. 7, fra afters S dated carat weil a fafac : @ Gi) eeta-aags errr sfatsra ania afatsrar Write the chemical equations involved in the following reactions : @ @) 8 @ @ @ @) 56/2/C Hoffmann-bromamide degradation reaction Carbylamine reaction aan aa 1 tte (A) aanpa 7K @) & we A afee gee 1 HS tat 9 fren K, (Bd erie) gern @ sit wi? we sree fae & few yer a fraen, aftean aeeniat thasiign a fanton ot eee? Gas (A) is more soluble in water than Gas (B) at the same temperature. Which one of the two gases will have the higher value of Kj; (Henry's constant) and why ? In non-ideal solution, what type of deviation shows the formation of maximum boiling azeotropes ? YEARS 4 QUESTION PAPER.COM9. Sa UH Te waters Wfiter CoCl,.6NH, Ht AgNO, & we fren oe at 2 fire & ua Het Me Agel & ain te saat ad Ti fafa : @ Sindee advan we Gi) Bode a aati, a4 When a coordination compound CoCl;.6NHg is mixed with AgNOa,, 3 moles of AgCl are precipitated per mole of the compound. Write @ Structural formula of the complex Gi) TUPAC name of the complex 10, fret et dca fetes ; 2 @ = BrF, Gi) XeFy arat an tal $e : @ Peet way & ueity fara FS So, #1 vetfed feat ane F? Gi) XeF, fern ae & SbF, Mer? Write the structures of the following : @ BrF, @) Xe, OR What happens when : @ SO, gas is passed through an aqueous solution Fe3+ salt ? Gi) XeF, reacts with SbF, ? 56/2/C 5 YEARS. P.T.O. (QUESTION PAPER.COM1. fr afifeasi A were ar sf sere fafae : @ CH3 CHg-C-O-CHg+ HI CH () CH3-CH,-CH-cH, —CwS73K OH _ @) CHCl, + aq.NaOH © CgH;-OH Gage Write the final product (s) in each of the following reactions : — CH (a) CHs-C-O-CHg+ HI CH () CHy-CH,-CH-cH, _Cv/S73K_ ou geal i) CHCly + aq.NaOH © OgH,—OH -BEECy PsaNeon YEARS 56/2/C 6 QUESTION PAPER.COM12. am ha wolafta a: 3 @ adtesiy a agit 7 @ Wr a 1 seni 7 Gi) otter a ae-2-ga F wear fre Hoyer seri + fafag : ® co CH,~CHg Brg, UV light 2 @ ———— O2N a Na @) eR Gy athe” C1 Gi) CHg-CH,-Br _ASON |, How do you convert : @) Chlorobenzene to biphenyl Gi) Propene to 1-iodopropane (ii) 2-bromobutane to but-2-ene OR Write the major product(s) in the following : a CH,—CHy Bro, UVlight > ‘ a ss O2N () 2CHs-cH-cn, 2 _, e 3 f 3 Gry ether a Gi) CHy-CH,~Br _A8CN |, S| 56/2/C 7 quest eokcom - PTO,13. 14, 15. @ Gi) i) @ @) Gi) @ Gy Gi) Gi) ert sik dace % ata & raters iat # fafers afer are 4 fire war a feist ada der 3? Yer Wels ak teen wets & fed ate & UH oH sae Aha) Write the structural difference between starch and cellulose. What type of linkage is present in Nucleic acids ? Give one example each for fibrous protein and globular protein. free & afar ot fate a am afer Caries & Frew Y sphere st ser afer eit 37 ar areas 3 art H Frente Fy vex st a efi eet 3? Name the method of refining of nickel What is the role of cryolite in the extraction of aluminium ? What is the role of limestone in the extraction of iron from its oxides ? are afer : ® @ i SO, Uw sary @ vais TeO, UH Sar FI ager Fertengs vet sa e1 1, # atten 101 afer fararettet 81 Give reasons : @ @) Gai) 56/2/C SO, is reducing while TeO, is an oxidizing agent. Nitrogen does not form pentahalide. ICI is more reactive than Ip. YEARS. QUESTION PAPER.COM16. @) PPA [Fe(H,0),)9+ & fee wa, Garsta oraEn sik fers fefiacs (44, Fe=26) (o) wBiestae [Pt(en),Cly]2+ BI Ue Rha ware faker sh warrata Pte a (a) For the complex [Fe(H,0),]3*, write the hybridization, magnetic “character and spin of the complex. (At. number : Fe= 26) (&) Draw one of the geometrical isomers of the complex [Pt(en),Cl]?* which is optically inactive. 17. 500pm SR WAR H MI TH TS bcc, TH H frees Ver 1 Ta I AS 7.5g m7 3% 1 eat & 300 g a fort wary dart Bd F? An element crystallizes in a b.c.c, lattice with cell edge of 500pm. The density of the element is 7.5g cm~3. How many atoms are present in 300 g of the element ? 18. Gi) wa aeataen F aepl a ea from ele? @ Fra agen A uacal a yea aif : 0 f I 0-CH)—-CH,-0-¢ é b Gi) SF atasiofeass get ser wy A agerAl St perafeaa Sif : Stcis, Teles, Asis @ What is the role of Sulphur in the vuleanization of rubber ? Gi) Identify the monomers in the following polymer : 0 g un {--cxy-c1y-0-8 < Sif a Gi) Arrange the following polymers in the increasing order of their intermolecular forces : Terylene. Polythene, Neoprene 56/2/C 9 YEARS P.O. QUESTION PAPER.COM19. 20. 56/2/C 10 wm wae a suite fase afiiea & fed Frat alee wa 7a : CyH,Cl(g) > CHy(e) + HCl) Time/sec dea TH/atm 0 0.30 300 0.50 @ feria aw oie sf) (Fea TA : log 2=0.301, log 3=0.4771, log 4=0.6021) For the first order thermal decomposition reaction, the following data were obtained : CaH,Cl(g) > CoHi,(e) + HOME) Time/sec Total pressure / atm o. 0.30 300 0.50 Calculate the rate constant (Given : log 2=0.301, log 3=0.4771, log 4=0.6021) fre & art et ating : @ Uhele pete ae afiien vei Oc G1 Gi) Seta Farr 4 (CH,), N et atten (CH), NH afte ergy 1 Gi) eRiad WHT at orien we GIR & aera seaaz ee FI Give reasons for the following : (@ Aniline does not undergo Friedal-Crafts reaction (i). (CH,)g NH is more basic than (CH,), N in an aqueous solution. , Gii) Primary amines have higher boiling point than tertiary amines. YEARS (QUESTION PAPER.COM21. 22, fr uel at ufeatia sifre : 3 @ arifeice wens Gi) Wher faaa Gi) Fafa Hees Define the following terms : @ — Lyophilic colloid (i) Zeta potential Gii) Associated colloids Wa MgSO, M=120gmol-HF4 gh 100 gua ty ae wag foerrt aaeria a ofaerr aifse, ge wae wee fe MgSO, #1 ha: arian a ar FI (K, Wa & fet =0.52 K kg mol-) Calculate the boiling point of solution when 4 g of MgSO, (M= 120 g mol~4) was dissolved in 100 g of water, assuming MgSO, undergoes complete ionization. (K,, for water=0.52 K kg mol~}) 56/2/C ul YEARS PTO QUESTION PAPER.COM23, add ea oro stay fee aot F Wel Bsn GMT GM eA six et aR afrafia wa ot a Gm a sted vee) we fen Se ont F a ed BST aka fin a3) fade & oH aediet fia at. war oh se cleat H Ta STA Sret A Seat sits et sik orn fen fh. fee Veet 4 difea F faa A Ss al ot it em at ai ae et dies at sik unite ora ae St Tere a am fis ai ene & sar fifie arm ae at sik hs a fer A tee TRIS BT TA silat wi oem Fret & a aire : @ firan & fer aeth (wen 8 ee ct) I cuter? @) tenfes en 2? ue sec df! Gi) wa tenfes after fer ae ca wifey? HIT FaeNET! Due to hectic and busy schedule, Mr. Singh started taking junk food in the lunch break and slowly became habitual of eating food irregularly to excel in his field. One day during meeting he felt severe chest pain and fell down. * Mr. Khanna, a close friend of Mr. Singh. took him to doctor immediately. ‘The doctor diagnosed that Mr. Singh was suffering from acidity and prescribed some medicines. Mr. Khanna advised him to eat home made food and change his lifestyle by doing yoga, meditation and some physical exercise. Mr. Singh followed his friend’s advice and after few days he started feeling better. After reading the above passage, answer the following : @ What are the values (at least two) displayed by Mr. Khanna ? Gi) What are antacids ? Give one example. (iii) Would it be advisable to take antacids for a long period of time ? Give reason. 24. (@) fre after a a atk Ba deat fafa : @ CH,COCI Hy,Pd-BaSO4 A H,N-OH B - 1.00, PC), Gi) CHgMgBr 2 HoT 4 HB YEAR: 56/2/C 12 QUESTION Pe com(b) © fa) ) @ © (a) ) © 56/2IC fre et oes Sify : @ CgH;-COCH, Hk C.H;-CHO # i) CH,COOH siRHCOOHy fr a ors aed BE eG & HH A ferfar CH,CHO, CH,COOH, CH,CH,OH aigat gea-frer ara 9 fafer carafe afifien a fafa fra al =afacrahfefers poner slit uit rH aed EE HA A orafeera aifary 5 1 C,H ;COCH,, CH;- CHO, CH,COCH, wratfastes are araifia, ya at afte aay vet tar? fre afuiea & sere at fefan : 1. G—-Bu)pAIH CH,CH,CH=CH-CH,CN 3495p > 0,H,0 2 frat ware € ASB 1 NaOH RL we ae w Baeert a then sade sant 2 wale A ey sada ae ara Bi Adak BS We fafer! Write the structures of A and B in the following feactions : @ CH,COC! Hy,Pd-BaSOq A H,N-OH B (i) CHsMgBr +002, me we A Ob, B Distinguish between : @ CgH,-COCH, and O,H,-CHO Gi) CH,COOH and HCOOH Arrange the following in,the increasing order of their boiling points : CH,CHO, CH,COOH, CH,CH,OH 13 YEARS P-T.O. QUESTION PAPER.COMOR (a) Write the chemical reaction involved in Wolff-Kishner reduction. (b) Arrange the following in the increasing order of their reactivity towards nucleophilic addition reaction : CgH,COCH,, CH, - CHO, CH,COCH, (©) Why carboxylic acid does not give reactions of carbonyl group ? @ Write the product in the following reaction . i-Bu)pAlH CH,CH,CH=CH-CH,cN 4g (© Aand B are two functional isomers of compound CyH,0. On heating with NaOH and Ig, isomer B furms yellow precipitate of iodoform whereas isomer A does not form any precipitate. Write the formulae of A and B. 25. (a) fra afiiwar & fet 298K KH E°,. St Vee ast 2Al(s)+ 3Cu2+(0.01M) > 2AI8+ (0.01M) + 3Cu(s) fen TH : E,.) = 1.98 V @ Aah Bs Bari orn we a cis Hsin ee A aaM & fare fee Sn Tal St ait eH? [w(Pe? Pe) = -0.44V] feat Wa: BA2+/A)= —2.37V : EP (B2+/B)= -o.v : awe @) CH,COOH % 0.001 mol L~1 facrad #1 arer#aT 8,905 x 10-8 S ema? BI Bas] he aTeraar atk ferent Sh (o) wr afeHeTA FferE fee TAT X (H+) = 349.6 S em? mol~2 34K N° (CHyCOO-)=40.9 S cm? mol! ©) erwaate da a ofontes sifse, en dat wa fags wars Ae EP 3 eT TT are fara afer Bt rae? i YEARS 56/2/C 4 QUESTION PAPER.COM(a) Calculate E°,,,) for the following reaction at 298K : 2A\(s)+ 3Cu2+(0,01M) - 2Al3+ (0.01M) + 8Cu(s) Given : E,.) = 1.98 V (b) Using the I? values of A and B, predict which is better for coating the surface of iron [E°(Fe?+/Fe) = — 0.44V] to prevent corrosion and why ? Given : E(A2+/A)= —2.37V : E° (B2+/B) = —0.14V OR (a) The conductivity of 0.001 mol L~? solution of CH;COOH is 3.905x 1075 S cm~1. Calculate its molar conductivity and degree of dissociation (a). Given \" (H+) =349.6 S em? mol~! and 4° (CH,COO~) = 40.9 S cm? mol! (b) Define electrochemical cell. What happens if external potential applied becomes greater than E°,,) of electrochemical cell ? 26. (@) fret at arm ufed wreRET : 5 @ SRSA & AY Mn Sere Se sae + 7 eae S Tah AS B We Sood ST are 4 St aha BI @) Or? + GH Veet STTETTH eI (ii) Co? + wan Gia BA F wake zn2+ cam The aI TI ) Fe attecti a pl aif: @ 2Mno, + 4KOH +0, 25 @) CnOF + 14Ht +6r > aeat 3d WaT Feit aa HS fea oma F .Sc Ti’ V. Gr Mn Fe Co Ni Cu Zn FS aK aia : @ sa ae wi fafay st afters sore aoe outer F) emit G) SH A Te Fr Tee sears F? (ai) “SH A aes Hae +3 Sra sae cule F? dv) FO Tet +3 sta F ya Sra e aK ea? 56I2/C 15 YEARS PTO QUESTION PAPER.COM(a) Account for the following : @ Mn shows the highest oxidation state of +7 with oxygen but with fluorine it shows the highest oxidation state of +4. (i) Cr? +is a strong reducing agent. Gi) Cu?* salts are coloured while Zn?+ salts are white, (b) Complete the following equations : @ 2Mn0, + 4KOH + 0, —4> Gi) CyO?" + 14H +6r 3 OR ‘lhe elements of 3d transition series are given as : Sc Ti V Cr Mn Fe Co Ni Cu 2n Answer the following : @ Write the element which shows maximum number of oxidation states. Give reason. G@) Which element has the highest m.p ? Gii) Which element shows only +8 oxidation state ? Gv) Which element is a strong oxidizing agent in +8 oxidation state and why ? YEARS 56/2/C 16 QUESTION PAPER.COM