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Documente Cultură
Oil Recovery
Vanessa Nuez-Lopez
Gulf Coast Carbon Center, Bureau of Economic Geology
Jackson School of Geosciences, University of Texas at Austin
Artificial Lift
Natural Flow
Secondary
Recovery
Conventional
Recovery
Pressure
Maintenance
Waterflood
Tertiary
Recovery
Thermal
Enhanced
Recovery
Chemical
Solvent
Other
Source: Adapted from the Oil & Gas Journal, Apr. 23, 1990
The process
Recycling
Water Pump
Surface Infrastructure
Production well
Production manifold
Injection well
Separator
Surface Infrastructure
CO2 recycling facility
CO2 compressor
ARI 2012
More than
120 million
incremental
barrels
through
2008
14000
Actual Oil
18% HCPV
CO Injection
2
16000
BOPD
1,000
18000
Barrels/Day
10,000
12000
10000
Recovery, % OOIP
P+S
To Date 37.2
8000
Continued
Waterflood
1988
1989
1990
1991
1992
1993
6000
Continued Waterflood
2000
1980 1981 1982 1983 1984 1985 1986 1987 1988 1989 1990 1991 1992
1994
Year
Year
EOR
45.2
6.7
40000
25% HCPV
CO Injection
2
30000
20000
10000
Continued Waterflood
0
1980 1981 1982 1983 1984 1985 1986 1987 1988 1989 1990 1991 1992
Year
Recovery, % OOIP
BOPD
50000
To Date
P+S
1500
BOPD
60000
2000
Recovery, % OOIP
CO2 Injection
70000
80000
3.2
4000
100
1987
EOR
1000
P+S
EOR
To Date 21.8
46% HCPV
CO2 Injection
20 MCF/D CO2
Source Secured
500
End of
Water Injection
0
1978
1980
1982
Continued Waterflood
1984
1986
Year
1988
1990
1992
NETL, 2008
Gross
feet
md
feet
API
cp
%HCPV
%OOIP
Net
MCF/STB
MCF/STB
11.1
9.0
15.2
18.0
6.5
9.2
9.7
9.5
2.4
6.3
5.0
11.0
7.8
4.6
5.0
6.5
3.2
1985
1985
1981
1983
1972
1982
1986
1972
1981
15.6
13.0
8.0
10.0
1974
1986
6.0
12.6
10.7
6.1
1981
1975
1983
1983
1981
1981
1976
1978
1982
Dollarhide
East Vacuum
Ford Geraldine
Means
North Cross
Northeast Purdy
Rangely
SACROC (17 pattern)
SACROC (14 pattern)
South Welch
Twofreds
Wertz
TX
NM
TX
TX
TX
OK
CO
TX
TX
TX
TX
WY
Trip. Chert
Oolitic dolomite
Sandstone
Dolomite
Trip. Chert
Sandstone
Sandstone
Carbonate
Carbonate
Dolomite
Sandstone
Sandstone
7,800
4,400
2,680
4,400
5,400
8,200
6,500
6,400
6,400
4,850
4,820
6,200
120
101
83
100
106
148
160
130
130
92
104
165
17.0
11.7
23.0
9.0
22.0
13.0
15.0
9.4
9.4
12.8
20.3
10.7
9
11
64
20
5
44
5 to 50
3
3
13.9
33.4
16
48
71
23
54
60
40
110
139
139
132
18
185
40
38
40
29
44
35
32
41
41
34
36
35
0.4
1.0
1.4
6.0
0.4
1.5
1.6
0.4
0.4
2.3
1.4
1.3
30
30
30
55
40
30
30
30
30
25
40
60
14.0
8.0
17.0
7.1
22.0
7.5
7.5
7.5
9.8
7.6
15.6
10.0
OK
MS
NM
NM
CA
LA
TX
LA
WY
Sandstone
Sandstone
Anhydritic dolomite
Dolomitic sandstone
Sandstone
Sandstone
Dolomitic sandstone
Sandstone
Sandstone
1,950
10,400
4,050
3,700
9,200
8,180
4985
13,000
3,000
95
248
90
90
235
183
105
225
104
17.0
23.4
10.0
11.0
15.0
26.4
12.0
26.0
19.5
57
75
11.2
13.9
9
230
8
1200
28.5
21
30
49
23
136
15
75
186
22
47
39
36
36
36
32
32
33
39
2.1
0.4
0.8
0.8
0.5
0.9
2.0
0.3
1.4
35
160
30
30
63
19
26
24
30
14.0
21.0
8.2
17.7
15.0
20.0
20.0
8.7
12.9
producing pilots
Garber
Little Creek
Majamar
Majamar
North Coles Levee
Quarantine Bay
Slaughter Estate
Weeks Island
West Sussex
27.0
11.6
8.1
7.4
16.7
7.9
8.9
2.4
3.7
3.3
11.7
6.3
10.4
12.5
8.9
6.3
6.4
6.0
Gross
Net
AVERAGE
MEDIAN
AVERAGE
MEDIAN
PCOR
BIG SKY
MRCSP
WESTCARB
MGSC
SWP
SECARB
FutureGen 2.0
CCPI
ICCS Area 1
FutureGen 2.0
Southern Company
HECA
NRG
Leucadia Energy
Questions?
Introduction
What is CO2-EOR?
CO2-EOR is a technology that targets the residual oil in depleted oil reservoirs
by the injection of carbon dioxide (CO2).
Where is it applied?
In depleted light-oil reservoirs that have gone through
primary recovery (natural flow) and, in most cases,
secondary recovery (mainly waterflooding).
FutureGen 2.0
CCPI
ICCS Area 1
FutureGen 2.0
Southern Company
HECA
Leucadia Energy
Problem Statement
Is CO2-EOR a valid option for greenhouse gas emission reduction? Are geologically stored
carbon volumes larger that direct/indirect emissions resulting from CO2-EOR operations?
Carbon emitted
Carbon
captured
Carbon utilized
(CO2-EOR)
Carbon stored
34
Related Literature
[Kg CO2e/MWh]
939(Coal Plant)
790 (SaskPower Mix Grid)
952 (Ref. US Coal-Fired Power Plant)
712 (U.S grid, average) (*)
538 ERCOT, 299 CAMX & 604.5 SRSO (2007) (*)
410 (Power and CO2 supply from same PP) (*)
611 US Mix, 649 ERCOT & 746 NGSC (2013) (*)
Natural CO2
reservoir
Electricity
Grid
kg CO2e/MWh
4
18
CO2
transport to
eld
Published Literature
Aycaguer et al. 2001, 40 years
Suebsiri et al. 2006, 25 years
Khoo and Tan 2006, 40 years
Jaramillo et al. 2009, 8-21 years
DOE-NETL 2009 years: West Texas (WT)-30,
California (CA)-24 & Mississippi (MS)-21
FOX, 1 year (2007)
Hertwich et al. 2008, 30 years
Cooney et al. 2015, 25 years
50 KgCO2e/bbl or 9
gCO2e/MJ
25 KgCo2/Bbl or 5 gCO2e/
MJ
10 gCO2e/MJ
<1% of LCA (*)
Geological
carbon
sequestra<on
(KgCO2e/Bbl)
CO2-EOR
61
opera<ons
30
32
57
17-44 (44 WT, 24 CA, 36 MS)
100 (CO2, no CO2e) (*)
3.02-20.4
60-165 (*)
Crude oil
transport
Petroleum
rening
Product
transport
4.8 kg CO2/kg gasoline (only) (*)
395 KgCO2e/bbl or 67 gCO2e/MJ
469 kgCO2/Bbl or 80 gCO2e/MJ
97 Mton CO2 (*)
75 gCO2e/MJ
Product
combus<on
(a) Study boundaries within Canada. CO2 emissions data from U.S. side (capture), not included.
(b) Power Plant with CCS supplies both CO2 and electricity to EOR site
(c) Supercri<cal Pulverized Coal (SCPC) and Natural Gas Combined Cycle (NGCC) Power Plants, CO2 not CO2e
(based on net power).
(*) Data extracted from paper. Other data are es<mated for compara<ve purposes based on literature or public
data.
Injection/production wells
Production separation
CO2 separation
CO2 compression
41
50
GHG Intensity, %
40
30
20
10
0
Inje<on Wells
Produc<on
Wells
Fluid Phase
Separa<on
Gas Processing
CO2
Compression
Fract - Refrg
1.5
13.5
6.5
9.5
46
Ryan Holmes
9.5
4.5
37.5
32.5
Membrane
3.5
53.5
35
CO2 injection
[MMCF]
CO2 Utilization
[MMCF/bbl]
43
Field Study
(Cranfield, Mississippi)
It provides the optimal mass accounting data set as it
was required by its comprehensive SECARB MVA
program
It is a desirable direct injection (no WAG), which is
favorable for achieving NCNO
Pattern geometry and operations repeated
systematically around field development
Provides a simpler environment than many CO2-EOR
floods
44
Field Setting
Cranfield overview:
Clastic Mississippi field
Apex of 4-way closed anticline
Main pay is ~10,000 ft deep
Pi = 4,600 psi, Ti = 150F
Original gas cap
Productive during 1940s and 50s
CO2 injection started in 2007
Available mass accounting data
as required by SECARBs
monitoring program.
Current activities:
Trapping Mechanisms
Additional funds allowed us to add valuable work to the
modeling tasks by studying the trapping mechanisms
that contribute to the geological permanence of the
stored CO2
1.
2.
3.
4.
Residual/capillary trapping
CO2 dissolution into brine
CO2 dissolution into oil
Mineral trapping
Benson, 2003
2 in
Summary
Accomplishments:
Selection of system boundaries relevant to NCNO classification:
gate-to-grave
Identification of critical CO2 emission components within the EOR
site
Gathered and classifying Cranfield mass accounting data
Started numerical simulation tasks
Future Plans:
Conclusions
Carbon balance of CO2 EOR is sensitive to the system boundary.
In a gate-to-gate life cycle analysis, the electricity consumption
(purchased and generated) is responsible for almost all the
emissions associated with the EOR operation, particularly at the
CO2 separation and compression processes.
Combustion of the refined product is the largest CO2 emissions
contributor in the entire cradle to grave system.
Carbon balance is sensitive to CO2 flood performance (CO2
utilization rates).
A universal methodology for NCNO classification will certainly
benefit CO2-EOR operations as there might be an economic impact
if potential future regulations provide value to the emissions and/or
storage of CO2.
51
Questions?