Ai TS-4 (XI) - SET - A

ALL INDIA INTERNAL TEST SERIES
CHEMISTRY, MATHEMATICS & PHYSICS

SET A
APT - 5
080120.1
Time Allotted : 3 Hours
Ai2TS-4
Maximum Marks: 234
INSTRUCTIONS
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
You are not allowed to leave the Examination Hall before the end of the test.
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet before
attempting the paper. Wrong CODE or no CODE will give wrong results.
A.
General Instructions
Attempt ALL the questions. Answers have to be marked on the OMR sheets.
This question paper contains Three Sections.
Section I is Chemistry, Section II is Mathematics and Section III is Physics.
Each Section is further divided into three Parts: Part A, Part B & Part C.
Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.
CLASS XI
B.
Filling of OMR Sheet
1.
3.
Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
OMR sheet contains alphabets, numerals & special characters for marking answers.
C.
Marking Scheme For All Three Parts.
(i)
PART-A (01 10) contains 10 Multiple Choice Questions which have One or More Than One Correct
answer. Each question carries +3 marks for correct answer. There is no negative marking.
(ii)
PART-B (01 02) contains 2 Matrix Match Type Question which have statements given in 2 columns.
Statements in the first column have to be matched with statements in the second column. There may be
One or More Than One Correct choices. Each question carries +8 marks for all correct answer however for
each correct row +2 marks will be awarded and 1 mark for each row matched incorrectly.
2.
(iii) PART-C (01 08) contains 8 Numerical Based questions with Single Digit Integer as answer, ranging from 0
to 9 and each question carries +4 marks for correct answer and 2 mark for wrong answer.
Name of Candidate :
Batch ID :
Date of Examination :
/ 2 0 1
Enrolment Number :
FIITJEE
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
Website: www.fiitjee.com, Mail : aiits@fiitjee.com
Ai TS 4 (XI ) | SET A | APT 5 |
Page |1
SECTION 1 (Chemistry)
PART A
(Multi Correct Choice Type)
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE OR MORE may be correct.
In the potential energy diagram for a reactions in which X is converting into Z, which of the following
statements are correct?
Potential energy
1.
X
Z
Electronic reorganization
(A)
(B)
(C)
(D)
2.
X represents reactant
Y represents a reaction intermediate
Y represents a transition state.
Z represents a product.
What is true about the molecules shown?

H
H3C
H3C
O
H
Cl
H
CH3
HC
C
Br
(I)
(II)
(III)
(A) (I) is optically active

(C) (IV) and (V) are functional isomers
CH3
O
CH3
H3C
C2H5
OH
C2H5
(V)
(IV)
(B) (II) and (III) are position isomers

(D) (II) is optically active
CH 2 Cl
3.
Na Dry ether
H3C
CH 2Cl
Products obtained in above Wurtz reaction is/are
CH3
(A)
(B)
H3C
CH3
H3C
CH3
(C)
(D)
H3C
CH3
H3C
Space for rough work
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4.
Which of the following is an aromatic cation?

(A)
5.
Page |2
(B)
(C)
(D)
NH 2
CH
CO O
HNO3 ,
H ,
3
2
A
B
C
H 2 SO4
H 2O
NH2
NH 2
NO 2
(A) is
(B) is
(A)
(B)
CH3
CH3
O
NH 2
(C)
(A) has an amide functional group
(D)
(C) is
NO 2
FIITJEE
Page |3
6.
Cl2 , h
2
Z
W
H excess
hot alkaline
KMnO4
X Y
OH
OH
(A)
(X) is
(B)
Compound (Z) is
OH
OH
O
O
OH
(C)
(X) is
and
C
OH
OH
(Y) is
(W) is
(D)
OH
Cl
O
O
7.
Which of the following options are correct for the reaction shown below:
5Zn V2O5
5ZnO 2V
(V = 50.94, Zn = 65.38 and O = 16)
(A) Equivalent weight of 1 g equivalent of Zn is 32.69 g
(B) Equivalent weight of 1 g equivalent of V2O5 is 18.2 g
(C) Equivalent weight of 1 g equivalent of ZnO is 40.69 g
(D) Equivalent weight of 1 g equivalent of V is 10.19 g
8.
9.
10.
Which of the following molecules/ions are linear?
(A) BeCl2
(B) ICl2
(C) CS2
(D) ICl2
Diagonal relationship is shown by

(A) Be and Al
(B) Li and Mg
(D) B and P
(C) Mg and Al
On addition of cis-1-2-diol in aqueous solution of boric acid.

+
(A)
H ion concentration increases
(B)
(C)
is formed
(D)
H ion concentration decreases
BO33 is formed
FIITJEE
Page |4
PART B
(Matrix Match Type)
This section contains 2 Matrix Match questions. Each question has statements given in 2 columns. Statements in the
first column have to be matched with statements in the second column.
1. Match Column-I with Column-II
Column-I
(A)
(B)
COOH
H
Br
Br
Br
P.
Column-II
Aromatic
Q.
Optically active (surely dextrorotatory)
R.
Meso compound
S.
Thermodynamically stable
COOH
(C)
Br
H
CH3
CH3
H
(D)
Br
Me
Me
2.
Column I contains the metal while column II contains the characteristic of metal. Match the metal in column-I
with its characteristic in column II.
(A)
(B)
(C)
(D)
Column-I (Metal)
Li
Mg
Na
Ca
P.
Q.
R.
S.
Column-II (Characteristic)
Produce colour on flame
Produce blue solution in liquid NH3
Produce nitride directly with air
Produce peroxide with excess of O2 (main
product)
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Page |5
PART C
(Integer Answer Type)
This section contains 08 multiple choice questions. The answer to each question is a single digit integer, ranging
from 0 to 9 (both inclusive).
1.
If the kinetic energy of a particle is decreased by
1
times of original, de Broglie wavelength becomes y times.
4
What is y ?
3
2.
A gas expands from a volume of 3 dm to 5 dm against a constant presence of 30 atm. The work done during
expansion is used to heat 10 mole of water at temperature 290K. Calculate the change in temperature of
1 1
water (Specific heat of water = 4.184 J K g )
3.
At 400 K, the root mean square speed (rms) of gas X (molecular mass = 40) is equal to the most probable
speed of gas Y at 60 K. The molecular mass of gas Y is
4.
How many distinct monochlorinated products, (including steriosmers) may be obtained when the alkane
shown below is heated in presence of Cl2?
1
2
O
5.
Sulphonation is the most favourable at the carbon number________.
CH3
NH
4
6.
How many functional group are present in the following compound?

O
CH 3
O
CH 2
CH 2 O
CH 3
O
N
7.
How many of the following compounds do not undergo Friedel-Crafts alkylation?

O
O
NO 2
8.
CH3
OH
SO3H
N(CH 3)3
How many moles of RMgX reacts wtih one mole of

O
HC
CH C
OH
OH
FIITJEE
Page |6
SECTION 2 (Mathematics)
PART A
1.
If the lines az az b 0 and cz cz d 0 are mutually perpendicular, where

complex numbers and b and d are real numbers, then
(A) aa cc 0
(B) ac is purely imaginary
2
c
(C) arg
2.
If
C3 .
12!
5!3!2!
13
k
k 1
(A)
4.
a c
a c
The number of ways of arranging the letters AAAAA, BBB, CCC, D EE, and F in a row if the letters C are
separated from one another is
(A)
3.
(D)
a and c are non-zero
2
9
(B)
13!
5!3!3!2!
and
Si
k 1
1
2
(B)
(C)
36k
2
12
1
2
14!
3!3!2!
(D)
15!
13!
12! 13
C2
2
5!(3!) 2! 5!3!2! 5!3!
, then S1 + S2 is equal to
(C)
2
15
1
2
(D)
2
18
1
2
Consider the circle x y 8x 18 y 93 0 with the center C and a point P(2, 5) outside it. From the
point P, a pair of tangents PQ and PR are drawn to the circle with S as the mid point of QR.
The line joining P to C intersects the given circle at A and B. Which of the following hold(s) good?
(A) CP is the arithmetic mean of AP and BP
(B) PR is the geometrical mean of PS and PC
(C) PS is the harmonic mean of PA and PB
2
(D) The angle between the two tangents from P is tan

5.
Correct statement(s) is(are)

(A) In any triangle ABC a cos A b cos B c cos C s
(B) In any triangle ABC a cos A b cos B c cos C s
(C) In any triangle ABC, if a : b : c 4 : 5: 6 , then R : r 16 : 7
(D) In any triangle ABC, if a : b : c 4 : 5: 6 then R : r 7 :16
FIITJEE
Page |7
5 A
32
5 B
5 C
n
then D, E , F
E
,F
,nI
32
32
2
(A) cot D cot E cot E cot F cot D cot F 1

(B) cot D cot E cot F cot D cot E cot F
(C) tan D tan E tan E tan F tan F tan D 1
(D) tan D tan E tan F tan E tan D tan F
6.
Let A, B, C be angles of triangle ABC and let D
7.
If
r & r r r are roots of x2 r 2 (r 1) x r 5 0
n
(n 1) (n2 3n 1)
2
(C) f ' 0 1
9.
12 6 15 4n
sin x
1 sin x
(C)
If
2 r ) then
26
is non-zero then n takes the value A

(D) B
26
36 20
2
then sin x lies in
3
1
1
2 , 0
1
(D) 0,
4
(B)
1
2 ,1
a1x b1 y c1 a2 x b2 y c2 a3 x b3 y c3 0 , then lines
and
(3
r 1
If the coefficient of b c d e in the expansion of (a + b + 2c + d + e)

and the coefficient is B. Then
26
(A) A = 12
(B) A = 10
(C) B
108 18
If 1
(B) f n
(A) ,
,
2 2
10.
f n =
n
(n 1) (3n2 n 1)
2
(D) f ' 0 2
(A) f n
8.
and
a1 x b1 y c1 0, a2 x b2 y c2 0
a3 x b3 y c3 0
(A) cannot be parallel
(B) can be parallel
(C) may be concurrent (D) cant say anything
FIITJEE
Page |8
PART B
(Matrix Match Type)
1.
Column I
Column II
(A)
The number of rectangles that can be (P) Rational Number
obtained by joining four of the 12 vertices of
a 12 sided regular polygon is
(B)
In ABC , circumradius is 3 and inradius is (Q)

1.5
units.
If
the
value
of
a cot 2 A b2 cot 3 B c3 cot 4 C is
15
(C)
Let z1 , z2 , z3 and z4 be the roots of the (R)
13 3
equation z z 2 0 , then the value of

4
2z
r 1
(D)
If
1 is equal to
n
1
Sn tr n 2n 2 9n 13
6
r 1
and
(S)
31
(T)
20
f n tr then f 5 is
r 1
2.
Column I
Column - II
(A)
If A, B, C are angles of acute angled (P) 2
triangle,
then
minimum
value
of
4
4
4
tan A tan B tan C is
(B)
Number of integral values of a for which the (Q)

tan 2 x a 4 tan x 4 2a 0
equation
has at least one solution x 0,

(C)
24
Let (3x + 2x + c)12 =
A x
r 0
and
A19 1
A 5 27
(R)
(S)
Odd number
(T)
27
then c is
(D)
1 7
r
is
tan 2
7 r 1
16
FIITJEE
Page |9
PART C
1.
2.
Let n N ; Sn
If
3n
r 0
Cr and Tn 3n C3r . Find Sn 3Tn .

n
3n
r 0
th
2008
is imaginary (2009) roots of unity. If 2
2009
r 1
least value of (a + b + c) is 251 , find the value of

2
1
a 2b c
r
2
where a, b, c N . If the
3.
The figures 4, 5, 6, 7, 8 are written in every possible order without repetition. If the number of numbers greater
10
than 56000 is 2 Cr then prime value of r is ___________
4.
sin x 4cos x cos x 4sin x sec x a 4b 4ab 0 has real solution,

If the equation
where (x, a, b R), then a 2b is equal to
5.
The number of values of k for which x k 2 x k
6.
The value of cos
7.
Let
S
r 1
For 0
kx 2k 1 is a perfect square is
3
7
9
2
4
8
cos cos cos
cos cos cos
cos
is
20
20
20
20
15
15
15
15
9999
8.
r r 1
r 4 r 1
6
, if the solution of
cos ec
m 1
m 1 cos ec m 4
4
2 is
12
then
2 is
FIITJEE
P a g e | 10
SECTION 3 (Physics)
PART A
1.
A body of mass m is attached to a spring of spring constant k which hangs from the ceiling of an elevator at
rest in equilibrium. Now the elevator starts accelerating upwards with its acceleration varying with time as a =
pt + q, where p and q are positive constants. In the frame of elevator
(A) the block will perform SHM for all value of p and q
(B) the block will not perform SHM is general for all value of p and q expect p = 0
(C) the block will perform SHM provided for all value of p and q expect p = 0
(D) the velocity of the block will vary simple harmonically for all value of p and q
2.
A circular disk of radius r is revolving around a pivot while

rolling on a horizontal surface as shown in the figure.
The speed of the centre of mass of the disk remains
constant and is equal to v. Now choose the correct
statements.
(A) angular acceleration of the disc is zero
(B) centripetal acceleration of the centre of mass of the disc is zero

v2
(C) centripetal acceleration of the centre of mass of the disc is
R
(D) tangential acceleration of the centre of the disc is zero
3.
The spring balance A reads 2 kg with a block suspended from it. A balance B reads
5 kg when a beaker with liquid is put on the pan of the balance. The two balances
are now so arranged that the hanging mass is inside the liquid in the beaker as
shown in figure. In this situation:
(A) the balance A will read more than 2 kg
(B) the balance B will read more than 5 kg
(C) the balance A will read less than 2 kg and B will read more than 5 kg
(D) the balance A and B will read 2 kg and 5 kg respectively
4.
If a sample of metal weighs 210 g in air, 180 g in water and 120 g in a liquid:
(A) RD of metal is 3
(B) RD of metal is 7
(C) RD of liquid is 3
(D) RD of liquid is (1/3)
5.
A simple pendulum of length L and mass (bob) M is oscillating in a plane about a vertical line between angular
limit - and +. For an angular displacement , the tension in the string and the velocity of the bob
are T and V respectively. The following relations hold good under the above conditions
(A) Tcos = Mg
(B) T Mg cos =
MV 2
L
(C) the magnitude of the tangential acceleration of the bob a T g sin

(D) T = Mg cos
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6.
P a g e | 11
A 2kg mass attached to a string of length 1 m moves in a horizontal circle as a

o
conical pendulum. The string makes an angle = 30 with the vertical. Select the
2
correct alternative (s) (g = 10 m/s )
(A) the horizontal component of angular momentum of mass about the point of
2
support P is approximately 2.9 kg-m /s
(B) the vertical component of angular momentum of mass about the point of
2
support P is approximately 1.7 kg-m /s
dL
(C) magnitude of
( L = angular momentum of mass about point of support P) is
dt
kg m 2
approximately 10
s2
dL
(D)
will not hold good in this case
dt
7.
A gas expands such that its initial and final temperatures are equal. Also, the process followed by the gas
traces a straight line on the p V diagram
(A) the temperature of the gas remains constant throughout
(B) the temperature of the gas first increases and then decreases
(C) the temperature of the gas first decreases and then increases
(D) the straight line has negative slope
8.
Inside a uniform sphere of mass M (M is mass of complete sphere) and radius R, a cavity of radius R/3 is
made in the sphere as shown.
(A) Gravitational field inside the cavity is uniform

(B) Gravitational field inside the cavity is non-uniform
88GM
45R
(D) Escape velocity is defined for earth and particle system only
(C) The escape velocity of a particle projected from point A is
9.
A container of large uniform cross sectional area A resting on a horizontal surface holds two immiscible nonviscous and incompressible liquids of density d and 3d, each of height H/2. The lower density liquid is open to
the atmosphere having pressure P0. A tiny hole of area a (a << A) is punched on the vertical side of the lower
container at a height h (o <h<H/2) for which range is maximum.
(A) h = H/3
10.
(B) Range R
2H
3
(C) Range R
3H
2
(D) Velocity of efflex v
2
gH
3
A plank of mass M and length L is hinged at its mid point from a fixed support in vertical plane as shown.
Plank is free to rotate in vertical plane about the hinge. Two persons of equal mass running on the plank with
same speed v relative to the plank so that angular velocity of the plank remains constant. Assuming they
run till running is possible then v is :
(A) a constant
(B) independent of the separation between the persons
(C) independent of the distance of the persons from the hinge
(D) independent of their mass
FIITJEE
P a g e | 12
PART B
(Matrix Match Type)
1.
A mass is subjected to a force F = (at bx) i initially the mass lies at the origin at rest. Here x refers to the x
co-ordinate of the mass, t refers to the time elapsed. All the values are in S.I. units. (i.e. F, m, t, x, a and b).
Take m = 1 kg, a = 1 N/s, b = 1 N/m. Now match the list I (All values in List II are in S.I. units)
List I
List II
Maximum velocity attained by the
(A)
(P)
1
mass
Average velocity of the particle during
(B)
(Q)
2
the subsequent motion
Average acceleration of the particle
(C)
(R)
0
during subsequent motion
(D)
Position of particle at t =
(S)
1
2
2
2.
A cue stick apply a horizontal force F

continuously on an object kept on a rough
horizontal surface horizontally at a distance h
above the centre as shown in the figure.
match the following
(A)
(B)
Column I
If h = R and object is ring
If h = R/2 object is sphere
(P)
(Q)
(C)
(D)
If h = 2R/5 and object is sphere

If h = R/2 and object is cylinder
(R)
(S)
F
h
0
Column II
Object will roll without slipping for all value of F
Object will roll without slipping upto a certain value
of F
Friction will be in forward direction
Friction will be in backward direction
FIITJEE
P a g e | 13
PART C
2
1.
A spring of mass M = 3kg and spring constant k = 4 N/m. The spring lies on
a frictionless surface and one end of the spring is fixed to a wall as shown in
the figure. It can be assumed at any time that velocity of any point on the
spring is directly proportional to its distance from the wall. What is the time
period of oscillation of the spring (in second) if the free end of the spring is
slightly pulled from its natural length and released.
2.
Two soap bubbles of equal radii (R = 8cm) are stuck together with an intermediate film separating them.
3
Surface tension of solution forming bubbles is 710 . Newton/meter. What will be distance between the
centres of soap bubbles (in cm).
3.
Block A is on a frictionless horizontal table. A massless inextensible string fixed at one end of the string is
connected to block B of mass m. Initially the block B is is held at rest so that = 30. What will be the
2
2
magnitude of acceleration of block B just after it is released (in m/s , take g = 10 m/s )
4.
In the shown system A is a solid sphere of mass 2 kg and radius 1m. B is a cube of side 2m and mass 5 kg
and C is cylinder of mass 3 kg and radius 1m. The system is allowed to move on a fixed smooth inclined
2
plane of inclination 30. What will be the tension in the string connecting A and B. Take g = 10 m/s .
5.
A liquid is kept in a cylindrical vessel which is rotating about its axis, as a result of which the liquid rises at the
sides. Determine the difference in height (in meters) of the liquid at the centre of the vessel and its sides.
2
(Take = 10 rad/s, r = 1m, g = 10 m/s ).
6.
A container of volume 0.02 m contains a mixture of neon and argon gases at a temperature of 27C and
5
2
pressure of 110 N/m . The total mass of the mixture is 28 g. If the molecular weights of neon and argon are
20 and 40 respectively, determine the mass of neon (in grams) in the mixture, assuming gases to be ideal. (R
= 8.314 J/mole K).
7.
There are two smooth fixed hemispherical bowls A and B with radii R and 4R respectively. A point mass m is
gently released from the periphery of A and another mass 2m is released from the periphery of the bowl B. Let
TA and TB denote their respective time periods of oscillations, then what will be the ratio in TA/TB.
8.
In a uniform gravitational field g, which is acting vertically downward, a ball is thrown at an angle with
horizontal such that the initial (immediately after projection) radius of curvature is 8 times the minimum radius
of curvature. If angle of projection is 15, then find the value of .
FIITJEE

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ALL INDIA INTERNAL TEST SERIES

CHEMISTRY, MATHEMATICS & PHYSICS

Time Allotted : 3 Hours

Filling of OMR Sheet

Marking Scheme For All Three Parts.

Ai TS 4 (XI ) | SET A | APT 5 |

What is true about the molecules shown?

(A) (I) is optically active

(B) (II) and (III) are position isomers

Ai TS 4 (XI ) | SET A | APT 5 |

Which of the following is an aromatic cation?

(A) has an amide functional group

Ai TS 4 (XI ) | SET A | APT 5 |

Which of the following molecules/ions are linear?

Diagonal relationship is shown by

On addition of cis-1-2-diol in aqueous solution of boric acid.

H ion concentration decreases

Space for rough work

Ai TS 4 (XI ) | SET A | APT 5 |

Optically active (surely dextrorotatory)

Space for rough work

Ai TS 4 (XI ) | SET A | APT 5 |

If the kinetic energy of a particle is decreased by

Sulphonation is the most favourable at the carbon number________.

How many functional group are present in the following compound?

How many of the following compounds do not undergo Friedel-Crafts alkylation?

How many moles of RMgX reacts wtih one mole of

Ai TS 4 (XI ) | SET A | APT 5 |

If the lines az az b 0 and cz cz d 0 are mutually perpendicular, where

a and c are non-zero

(D) The angle between the two tangents from P is tan

Correct statement(s) is(are)

Ai TS 4 (XI ) | SET A | APT 5 |

(A) cot D cot E cot E cot F cot D cot F 1

Let A, B, C be angles of triangle ABC and let D

r & r r r are roots of x2 r 2 (r 1) x r 5 0

is non-zero then n takes the value A

a1x b1 y c1 a2 x b2 y c2 a3 x b3 y c3 0 , then lines

If the coefficient of b c d e in the expansion of (a + b + 2c + d + e)

(A) cannot be parallel

(B) can be parallel

(C) may be concurrent (D) cant say anything

Space for rough work

Ai TS 4 (XI ) | SET A | APT 5 |

In ABC , circumradius is 3 and inradius is (Q)

Let z1 , z2 , z3 and z4 be the roots of the (R)

equation z z 2 0 , then the value of

Number of integral values of a for which the (Q)

has at least one solution x 0,

Let (3x + 2x + c)12 =

Space for rough work

Ai TS 4 (XI ) | SET A | APT 5 |

Cr and Tn 3n C3r . Find Sn 3Tn .

is imaginary (2009) roots of unity. If 2

least value of (a + b + c) is 251 , find the value of

sin x 4cos x cos x 4sin x sec x a 4b 4ab 0 has real solution,

The number of values of k for which x k 2 x k

The value of cos

Space for rough work

Ai TS 4 (XI ) | SET A | APT 5 |

A circular disk of radius r is revolving around a pivot while

(B) centripetal acceleration of the centre of mass of the disc is zero

(C) the magnitude of the tangential acceleration of the bob a T g sin