Welcome to hitp:/iwww.trithucbonphuong.com cuuyé pé vE PH BE nim ving chuyén (é nay ta ean phai hieu due nhime khdi niém sau day. 1. BS dign ly ~ cia mot chat: Kha nang phn ly than ion eta mét chit ndo do trong dung dich née ‘Xét mot hgp chit MAC dé don gin ta cho M ¢6 dign tich = +1 va A c6 din tich =-1) MA M+A Bandiu C0 0 Phinly CC © Cin bing C-C CC ©) C Nhdn xét vi0“Cal > 02021 Néu a= 0 Chit khong dign ly . Néu «=I Chit dign ly hoan ton 2. Hiing s6 edn bing: K ‘Dé dinh gia kha ning phan ly cia mét chit thinh ion, ngOai86 gin ly ra ngudi ta con ding hing s6 dign ly K ‘Xét phuong trinh phn ly: MA MC + A°( LTA) ‘ K _ , Wl Yr’ duge goi li hing s6 phan ly &nhigt 46°khing di, K cing nh pK cing kin MAI K cdng lin pK cng nho > nly yéu dign ly man 6 phan ly axit va duge ky higu lac K, Khi MA li bazo thi ngudi ta goi Kyla hing sé phan ly bazo vi durge ky hiu ki: K, 3. Méi quan hé glita eéedai rong ava K, UF fOH 5. Khai nig pit cia mot ding dich ding dé do nog 6 (H°] trong mét dung dich King qua dc 6.Cach tinh pH Ki ndng 9 [IT ]=10" thia duge goi la pit pH = -Ie[H"] p08 = -Ig(OH] > plH"] + plOH”|=14 7. Cae dang bai tap vé xic dinh pH cia dung dich Dangt ‘ice dinh pH cia dung dich axit manh__( Phuong phap gi \Viét phuong trinh dign ly cia ec axit, tt dé tinh tong sé (mol) H* bing céch 4p dung cng thie Design and coppyright 2009 © NGUYEN AINHAN ‘Tel:0989 848 791Welcome to hitp://iwww.trithuebonphuong.com pH =-Ie{H"] Dang2 ‘Xie dink pH ciia dung dich bazo manh ( ‘Vist phuong trinh dign ly cia cae bazo, tds tinh. tong sé (mol) OWT, Ti [HOH] =10"" ta @ suy ra due $6 (mol) H” bing each ép dung cong thie pH! =—la[1"] ta s8 tim duce ai te pH. Dang3. ‘Nac dinh pH ciia dung dich axit véu (c <1) LLoai 1. Xae dinh pH cia axt yeu Khi x, Viet phusomg tri phan ly axit HA S=nll +A" (K) Ban dau C 0 0 Phinly xxx - Can bing Cx XX ; ie Ap ding peo rin in Ky =F TT = ta 8 dave phnton tinh bac ha ii prong tinny tas tinh duge gid tri pH. Cz. Ap dung céng thite [H"} = K,.C, > 7 av, BYK,.C, ‘Trong dé ta d& ding tinh durge pH. “ ny khoiig phai Khi nao cong ding diac) phn Iy Ky dupe ning d6 HT tid Cs. Ap dung eng thie pFT ; on axit, Co la nong 46 ban dau cua axit, va ndng 49 can biét a6 ai (trong do K, B hing si bing cia ait phi gin bing Cho dung axetic nding 46 0,1M vi 05d diga ly = 4% Gi: < cHcoon = cH,Coo” +i ‘Ap dung céng thie tinh 46 dign ly n_C_[H) 7 m 7 - MET 00% = 496» [41-]= 4.10" > pit =-Ig10 nm Cy 0,02 ory oo Vidu2 ‘Cho 1 dung dich X gém: NH; 0.1M va NHs 0,1M (biét hing s6 dién ly cia NH; Koy = 5.10") git pH ota X fs Ato Bas c79 D:93 Bai gi Design and copyright 2009 © NGUYEN AI NHAN ‘Tel:0989 8487912Welcome to http:/www:trtucbonphuong.com ‘NH,CI->NH; +c NH, SNH, HK =5.10" _ HEINE] | 193 i= = “*(mol/1) thay gid tri vao ta c6: INH] i. 2510015 10 [ir JAA PEs 10 (mol!) = pl =-le(6.10") = Ap dung cong thie pow = epee Lk ae dinh pH cia axtyéa va mudi ein anit yu vi dish d6m) ; "Phuong ol nae phon trinh ig ly ci musi va oe xi CHCOONa y Ne" > CH A CH,COOH —= H” CH,COO ey Bandiu y os Phan ly b b Can bing y-b b <> eotileneg semen “Tron 200ni! dung dich H:SO, 0,05M véi 300ml dung dich NaOH 0,06M. hay tinh gid ti pH cla dung dich thu duge. Hudug din gi 1.01.2 =0,02(mol) ,5.0,05 = 0,01(mol) >, yao =0,3.0,06 = 0,018(0n0!) Phuong trink phan img xay ra li: H+OH —» HO 0,02 0,018 0.018 ‘Sau phan tig trén con dir 0,02-0,018 = 0,002 (mol) 9,002 31H] = 2% 0,004 pH =—150,004 = 2,4 ad 0,2+0,3 - i. Design and coppyright 2009 © NGUYEN AINHAN 3Welcome to http:/‘vwww.trithucbonphuong.com Vidu6.2 Cho mot lit dung dich e6 pH = 4. H6i phai cho thém bao nhiéu ml NaOH 0,1M vio dé thu duge dung dich méi c6 pH=7 Hudng din gid: I 7 ‘tring trung tinh tte li s6 (mol) H = 6 (mot) Dung dich méi e6 pH = on 1g 6 nghia V.0,1-» V =0,001()=Iml Vidu6.3 ‘Cho mot lit dung dich A ¢6 pH =4. Hoi phai cho thém bao nhieu lit NaOH 0,1M vio dé thu duge dung dich méi eo pH = 5 ‘Hurdng din gai Dung dich Ac: pH =49[H"]=10% > n,, =10“(nol) Gia si ta cho vio V lit NaOH hay cho vio 0.1. V (mol) OF Phuong trink phan ng a H+ OH > HO n wo ‘Dung dich sau phan img ¢6 pH = 5 <7 co nghia la: vin fripoy bong axit tie fa sau phan {ing (1) axit con du suy ra OH di hit TAOS: My 4g, =O OLY) 91" ]= Theo si thiét dung dich moi ob pH = 5 [#1 Gi phong tinh nay ta suy ra Vidu6.4 % Cho mot lit dung dich vio a8 thu durge dung dich Dung dich Ae: pH=4—>[") 10% or Dung dich sau phan img ¢6 pH (2) axit het suy ra OH du. TA 05 hy cay = (OL ~10* mol) > [OH] = Tir diy tad ding tinh duge gif iV >7 cf nghia la moi truimg bazo tie la sau phin ting 10" 1-10") ye AY 10°) 5 -}= + low 10° Vidu6.5 (BH - KB - 2007) Design and coppyright 2009 © NGUYEN AL NHAN ‘Tel:0989 8487914Weleome to htp:/www tithucbonphuong com ‘Tru 100m dung dich (gdm Ba(OH); 0,1M vi NaOH 0,1M véi 400m dung dich (gm H:S0, 0,0375M vi HCI 0.012549 thu durge dung dich X, gi tri pH cia dung dich Xl: Al B2 C6 D7 Bai gid: } Moye = 2am, + race = 0605(m0l) na Sy, =Mge +250, = 0.035401) comnts 005 (mol) > [Ht] = aa Thy, (a) 0,035 -0,03 [H*] = 0,01 = 107 (moVit) > ni-2 Dates ‘ Vidu a6 ‘Cho 1 lit dung dich c6 pH = 4, pha thém Vinl NaOH 0,01M vio 48 thu dave dung dich smdicé pt A 10m B: C100 D:30ml Bai gidi: 66 nghia la mdi tra’mg trung tink Dessay hay 1, es A04=V,001=-V=10°It = 10ml > A ding Vidu 6.7 dung dich axit pH = $ va dung dich bazo pH = B:8:9 Col D3a = [1] - 105M Dung dich axit pt Ding dich bazo pli = 9 > pOH = 14-9 =5 = [OH] Goi Vs (i), Val la thé tch dung dich ait vit bazo en ly 0M =n, =10°V,Gmol); = 10 V, (mol) Khi tron 2 dung dich v6i nhau thu duge dung dich ¢6 pH = 8 (moi trang bazo) = pOH=4-8=6 Design and coppyright 2009 © NGUYEN AI NHANWeleome to hitp:/www:trithucbonphuong.com ©2 [0H] gy = 10°M = [FT] phn cng bit Phan img trang hoi xayakhiton: = HY + OH” = HO ‘Tnrde phan img: 1O°Vi. 10VE i phin ing: 108Vi oo 108V Sau phan img: ° 10° (V Vi) ‘Do dung dich sau khi trdn o6 néng 49 [OH] ~ 10“(M) > ny, 10, +V) Ta cd: 10°(Vz- Vi) = 10° (Vit V) = 9V2= IV, ‘Viidu 6, 8(Trich dé thi tuyén sinh dai hoc2008) “Tron lan V ml dung dich NaOH 0,01M v6i " 1.0 0.03 0.01 0.01 Hd) ~ taht Vidu 6.9 nb Tron 100 ml dung dich HCI va HNO; véi 100 ml dung dich OR agg a clang dich 6 pH~ 12. Gi tein a (biet trong moi dung eh [F1+][H-] = 10) Aus Feats €.003, Dan Huéng din gid pH= 12 poH fa) Tn OL OD: = 04 ->Dip iD, Vidu 6.10 (DH-KA- 2007) Cho m gam lip. Y in hop Mg, Al vio 250ml dung dich X chia hén hop axit HCL 1M vi axit H_S0, 0,5M thu duoe 5.32 it Hy (6 dhte) va dung dich ¥ (coi thé tich dung dich Akhéng 46i). Dung dich ¥ 6 pH li Al B2 c6 D7 Husng din giii 4c) = 9125.1 =0,25(m01) = 0,28 +0,28-0,5mol Iynsoy =9525.0,5.2 =0,25¢mol)) "Ho 2H +2e Ht Design and coppyright 2009 © NGUYEN AI NHAN ‘Te0989 848.7916‘Welcome to hitp:/‘www trithucbonphuong,.com 5.32 0.47Sml.....0.2375(m0l) a = ppg OTS) o : ny y =0,5-' i (mol [j= =10"(mol /| 699 7S“ 0.478 = 0,025) > 1H] = DF = 0,1 10°40) => pH=1 = Ading ‘Vidu 6. 117 rn 300ml dung dich NaOH 0,05 M c6 200ml dung dich HySOs 0,5M thu duge dung dich X, gi tri pH cua dung dieh X li: Ad B:3 2 D:s WH +OH = H,0 0,015 0,015 rt i y = 0,005(mol) 30,05 = 0,015(anol) 2.0,05.2 = 0,02(mol) |" ~"" 0,005 2 : 7 arog Ot =10 saiage mn Khai quat héa bai todn: Cho F, lit dung dich A e6 pH aCho M% lit dung dich B e6 pH b.TxGn bai dung dich dé lai vai nhau thi thu duge di 6 pH= ¢. Bign ludn ; Se 1, Neu pit “ass ‘mol cua H’ bing s6 mol OFF 10" y* 1 Cr ‘tr6n s6 mol eta s6 mol OH kn hon sé mol etia HT ot Tl 2. Néu pH = Sé.mel OM de BNO*T, 10°F) [01], « AON age s amma 4. Nd pt=7 ths hit ab ol oho bo ein OFF sé mol OM dre G0, -10°%,)-s[ a], =00-P 10ND 7 Ken, Dang 7 et pAt paftng bing nee, Phuong phip gidi Khi pha loang bing muse thi sé (mol) H” khong thay déi, ma chi c6 thé tich thay di, Do: ‘vay thiet lap phuong trinh tinh nong 4 H’ ta sé tim dirge pH. Vidu7 Cho mot dung dich ¢6 pH-3, Hoi phai pha loang dung dich tn bao nhiéw lin d& thu duge dung dich e6 pH = 4 Hung din ei Design and copyright 2009 © NGUYEN AI NHAN ‘Tel:0989 8487917Welcome to http://www.trithuebonphuong.com [Xét Vi lit dung dich 6 pH =3 >[H7]=10° yn, =¥, 10°), Gi sir thm vao Vs lit made thi ta duge dung dich méi cé thé tich la (V,+V.) va ¢& pH =4->(H7]=107 9n,. =(%, +¥,).10°Q) Su pha trdn khéng lim thay dai sé (anol) ném tir (1) va 2) ta suy ra yy or yao» HAF 107 7 % 0 Nhiin.xét: Ta e6 thé gic nhanh dang todin néy nhue sau: . Gié sir o6 mt dung dich 06 pH = a. Hoi phai pha lodng dung dich trén bao nhieu lin ‘ing mde dé thu deve dung dich mit eo pH Giai yA? 0» ¥; ~9¥; —» phi pha lang 10 tin sé lin pha loang la: ~ nol Cé em o6 thé ty chimg minh digu nay) Ehwong php ght ‘Viet phaomg trinh ign phan tr xe dink ning a Vidus ‘ign phan 100m! dung dich CuSO. v6i dign ai thoi gian 1 gid véi ewong, 49 dign phan I=0,16A. Tinh pH eta dung dich sau kiidiéuphiin (Coi thé tich khong thay 09 6 0,003(mol) 0,006 0,006(mo1) > [4] Ja(0,06)=1,22 Vidu 8 2. Bign phin dung dich CuSO, v6i dign ove 6 trong thoi gan 60 phi, wimg {a dong dign cd dinh 10,164. Ki hrong Cu thoat ra tren dign eve va pH dung dich tha urge sau thoi gian dign phn la AL gyal B: 0,19 va 1,22 1,28 va3 1D: 0,64 va2 Huéng din gi Alt p dung cong thie: mg, ZS em them phuong phip dign phin eta TH.S ‘Neuyén AiNhan) 640,16.60.60 2.96500 Phuong tinh dign phiin dung dich: CuSO, Me .19(8) Design and coppyright 2009 © NGUYEN AI NHAN Tel0989 8487918‘Welcome to hitp://www.trithucbonphuong.com Cus0,+H,0-*+0us 50, +1180, O18 on,, = 2012 — O19 _ 9 095038 = 5,988.10" (mol) oe G32 pH = -IpS,938.107= 1,22 Ww 8.3. Digm phin dung dich chia a mol CuSO, va b mol NC] vi dign oe tro €5 ining ngin xép Dé dung dich sau dign phan co thé lim phenolphtalein chuyén sang mi hnbng thi dida kin eb ava bli ‘A be2a B.b2a cB D.2b-a teases - Phuong trinh phan tmg dign phan la Y 2CuSO, +2H,0 ->2Cu+2H,50,+0, 4 ; ENS 2NaC1 +2110 2NaOH + 1, PH, b b 4 H.S0,+2NaOH > Na,S0,+H.0 Y a Ding dich saw phn tng lim Jnayn tinh mat ng chim 6 sa pin ting 2 NaOH con di. ->b>2 Ww 84 Tan 1.28 gam CuSO, dem dign phn hoa oan , sau met hi gan thu dire 800ml dung dich 6 pH=12,Higu suat phan img dién phan li A258 C75 D.80 Hung din git pH =2>[H"]=10° =0,01M Ig. =0,01.0,8= 0,008 ry, = 0,040! Phuong tinh din phn Ii 2CUSO, + 24,029 2Cu+241,80,+0, > 0,008 0,004 0,004 = 2:008.100.100% ong schon 1.28 Dign phan c6 mang ngan voi dign eve bing Pt 100ml dung dich CuSO, 0,1M vit NaCl 0,1M vei cumg d6 0,5. Dung dich sau phan ting ¢6 pH=2 Higu suat phan img dign phin H1=100%. Thos gian dign phan fa A 40535 B, 38605 ©. 1930s D.21238 ‘Huéng din gid Design and copyright 2009 © NGUYEN AI NHAN ‘Tek0989 848791Welcome to http:!svww rithucbonphuong.com Cue am Cue drone) Cu” H(H20), Na" CF, OH'(H20),80." de> Cull) 2Ch > Cl,+ 262) 0.0085 0,011 0,008 0,010,005 0,01 Dung dich sau phan img eb pH=2 2H,0->0,+ de + 4H"Q) pH =2>[H"]=10° 0,001 0,001 >, =0,1.0,01= 0,001m0f dy ra cde phin ting (1) (2) va (3) va 2) da | Ap dung cng thire song. Tit(1,2,3) ta 6658 moe tro di la wore THL2) pot 0019650 a9, 05 chon D rc was wag phan dung dich hon hop NaOH 0,01M vi NaNOs cudng 6 =SA voi thoi gian Igy (Coit tch dung dich King thay pH sau dign phn th Ald B10 D.2 ‘Vi dign phan hon hop trén thye chat la ie nén dung dich sau din phn 5 ign phn 100ml dung dich NaC 93A (Coi thé tich khong he sust dign phan 100%, Cl khOng hoa tan trong ‘nuréc). Thoi gian dign phan, 12 la A505 1 D.2008 Huong din gia. Dung dich sau di —>poH-2 —>[OH}-0.01 Cue am ©) Cae durongt*) WO), Nav Cl. OH G0) 2CF > Ch, + 2e(2) 7 0,001 0,005 0,001 2H,O+ 22> H,+ 20H 0,001 0,001 0,0005 0,001 Ap dung céng tite F _ 0,001.96500 _ 7 T 193 ~ chon A. Design and copyright 2009 © NGUYEN AI NHAN Tel:0989 848.791 10Welcome to http://www.trithucbonphuong.com ign phan 100 mi dung dich A chita ding thoi HCI 0,1M va NaCl 0,2M véi dign cue ‘ro 06 mang ngdn xop t6i Khi 6 anot thost ra 0.224 lit ki (dk) thi ngimng dign phan (Coi the tich dung dich thay di khong dang ke). pH sau dign phan la AT B.S 13 D.12 Phuong tinh dign phn tai ea dign eve la Tai anot Cr +Ch,+ 2 0.01 0.02 n Tai catot YY 2H +20 Hy Boe a ane Acer aN lor jens pon a Vidu 8.8 Dien phan 100ml dung. > pH =13. ji voi dign cue tro v6 thoi gian | gid v6i cuong dich sau khi dign phan (Coi thé tich khong thay A350 C169 D.1,75 Hung din gif Ap dung dinh ta 08: 4.0,16.3600 0.9 m= S18, py, = 20 =0,19(g) > ng, =? = 0,003¢ma0) nF 9650.2 rere _ Phuong trinh phan img dign phan li 2CuSO, + 2HZ0 —* > 2Cu+ 0; +2H,80, (1) 0,003 0,003 0,003, Theo (1) Igo, = 9.00301) > HO, > 2° +507 > yy “> pH = 1e( 0,06) =1,22 > Chon B. Design and coppyright 2009 © NGUYEN AINHAN Tc0989 848 79111Welcome to http:/www.trithucbonphuong.com BALTAP AP DUNG (Cf 1: Mét thi sudng ngap aude 08 d pH-7. Bé khit chua cho moi trudng va bin phiin ‘Uré ngudi ta lam nur sau: (chon giai phap ding). ‘A. Diing CaO dé kh hua sau mgt thes gian mi bon Use. B. Bon Ure sau 6 ding CaCOs dé khit chu Bong thi dina Ure vi Cad, . Bon Uré mét th gian ri dung Ca0. Chon A. Diing CaO de khit chua sau mst th gian méi bon Ure. (Céiu 2: Mot dung dich c6 néng 45 H” bing 0,001M, pH va [OH] cia dung dich bing A. pH =2,(0H] = 10""M. B, pH= 2.(0H]= 10"'M. ©. pH =3(O1] = 10M. D. pH =3,[OH] = 10M. Ap dung céng thire pH = -Ie{H"] + pOH = -ls[OH"] > pl" }+ plOH]=14 Chon. rc Cau 3: Ba dung dich sau o6 cing néug 46 (molyt: Hs SBR eso. tc oats C.NaHSO,; H,SO,; Na;SO, 1: NaHSO,: #80, H,SO,; NaH'SO, du c6 moi uudme axit nhung ct pH thip hon do 6 tinh axits marth) NasSO, duge tao tr mudi ia axit ma serih nén_ pH=7. Chon B (Cu 4: Dung dich nio sau day eé'p * ~ ‘A.CH;COONs ——BLNas ©.Cuso, ehdt we CuSO, duve to bai a vi bazo yéu néa pH<7 CHCOONa duge tqo°b6i axis yéu vi bazo manb nen pHI>7.. Nas$O¢ dugetgo tif muéi eva axit manh vi bazo manh nén. pH~7 Chon C. Ciu &: Cho (02 hip thy hodn toin vio dung dich ehita a (mol) NaOH. Dung dich thu dupe 6 aw prt 1a A.pH>? B.pH=7 ©pHe7 D. Phy thuge vioa 2NO; + 2NaOH -> NaNO; + NaNO: + HO. ‘amol amol = amol_—amol Si NaNO» x(mol) ma Sau phn éng thu dye mudi trung hos NaNO; a(mol) va NaNO: li mui tao bei axit yéu va bazo man nn: NO; + H,O->HNO, + OH-se st hign OH lam cho dung dich c6 tinh bazo nén pH > 7 = C ding Cau 6: Cho cée dung dich dign ti maah cing nng dé. (mol): NAHCO.(1); NaOH); NasCOs(3); Ba(OH.(). Tir pH ea dung dich tang din theo day Design and coppyright 2009 © NGUYEN AI NHAN ‘Tel0989 848.791 12Welcome to hitp:/wiww trithucbonphuong.com A124 BIs42 Co 1d2e4 D.1243 NaHCO,(1) wong tink vita cho vita nhin proton, Na:CO\G) chi nhin proton. So sdnh tinh bazo cia (1) va (3) ta e6 3 manh hen, Ba(OHD;(), NaOHQ); déu e6 eing Ba(OH),(4), phan lira nhieu hon, Chon C Cu 7: Cho a (mol) COs téc dung v6 b (mol) (mol) NaOH. Khi a: b=I: | thi pH thu iso la ‘A. pHe7 B. pi? ©. pHeT D.pieM Cau 8: C5 mot dung dich pH 6. Hoi phai pha loaing bao nhigu lin biing made d& 66 crac dung dich mi pH=82 : ‘A. 100 B99 C.Katquikhic ——-D.10 Chon €. «. (Cu 9: Chon cat sai ‘A. Dung dich muoi NaCl e6 pH B. Dung dich muoi CHsCOOK cé pH > 7. C. Dung dich NaH1SOs 66 pH <7. D. Dung dich muoi NaHCO; e6 pH <7 Dung dich mudi NaCl duge tao thanh tir ‘manh nén ¢6 pH=7, Dung dich mudi CHsCOOK tao think tir i bazo manh nén &6 pH > 7. Dung dich oHSO. kh ng pa ra pW’ nn 06 pH <7. Dung dich mudi NaHCO; ie 1 ny dutge tao thinh tir tao thanb tit ait yeas bao nuphntace ys 15 Cho doe ih “an 1,8. 10°, ptf oda dung dich rén bs oe . Ap dung cing thi Khong thé pha loang ti moi trang axit thanh moi treme: —< bing mide dire, < G, =-log YOL1,8.10" = 2,87.Chon Cau 11. Bon wo sau dy khdng lam thay d&i 46 chua (46 pH)etia dit ‘A. Dam hai ki B.(NH);CO €. Ca(OH): D.NHCL Chon B. (NH):CO Cau 12: C6 4 dung dich déu ¢6 néng 49 bing nhau: HCl e6 pH = a; 280; ¢6 pH = b: ‘NELCl e6 pH=c va NaOH co pH= d; Ket qua nio sau day la ding ? Accacd7, CaligONa duge tgo thinh tir axityéu va bazo manh nén pH>7 NaHCO; durge tao than tir axit yu via bazo manh nén pH>7 Chon B. Ap dung tinh pH eta axit yéu ta 06 pl ‘Cu 16: Khi cho tir tir dung dich A chia x (mol) HCI vio'dung dich B chia y (mol) 1Na;COs sau, khi cho hét A vio B ta doe dung dich X. He y thi pH cia dung dich nur thé nio? ‘A. pHET B.pH=7 © Phuong trinh phan ing fa RHC + Na.CO,—rNaCl-+00, 4H x=2y y ‘Nhung do CO; bj hia tan mét phan t Dy a i sng nén pH=7. Chon A. (Cu 17: Trdn 3 dung dich H:SO% ): 0.2M: HCLO,3M véi nig thé tich hing hau thu drge dung dich X. Li nding dich X cho phan img véi V lit dung dich Y goin NOT 02M vi KOH Pat © dug dich Z e6 pl 2 Gid iV li OY it C.0.214 lit 1D. 0,134 lit ALO lit Dé don gin ta choir Sie Wa Lit $6 mol H” do, ), Phin lira la 0.2mol. 6 mol He an lira la 0,2moL phan lira la 0.3m. Tong sé mol Ido ba axits nay phin lira la O,7mol(trong 3 lit dung dich). 1g s6 mol OH do hai bazo NaOH 0,2M va KOI 0,29M pha lira la 0,49V mol Phong trinh phan img trung hoa H+ OW > HO 049" 0,497 ‘Sau phan jma pH=2 ¢6 nghia lH” cén dur nén OH’ tham gia phan tmg het ‘$6 mol H dil 0,7-0,49V. Thé tich sau khi pha tron la 3-V Dung dich thu due ¢6 pH=2 hay [HJ=10* D. pieT pr] 9 7-047 12, 0340 ‘Cu 18: Dung dich Fex(SO:)s 66: ‘A. ple? B. pll<7 Cpe D. pit27 Design and copyright 2009 © NGUYEN AI NHAN ‘Tel:0989 848 79114Welcome to http://www trithucbonphuong.com Fe(S0.)s due tao thin tir axits manh va bazo yéu nén thiy phn teo mdi trang ait ‘Cu 19: Cho cic dung dich sau: NH.CK1); NHAHSO,(2):(NH):S (3);(NH.)2Cr20> (4). Sip xép cc dung dich theo th tw ting din pH Ii: Ae d3<1-2 B.L2<43) e243 (NH):S duge tao than tir axit yéu va bazo yéu nén pH Kin nit, NHHSO, con c6 kha nang phan lira ion H’ rit man nén pH thip nt Chon €. DIs42 ‘Cu 20: Cho hai dung dich Fe(SO4); 05 pH quan he gia x vi y li Axey Bxdy Gx C.NoOH=CH:COONa D. dive Khéng so sinh duge vi mot chat ludn c6 pH>7 va mot mn c6 pH=7. Chon. (Cau 22: Hoa tan cic mudi: NaHCOs(1); NaOH); Ba(OH),(3). M&i mudi déu ty a gam. Thit tu pH cia dung dich ting dn theo d Ale _ Bis? 23241 D132 Dé ding nhén thiy NaHCO; vita ¢6 kh nfingycho va niin proton nén pH ctla nd khong thé kim nhat duge. 4 Lay cing long gam thi sé hin li ra nhigu hon nén pH cao hom so wit Ba(OH): Chon, (Cau 23: Khi dign ag dich mudi, gia tr] pH & khu vye @ gin mét dign eye ting lén. Dung dich tmudi dem dién phan li A. CuSO: B.KCI C.K:S0. D. AgNO, CuSO, AgNO; fn cho mdi trade axits, «ign phiin K.SO; thue chit la dign phan nude. «ign phin KCI cho moi trumg kiém. Chon B. ‘Cau 24: Nhimg ngudi di bit hron ¢6 kinh nghiém sau: "O nhiing thita rubng ma muse ¢6 rau gach giam thi 6 ving dé Khong 0% aon sinh sng °Vay nhiing ving on kbing sinh, sOng trén thi cd mdi trang pH nh thé no? ‘A. pHs? B. pH? C. pH? D. plied ‘Trén canh ddng, noi nto ma muse co miu gidng mau gach giam( gach cua dong) ‘Thi noi dé e6 chia nhigu Ton Fe™, Fe** mi hai ion niy thay phin manh tao moi ‘rung axis nén pH7. Chon A. Céiu 24: Nhigt phn hodn toi m gam Cu(NOs); thu duge chit rin X va hén hop Ki Y. Hip thu hoan ton khi Y vio nude ch thu durge 200 ml dung dich c6 pH ~ 1. Khoi hong ‘Ca(NO4)2 dem nit phan Ii A 18, 8 gam. B.9,4 gam €.3,76 gam D.1,88 gam Design and copyright 2009 © NGUYEN AI NHAN Tel: 0989 848.791 15‘Welcome to http://www.trithucbonphuong.com (Cau 25: Digu kign nao la dung trong céc ct sau? : ‘A. Khi dign phan dung dich NaC! thi pH cia dung dich gidm din B. Khi dign phan dung dich hon hop HCI + NaCl thi pH eia dung dich tang din C. Khi dign phan dung dich CuSO; thi pH cia dung dich ting dan 1D. Khi dign phan hin hap dung dich CuSO, + NaC thi pH ctia dung dich khong di hi dign phn dung dich NaCl thi pH cia dung dieh ting din : Khi dign phan dung dich hén hop HCI + NaCl thi pH cua dung dieh tang din Khi dign phan dung dich CuSO, thi pH cia dung dich giam dan : Khi dign phan hén hop dmg dich CuSO. + NaCl thi pH cia dung dich ting dan’ Chon B. ‘Cu 26: Neu ta tién hin trong phong thi nghiem ¢ nhiet dO phong ahur sau: Cho a (amo) CO: tée dung véi b (mol) (mol) NaOH. Khi a: b=I: 2 thi pH thu doe la ‘st? Booey cpt? Dips © + 2NaOH > NesCO, FO S ‘Dung dich thu duve chia NayCOs nén pH>7. Chon B (Cu 27: Trong cae dung dich on IkNaxCOs s6 dung dich e6 pH > 7 a: Ad B.3 NaHCO, Na;COs dau e6 pH=7. Chon D. ‘Ca 28: Cho 1 gam hin hop hai kim lo >. toan vito made thi thu dirge xung dich X, hap thy toan bo 0.112 lit kh Naito dung dich X thi duge dung dich ¥ vane A plist pT pies Cfu 29: Cho céc mudi sau:\ Ni ae "NaHSO,(2), Na:HPO,(3), NaH PO,(4), NaHICOs(5) AICks (6) ¢6 bao nhiéu dung dich e6 pH pH <7? AS C6 DS NaHSO\(1), AICK ( (4), Béu cho pH=7.Chon A. (Cu 30: Tri vita 6) ira gidng, néu hing muse mua vito mst ede sach may do pH vao thi gi tripH may chi sé la A. pH? B. pl-T . Khong xée dinh_ —_D, pH<7 “Troi vra méi mura widng, hrgng Kh thai da tan edn nhieu nén pH<7. Chon D. ‘Cau 31: Cho hai dung dich HCI va HF cé ciing néng dé. So sénh pH cia hai dung dich la: ALHCL< HE B.HCI=HF . Khong so sink dupe D.HCI> HF HCI va HF thi HCk manh hon phin lia nbiéu ion HY hon nén p< hon eta HF. (Cau 32: Troi vita méi mua gidng (khong 06 sim st) sau khi mua duoc mét ting, nda Inimg mutée mua vio mét cdc sach roi cam may do pH vio thi gi tri pH may chi sé la: Ap B.pH>7 C.pHe7 'D. Khong xe inh Saw khi mua khoang | tiéng dng hé thi ca khi hoa tan da hét nén pH=7, Chon A. Design and coppyright 2009 © NGUYEN AI NHAN, Tel:0989 848 791 16‘Welcome to hntp://www.trithuebonphuong.com Cau 38: Cho cic dung dich mudi sav: NaCl, NaF, CuS0,Na,SO,NaNO,, $5 dung dich anu6i sau Khi ign phan cho pl >7 fi a2 Ba cs Dil NaCl dign phan cho moi tring kiém nén pl¥>7. Chon D. iu 34: Cho 3 dung dich sau o6 eiing ning 46 (mol): NaHICO, NaOH, Na:COs pH cia ching tng theo thirtw: ‘A. NagCOa; NaOH; NeHCOs B. NaOH; NaxCOs; NaHCO: ©. NaHCOs; NasCOs: NaOH D. NaOH; NaHCOs; NaCO; Chon ¢. Cu 35: Cin thém bao nhiéu lit nude vito V lt duag dich HCI e6 pl = 4 8 thu duge dung djeh mi pH = 5? AY B. 100 csv D.10v Chon A. Cau 36: Cac dung dich HCL H.$0,CH,COOH eé cing pH thi (ott xép theo ‘thirty ting dn a A. HCL CHsCOOH, 1.50, B.HCI, H,S0, 1H C.CH:COOH, HCL F280. D.HLSO, "00H Chon D. Céiu 37: Cho ee dung dich ¢6 ciing ndng 46 (mol) lt DH céc dung dich duge xep theo tit gi di a ABQ B.2)3) 0) : L, (2)Ba(OH), (3) NHs Dd.) QB) WS ign ¢. (Cau 38: Dung dich X chita hin hop va'Ba(OH): c6 ndng 46 twong ting 1a 0,2M vi 0,IM. Dung djeh Y chita 1s va HCI 6 nong 6 lan lugt la 0,25M va O.7SML The th ng eh can tg hb ve 40 mi dng ich Y M015 It B00 Coats 0.125 it (Cin 49: Cho 5 lit dang die nnéng d6 0,000SM. Gia tri pH li: cA D3 +h A chia y (mol) Na;COs vao dung dich B chtta x (mol) B ta due dung dich X, H6i khi x= 2y thi pH ctia dung dieh 8 dui hét CO.) ? B. pHe7 C.pH=7 D. lcpleld Céu 41; Cho 300m dung dich hdn hop HCI va HINO; c6 pH = 1 vio 200ml dung dich ‘NaOH 0,175M, dung dich thu duge e6 pH bing: AB BA? cu D2 Design and coppyright 2009 © NGUYEN AI NHAN, Tel:0989848.791 17