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REFINERY 6960-000-DS-0011

MATERIAL PAGE 1 of 4
BALANCE REV: D4

REVISION 01 D1 D2 D3 D4
DATE JUL 00 Jul 00 30 April 04 7 July 04 30 August 04
ORIG. BY A J Creek A J Creek A. Sirven P. Nyvlt A. Sirven
APP. BY A J Creek A J Creek S. Glavas S. Glavas S. Glavas
SIGNATURE A J Creek
STATUS For FDC Issue for Issue for
Approval FDC FDC

Pages modified under revision D2 : All


Pages modified under revision D3 : 2,3,4
Pages modified under revision D4 : 2,3

Contract: 7303 N

Client’s Name: VIETNAM OIL AND GAS


CORPORATION (PETROVIETNAM)

Project Title: DUNG QUAT REFINERY PROJECT – FEED


DEVELOPMENT CONTRACT

Project Location: DUNG QUAT, VIETNAM

CONTENTS

SECTION SUBJECT

1. INTRODUCTION

2. REFINERY EXPECTED MATERIAL BALANCE

3. CDU STREAM DATA

4. MATERIAL BALANCE LIMITING CONSTRAINTS

Attachments

1A Bach Ho crude - RFCC operating in maximum distillate mode


1B Bach Ho crude - RFCC operating in maximum gasoline mode
1C Mixed crude - RFCC operating in maximum distillate mode
1D Mixed crude - RFCC operating in maximum gasoline mode

2A CDU Stream Data - Bach Ho


2B CDU Stream Data - Mixed Crude

5.000.DS.0011_D4.doc
6960-000-DS-0011 REFINERY
PAGE 2 of 4 MATERIAL
REV: D4 BALANCE

1. INTRODUCTION

This document presents the refinery expected material balances for the following four
refinery operating cases:
• Bach Ho crude - RFCC operating in maximum distillate mode
• Bach Ho crude - RFCC operating in maximum gasoline mode
• Mixed crude - RFCC operating in maximum distillate mode
• Mixed crude - RFCC operating in maximum gasoline mode

The mixed crude case is defined as the refinery processing a mix of Bach Ho and Dubai
crude in the ratio of 5.5 million tonnes per annum of Bach Ho to 1 million tonnes per
annum of Dubai crude.

The refinery material balances have been prepared considering minimum benzene
gasoline mode of operation (i.e. light naphtha cut of C5 – 82°C from NHT naphtha
splitter is sent to the Isomerisation Unit).

The refinery material balances are presented in Attachments 1A, 1B, 1C & 1D attached.
The material balances include mass and liquid volume flows corresponding to the
Stream Numbers included on the Process Flow Diagram - Refinery Flow Scheme - Doc
No. 6960-000-20-0001.

The refinery material balances also include Product Blending Balances for each
operating case. The Blending Balances present a summary of the key intermediate and
final product flows and product qualities.

The overall material balances have been produced using process data from the crude
assays and the individual process unit expected material balances and stream data.
The refinery intermediate streams were used to calculate the finished product flow rates.
The product blending was optimized against a given set of constraints inclusive of
product specifications. For example Kerosene can be routed to Jet A-1 sales or can be
used for blending into Auto Diesel to balance the pour point properties of the heavier
gas oils.

Attachment 2A & 2B present the key CDU stream property data for the CDU processing
either 100% Bach Ho crude or the refinery processing mixed crude.

The material balances mass and volume flow rates are based on calculated flows based
on stream days. The refinery design is based on all processing units operating for 8000
hours annually, which is equivalent to stream factor of 0.913.

2. REFINERY EXPECTED MATERIAL BALANCE

The refinery expected material balances are presented for two different crude
processing operations and two different RFCC operating modes.

The CDU Basis of Design document 6960-011-PS-0002 defines basis used for the cut
points on the crude unit. These are also presented on the CDU key stream properties
included in Attachments 2A and 2B.

5.000.DS.0011_D4.doc
REFINERY 6960-000-DS-0011
MATERIAL PAGE 3 of 4
BALANCE REV: D4

The RFCC operating modes - Maximum Distillate and Maximum Gasoline - are defined
in the RFCC BED Package for Unit 15.

The refinery material balances are presented in Attachments 1A, 1B, 1C & 1D. The
following notes further explain the basis used and set out any assumptions required in
producing these material balances.
• Flows are predicted actual operating flows based on crude assay data and licensor
expected yields and do not necessarily represent unit design capacities. For
example the Basis of Design for the NHT/CCR includes a design margin on the
quantity of heavy naphtha that can be processed. The material balances presented
are based on processing all the heavy naphtha available.
• Minimum benzene gasoline mode of operation (i.e. light naphtha cut of C5 – 82°C
containing benzene precursors from NHT naphtha splitter is sent to the
Isomerisation Unit).
• Stream properties are based on crude assay data and licensor expected values
• For each of the four Refinery Operating cases, expected Gasoline Blending
balances present two alternate cases: production of RON 95 and RON 90 Mogas or
production of RON 92 and RON 90 Mogas simultaneously. All gasoline blending
calculation results are presented for summer gasoline grade.
• All refinery fuel oil is assumed to be DCO. Refinery fuel oil consumption is based on
Power Plant operation at nominal design power generation capacity (i.e. power
supply to the Polypropylene Plant and/or power export to the EVN grid if possible).
Refinery fuel oil requirements consider that excess C4s are sent to the fuel gas
system (see section 4).
• It is assumed all kerosene not used for blending to diesel and fuel oil is sold as Jet
A1 (i.e. no kerosene sales)
• The following margins were used for limiting constraints to account for test method
repeatability:
0.2 for Mogas RON and MON
3.2 kPa for Mogas RVP
2° C for Auto Diesel 90% vol. boiling temperature (ASTM D86)
2.5° C for Fuel Oil Pour Point

For the Bach Ho - Max Gasoline case and for mixed crude max gasoline case - a
minimum quantity of Jet A-1 has been included as a constraint to the refinery balance.
The minimum Jet A-1 production is set at 659 Tonnes per stream day.

3. CDU STREAM DATA

The CDU key stream property data for Bach Ho and mixed crude processing is
presented in Attachments 2A and 2B respectively. The data presented is based on the
crude assay data and from the CDU process unit simulations.

5.000.DS.0011_D4.doc
6960-000-DS-0011 REFINERY
PAGE 4 of 4 MATERIAL
REV: D4 BALANCE

4. MATERIAL BALANCE LIMITING CONSTRAINTS

During preparation of the refinery expected material balances the following material
constraints were noted:
• The RVP of summer grade gasoline (60 kPa) and minimum C3 content of LPG (20%
mol) specifications does not enable all C4s to be used in Refinery products and
consequently some C4s are sent to Fuel Gas.
• For the production of 95 RON Gasoline, the 50% vol. boiling temperature (120°C) is
very close to limiting the production due to the relatively large quantity of reformate
required in this blend.
• Due to the large quantity of LCO which is available for Auto Diesel production
during Maximum Distillate operation, the diesel Pour Point is not a constraint.
However, the quantity of HGO which can be blended in Auto Diesel is limited by the
90% vol. distillation temperature (370°C) and some HGO must be sent to Fuel Oil
product.

5.000.DS.0011_D4.doc
VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) Page 1 of 5
DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 1A

BLOCK FLOW DIAGRAM EXPECTED MASS BALANCE CRUDE BLEND : 100% Bach Ho OPERATING CASE : Max Distillate

STREAM 1 2 3 4 5 6 7 8 9 10 11 12 13
DESCRIPTION Sweet Sour CDU Light Total Raw Kero Light Gas Heavy Atom CDU LPG RFCC LCO DCO
Crude Crude OffGas Naph to Naphtha Oil Gas Oil Residue Naph From
Isom RFCC
TPSD 19500 - 7 683 2668 1223 4216 1722 9623 44 3137 3901 660
BPSD 147976 - - 6361 23215 9920 32775 13041 68482 485 27601 28401 4327

STREAM 14 15 16 17 18 19 20 21 22 23 24 25 26
DESCRIPTION LTU Feed Treated Prop Propane Mixed C4's to C4's to LPG to Naph to CCR LPG Reform RFCC 95 RON to
LPG ylene C4's LPG Sphere Sales CCR ate Naph Sales
TPSD 1348 1347 321 147 864 680 184 882 1975 55 1761 3137 2706
BPSD 15009 15000 3866 1782 9163 7221 1948 9634 16856 638 13392 27601 22727

STREAM 27 28 29 30 31 32 38 39 40 41 42 43 44
DESCRIPTION Jet A1 to Kero to LGO to HGO to LCO to Auto LGO to
Sales Auto Auto Auto Auto Diesel Fuel Oil HGO to LCO to NHT gas DCO to
Diesel Diesel Diesel Diesel Fuel Oil Fuel Oil Fuel Oil to RFCC Fuel Oil
TPSD 1223 0 4216 1017 3808 9041 - - 705 95 971 14 171
BPSD 9920 0 32775 7700 27846 68321 - - 5341 693 7156 - 1122

STREAM 45 47 48 49 50 51 52 53 54 55 61 62 71
DESCRIPTION Isomerate Reform RFCC Isomerate Reform RFCC
90 RON to C4's to 95 to 95 to 95 Naph to C4's to 90 to 90 to 90 Naph to Excess ISOMERA LGO to
Sales RON RON RON 95 RON RON RON RON 90 RON C4 HDT LCO TE LCO HDT
TPSD 2923 43 489 1291 883 34 164 470 2255 107 3902 653 -
BPSD 25349 452 4690 9820 7765 365 1576 3572 19836 1131 28539 6266 -
VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) Page 2 of 5
DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 1A

BLOCK FLOW DIAGRAM EXPECTED MASS BALANCE CRUDE BLEND : 100% Bach Ho OPERATING CASE : Max Distillate
STREAM 81
DESCRIPTION HGO to
LCO HDT
TPSD -
BPSD -
VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) Page 3 of 5
DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 1A
Product Blending Balances
Bach Ho Maximum Distillate Case - Expected Balance

Product LPG
Components Total
Stream No 23 19 17 21
Stream Name CCR LPG C4's to Propane LPG to
LPG Sales
Flow TPSD 55 680 147 882
Flow BPSD 638 7221 1784 9634
RVP kPa 1113 441 1255 667
C3 Content Mol% 35.6 0.8 87.5 20
SG 0.544 0.592 0.518 0.576

95 RON - 90 RON GASOLINE POOL


Product 95 RON Gasoline
Components Total

Stream No 47 48 49 50 26
Stream Name C4's to 95 Isomerate Reform to RFCC 95 RON to
RON to 95 RON 95 RON Naph to 95 Sales
RON
Flow TPSD 43 489 1291 883 2706
Flow BPSD 452 4690 9820 7765 22727
RON 98.7 86.4 102 91.7 95.2
MON 88.4 84.4 90 79.6 85.2
Sulphur wt % 0.001 0 0 0.001 < 10 ppm
Density kg/m3 593 656 827 715 749
RVP kPa 441 88 18 51 57
Olefins Vol% 58 0 1 43 16
Benzene Vol% 0 0 1 1 1
Aromatics Vol% 0 0 77 15 38
Product 90 RON Gasoline
Components Total
Stream No 51 52 53 54 45
Stream Name C4's to 90 Isomerate Reform to RFCC 90 RON to
RON to 90 RON 90 RON Naph to 90 Sales
RON
Flow TPSD 34 164 470 2255 2923
Flow BPSD 365 1576 3572 19836 25349
RON 98.7 86.4 102 91.7 92.9
MON 88.4 84.4 90 79.6 81.2
Sulphur wt % 0.001 0 0 0.001 < 10 ppm
Density kg/m3 593 656 827 715 725
RVP kPa 441 88 18 51 57
Olefins Vol% 58 0 1 43 35
Benzene Vol% 0 0 1 1 1
Aromatics Vol% 0 0 77 15 23
VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) Page 4 of 5
DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 1A
Product Blending Balances
Bach Ho Maximum Distillate Case - Expected Balance
92 RON - 90 RON GASOLINE POOL
Product 92 RON Gasoline
Components Total
Stream No 47 48 49 50 26
Stream Name C4's to 92 Isomerate Reform to RFCC 92 RON to
RON to 92 RON 92 RON Naph to 92 Sales
RON
Flow TPSD 72 653 1704 2895 5325
Flow BPSD 765 6266 12960 25470 45461
RON 98.7 86.4 102 91.7 94.0
MON 88.4 84.4 90 79.6 83.2
Sulphur wt % 0.001 0 0 0.001 < 10 ppm
Density kg/m3 593 656 827 715 737
RVP kPa 441 88 18 51 57
Olefins Vol% 58 0 1 43 25
Benzene Vol% 0 0 1 1 1
Aromatics Vol% 0 0 77 15 30
Product 90 RON Gasoline
Components Total

Stream No 51 52 53 54 45
Stream Name C4's to 90 Isomerate Reform to RFCC 90 RON to
RON to 90 RON 90 RON Naph to 90 Sales
RON
Flow TPSD 5 - 57 242 304
Flow BPSD 53 - 432 2131 2616
RON 98.7 86.4 102 91.7 93.5
MON 88.4 84.4 90 79.6 81.2
Sulphur wt % 0.001 0 0 0.001 < 10 ppm
Density kg/m3 593 656 827 715 731
RVP kPa 441 88 18 51 57
Olefins Vol% 58 0 1 43 36
Benzene Vol% 0 0 1 1 1
Aromatics Vol% 0 0 77 15 25
VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) Page 5 of 5
DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 1A
Product Blending Balances
Bach Ho Maximum Distillate Case - Expected Balance

Product Jet A1
Components Total
Stream No 27 27
Stream Name Jet A1 to Jet A1 to
Sales Sales
Flow TPSD 1223 1223
Flow BPSD 9220 9920
Density kg/m3 775 775
Sulphur wt ppm 50 50
Flash Point C 48 48
Smoke Point mm 31 31
Freeze Point C -52 -52

Product Auto Diesel


Components Total
Stream No 28 29 30 31 32
Stream Name Kero to LGO to HGO to LCO to Auto
Auto Auto Auto Auto Diesel
Diesel Diesel Diesel Diesel
Flow TPSD 0 4216 1017 3808 9041
Flow BPSD 0 32775 7700 27846 68321
Density kg/m3 775 809 831 860 832
Sulphur wt ppm 50 200 290 50 147
Pour Point C -58 -3 20 -19 -2
ASTM D86 90% C 204 322 405 340 368
Cetane Index 47 60 64 42 53

Product Fuel Oil


Components Total
Stream No 38 39 40 41 44 42
Stream Name Kero to LGO to HGO to LCO to DCO to Fuel Oil
Fuel Oil Fuel Oil Fuel Oil Fuel Oil Fuel Oil
Flow TPSD - - 705 95 171 971
Flow BPSD - - 5341 693 1122 7156
Density kg/m3 - - 831 860 960 854
Sulphur wt ppm - - 290 50 700 339
Pour Point C - - 20 -19 20 19
VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) Page 1 Of 5
DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 1B

BLOCK FLOW DIAGRAM EXPECTED MASS BALANCE CRUDE BLEND 100% Bach Ho OPERATING CASE: Max Gaso

STREAM 1 2 3 4 5 6 7 8 9 10 11 12 13
DESCRIPTION Sweet Sour LPG off Light Total Raw Kero Light Gas Heavy Atom CDU LPG RFCC LCO DCO
Crude Crude CDU Naph to Naphtha Oil Gas Oil Residue Naph From
Isom RFCC
TPSD 19500 0 7 683 2668 1223 4216 1722 9623 44 5101 1345 699
BPSD 147976 0 - 6361 23215 9920 32775 13041 68482 485 43837 9287 4216

STREAM 14 15 16 17 18 19 20 21 22 23 24 25 26
DESCRIPTION LTU Feed Treated Prop Propane Mixed C4's to C4's to LPG to Naph to CCR LPG Reform RFCC 95 RON to
LPG ylene C4's LPG Sphere Sales CCR ate Naph Sales
TPSD 1827 1825 462 172 1170 790 379 1018 1975 55 1761 5101 2604
BPSD 20298 20286 5562 2093 12408 8384 4024 11108 16856 638 13392 43837 21770

STREAM 27 28 29 30 31 32 38 39 40 41 42 43 44
DESCRIPTION Jet A1 to Kero to LGO to HGO to LCO to Auto LGO to
Sales Auto Auto Auto Auto Diesel Fuel Oil HGO to LCO to NHT gas DCO to
Diesel Diesel Diesel Diesel Fuel Oil Fuel Oil Fuel Oil to RFCC Fuel Oil
TPSD 659 564 4216 359 1802 6941 - - 740 166 1128 14 223
BPSD 5347 4573 32775 2714 13134 53197 - - 5601 1210 8154 - 1344

STREAM 45 47 48 49 50 51 52 53 54 55 61 62 71
DESCRIPTION Isomerate Reform RFCC Isomerate Reform RFCC
90 RON C4's to 95 to 95 to 95 Naph to C4's to 90 to 90 to 90 Naph to Excess ISOMERA LGO to
to Sales RON RON RON 95 RON RON RON RON 90 RON C4 HDT LCO TE LCO HDT
TPSD 5135 64 443 1189 908 159 210 572 4193 159 1968 653 -
BPSD 44090 675 4250 9040 7805 1690 2016 4352 36032 1659 14344 6266 -
VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) Page 2 Of 5
DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 1B

BLOCK FLOW DIAGRAM EXPECTED MASS BALANCE CRUDE BLEND 100% Bach Ho OPERATING CASE: Max Gaso
STREAM 81
DESCRIPTION HGO to
LCO HDT
TPSD 624
BPSD 4726
VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) Page 3 Of 5
DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 1B
Product Blending Balances
Bach Ho Maximum Gasoline Case - Expected Balance

Product LPG
Components Total
Stream No 23 19 17 21
Stream Name CCR LPG C4's to Propane LPG to
LPG Sales
Flow TPSD 55 790 172 1018
Flow BPSD 638 8384 2093 11108
RVP kPa 1113 440 1255 663
C3 Content Mol% 35.6 0.8 87.5 20
SG 0.546 0.593 0.518 0.576

95 RON - 90 RON GASOLINE POOL


Product 95 RON Gasoline
Components Total
Stream No 47 48 49 50 26
Stream Name C4's to 95 Isomerate Reform to RFCC 95 RON to
RON to 95 RON 95 RON Naph to 95 Sales
RON
Flow TPSD 64 443 1189 908 2604
Flow BPSD 675 4250 9040 7805 21770
RON 98.7 86.4 102 91.8 95.2
MON 88.3 84.4 90 79.6 85.2
Sulphur wt % 0.001 0 0 0.001 < 10 ppm
Density kg/m3 593 656 827 732 752
RVP kPa 440 88 18 34 57
Olefins Vol% 58 0 1 33 14
Benzene Vol% 0 0 1 1 1
Aromatics Vol% 0 0 77 26 41
Product 90 RON Gasoline
Components Total
Stream No 51 52 53 54 45
Stream Name C4's to 90 Isomerate Reform to RFCC 90 RON to
RON to 90 RON 90 RON Naph to 90 Sales
RON
Flow TPSD 159 210 572 4193 5135
Flow BPSD 1690 2016 4352 36032 44090
RON 98.7 86.4 102 91.8 92.8
MON 88.3 84.4 90 79.6 81.2
Sulphur wt % 0.001 0 0 0.001 < 10 ppm
Density kg/m3 593 656 827 732 733
RVP kPa 440 88 18 34 57
Olefins Vol% 58 0 1 33 29
Benzene Vol% 0 0 1 1 1
Aromatics Vol% 0 0 77 26 29
VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) Page 4 Of 5
DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 1B
Product Blending Balances
Bach Ho Maximum Gasoline Case - Expected Balance

92 RON - 90 RON GASOLINE POOL


Product 92 RON Gasoline
Components Total
Stream No 47 48 49 50 26
Stream Name C4's to 92 Isomerate Reform to RFCC 92 RON to
RON to 92 RON 92 RON Naph to 92 Sales
RON
Flow TPSD 131 653 1420 2912 5117
Flow BPSD 1390 6266 10800 25025 43481
RON 98.7 86.4 102 91.8 93.8
MON 88.3 84.4 90 79.6 83.2
Sulphur wt % 0.001 0 0 0.001 < 10 ppm
Density kg/m3 593 656 827 732 740
RVP kPa 440 88 18 34 57
Olefins Vol% 58 0 1 33 21
Benzene Vol% 0 0 1 1 1
Aromatics Vol% 0 0 77 26 34
Product 90 RON Gasoline
Components Total
Stream No 51 52 53 54 45
Stream Name C4's to 90 Isomerate Reform to RFCC 90 RON to
RON to 90 RON 90 RON Naph to 90 Sales
RON
Flow TPSD 92 - 341 2189 2622
Flow BPSD 975 - 2592 18812 22379
RON 98.7 86.4 102 91.8 93.3
MON 88.3 84.4 90 79.6 81.2
Sulphur wt % 0.001 0 0 0.001 < 10 ppm
Density kg/m3 593 656 827 732 737
RVP kPa 440 88 18 34 57
Olefins Vol% 58 0 1 33 30
Benzene Vol% 0 0 1 1 1
Aromatics Vol% 0 0 77 26 31
VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) Page 5 Of 5
DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 1B
Product Blending Balances
Bach Ho Maximum Gasoline Case - Expected Balance
Product Jet A1
Components Total
Stream No 27 27
Stream Name Jet A1 to Jet A1 to
Sales Sales
Flow TPSD 659 659
Flow BPSD 5347 5347
Density kg/m3 775 775
Sulphur wt ppm 50 50
Flash Point C 51 51
Smoke Point mm 31 31
Freeze Point C -52 -52

Product Auto Diesel


Components Total
Stream No 28 29 30 31 32
Stream Name Kero to LGO to HGO to LCO to Auto
Auto Auto Auto Auto Diesel
Diesel Diesel Diesel Diesel
Flow TPSD 564 4216 359 1802 6941
Flow BPSD 4573 32775 2714 13134 53197
Density kg/m3 775 809 831 863 821
Sulphur wt ppm 50 200 290 50 154
Pour Point C -58 -3 20 5 0
ASTM D86 90% C 204 322 405 385 348
Cetane Index 48 60 64 41 55

Product Fuel Oil


Components Total
Stream No 38 39 40 41 44 42
Stream Name Kero to LGO to HGO to LCO to DCO to Fuel Oil
Fuel Oil Fuel Oil Fuel Oil Fuel Oil Fuel Oil
Flow TPSD - - 740 166 223 1128
Flow BPSD - - 5601 1210 1344 8154
Density kg/m3 - - 831 862 1043 870
Sulphur wt ppm - - 290 50 1000 395
Pour Point C - - 20 5 20 19
VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) Page 1 of 5
DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 1C

BLOCK FLOW DIAGRAM EXPECTED MASS BALANCE CRUDE BLEND : Mixed Case OPERATING CASE : Max Dist

STREAM 1 2 3 4 5 6 7 8 9 10 11 12 13
DESCRIPTION Sweet Sour LPG off Light Total Raw Kero Light Gas Heavy Atom CDU LPG RFCC LCO DCO
Crude Crude CDU Naph to Naphtha Oil Gas Oil Residue Naph From
Isom RFCC
TPSD 16500 3000 8 684 2673 1221 4146 1695 9635 61 3051 3888 606
BPSD 125210 21697 - 6373 23294 9881 32075 12732 67625 677 26695 27763 3834

STREAM 14 15 16 17 18 19 20 21 22 23 24 25 26
DESCRIPTION LTU Feed Treated Prop Propane Mixed C4's to C4's to LPG to Naph to CCR LPG Reform RFCC 95 RON to
LPG ylene C4's LPG Sphere Sales CCR ate Naph Sales
TPSD 1422 1421 332 165 908 759 150 979 1979 55 1764 3051 3041
BPSD 15835 15824 3993 2001 9653 8058 1589 10691 16890 639 13419 26695 25540

STREAM 27 28 29 30 31 32 38 39 40 41 42 43 44
DESCRIPTION Jet A1 toKero to LGO to HGO to LCO to Auto LGO to
Sales Auto Auto Auto Auto Diesel Fuel Oil HGO to LCO to NHT gas DCO to
Diesel Diesel Diesel Diesel Fuel Oil Fuel Oil Fuel Oil to RFCC Fuel Oil
TPSD 1221 0 4146 952 3767 8865 - - 743 93 912 14 76
BPSD 9881 0 32075 7150 27389 66614 - - 5582 673 6737 - 482

STREAM 45 47 48 49 50 51 52 53 54 55 61 62 71
DESCRIPTION Isomerate Reform RFCC Isomerate Reform RFCC
90 RON C4's to 95 to 95 to 95 Naph to C4's to 90 to 90 to 90 Naph to Excess ISOMERA LGO to
to Sales RON RON RON 95 RON RON RON RON 90 RON C4 HDT LCO TE LCO HDT
TPSD 2520 51 549 1415 1025 39 106 350 2026 60 3859 655 -
BPSD 21808 545 5265 10760 8970 412 1012 2659 17725 632 28062 6277 -
VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) Page 2 of 5
DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 1C

BLOCK FLOW DIAGRAM EXPECTED MASS BALANCE CRUDE BLEND : Mixed Case OPERATING CASE : Max Dist
STREAM 81
DESCRIPTION HGO to
LCO HDT
TPSD -
BPSD -
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DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 1C
Product Blending Balances
Mixed Crude Maximum Distillate Case - Expected Balance

Product LPG
Components Total
Stream No 23 19 17 21
Stream Name CCR LPG C4's to Propane LPG to
LPG Sales
Flow TPSD 55 759 165 979
Flow BPSD 638 8058 2001 10691
RVP kPa 1113 438 1255 662
C3 Content Mol% 35.6 0.8 87.5 20
SG 0.546 0.592 0.518 0.576

95 RON - 90 RON GASOLINE POOL


Product 95 RON Gasoline
Components Total

Stream No 47 48 49 50 26
Stream Name C4's to 95 Isomerate Reform to RFCC 95 RON to
RON to 95 RON 95 RON Naph to 95 Sales
RON
Flow TPSD 51 549 1415 1025 3041
Flow BPSD 545 5265 10760 8970 25540
RON 98.4 86.4 102 92.0 95.2
MON 88.4 84.4 90 79.5 85.2
Sulphur wt % 0.001 0 0 0.001 < 10 ppm
Density kg/m3 592 656 827 719 749
RVP kPa 438 88 18 48 57
Olefins Vol% 58 0 1 45 18
Benzene Vol% 0 0 1 2 1
Aromatics Vol% 0 0 77 12 36
Product 90 RON Gasoline
Components Total
Stream No 51 52 53 54 45
Stream Name C4's to 90 Isomerate Reform to RFCC 90 RON to
RON to 90 RON 90 RON Naph to 90 Sales
RON
Flow TPSD 39 106 350 2026 2520
Flow BPSD 412 1012 2659 17725 21808
RON 98.4 86.4 102 92.0 93.1
MON 88.4 84.4 90 79.5 81.2
Sulphur wt % 0.001 0 0 0.001 < 10 ppm
Density kg/m3 592 656 827 719 727
RVP kPa 438 88 18 48 57
Olefins Vol% 58 0 1 45 38
Benzene Vol% 0 0 1 2 1
Aromatics Vol% 0 0 77 12 19
VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) Page 4 Of 5
DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 1C
Product Blending Balances
Mixed Crude Maximum Distillate Case - Expected Balance
92 RON - 90 RON GASOLINE POOL
Product 92 RON Gasoline
Components Total
Stream No 47 48 49 50 26
Stream Name C4's to 92 Isomerate Reform to RFCC 92 RON to
RON to 92 RON 92 RON Naph to 92 Sales
RON
Flow TPSD 90 655 1764 3051 5561
Flow BPSD 960 6277 13419 26695 47351
RON 98.4 86.4 102 92.0 94.2
MON 88.4 84.4 90 79.5 83.35
Sulphur wt % 0.001 0 0 0.001 < 10 ppm
Density kg/m3 592 656 827 719 739
RVP kPa 438 88 18 48 57
Olefins Vol% 58 0 1 45 27
Benzene Vol% 0 0 1 2 1
Aromatics Vol% 0 0 77 12 28
Product 90 RON Gasoline
Components Total
Stream No 51 52 53 54 45
Stream Name C4's to 90 Isomerate Reform to RFCC 90 RON to
RON to 90 RON 90 RON Naph to 90 Sales
RON
Flow TPSD - - - - -
Flow BPSD - - - - -
RON 98.4 86.4 102 92.0 -
MON 88.4 84.4 90 79.5 -
Sulphur wt % 0.001 0 0 0.001 -
Density kg/m3 592 656 827 719 -
RVP kPa 438 88 18 48 -
Olefins Vol% 58 0 1 45 -
Benzene Vol% 0 0 1 2 -
Aromatics Vol% 0 0 77 12 -
VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) Page 5 Of 5
DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 1C
Product Blending Balances
Mixed Crude Maximum Distillate Case - Expected Balance

Product Jet A1
Components Total
Stream No 27 27
Stream Name Jet A1 to Jet A1 to
Sales Sales
Flow TPSD 1221 1221
Flow BPSD 9881 9881
Density kg/m3 777 777
Sulphur wt ppm 310 310
Flash Point C 48 48
Smoke Point mm 30 30
Freeze Point C -52 -52

Product Auto Diesel


Components Total
Stream No 28 29 30 31 32
Stream Name Kero to LGO to HGO to LCO to Auto
Auto Auto Auto Auto Diesel
Diesel Diesel Diesel Diesel
Flow TPSD 0 4146 952 3767 8865
Flow BPSD 0 32075 7150 27389 66614
Density kg/m3 777 813 837 865 837
Sulphur wt ppm 310 2000 3710 350 1482
Pour Point C -57 -4 20 -17 -3
ASTM D86 90% C 204 321 404 340 368
Cetane Index 46 59 62 37 50

Product Fuel Oil


Components Total
Stream No 38 39 40 41 44 42
Stream Name Kero to LGO to HGO to LCO to DCO to Fuel Oil
Fuel Oil Fuel Oil Fuel Oil Fuel Oil Fuel Oil
Flow TPSD - - 743 93 76 912
Flow BPSD - - 5582 673 482 6737
Density kg/m3 - - 837 865 994 851
Sulphur wt ppm - - 3710 350 8350 3756
Pour Point C - - 20 -17 20 19
VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) Page 1 of 5
DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 1D

BLOCK FLOW DIAGRAM EXPECTED MASS BALANCE CRUDE BLEND : Mixed Crude OPERATING CASE : Max Gaso

STREAM 1 2 3 4 5 6 7 8 9 10 11 12 13
DESCRIPTION Sweet Sour LPG off Light Total Raw Kero Light Gas Heavy Atom CDU LPG RFCC LCO DCO
Crude Crude CDU Naph to Naphtha Oil Gas Oil Residue Naph From
Isom RFCC
TPSD 16500 3000 8 684 2673 1221 4146 1695 9635 61 4798 1402 726
BPSD 125210 21697 - 6373 23294 9881 32075 12732 67625 677 41007 9526 4182

STREAM 14 15 16 17 18 19 20 21 22 23 24 25 26
DESCRIPTION LTU Feed Treated Prop Propane Mixed C4's to C4's to LPG to Naph to CCR LPG Reform RFCC 95 RON to
LPG ylene C4's LPG Sphere Sales CCR ate Naph Sales
TPSD 1813 1812 448 188 1156 857 299 1099 1979 55 1764 4798 3122
BPSD 20184 20170 5384 2277 12260 9093 3174 12001 16890 639 13419 41007 26090

STREAM 27 28 29 30 31 32 38 39 40 41 42 43 44
DESCRIPTION Jet A1 to Kero to LGO to HGO to LCO to Auto LGO to
Sales Auto Auto Auto Auto Diesel Fuel Oil HGO to LCO to NHT gas DCO to
Diesel Diesel Diesel Diesel Fuel Oil Fuel Oil Fuel Oil to RFCC Fuel Oil
TPSD 659 562 2530 160 3750 7002 - - 632 148 1135 14 354
BPSD 5333 4548 19572 1201 27815 53135 - - 4747 1100 7890 - 2043

STREAM 45 47 48 49 50 51 52 53 54 55 61 62 71
DESCRIPTION Isomerate Reform RFCC Isomerate Reform RFCC
90 RON C4's to 95 to 95 to 95 Naph to C4's to 90 to 90 to 90 Naph to Excess ISOMERA LGO to
to Sales RON RON RON 95 RON RON RON RON 90 RON C4 HDT LCO TE LCO HDT
TPSD 4320 78 529 1387 1127 146 125 377 3671 75 3898 655 1616
BPSD 36995 830 5075 10550 9635 1552 1202 2869 31372 792 28914 6277 12503
VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) Page 2 of 5
DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 1D

BLOCK FLOW DIAGRAM EXPECTED MASS BALANCE CRUDE BLEND : Mixed Crude OPERATING CASE : Max Gaso
STREAM 81
DESCRIPTION HGO to
LCO HDT
TPSD 903
BPSD 6784
VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) Page 3 Of 5
DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 1D
Product Blending Balances
Mixed Crude Maximum Gasoline Case - Expected Balance

Product LPG
Components Total
Stream No 23 19 17 21
Stream Name CCR LPG C4's to Propane LPG to
LPG Sales
Flow TPSD 55 857 188 1099
Flow BPSD 639 9093 2277 12001
RVP kPa 1113 438 1255 660
C3 Content Mol% 35.6 0.8 87.5 20
SG 0.546 0.593 0.518 0.576

95 RON - 90 RON GASOLINE POOL


Product 95 RON Gasoline
Components Total

Stream No 47 48 49 50 26
Stream Name C4's to 95 Isomerate Reform to RFCC 95 RON to
RON to 95 RON 95 RON Naph to 95 Sales
RON
Flow TPSD 78 529 1387 1127 3122
Flow BPSD 830 5075 10550 9635 26090
RON 98.5 86.4 102 92.1 95.2
MON 88.3 84.4 90 79.9 85.2
Sulphur wt % 0.001 0 0 0.001 < 10 ppm
Density kg/m3 593 656 827 736 753
RVP kPa 438 88 18 32 57
Olefins Vol% 58 0 1 33 15
Benzene Vol% 0 0 1 1 1
Aromatics Vol% 0 0 77 26 41
Product 90 RON Gasoline
Components Total
Stream No 51 52 53 54 45
Stream Name C4's to 90 Isomerate Reform to RFCC 90 RON to
RON to 90 RON 90 RON Naph to 90 Sales
RON
Flow TPSD 146 125 377 3671 4320
Flow BPSD 1552 1202 2869 31372 36995
RON 98.5 86.4 102 92.1 93.0
MON 88.3 84.4 90 79.9 81.2
Sulphur wt % 0.001 0 0 0.001 < 10 ppm
Density kg/m3 593 656 827 736 735
RVP kPa 438 88 18 32 57
Olefins Vol% 58 0 1 33 30
Benzene Vol% 0 0 1 1 1
Aromatics Vol% 0 0 77 26 28
VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) Page 4 Of 5
DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 1D
Product Blending Balances
Mixed Crude Maximum Gasoline Case - Expected Balance
92 RON - 90 RON GASOLINE POOL
Product 92 RON Gasoline
Components Total
Stream No 47 48 49 50 26
Stream Name C4's to 92 Isomerate Reform to RFCC 92 RON to
RON to 92 RON 92 RON Naph to 92 Sales
RON
Flow TPSD 177 655 1634 3682 6149
Flow BPSD 1880 6277 12430 31470 52057
RON 98.5 86.4 102 92.1 94.0
MON 88.3 84.4 90 79.9 83.2
Sulphur wt % 0.001 0 0 0.001 < 10 ppm
Density kg/m3 593 656 827 736 743
RVP kPa 438 88 18 32 57
Olefins Vol% 58 0 1 33 22
Benzene Vol% 0 0 1 1 1
Aromatics Vol% 0 0 77 26 34
Product 90 RON Gasoline
Components Total
Stream No 51 52 53 54 45
Stream Name C4's to 90 Isomerate Reform to RFCC 90 RON to
RON to 90 RON 90 RON Naph to 90 Sales
RON
Flow TPSD 47 - 130 1116 1293
Flow BPSD 503 - 989 9537 11029
RON 98.5 86.4 102 92.1 93.3
MON 88.3 84.4 90 79.9 81.2
Sulphur wt % 0.001 0 0 0.001 < 10 ppm
Density kg/m3 593 656 827 736 738
RVP kPa 438 88 18 32 57
Olefins Vol% 58 0 1 33 31
Benzene Vol% 0 0 1 1 1
Aromatics Vol% 0 0 77 26 29
VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) Page 5 Of 5
DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 1D
Product Blending Balances
Mixed Crude Maximum Gasoline Case - Expected Balance

Product Jet A1
Components Total
Stream No 27 27
Stream Name Jet A1 to Jet A1 to
Sales Sales
Flow TPSD 659 659
Flow BPSD 5333 5333
Density kg/m3 777 777
Sulphur wt ppm 310 310
Flash Point C 51 51
Smoke Point mm 30 30
Freeze Point C -52 -52

Product Auto Diesel


Components Total
Stream No 28 29 30 31 32
Stream Name Kero to LGO to HGO to LCO to Auto
Auto Auto Auto Auto Diesel
Diesel Diesel Diesel Diesel
Flow TPSD 562 2530 160 3750 7002
Flow BPSD 4548 19572 1201 27815 53135
Density kg/m3 777 813 837 848 829
Sulphur wt ppm 310 2000 3710 350 1020
Pour Point C -57 -4 20 4 0
ASTM D86 90% C 204 321 404 381 350
Cetane Index 46 59 62 49 53

Product Fuel Oil


Components Total
Stream No 38 39 40 41 44 42
Stream Name Kero to LGO to HGO to LCO to DCO to Fuel Oil
Fuel Oil Fuel Oil Fuel Oil Fuel Oil Fuel Oil
Flow TPSD - - 632 148 354 1135
Flow BPSD - - 4747 1100 2043 7890
Density kg/m3 - - 837 848 1092 905
Sulphur wt ppm - - 3710 350 10300 5330
Pour Point C - - 20 4 20 19
VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) Page 1 of 1
DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 2A
KEY STREAM PROPERTIES

100% Bach-Ho
Property Whole Crude LPG/offgas Light naphtha (1) Heavy naphtha (1) Kerosene LGO HGO Residue

Cut start temperature ( OC) - - 15 70 165 205 330 >370


Cut end temperature ( OC) - <15 70 165 205 330 370 -

Wt% Yield on crude 100 0.3 2.7 10.6 6.3 21.4 8.6 50.1
Production kT/annum 6500 20 175 689 410 1391 559 3256
Production T/stream day 19500 59 526 2067 1229 4173 1677 9769

Specific gravity (15/15) 0.8289 - 0.65 0.741 0.776 0.811 0.830 0.882
Sulphur wt% 0.03 - 0.001 0.001 0.005 0.020 0.029 0.054
Aromatics wt% - - - 12.7 11.3 9.6 - -
Flash point (OC) - - - - 51 77 150 -
Freeze Point (OC) - - - - -52 4 29 -
Cloud Point (OC) - - - - -56 0 26 -
Pour Point (OC) 33 - - - -58 -2 24 -
Cetane index (D976) - - - - 48.9 62.7 64.1 -
Kinematic viscosity at 38 OC (cst) 6.75 - - - 1.1 3 8.3 -
Kinematic viscosity at 50 OC (cst) - - - - 0.8 2.4 5.8 -
RON - - 58.9 42.6 - - - -
MON - - 58.9 40.5 - - - -
ppm Ni 0.22 - - - - - - 1
ppm V 0.02 - - - - - - 0
RVP (kPa) 20.2 - 75.6 7.1 - - - -

ASTM D86 distillation ( oC at vol% recovered)


5% - - 47 90 177 220 322 352
10% - - 49 107 181 230 332 372
30% - - 55 122 186 253 355 426
50% - - 60 130 188 275 368 467
70% - - 64 140 194 296 379 539
90% - - 68 156 204 322 405 733
95% - - 78 165 213 331 414 794
Notes : 1- Light Naphtha and Heavy Naphtha are produced as one stream from Unit 11 (Full Range Naphtha from CDU Stripper bottom)
VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) Page 1 of 1
DUNG QUAT REFINERY PROJECT
FEED DEVELOPMENT CONTRACT 7303N
05-000-DS-0011
ATTACHMENT 2B
KEY STREAM PROPERTIES

85% Bach-Ho/15% Dubai mix


Property Whole Crude LPG/offgas Light naphtha (1) Heavy naphtha (1) Kerosene LGO HGO Residue

Cut start temperature ( OC) - - 15 70 165 205 330 370


Cut end temperature ( OC) - <15 70 165 205 330 370 -

Wt% Yield on crude 100 0.4 2.7 11.0 6.3 21.1 8.5 50.0
Production kT/annum 6500 27 177 713 407 1371 553 3255
Production T/stream day 19500 82 531 2139 1221 4114 1658 9765

Specific gravity (15/15) 0.835 - 0.646 0.741 0.778 0.815 0.837 0.893
Sulphur wt% 0.35 - 0.003 0.010 0.031 0.200 0.371 0.550
Aromatics wt% - - - 12.7 12.4 12.3 - -
Flash point (OC) - - - - 49 76 153 -
Freeze Point (OC) - - - - -52 2 27 -
Cloud Point (OC) - - - - -55 -2 23 -
Pour Point (OC) 27.6 - - - -57 -4 21 -
Cetane index (D976) - - - - 47.8 61.3 62.0 -
Kinematic viscosity at 38 OC (cst) - - - - 1.1 3 8.3 -
Kinematic viscosity at 50 OC (cst) - - - - 0.8 2.4 5.8 -
RON - - 60.3 43.4 - - - -
MON - - 60.1 41.2 - - - -
ppm Ni 1.06 - - - - - - 5
ppm V 4.33 - - - - - - 10.5
RVP (kPa) 6.64 - 75.1 7.4 - - - -

ASTM D86 distillation ( oC at vol% recovered)


5% - - 43 90 173 219 320 353
10% - - 48 106 180 228 331 372
30% - - 50 119 185 252 354 427
50% - - 52 128 187 275 367 470
70% - - 64 138 198 295 378 539
90% - - 69 155 204 321 404 731
95% - - 78 164 212 331 413 807
Notes : 1- Light Naphtha and Heavy Naphtha are produced as one stream from Unit 11 (Full Range Naphtha from CDU Stripper bottom)

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