Documente Academic
Documente Profesional
Documente Cultură
Overview
While the term polymer in popular usage suggests "plastic",
polymers comprise a large class of natural and synthetic materials
with a variety of properties and purposes. Natural polymer materials
such as shellac and amber have been in use for centuries. Paper is
manufactured from cellulose, a naturally occurring polysaccharide
found in plants. Biopolymers such as proteins and nucleic acids play
important roles in biological processes.
Henri Braconnot's pioneering work in derivative cellulose
compounds is perhaps the earliest important work in modern
polymer science. The development of vulcanization later in the
nineteenth century improved the durability of the natural polymer
rubber, signifying the first popularized semi-synthetic polymer. The
first wholly synthetic polymer, Bakelite, was discovered in 1907.
Polymer science
Most polymer research may be categorized as polymer science, a
sub-discipline of materials science which includes researchers in
chemistry (especially organic chemistry), physics, and engineering.
The field of polymer science includes both experimental and
theoretical research. The IUPAC recommends that polymer science
be roughly divided into two subdisciplines: polymer chemistry (or
macromolecular chemistry) and polymer physics. In practice the
distinction between the two is rarely clearcut.
Etymology
The word polymer is derived from the Greek words πολύ- - poly-
meaning "many"; and μέρος - meros meaning "part". The term was
coined in 1833 by Jöns Jacob Berzelius, although his definition of a
polymer was quite different from the modern definition. (see New
chemical terms)
Historical development
Starting in 1811, Henri Braconnot did pioneering work in derivative
cellulose compounds, perhaps the earliest important work in
polymer science. The development of vulcanization later in the
nineteenth century improved the durability of the natural polymer
rubber, signifying the first popularized semi-synthetic polymer. In
1907, Leo Baekeland created the first completely synthetic polymer,
Bakelite, by reacting phenol and formaldehyde at precisely
controlled temperature and pressure. Bakelite was then publicly
introduced in 1909.
Describing polymers
Molecular description
Macroscopic description
Polymer synthesis
The repeating unit of the polymer polypropylene
Laboratory synthesis
Biological synthesis
Microstructure of part of a DNA double helix biopolymer
Main article: Biopolymer
Polymer properties
Polymer properties are broadly divided into several classes based on
the scale at which the property is defined as well as upon its
physical basis. The most basic property of a polymer is the identity
of its constituent monomers. A second set of properties, known as
microstructure, essentially describe the arrangement of these
monomers within the polymer at the scale of a single chain. These
basic structural properties play a major role in determining bulk
physical properties of the polymer, which describe how the polymer
behaves as a continuous macroscopic material. Chemical properties,
at the nano-scale, describe how the chains interact through various
physical forces. At the macro-scale, they describe how the bulk
polymer interacts with other chemicals and solvents.
Microstructure
Polymer architecture
Chain length
Tacticity
Crystallinity
Chain conformation
Mechanical properties
A polyethylene sample necking under tension.
Tensile strength
Transport properties
Phase behavior
Melting point
Mixing behavior
Inclusion of plasticizers
Chemical properties
The attractive forces between polymer chains play a large part in
determining a polymer's properties. Because polymer chains are so
long, these interchain forces are amplified far beyond the
attractions between conventional molecules. Different side groups
on the polymer can lend the polymer to ionic bonding or hydrogen
bonding between its own chains. These stronger forces typically
result in higher tensile strength and higher crystalline melting
points.
Common
ACS name IUPAC name
name
Poly(ethylene Poly(oxyethylene) Poly(oxyethene)
oxide) or PEO
Poly(oxy-1,2-
Poly(ethylene
ethanediyloxycarbony Poly(oxyetheneoxyterephthalo
terephthalate)
l-1,4- yl)
or PET
phenylenecarbonyl)
Poly[amino(1-oxo-1,6- Poly[amino(1-oxohexan-1,6-
Nylon 6
hexanediyl)] diyl)]
Polymer characterization
The characterization of a polymer requires several parameters
which need to be specified. This is because a polymer actually
consists of a statistical distribution of chains of varying lengths, and
each chain consists of monomer residues which affect its properties.
Safety Precautions
• Wear safety goggles at all times in the laboratory.
• Styrene is harmful by inhalation. It is an irritant to the eyes
and respiratory system. Work in awell ventilated area.
• Methyl ethyl ketone is an irritant. Work in a well ventilated
area.
Materials needed
• Styrene casting resin
• Casting resin catalyst, methyl ethyl ketone
• Half of a small petri dish
• Stirring rod
• Optional: A clean dry coin, such as a penny
Procedure
• Measure 15 mL of styrene casting resin into a paper cup.
• Add 5 drops of catalyst to the resin. Stir well.
• Pour the resin mixture into a clean half of a petri dish. Allow
the mixture to sit, undisturbed, forapproximately one hour or
until hard.
• If desired, a clean, dry penny can be added to the resin after it
has set for about 5 minutes. Toavoid air bubbles, coat the
penny with a small amount of the mixed resin before adding it
to theresin mixture in the petri dish.
Safety Precautions
• Wear safety goggles at all times in the laboratory.
• The materials in this experiment are considered toxic. They
are irritants to the eyes and mucousmembranes. Wear gloves
and work in a well ventilated area.
Materials needed
• Hexamethylenediamine (1,6-hexanediamine), 5% aqueous
solutionSebacoyl chloride (or adipyl chloride), 5% solution in
cyclohexaneSodium hydroxide, NaOH, 20% aqueous solution
• Beaker, 50 mL
• Forceps
• Stirring rod.
Procedure
• Pour 10 mL of hexamethylenediamine solution into a 50 mL
beaker.
• Add 10 drops of 20% sodium hydroxide solution. Stir.
• Carefully add 10 mL of sebacoyl chloride solution by pouring it
down the wall of the tilted beaker.Two layers should be
evident in the beaker and there should be an immediate
formation of apolymer film at the interface between the two
liquids.
• Using forceps, pick up the mass at the center and slowly draw
out the nylon, allowing a “rope” tobe formed. Use a stirring
rod to wrap the rope and continue to pull it slowly from the
mixture interface.
• Wash the nylon well with water before handling.
• Stir any remaining solutions left in the beak to form additional
polymer. Wash the nylon wellwith water.
• Commercially, nylon is made by mixing the components in
bulk. Nylon thread, rod, and sheet aremade by melting and
forming or extruding the polymer.
Polymeric Sulfur
Materials Needed
Sulfur
Safety Precautions
It is recommended that a hot plate be used in heating the sulfur in
this preparation. This will prevent thesulfur from igniting and
burning to form toxic sulfur dioxide, a strong irritant. Keep the
beaker of sulfurcovered with a watch glass to minimize sulfur vapors
escaping from the beaker.
Procedure
• Heat ordinary sulfur to a temperature between 140-170°C.
The sulfur will turn red and become viscous above159°C. At
175°C, the viscosity of the molten sulfur begins to decrease.
• Pour the hot melt into water in a thin stream. When cool, it
forms rubbery fibers of the Polymeric sulfur. Thepolymer is not
stable at room temperature and it will eventually harden,
returning to its normal yellow color, whenthe molecules
reform into eight-membered rings.
Polymer degradation
A plastic item with thirty years of exposure to heat and cold, brake
fluid, and sunlight. Notice the discoloration, swollen dimensions, and
tiny splits running through the material
Product failure