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College of Engineering
Writing Assignment
AbdulahIbraheem Al Hamadi
@29371
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First of all, as one might expect from the consideration of the mobility of the molecules,
the diffusion coefficients are generally higher for gases than for liquids which are higher than
the values reported for solids. For example, Carbon dioxide in air has a diffusion coefficient
of (16×10-6 m²/s), and in water its coefficient is (16×10-10 m²/s)[2].Based on this the effect of
temperature on the diffusion coefficient is not the same for the three phases. In general, as the
temperature increases the diffusion coefficient increases. The dependence of the diffusion
coefficient on temperature for gases can be expressed using the following equation [3]:
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So it can be seen that for gases the relation between diffusion coefficient and temperature is
given by:
*
Where: D is the diffusion coefficient, Dois the maximum diffusion coefficient (at infinite
temperature), EAis the activation energy for diffusion in dimensions of (energy per amount of
substance), T is the temperature (K or oR), and R is the gas constant in dimensions of (energy
per temperature per amount of substance).
The effect of concentration on the diffusion coefficient can be seen from the equation:
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From this equation it can be seen that as the concentration gradient increases the diffusion
coefficient increases. Also, the values of liquid diffusion coefficients reveals that they depend
on concentration due to the changes in viscosity with concentration and the changes in the
degree of ideality of the solution.
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[1]Welty, J. R., Wicks, C.E. (1969). Fundamentals of Momentum, Heat, and Mass
Transfer.USA: Wiley.
[2] http://www.cco.caltech.edu/~brokawc/Bi145/Diffusion.html
[3] E.L. Cussler, "Diffusion. Mass Transfer in Fluid Systems", 2nd edition, Cambridge
University Press, 1997