TPD/TPR data - raw

Acquired by Quantachrome TPRWin v2.0

File name: HALLOY-Ni1.QTP

Description: HALLOY-Ni1
Created by: NURY Analysis Date: 2/5/2011
Run: 1 of 1
Sample Weight: 0.056 g
Adsorbate: Ammonia Flow rate: 80
Attenuation: 16 Detector current: 150.0 mA

Time Signal Temperature

[sec] [mV] [C]

1 4 -0.244 35.2
2 9 -0.244 39.4 -0.976
3 14 -0.244 43.7 -0.488
4 19 -0.244 42.3 -0.976
5 24 -0.244 49.7 -0.488
6 29 -0.244 53 -0.976
7 34 -0.244 58.9 -0.488
8 39 -0.244 62.4 -0.976
9 44 -0.244 65.4 -0.488
10 49 -0.244 65.4 -0.976
11 54 -0.488 73.3 -0.976
12 59 -0.488 77.2 -1.952
13 64 -0.244 80.8 -0.488
14 69 -0.488 82.6 -1.952
15 74 -0.488 83.2 -0.976
16 79 -0.488 85 -1.952
17 84 -0.488 89.7 -0.976
18 89 -0.488 92.1 -1.952
19 94 -0.488 93.9 -0.976
20 99 -0.488 95.7 -1.952
21 104 -0.488 98.1 -0.976
22 109 -0.488 99.9 -1.952
23 114 -0.488 99.9 -0.976
24 119 -0.488 102.9 -1.952
25 124 -0.488 101.1 -0.976
26 129 -0.732 103.5 -2.928
27 134 -0.732 107.1 -1.464
28 139 -0.732 104.7 -2.928
29 144 -0.732 110.7 -1.464
30 149 -0.732 110.3 -2.928
31 154 -0.732 113.7 -1.464
32 159 -0.732 115.7 -2.928
33 164 -0.732 114.9 -1.464
34 169 -0.732 119.1 -2.928
35 174 -0.732 122.7 -1.464
36 179 -0.977 124.7 -3.908
37 184 -0.977 127.1 -1.954
38 189 -0.977 128.1 -3.908
39 194 -0.977 128.4 -1.954
40 199 -0.977 133.2 -3.908
41 204 -0.977 136 -1.954
42 209 -0.977 134.4 -3.908
43 214 -0.732 139 -1.464
44 219 -0.488 141.4 -1.952
45 224 -0.488 141.6 -0.976
46 229 -0.244 146.2 -0.976
47 234 0.244 149.3 0.488
48 239 0.732 150.5 2.928
49 244 1.709 152.9 3.418
50 249 2.441 149.5 9.764
51 254 3.418 152.5 6.836
52 259 4.639 158 18.556
53 264 5.615 159.6 11.23
54 269 6.836 162.6 27.344
55 274 8.057 159.8 16.114
56 279 9.033 165.6 36.132
57 284 10.01 167.5 20.02
58 289 10.742 168.9 42.968
59 294 11.719 167.1 23.438
60 299 12.207 168.3 48.828
61 304 12.939 171.1 25.878
62 309 13.184 176.8 52.736
63 314 13.672 176 27.344
64 319 13.672 179.6 54.688
65 324 13.916 177.4 27.832
66 329 14.16 184.7 56.64
67 334 14.404 185.3 28.808
68 339 14.404 185.1 57.616
69 344 14.648 185.3 29.296
70 349 14.648 187.5 58.592
71 354 14.648 188.4 29.296
72 359 14.893 194.4 59.572
73 364 14.893 191.4 29.786
74 369 14.893 194.8 59.572
75 374 15.137 199.7 30.274
76 379 15.137 197.5 60.548
77 384 15.381 202.7 30.762
 78 389 15.381 199.7
79 394 15.381 203.6
80 399 15.381 206.4
81 404 15.381 208.4
82 409 15.137 212.7
83 414 15.381 212.4
84 419 15.137 214.5
85 424 15.137 213.6
86 429 14.893 217.3
87 434 14.893 219.4
88 439 14.648 216.7
89 444 14.404 221.2
90 449 14.404 223.6
91 454 14.16 225.4
92 459 14.16 229.7
93 464 13.916 230.3
94 469 13.672 229
95 474 13.428 234.5
96 479 13.184 231.5
97 484 13.184 234.5
98 489 13.184 237.5
99 494 12.939 239.9
100 499 12.695 242.7
101 504 12.695 242.4
102 509 12.451 242.1
103 514 12.207 244.2
104 519 12.207 249.6
105 524 12.207 249
106 529 11.963 253.2
107 534 11.719 254.4
108 539 11.719 256.2
109 544 11.475 256.8
110 549 11.23 257.4
111 554 11.23 261
112 559 10.986 262.2
113 564 10.986 265.2
114 569 10.742 262
115 574 10.498 265.2
116 579 10.498 265.8
117 584 10.254 267.6
118 589 10.254 268.8
119 594 10.01 270.6
120 599 9.766 275.4
121 604 9.766 274.2
122 609 9.521 279.6
123 614 9.521 279
124 619 9.277 278.4
125 624 9.033 280.8
126 629 9.033 285
127 634 8.789 283.2
128 639 8.545 288.6
129 644 8.545 288.6
130 649 8.301 292.2
131 654 8.301 293.3
132 659 8.301 293.9
133 664 8.057 296.3
134 669 8.057 293.3
135 674 7.812 299.3
136 679 7.812 299.9
137 684 7.812 298.1
138 689 7.568 303.4
139 694 7.568 305.6
140 699 7.324 307.6
141 704 7.324 306.4
142 709 7.324 311.1
143 714 7.08 310.6
144 719 7.08 314.1
145 724 7.08 313.5
146 729 6.836 317.1
147 734 6.592 316.1
148 739 6.592 319.4
149 744 6.592 321.2
150 749 6.592 319.4
151 754 6.348 321.2
152 759 6.348 321.8
153 764 6.104 327.7
154 769 6.104 325.3
155 774 5.859 327.7
156 779 5.859 332.4
157 784 5.859 332.4
158 789 5.615 333.5
159 794 5.615 333.5
160 799 5.615 338.8
161 804 5.615 335.9
162 809 5.615 341.2
163 814 5.371 338.2
164 819 5.371 341.2
165 824 5.371 345.8
166 829 5.127 346.4
167 834 5.127 348.2
168 839 5.127 349.9
169 844 5.127 352.8
170 849 4.883 352.3
171 854 4.883 354.6
172 859 4.883 353.1
173 864 4.883 353.4
174 869 4.883 358.7
175 874 4.639 360.4
176 879 4.639 362.2
177 884 4.639 359.8
178 889 4.639 364.1
179 894 4.639 364.5
180 899 4.639 363
181 904 4.639 368.8
182 909 4.395 369.7
183 914 4.395 368
184 919 4.395 371.7
185 924 4.395 373.4
186 929 4.395 376.9
187 934 4.395 377.5
188 939 4.395 374.3
189 944 4.15 380.1
190 949 4.15 382.7
191 954 4.15 382.1
192 959 4.15 383
193 964 4.15 382.7
194 969 4.15 384.4
195 974 4.15 385.6
196 979 4.15 387.9
197 984 4.15 391.1
198 989 3.906 392.5
199 994 3.906 392.2
200 999 3.906 394.6
201 1004 3.906 400.3
202 1009 3.906 400.5
203 1014 3.906 400.5
204 1019 3.906 402.6
205 1024 3.906 404.6
206 1029 3.906 406.3
207 1034 3.662 404
208 1039 3.662 405.7
209 1044 3.662 410.3
210 1049 3.662 408.6
211 1054 3.662 412.6
212 1059 3.662 416
213 1064 3.662 417.2
214 1069 3.662 419.5
215 1074 3.662 420.6
216 1079 3.662 420.6
217 1084 3.418 419.3
218 1089 3.418 425.2
219 1094 3.418 421.8
220 1099 3.418 426.9
221 1104 3.418 429.2
222 1109 3.418 430.4
223 1114 3.418 428.1
224 1119 3.418 433.8
225 1124 3.418 432.1
226 1129 3.174 436.6
227 1134 3.174 435.5
228 1139 3.174 438.4
229 1144 3.174 441.2
230 1149 3.174 442.9
231 1154 3.174 441.2
232 1159 3.174 445.8
233 1164 3.174 447.5
234 1169 2.93 444.6
235 1174 2.93 450.4
236 1179 3.174 451.5
237 1184 2.93 449.8
238 1189 2.93 453.2
239 1194 2.93 456.1
240 1199 2.686 456.1
241 1204 2.686 457.2
242 1209 2.93 460
243 1214 2.686 457.2
244 1219 2.686 461.8
245 1224 2.686 465.7
246 1229 2.686 465.7
247 1234 2.441 463.5
248 1239 2.441 465.2
249 1244 2.441 470.9
250 1249 2.441 472
251 1254 2.441 473.2
252 1259 2.441 473.4
253 1264 2.441 477.7
254 1269 2.441 476.6
255 1274 2.441 479.4
256 1279 2.197 478.9
257 1284 2.197 481.1
258 1289 2.197 484
259 1294 2.197 482.8
260 1299 2.197 486.8
261 1304 2.197 489.7
262 1309 1.953 491.6
263 1314 2.197 492.5
264 1319 1.953 493.7
265 1324 1.953 490.2
266 1329 1.953 497.1
267 1334 1.953 494.8
268 1339 1.709 497.9
269 1344 1.953 498.8
270 1349 1.953 504.5
271 1354 1.709 501.6
272 1359 1.709 501.1
273 1364 1.709 507.9
274 1369 1.709 508.5
275 1374 1.709 507.6
276 1379 1.709 509.3
277 1384 1.465 513
278 1389 1.465 511.6
279 1394 1.465 511.6
280 1399 1.221 513.8
281 1404 0.977 515.3
282 1409 0.732 518.7
283 1414 0.732 520.4
284 1419 0.488 521
285 1424 0.488 523.3
286 1429 0.244 527.5
287 1434 0.244 524.7
288 1439 0.244 529.2
289 1444 0 532.4
290 1449 0 534.4
291 1454 0 533.8
292 1459 0 536.1
293 1464 -0.244 536.7
294 1469 -0.244 539.5
295 1474 -0.244 541.2
296 1479 -0.244 538.4
297 1484 -0.488 543.5
298 1489 -0.244 545.2
299 1494 -0.488 547
300 1499 -0.488 548.7
301 1504 -0.488 545.6
302 1509 -0.488 548.7
303 1514 -0.488 553.8
304 1519 -0.488 553.8
305 1524 -0.488 556.5
306 1529 -0.732 557.3
307 1534 -0.488 555
308 1539 -0.488 559
309 1544 -0.732 560.1
310 1549 -0.488 563.6
311 1554 -0.732 563.9
312 1559 -0.732 566.4
313 1564 -0.732 568.7
314 1569 -0.732 570.2
315 1574 -0.977 570.4
316 1579 -0.732 570.4
317 1584 -0.732 570.4
318 1589 -0.732 572.2
319 1594 -0.977 578.5
320 1599 -0.977 575.6
321 1604 -0.977 580.8
322 1609 -0.977 581.3
323 1614 -0.977 583.6
324 1619 -0.977 582.5
325 1624 -1.221 583.1
326 1629 -1.221 588.8
327 1634 -1.221 585.9
328 1639 -0.977 589.4
329 1644 -1.221 590
330 1649 -1.221 595.7
331 1654 -1.221 595.7
332 1659 -1.221 598.6
333 1664 -1.221 596.9
334 1669 -1.221 598.6
335 1674 -1.221 599.8
336 1679 -1.221 604.4
337 1684 -1.221 602.7
338 1689 -1.221 606.1
339 1694 -1.221 607.3
 16

14

Signal (mV)
12

10

0
22

61.7
80.1
33.3
47

90.2
101.6
117.2
128.6
139.5
147.3
161.9
174
185
192.3
205.6
219.2
226.3
238.4
246.2
253.5
267.9
276.3
286.4
295.4
301
sitios de acidez debil
Tempera
n 78
b 199.7
a 35.2

h 2.11
Halloy Natural
Time Signal Temperature
650.831596 [sec] [mV] [C]

0 22
4 0.244 26.2
9 0.244 28
14 0.244 31.6
19 0.244 31.6
24 0.244 28.6
29 0.244 33.3
34 0.244 33.9
39 0.244 36.9
44 0.244 36.3
49 0.244 38.1
54 0.244 44
59 0.244 47
64 0.244 47
69 0 49.3
 74 0 57
79 0 58.2
84 0 59.4
89 0 61.7
94 0 67.7
99 0 72.4
104 0 73.6
109 0 74.8
114 0 77.1
119 0.244 80.1
124 0 79.2
129 0.244 83.1
134 0.244 86.1
139 0.244 88.4
144 0.244 86.1
149 0 90.2
154 0 89
159 0 96.2
164 0 95.6
169 0.244 96.2
174 0 101.6
179 0 101.6
184 0 104.6
189 0 106.4
194 0 110.2
199 0.244 110
204 0 110.6
209 0 117.2
214 0 119.6
219 0 120.8
224 0 125.6
229 0 125.6
234 0.244 127.4
239 0.244 128.6
244 0.244 130.4
249 0.244 132.8
254 0.488 134.6
259 0.488 135.2
264 0.732 138.3
269 0.732 139.5
274 0.732 140.7
279 0.732 144.9
284 0.977 144.9
289 0.977 143.1
294 0.977 146.7
299 0.977 147.3
304 0.977 153.4
309 0.977 155.8
314 0.977 157.6
319 0.977 157
324 1.221 159.5
329 1.221 161.9
334 1.221 163.4
339 1.221 165.5
344 1.221 168.6
349 1.465 168.6
354 1.465 172.2
359 1.709 174
364 1.953 171.9
369 2.197 175.3
374 2.441 177.3
379 2.686 181.9
384 3.174 183.2
389 3.418 185
394 3.906 185
399 4.395 189.2
404 4.639 190.1
409 5.127 192.9
414 5.371 189.8
419 5.859 192.3
424 6.104 197.7
429 6.592 199
434 6.836 201.6
439 7.08 198.4
444 7.324 204.4
449 7.568 205.6
454 7.812 209.3
459 7.812 211.4
464 7.812 211.1
469 8.057 211.1
474 8.301 212.3
479 8.301 219.2
484 8.301 219.6
489 8.545 221.4
494 8.301 222.6
499 8.545 224.5
504 8.545 223.2
509 8.545 226.3
514 8.545 225.3
519 8.301 231.4
524 8.301 234.1
529 8.301 236.6
534 8.301 234.1
539 8.301 238.4
544 8.057 242
549 8.057 243.2
554 8.057 245
559 8.057 242
564 7.812 247.4
569 7.812 246.2
574 7.568 249.3
579 7.568 252.9
584 7.568 254.1
589 7.324 255.3
594 7.324 255.5
599 7.324 253.5
604 7.08 257.1
609 7.08 260.1
614 6.836 263.1
619 6.836 264.9
624 6.592 264.9
629 6.592 267.9
634 6.592 268.5
639 6.592 270.3
644 6.348 272.1
649 6.348 273.3
654 6.348 275.9
659 6.104 276.3
664 6.348 275.7
669 6.104 276.3
674 5.859 279.9
679 5.859 283.7
684 5.859 284.3
689 5.615 286.4
694 5.615 287
699 5.615 285.3
704 5.615 288.8
709 5.371 289.4
714 5.371 294.8
719 5.371 295.4
724 5.371 298.9
729 5.127 295.4
734 5.127 301.9
739 5.127 302.8
744 4.883 304.3
749 4.883 301
754 4.883 305.5
759 4.883 308.4
764 4.639 310.8
769 4.639 309
774 4.639 310.8
779 4.639 313.4
784 4.639 312
789 4.395 316.7
794 4.395 317
799 4.395 318.1
804 4.395 318.1
809 4.395 319.1
814 4.395 322.9
819 4.15 324.4
 824 4.15 325.6
829 4.15 328.1
834 4.15 331.4
839 4.15 332
844 4.15 334.6
849 3.906 334.4
854 3.906 334
859 3.906 335
864 4.15 337
869 3.906 341.6
874 3.906 342
879 3.662 344.3
884 3.662 346.9
889 3.662 348.1
894 3.662 348.1
899 3.662 346.3
904 3.662 348.7
909 3.662 350.4
914 3.662 352.2
919 3.662 353.9
924 3.418 358.6
929 3.662 358.9
934 3.418 362.4
939 3.662 363.6
944 3.418 362.6
949 3.418 366.7
954 3.418 367.6
959 3.418 365.3
964 3.662 368.4
969 3.662 370.2
974 3.662 370.5
979 3.418 370.8
984 3.662 375.7
989 3.418 379.2
994 3.418 377.1
999 3.418 381.8
1004 3.418 379.5
1009 3.418 381.2
1014 3.418 386.7
1019 3.418 387
1024 3.418 388.7
1029 3.418 385.2
1034 3.662 390.2
1039 3.418 391.6
1044 3.418 391.6
1049 3.662 395.6
1054 3.418 393.3
1059 3.418 397.3
1064 3.418 396.8
1069 3.418 397.3
1074 3.662 403.7
1079 3.418 401.4
1084 3.418 404
1089 3.418 409.4
1094 3.174 410
1099 3.418 410.6
1104 3.418 412.9
1109 3.174 412.3
1114 3.174 414
1119 3.418 413.4
1124 3.174 418
1129 3.174 419.2
1134 3.174 422.6
1139 3.174 421.4
1144 3.174 426
1149 3.174 425.5
1154 3.174 430
1159 3.174 426.6
1164 3.174 431.7
1169 3.174 433.5
1174 3.174 433.5
1179 2.93 436.9
1184 2.93 436.9
1189 2.93 436.3
1194 2.93 439.7
1199 2.93 441.5
1204 2.93 443.2
1209 2.93 441.5
1214 2.686 445.5
1219 2.686 442.6
1224 2.686 447.2
1229 2.686 448.3
1234 2.686 451.7
1239 2.686 452.9
1244 2.686 451.7
1249 2.441 456.3
1254 2.686 459.1
1259 2.441 459.7
1264 2.441 460.3
1269 2.441 461.4
1274 2.197 462.6
1279 2.441 464.8
1284 2.441 464.3
1289 2.197 470
1294 2.197 468.8
1299 2.197 472.3
1304 2.197 470
1309 2.197 472.8
1314 2.197 475.7
1319 2.197 478
1324 2.197 479.7
1329 2.197 481.4
1334 1.953 479.7
1339 2.197 484.2
1344 1.953 485.9
1349 1.953 484.8
1354 1.953 486.5
1359 1.953 489.9
1364 1.709 487.1
1369 1.953 489.3
1374 1.953 495
1379 1.709 496.2
1384 1.953 499
1389 1.953 497.3
1394 1.953 501.5
1399 1.709 502.4
1404 1.709 504.2
1409 1.709 504.2
1414 1.709 508.7
1419 1.953 507
1424 1.709 512.7
1429 1.709 513.3
1434 1.709 515
1439 1.709 515
1444 1.709 511
1449 1.709 515
1454 1.709 519
1459 1.709 520.7
1464 1.709 520.1
1469 1.465 524.1
1474 1.709 521.8
1479 1.709 524.7
1484 1.709 527
1489 1.709 531.5
1494 1.709 533.2
1499 1.709 533.2
1504 1.709 536.7
1509 1.953 537.2
1514 1.709 536.7
1519 1.709 539
1524 1.709 542.1
1529 1.709 544.1
1534 1.709 547.8
1539 1.709 548.7
1544 1.953 550.6
1549 1.709 552.1
1554 1.709 551.5
1559 1.709 553.3
1564 1.953 553.3
1569 1.709 558.4
1574 1.953 559.8
1579 1.953 557.8
1584 1.953 561.9
192.3
205.6
219.2
226.3
238.4
246.2
253.5
267.9
276.3
286.4
295.4
301
313.4
319.1
332

Temperatura (°C)
341.6
346.3
358.9
365.3
379.2
387
395.6
401.4
412.3
421.4
433.5
441.5
448.3
459.7
470
478
484.8
496.2
504.2
515
524.1
533.2
544.1
553.3
TPD HN
TPD Ni5%
TPD Ni5%
TPD HN
 TPD/TPR data - raw
Acquired by Quantachrome TPRWin v2.0

File name: HALLOY-Ni1.QTP

Description: HALLOY-Ni1
Created by: NURY Analysis Date: 2/5/2011
Run: 1 of 1
Sample Weight: 0.056 g
Adsorbate: Ammonia Flow rate: 80
Attenuation: 16 Detector current: 150.0 mA

Time Signal Temperature

[sec] [mV] [C]

1 4 -0.244 35.2
2 9 -0.244 39.4 0.976
3 14 -0.244 43.7 0.488
4 19 -0.244 42.3 0.976
5 24 -0.244 49.7 0.488
6 29 -0.244 53 0.976
7 34 -0.244 58.9 0.488
8 39 -0.244 62.4 0.976
9 44 -0.244 65.4 0.488
10 49 -0.244 65.4 0.976
11 54 -0.488 73.3 0.976
12 59 -0.488 77.2 1.952
13 64 -0.244 80.8 0.488
14 69 -0.488 82.6 1.952
15 74 -0.488 83.2 0.976
16 79 -0.488 85 1.952
17 84 -0.488 89.7 0.976
18 89 -0.488 92.1 1.952
19 94 -0.488 93.9 0.976
20 99 -0.488 95.7 1.952
21 104 -0.488 98.1 0.976
22 109 -0.488 99.9 1.952
23 114 -0.488 99.9 0.976
24 119 -0.488 102.9 1.952
25 124 -0.488 101.1 0.976
26 129 -0.732 103.5 2.928
27 134 -0.732 107.1 1.464
28 139 -0.732 104.7 2.928
29 144 -0.732 110.7 1.464
30 149 -0.732 110.3 2.928
31 154 -0.732 113.7 1.464
32 159 -0.732 115.7 2.928
33 164 -0.732 114.9 1.464
34 169 -0.732 119.1 2.928
35 174 -0.732 122.7 1.464
36 179 -0.977 124.7 3.908
37 184 -0.977 127.1 1.954
38 189 -0.977 128.1 3.908
39 194 -0.977 128.4 1.954
40 199 -0.977 133.2 3.908
41 204 -0.977 136 1.954
42 209 -0.977 134.4 3.908
43 214 -0.732 139 1.464
44 219 -0.488 141.4 1.952
45 224 -0.488 141.6 0.976
46 229 -0.244 146.2 0.976
47 234 0.244 149.3 0.488
48 239 0.732 150.5 2.928
49 244 1.709 152.9 3.418
50 249 2.441 149.5 9.764
51 254 3.418 152.5 6.836
52 259 4.639 158 18.556
53 264 5.615 159.6 11.23
54 269 6.836 162.6 27.344
55 274 8.057 159.8 16.114
56 279 9.033 165.6 36.132
57 284 10.01 167.5 20.02
58 289 10.742 168.9 42.968
59 294 11.719 167.1 23.438
60 299 12.207 168.3 48.828
61 304 12.939 171.1 25.878
62 309 13.184 176.8 52.736
63 314 13.672 176 27.344
64 319 13.672 179.6 54.688
65 324 13.916 177.4 27.832
66 329 14.16 184.7 56.64
67 334 14.404 185.3 28.808
68 339 14.404 185.1 57.616
69 344 14.648 185.3 29.296
70 349 14.648 187.5 58.592
71 354 14.648 188.4 29.296
72 359 14.893 194.4 59.572
73 364 14.893 191.4 29.786
74 369 14.893 194.8 59.572
75 374 15.137 199.7 30.274
76 379 15.137 197.5 60.548
77 384 15.381 202.7 30.762
 78 389 15.381 199.7
79 394 15.381 203.6
80 399 15.381 206.4 61.524
81 404 15.381 208.4 30.762
82 409 15.137 212.7 60.548
83 414 15.381 212.4 30.762
84 419 15.137 214.5 60.548
85 424 15.137 213.6 30.274
86 429 14.893 217.3 59.572
87 434 14.893 219.4 29.786
88 439 14.648 216.7 58.592
89 444 14.404 221.2 28.808
90 449 14.404 223.6 57.616
91 454 14.16 225.4 28.32
92 459 14.16 229.7 56.64
93 464 13.916 230.3 27.832
94 469 13.672 229 54.688
95 474 13.428 234.5 26.856
96 479 13.184 231.5 52.736
97 484 13.184 234.5 26.368
98 489 13.184 237.5 52.736
99 494 12.939 239.9 25.878
100 499 12.695 242.7 50.78
101 504 12.695 242.4 25.39
102 509 12.451 242.1 49.804
103 514 12.207 244.2 24.414
104 519 12.207 249.6 48.828
105 524 12.207 249 24.414
106 529 11.963 253.2 47.852
107 534 11.719 254.4 23.438
108 539 11.719 256.2 46.876
109 544 11.475 256.8 22.95
110 549 11.23 257.4 44.92
111 554 11.23 261 22.46
112 559 10.986 262.2 43.944
113 564 10.986 265.2 21.972
114 569 10.742 262 42.968
115 574 10.498 265.2 20.996
116 579 10.498 265.8 41.992
117 584 10.254 267.6 20.508
118 589 10.254 268.8 41.016
119 594 10.01 270.6 20.02
120 599 9.766 275.4 39.064
121 604 9.766 274.2 19.532
122 609 9.521 279.6 38.084
123 614 9.521 279 19.042
124 619 9.277 278.4 37.108
125 624 9.033 280.8 18.066
126 629 9.033 285 36.132
127 634 8.789 283.2 17.578
128 639 8.545 288.6 34.18
129 644 8.545 288.6 17.09
130 649 8.301 292.2 33.204
131 654 8.301 293.3 16.602
132 659 8.301 293.9 33.204
133 664 8.057 296.3 16.114
134 669 8.057 293.3 32.228
135 674 7.812 299.3 15.624
136 679 7.812 299.9 31.248
137 684 7.812 298.1 15.624
138 689 7.568 303.4 30.272
139 694 7.568 305.6 15.136
140 699 7.324 307.6 29.296
141 704 7.324 306.4 14.648
142 709 7.324 311.1 29.296
143 714 7.08 310.6 14.16
144 719 7.08 314.1 28.32
145 724 7.08 313.5 14.16
146 729 6.836 317.1 27.344
147 734 6.592 316.1 13.184
148 739 6.592 319.4 26.368
149 744 6.592 321.2 13.184
150 749 6.592 319.4 26.368
151 754 6.348 321.2 12.696
152 759 6.348 321.8 25.392
153 764 6.104 327.7 12.208
154 769 6.104 325.3 24.416
155 774 5.859 327.7 11.718
156 779 5.859 332.4 23.436
157 784 5.859 332.4 11.718
158 789 5.615 333.5 22.46
159 794 5.615 333.5 11.23
160 799 5.615 338.8 22.46
161 804 5.615 335.9 11.23
162 809 5.615 341.2 22.46
163 814 5.371 338.2 10.742
164 819 5.371 341.2 21.484
165 824 5.371 345.8 10.742
166 829 5.127 346.4 20.508
167 834 5.127 348.2 10.254
168 839 5.127 349.9 20.508
169 844 5.127 352.8 10.254
170 849 4.883 352.3 19.532
171 854 4.883 354.6 9.766
172 859 4.883 353.1 19.532
173 864 4.883 353.4 9.766
174 869 4.883 358.7 19.532
175 874 4.639 360.4 9.278
176 879 4.639 362.2 18.556
177 884 4.639 359.8 9.278
178 889 4.639 364.1 18.556
179 894 4.639 364.5 9.278
180 899 4.639 363 18.556
181 904 4.639 368.8 9.278
182 909 4.395 369.7 17.58
183 914 4.395 368 8.79
184 919 4.395 371.7 17.58
185 924 4.395 373.4 8.79
186 929 4.395 376.9 17.58
187 934 4.395 377.5 8.79
188 939 4.395 374.3 17.58
189 944 4.15 380.1 8.3
190 949 4.15 382.7 16.6
191 954 4.15 382.1 8.3
192 959 4.15 383 16.6
193 964 4.15 382.7 8.3
194 969 4.15 384.4 16.6
195 974 4.15 385.6 8.3
196 979 4.15 387.9 16.6
197 984 4.15 391.1 8.3
198 989 3.906 392.5 15.624
199 994 3.906 392.2 7.812
200 999 3.906 394.6
201 1004 3.906 400.3
202 1009 3.906 400.5 15.624
203 1014 3.906 400.5 7.812
204 1019 3.906 402.6 15.624
205 1024 3.906 404.6 7.812
206 1029 3.906 406.3 15.624
207 1034 3.662 404 7.324
208 1039 3.662 405.7 14.648
209 1044 3.662 410.3 7.324
210 1049 3.662 408.6 14.648
211 1054 3.662 412.6 7.324
212 1059 3.662 416 14.648
213 1064 3.662 417.2 7.324
214 1069 3.662 419.5 14.648
215 1074 3.662 420.6 7.324
216 1079 3.662 420.6 14.648
217 1084 3.418 419.3 6.836
218 1089 3.418 425.2 13.672
219 1094 3.418 421.8 6.836
220 1099 3.418 426.9 13.672
221 1104 3.418 429.2 6.836
222 1109 3.418 430.4 13.672
223 1114 3.418 428.1 6.836
224 1119 3.418 433.8 13.672
225 1124 3.418 432.1 6.836
226 1129 3.174 436.6 12.696
227 1134 3.174 435.5 6.348
228 1139 3.174 438.4 12.696
229 1144 3.174 441.2 6.348
230 1149 3.174 442.9 12.696
231 1154 3.174 441.2 6.348
232 1159 3.174 445.8 12.696
233 1164 3.174 447.5 6.348
234 1169 2.93 444.6 11.72
235 1174 2.93 450.4 5.86
236 1179 3.174 451.5 12.696
237 1184 2.93 449.8 5.86
238 1189 2.93 453.2 11.72
239 1194 2.93 456.1 5.86
240 1199 2.686 456.1 10.744
241 1204 2.686 457.2 5.372
242 1209 2.93 460 11.72
243 1214 2.686 457.2 5.372
244 1219 2.686 461.8 10.744
245 1224 2.686 465.7 5.372
246 1229 2.686 465.7 10.744
247 1234 2.441 463.5 4.882
248 1239 2.441 465.2 9.764
249 1244 2.441 470.9 4.882
250 1249 2.441 472 9.764
251 1254 2.441 473.2 4.882
252 1259 2.441 473.4 9.764
253 1264 2.441 477.7 4.882
254 1269 2.441 476.6 9.764
255 1274 2.441 479.4 4.882
256 1279 2.197 478.9 8.788
257 1284 2.197 481.1 4.394
258 1289 2.197 484 8.788
259 1294 2.197 482.8 4.394
260 1299 2.197 486.8 8.788
261 1304 2.197 489.7 4.394
262 1309 1.953 491.6 7.812
263 1314 2.197 492.5 4.394
264 1319 1.953 493.7 7.812
265 1324 1.953 490.2 3.906
266 1329 1.953 497.1 7.812
267 1334 1.953 494.8 3.906
268 1339 1.709 497.9 6.836
269 1344 1.953 498.8 3.906
270 1349 1.953 504.5 7.812
271 1354 1.709 501.6 3.418
272 1359 1.709 501.1 6.836
273 1364 1.709 507.9 3.418
274 1369 1.709 508.5 6.836
275 1374 1.709 507.6 3.418
276 1379 1.709 509.3 6.836
277 1384 1.465 513 2.93
278 1389 1.465 511.6 5.86
279 1394 1.465 511.6 2.93
280 1399 1.221 513.8 4.884
281 1404 0.977 515.3 1.954
282 1409 0.732 518.7 2.928
283 1414 0.732 520.4 1.464
284 1419 0.488 521 1.952
285 1424 0.488 523.3 0.976
286 1429 0.244 527.5 0.976
287 1434 0.244 524.7 0.488
288 1439 0.244 529.2 0.976
289 1444 0 532.4 0
290 1449 0 534.4 0
291 1454 0 533.8 0
292 1459 0 536.1 0
293 1464 -0.244 536.7 -0.488
294 1469 -0.244 539.5 -0.976
295 1474 -0.244 541.2 -0.488
296 1479 -0.244 538.4 -0.976
297 1484 -0.488 543.5 -0.976
298 1489 -0.244 545.2 -0.976
299 1494 -0.488 547 -0.976
300 1499 -0.488 548.7 -1.952
301 1504 -0.488 545.6 -0.976
302 1509 -0.488 548.7 -1.952
303 1514 -0.488 553.8 -0.976
304 1519 -0.488 553.8 -1.952
305 1524 -0.488 556.5 -0.976
306 1529 -0.732 557.3 -2.928
307 1534 -0.488 555 -0.976
308 1539 -0.488 559 -1.952
309 1544 -0.732 560.1 -1.464
310 1549 -0.488 563.6 -1.952
311 1554 -0.732 563.9 -1.464
312 1559 -0.732 566.4 -2.928
313 1564 -0.732 568.7 -1.464
314 1569 -0.732 570.2 -2.928
315 1574 -0.977 570.4 -1.954
316 1579 -0.732 570.4 -2.928
317 1584 -0.732 570.4 -1.464
318 1589 -0.732 572.2 -2.928
319 1594 -0.977 578.5 -1.954
320 1599 -0.977 575.6 -3.908
321 1604 -0.977 580.8 -1.954
322 1609 -0.977 581.3 -3.908
323 1614 -0.977 583.6 -1.954
324 1619 -0.977 582.5 -3.908
325 1624 -1.221 583.1 -2.442
326 1629 -1.221 588.8 -4.884
327 1634 -1.221 585.9 -2.442
328 1639 -0.977 589.4 -3.908
329 1644 -1.221 590 -2.442
330 1649 -1.221 595.7 -4.884
331 1654 -1.221 595.7 -2.442
332 1659 -1.221 598.6 -4.884
333 1664 -1.221 596.9 -2.442
334 1669 -1.221 598.6 -4.884
335 1674 -1.221 599.8 -2.442
336 1679 -1.221 604.4 -4.884
337 1684 -1.221 602.7 -2.442
338 1689 -1.221 606.1
339 1694 -1.221 607.3
 16

14

Signal (mV)
12

10

sitios de acidez debil

n 78 0
b 199.7
22

47

80.1
90.2
101.6
117.2
128.6
139.5
147.3
161.9

192.3
205.6
219.2
226.3
238.4
246.2
253.5
267.9
276.3
286.4
295.4
33.3

61.7

185
174
a 35.2

h 2.11 Tempera
Halloy Natural
Time Signal Temperature
758.93 [sec] [mV] [C]

sitios de acidez media 0 22

n 122 4 0.244 26.2
b 394.6 9 0.244 28
a 203.6 14 0.244 31.6
19 0.244 31.6
h 1.566 24 0.244 28.6
29 0.244 33.3
1582.2654 34 0.244 33.9
39 0.244 36.9
44 0.244 36.3
49 0.244 38.1
sitios de acidez fuerte 54 0.244 44
n 138 59 0.244 47
b 606.1 64 0.244 47
a 400.3 69 0 49.3
 74 0 57
h 1.491 79 0 58.2
84 0 59.4
280.9513 89 0 61.7
94 0 67.7
99 0 72.4
104 0 73.6
109 0 74.8
114 0 77.1
119 0.244 80.1
124 0 79.2
129 0.244 83.1
134 0.244 86.1
139 0.244 88.4
144 0.244 86.1
149 0 90.2
154 0 89
159 0 96.2
164 0 95.6
169 0.244 96.2
174 0 101.6
179 0 101.6
184 0 104.6
189 0 106.4
194 0 110.2
199 0.244 110
204 0 110.6
209 0 117.2
214 0 119.6
219 0 120.8
224 0 125.6
229 0 125.6
234 0.244 127.4
239 0.244 128.6
244 0.244 130.4
249 0.244 132.8
254 0.488 134.6
259 0.488 135.2
264 0.732 138.3
269 0.732 139.5
274 0.732 140.7
279 0.732 144.9
284 0.977 144.9
289 0.977 143.1
294 0.977 146.7
299 0.977 147.3
304 0.977 153.4
309 0.977 155.8
314 0.977 157.6
319 0.977 157
324 1.221 159.5
329 1.221 161.9
334 1.221 163.4
339 1.221 165.5
344 1.221 168.6
349 1.465 168.6
354 1.465 172.2
359 1.709 174
364 1.953 171.9
369 2.197 175.3
374 2.441 177.3
379 2.686 181.9
384 3.174 183.2
389 3.418 185
394 3.906 185
399 4.395 189.2
404 4.639 190.1
409 5.127 192.9
414 5.371 189.8
419 5.859 192.3
424 6.104 197.7
429 6.592 199
434 6.836 201.6
439 7.08 198.4
444 7.324 204.4
449 7.568 205.6
454 7.812 209.3
459 7.812 211.4
464 7.812 211.1
469 8.057 211.1
474 8.301 212.3
479 8.301 219.2
484 8.301 219.6
489 8.545 221.4
494 8.301 222.6
499 8.545 224.5
504 8.545 223.2
509 8.545 226.3
514 8.545 225.3
519 8.301 231.4
524 8.301 234.1
529 8.301 236.6
534 8.301 234.1
539 8.301 238.4
544 8.057 242
549 8.057 243.2
554 8.057 245
559 8.057 242
564 7.812 247.4
569 7.812 246.2
574 7.568 249.3
579 7.568 252.9
584 7.568 254.1
589 7.324 255.3
594 7.324 255.5
599 7.324 253.5
604 7.08 257.1
609 7.08 260.1
614 6.836 263.1
619 6.836 264.9
624 6.592 264.9
629 6.592 267.9
634 6.592 268.5
639 6.592 270.3
644 6.348 272.1
649 6.348 273.3
654 6.348 275.9
659 6.104 276.3
664 6.348 275.7
669 6.104 276.3
674 5.859 279.9
679 5.859 283.7
684 5.859 284.3
689 5.615 286.4
694 5.615 287
699 5.615 285.3
704 5.615 288.8
709 5.371 289.4
714 5.371 294.8
719 5.371 295.4
724 5.371 298.9
729 5.127 295.4
734 5.127 301.9
739 5.127 302.8
744 4.883 304.3
749 4.883 301
754 4.883 305.5
759 4.883 308.4
764 4.639 310.8
769 4.639 309
774 4.639 310.8
779 4.639 313.4
784 4.639 312
789 4.395 316.7
794 4.395 317
799 4.395 318.1
804 4.395 318.1
809 4.395 319.1
814 4.395 322.9
819 4.15 324.4
 824 4.15 325.6
829 4.15 328.1
834 4.15 331.4
839 4.15 332
844 4.15 334.6
849 3.906 334.4
854 3.906 334
859 3.906 335
864 4.15 337
869 3.906 341.6
874 3.906 342
879 3.662 344.3
884 3.662 346.9
889 3.662 348.1
894 3.662 348.1
899 3.662 346.3
904 3.662 348.7
909 3.662 350.4
914 3.662 352.2
919 3.662 353.9
924 3.418 358.6
929 3.662 358.9
934 3.418 362.4
939 3.662 363.6
944 3.418 362.6
949 3.418 366.7
954 3.418 367.6
959 3.418 365.3
964 3.662 368.4
969 3.662 370.2
974 3.662 370.5
979 3.418 370.8
984 3.662 375.7
989 3.418 379.2
994 3.418 377.1
999 3.418 381.8
1004 3.418 379.5
1009 3.418 381.2
1014 3.418 386.7
1019 3.418 387
1024 3.418 388.7
1029 3.418 385.2
1034 3.662 390.2
1039 3.418 391.6
1044 3.418 391.6
1049 3.662 395.6
1054 3.418 393.3
1059 3.418 397.3
1064 3.418 396.8
1069 3.418 397.3
1074 3.662 403.7
1079 3.418 401.4
1084 3.418 404
1089 3.418 409.4
1094 3.174 410
1099 3.418 410.6
1104 3.418 412.9
1109 3.174 412.3
1114 3.174 414
1119 3.418 413.4
1124 3.174 418
1129 3.174 419.2
1134 3.174 422.6
1139 3.174 421.4
1144 3.174 426
1149 3.174 425.5
1154 3.174 430
1159 3.174 426.6
1164 3.174 431.7
1169 3.174 433.5
1174 3.174 433.5
1179 2.93 436.9
1184 2.93 436.9
1189 2.93 436.3
1194 2.93 439.7
1199 2.93 441.5
1204 2.93 443.2
1209 2.93 441.5
1214 2.686 445.5
1219 2.686 442.6
1224 2.686 447.2
1229 2.686 448.3
1234 2.686 451.7
1239 2.686 452.9
1244 2.686 451.7
1249 2.441 456.3
1254 2.686 459.1
1259 2.441 459.7
1264 2.441 460.3
1269 2.441 461.4
1274 2.197 462.6
1279 2.441 464.8
1284 2.441 464.3
1289 2.197 470
1294 2.197 468.8
1299 2.197 472.3
1304 2.197 470
1309 2.197 472.8
1314 2.197 475.7
1319 2.197 478
1324 2.197 479.7
1329 2.197 481.4
1334 1.953 479.7
1339 2.197 484.2
1344 1.953 485.9
1349 1.953 484.8
1354 1.953 486.5
1359 1.953 489.9
1364 1.709 487.1
1369 1.953 489.3
1374 1.953 495
1379 1.709 496.2
1384 1.953 499
1389 1.953 497.3
1394 1.953 501.5
1399 1.709 502.4
1404 1.709 504.2
1409 1.709 504.2
1414 1.709 508.7
1419 1.953 507
1424 1.709 512.7
1429 1.709 513.3
1434 1.709 515
1439 1.709 515
1444 1.709 511
1449 1.709 515
1454 1.709 519
1459 1.709 520.7
1464 1.709 520.1
1469 1.465 524.1
1474 1.709 521.8
1479 1.709 524.7
1484 1.709 527
1489 1.709 531.5
1494 1.709 533.2
1499 1.709 533.2
1504 1.709 536.7
1509 1.953 537.2
1514 1.709 536.7
1519 1.709 539
1524 1.709 542.1
1529 1.709 544.1
1534 1.709 547.8
1539 1.709 548.7
1544 1.953 550.6
1549 1.709 552.1
1554 1.709 551.5
1559 1.709 553.3
1564 1.953 553.3
1569 1.709 558.4
1574 1.953 559.8
1579 1.953 557.8
1584 1.953 561.9
 185
192.3
205.6
219.2
226.3
238.4
246.2
253.5
267.9
276.3
286.4
295.4
301
313.4

Temperatura (°C)
319.1
332
341.6
346.3
358.9
365.3
379.2
387
395.6
401.4
412.3
421.4
433.5
441.5
448.3
459.7
470
478
484.8
496.2
504.2
515
524.1
533.2
544.1
553.3
TPD HN
TPD Ni5%
TPD Ni5%
TPD HN