Monomero al Dimero

VO2(OH)2VO2

-1
pV'

Monomero al Dimero
pH
pV'
0
-21.13
3.3
-4.63
3.3
-4.63
4
-2.53
4
-2.53
8.55
2.02
8.55
2.02
10.01
0.56
10.01
0.56
14.26
0.56
14.26
0.56
15
-0.92

-6

HV2O73-

-11

VO(OH)3

-16
-21
0

8
pH

Dimero al Trimero
20

Trimero al Tetramero
pH
pV'
0
3.3
2.89
4
4
8.55
8.55

10
5

pV'

5.34
8.64
8.69
8.69
8.69
4.14
4.14
1.22
1.22
-11.53
-11.53
-14.49

HV2O73-

15

0
-5

V3O93-

-10
-15
0

8
pH

Trimero al Tetramero
-4.89
1.71
1.3
2.41
2.41
2.41
2.41

7
5

V3O93-

3
pV'

Dimero al Trimero
pH
pV'
0
3.3
3.3
4
4
8.55
8.55
10.01
10.01
14.26
14.26
15

1
-1
-3

V4O124-

9.89
14.26
15

-3

1.07
-3.3
-4.78

-5
0

8
pH

Dismutacin
4

pV'

-1

-6

-11

-16
0

4
2
0
-2
-4
-6
-8
-10
-12
-14

10

15

20
Series2
Series3
Series4
Series1

-14
-16

4
2
0
0

10

12

-2
-4
-6
-8
-10
-12
-14
-16

Dismutacin
4

pV'

-1

-6

-11

-16
0

10

pH

Dismutacin

Dismutacin
VO2(OH)2-

VO2(OH)24

VO2+
-1

V3O93-

pV'

VO(OH)3
-6

V4O124-11

-16
0

8
pH

Tetramero al decamero
pH
pV'
0
1.655
3.3
4.955
3.3
4.955
3.6
4.955
3.6
4.955
4 5.02166667
4 5.02166667
6.15
3.23
6.15
3.23
8.55
1.63
8.55
1.63
11.5275
-3.3325
14.26 -7.88666667
15
-9.86

Tetramero al decamero
V4O124-

pV'

-2

V10O26(OH)24-

V10O27(OH)5-

V10O28

-7

-12 0

8
pH

Dismutacin
VO2(OH)2VO3(OH)24

VO3(OH)
4

VO2+
-1

V3O93-

pV'

VO(OH)3

V4O124-

-6

V10O26(OH)24-

-11

V10O28

V10O27(OH)5-

-16
0

10

pH

Dismutacin
pH
pV
11.5275
-2.986875
14.26
-7.76875
14.26
-7.76875
15
-9.80375

VO2+
-1
pV'

VO(OH)3
-6

V10O26(OH)24-

-11

-16
0

Dimero al Trimero

ero al Dimero
15

VO3

(OH)2-

10
5
pV'

V2O74-

-5
-10
-15

VO7

3-

-20
-25

10

12

14

8
pH

Dismutacin Monomero al Trimero

al Trimero

VO2(OH)2VO2+

V2O74pV'

-1

V3O93-

-6
-11

VO(OH)3

-16
10

12

14

8
pH

Dismutacin Monomero al Trim

al Tetramero

VO2(OH)24

VO2+

pV'

-1

V3O93-

-6
-11

VO(OH)3

-11

VO(OH)3

-16
10

12

14

16

8
pH

Dismutacin
V3O93-

10

12

pH

Series2
Series3
Series4
Series1

Monomero al Dimero
Dimero al Trimero
pH
pV'
pH
pV'
0
-21.13
0
2.98
-6.23
3.3
3.3
-4.63
3.3
4
-2.53
4
4
-2.53
4
8.55
2.02
8.55
8.55
2.02
8.55
10.01
0.56
10.01
10.23
0.56
10.01
14.26
0.56
14.26
14.26
0.56
14.26

5.34
8.64
8.69
8.69
8.69
4.14
4.14
1.22
1.22
-11.53
-11.53

15

-0.92

15

-14.49

0 -6.87666667
2.98
1.07

14

16
Series5
Series2
Series3
Series4
Series1

dismutacion del monomero al tetramero

9.89
1.07
10.23 0.61666667

Series4
M-D
D-T
Series1

12

14

ismutacin
VO3(OH)2-

3-

VO3(OH)2-

VO43-

M-Tetra

V2O74-

M-Tetra
Tri-Tetra
M-D
D-T
M-Tri

10

12

14

o al decamero

10O28

10

12

14

16

Dismutacin
VO2(OH)2(OH)2-

VO43-

VO3
4

(OH)

VO3

VO43-

VO2+

Tetra-Deca
-1

M-Tetra

V3O93-

VO(OH)3

pV'

M-Tetra

V2O74-

-6

Tri-Tetra

V4O124-

M-D
D-T

-11

M-Tri
-16
12

14

8
pH

Dismutacin
VO2(OH)2-

VO3(OH)2-

VO43D-Tri

V3O93-

VO(OH)3

Tetra-Deca

V2O74-

M-Tetra

V4O12

4-

M-Tetra
Tri-Tetra

V10O28

V10O27(OH)5-

M-D
Series3

8
pH

10

12

14

M-Tri

10

mero al Trimero

pH

V2O74-

10

12

14

16

pV'
0
3.3
3.3
4
4
8.55
8.55
10.01
10.23
14.26
14.26
15

-21.13
-4.63
-4.63
-2.53
-2.53
2.02
2.02
0.56
0.56
0.56
0.56
-0.92

pH

Dimutacion del monomero al Trimero

Monomero al Trimero
VO3(OH)2-

Dismutacin Monomero al Trimero

pH
pV'
0
5.34
-7.87
3.3
8.64
2.03
2.89
8.69
1.415
4
8.69
3.08
4
8.69
3.08
8.55
4.14
3.08
8.55
4.14
3.08
9.89
1.46
1.07
10.23
0.56
0.56
11.5275
-3.3325
14.26
-11.53
15
-14.49

VO73-

V2O74-

M-D
D-T
M-T

10

12

14

in Monomero al Trimero
VO3(OH)2-

VO43-

V2O74-

M-D
D-T
M-T

M-T

10

12

14

pH

Tri-Tetra
M-D
D-T
Series1

14

Dismutacin Monomero al Trimero

Trimero al Tetramero
pH
pV'
pH
pV'
0 -6.87666667
-7.87
0
2.98
1.07
1.07
2.98
3.3
8.69
2.03
3.3
4
8.69
3.08
4
4
8.69
3.08
4
8.55
4.14
3.08
8.55
8.55
4.14
3.08
8.55
10.01
1.22
0.89
14.26
10.23
0.56
0.56
14.26
14.26
-11.53
15
14.26
-11.53

-4.89
1.07
1.71
2.41
2.41
2.41
2.41
-3.3
-3.3
-4.78

15

-14.49

Dismutacin

-1

pV'

M-Tetra
Tri-Tetra
-6

M-D
D-T
M-Tri

-11

-16

-16
0

8
pH

mutacin
VO3(OH)2-

VO43-

10

12

14

VO3(OH)

VO43-

M-Tetra

V2O74-

M-Tetra
Tri-Tetra
M-D
D-T
M-Tri

12

14

Dismutacin
VO2(OH)2VO3(OH)24

VO2+
-1

V3O93-

VO(OH)3

pV'

10

V4O124-

-6

V10O26(OH)24-

-11

V10O28

V10O27(OH)5-

-16
0

8
pH

10

12

M-Tetra
Tri-Tetra
M-D
D-T
M-Tri

VO43-

Tetra-Deca
M-Tetra

V2O74-

M-Tetra
Tri-Tetra
M-D
D-T
M-Tri

12

14