P PHR l42P- Quiz#7 - F2000

(points)

(2) 1. Define intrinsic partition coeffient for a weak acid.

Crh{
-T-

n
\r \ r*'.d'Ji . , ,
i" i r - t t t . u V

(2) 2. Define apparentpartition coeffientfor a weak base.

I
l r W ['\],
t6'z?]o
K I 0\
s*-F#

-fP Rorlu* [K*ju

<-

[u] u* [nu{*
l\n

I (2) 3. Write an equationwhich relatesKoo,, to pH for a weak base. Be certail

that pH is explicitly mentionedin your equation.

u t Y= Yo*-
K:* 'o /+ tqeK^-PH

(3) 4. Sketcha graphof Kuoovs pH for a weak base. Indicatepredominant

speciesat variouspointson the graphas hasbeendonein lecture.
Indicateany particularlysignificantpoint on your graph.

K"
. .Lnot
e"!
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