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  • Lipid Oxidation

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    Qotrun Nnada
    48 vizualizări14 pagini
    This document discusses types of rancidity in lipids, specifically hydrolytic and oxidative rancidity. It describes oxidative rancidity as occurring in two parts - formation of lipid hydroperoxides followed by their breakdown. The process of oxidative rancidity involves initiation, propagation, and termination steps. Factors like fatty acid composition, temperature, water activity, metals, oxygen, and light affect the rate of rancidity. Antioxidants like metal chelators and radical scavengers can help prevent rancidity.

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    This document discusses types of rancidity in lipids, specifically hydrolytic and oxidative rancidity. It describes oxidative rancidity as occurring in two parts - formation of lipid hydroperoxides followed by their breakdown. The process of oxidative rancidity involves initiation, propagation, and termination steps. Factors like fatty acid composition, temperature, water activity, metals, oxygen, and light affect the rate of rancidity. Antioxidants like metal chelators and radical scavengers can help prevent rancidity.

    Drepturi de autor:

    Attribution Non-Commercial (BY-NC)
    Descărcați ca PPT, PDF, TXT sau citiți online pe Scribd
    Indicator pentru conținut neadecvat
    48 vizualizări14 pagini

    Lipid Oxidation

    Încărcat de

    Qotrun Nnada
    This document discusses types of rancidity in lipids, specifically hydrolytic and oxidative rancidity. It describes oxidative rancidity as occurring in two parts - formation of lipid hydroperoxides followed by their breakdown. The process of oxidative rancidity involves initiation, propagation, and termination steps. Factors like fatty acid composition, temperature, water activity, metals, oxygen, and light affect the rate of rancidity. Antioxidants like metal chelators and radical scavengers can help prevent rancidity.

    Drepturi de autor:

    Attribution Non-Commercial (BY-NC)
    Descărcați ca PPT, PDF, TXT sau citiți online pe Scribd
    Indicator pentru conținut neadecvat
    din 14

    Lipid Oxidation

    FDSC400

    Types of Rancidity
    Hydrolytic rancidity
    Lipase Free fatty acids provide aroma

    Oxidative rancidity
    Radical oxidation Aldehydes and other compounds provide aroma

    Oxidative Rancidity
    Part 1: Form lipid hydroperoxides Part 2: Break down lipid hydroperoxides

    Oxidative Rancidity
    Initiation
    A radical is formed

    Propagation
    Radicals react and transfer their unpaired electron to other compounds

    Termination
    Two radicals combine to stop the reaction

    The Pentadiene Structure


    H H H C C C C C H H H
    RH R

    . H

    Radical Migration

    Addition of Oxygen - Propagation R . +O2 ROO .

    ROO +RH

    ROOH

    +R .

    Each methylene interrupter can lead to three possible lipid hydroperoxides!

    Termination

    Part 2: Hydroperoxide Breakdown


    (1)

    (2)

    Factors affecting rate


    Fatty acid composition Temperature Water activity Metal ions Oxygen Light

    Antioxidants
    Metal chelators Radical scavengers (primary and secondary)

    citrate, EDTA

    BHA, BHT, tocopherol

    Radical Scavenging Antioxidants

    e.g.: w3 PUFA Supplemented Yogurt


    w3 oil water

    Homogenize
    Pasteurize Store/ship w3 emulsion milk Culture ingredients

    Pasteurize

    Homogenize

    Pack

    Ferment

    Store

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