C2H4Cl2 ==> C2H3Cl + HCl

(1)

(3)

(2)

coef = [-1 1 1];

T0 = 450 + 273=723 K
P = 1 atm
d = 0.1 m
DM0 = [4.06 0 0] kmol/h
XAF = 0.7
Mmol = [99 36.5 62.5]
Dhr = 16240 kcal/kmol
Tp = T0 + 100=823 K
Cp = a + bT +cT^2 + dT^3, J/mol/K
AC = [5.949 20.19e-2 -15.36e-5 4.773e-8
30.67 -0.7201e-2 1.246e-5 -0.389e-8
5.949 20.19e-2 -15.36e-5 4.773e-8] coef Cp
AC =

5.9490

0.2019 -0.0002

30.6700 -0.0072
5.9490

0.0000

0.0000 -0.0000

0.2019 -0.0002

0.0000

ita = ita0*(273+C)/(T+C)*(T/273)^1.5, Pa.s

AI = [1.27e-5 340
1.77e-5 260
1.27e-5 340] ita0 si C

AI =

0.0000 340.0000
0.0000 260.0000
0.0000 340.0000
lam = a + b*(T-273), W/m/K
AL = [0.0179 1.32e-4
0.0136 4.64e-5
0.0179 1.32e-4]; % a,b
AL =

0.0179

0.0001

0.0136

0.0000

0.0179

0.0001

Calcule preliminare
ST = pi*d^2/4=0.0079
Dm = DM0*Mmol'=401.9400
Dmsp = Dm/ST=5.1177e+004kg/mp/h

Initializariz = 0;
T = T0;
XA = 0;
pas = 0.01;
vra = 1;
rez = zeros(100,4)

rez =

0 723.0000

1.0000

2.0000

0.0424 730.7657 11.4356

4.0000

0.0869 734.2657 11.4677

6.0000

0.1307 736.6418 11.1650

8.0000

0.1732 738.7062 10.7969

10.0000

0.2143 740.6699 10.4282

12.0000

0.2539 742.5921 10.0729

14.0000

0.2922 744.4920

9.7326

16.0000

0.3292 746.3772

9.4058

18.0000

0.3650 748.2520

9.0908

20.0000

0.3996 750.1195

8.7859

22.0000

0.4330 751.9820

8.4895

24.0000

0.4653 753.8418

8.2003

26.0000

0.4964 755.7007

7.9171

28.0000

0.5265 757.5603

7.6392

30.0000

0.5556 759.4222

7.3655

32.0000

0.5835 761.2877

7.0955

34.0000

0.6105 763.1578

6.8285

36.0000

0.6364 765.0334

6.5641

38.0000

0.6613 766.9154

6.3018

40.0000

0.6851 768.8042

6.0414

41.3000

0.7001 770.0356

5.8729

ii = 0;

contor pasi

iscr = 0;

contor scriere

comp = 200;

% pas de afisare (ca multiplu de pasi de integrare)

mod(ii,comp) == 0=130
iscr = iscr + 1=22;
rez(iscr,:) = [z XA T vra]= 41.3000

0.7001 770.0356

5.8729

imax = iscr=22;
calcul fr. molare

DM = DM0 + coef*DM0(1)*XA=1.2180

2.8420

2.8420;

DMT = sum(DM)= 6.9020;

y = DM/DMT=0.1765

0.4118

0.4118;

calcul proprietati

mt = [1 T T^2 T^3]'=1.0e+008 *

0.0000
0.0000
0.0059
4.5658;
Cp = AC*mt= 92.1342
30.7370
92.1342
J/mol/K!!!
ita = AI(:,1).*(273+AI(:,2))./(T+AI(:,2))*(T/273)^1.5= 1.0e-004 *

0.3322
0.4339
0.3322
Pa s
lam = AL(:,1)+AL(:,2)*(T-273)= 0.0835
0.0367
0.0835
W/m/K

medieri cu fr. Molare

Cpmed = y*Cp=66.8532 J/mol/K ;
itamed = y*ita=3.7409e-005 Pa s;
lammed = y*lam=0.0642 W/m/K;
Mmed = y*Mmol'= 58.2356;
calcul viteza
k = 29.5e8*exp(-28000/1.987/T)= 33.2788 kmol/mc/h/atm
vra = k*P*y(1)= 5.8729;

calcul alfa

Re = Dmsp/3600*d/itamed= 3.8001e+004;
Pr = Cpmed*1e3/Mmed*itamed/lammed= 0.6687;
Nu = 0.023*Re^0.8*Pr^0.33= 92.8745;
alfa = Nu*lammed/d= 59.6424;

calcul derivate

derX = ST/DM0(1)*vra= 0.0114;

derT = Mmed/Dmsp/Cpmed*(-Dhr*vra*4.186 - 4/d*3.6*alfa*(T-Tp)= 0.9484);
% 4.186 transforma kcal in kJ;
% 3.6 transforma W in kJ/h
% integrare

ii = ii + 1= 4130;
z = z + pas= 41.3000;
XA = XA + derX*pas= 0.7001;

T = T + derT * pas= 770.0356;

iscr = iscr + 1= 22;

imax = iscr= 22;

rez(iscr,:) = [z XA T vra]= 41.3000

0.7001 770.0356

rez = rez(1:imax,:)=
0

0 723.0000

1.0000

2.0000

0.0424 730.7657 11.4356

4.0000

0.0869 734.2657 11.4677

6.0000

0.1307 736.6418 11.1650

8.0000

0.1732 738.7062 10.7969

10.0000

0.2143 740.6699 10.4282

12.0000

0.2539 742.5921 10.0729

14.0000

0.2922 744.4920

9.7326

16.0000

0.3292 746.3772

9.4058

18.0000

0.3650 748.2520

9.0908

20.0000

0.3996 750.1195

8.7859

22.0000

0.4330 751.9820

8.4895

24.0000

0.4653 753.8418

8.2003

26.0000

0.4964 755.7007

7.9171

28.0000

0.5265 757.5603

7.6392

30.0000

0.5556 759.4222

7.3655

32.0000

0.5835 761.2877

7.0955

34.0000

0.6105 763.1578

6.8285

36.0000

0.6364 765.0334

6.5641

38.0000

0.6613 766.9154

6.3018

40.0000

0.6851 768.8042

6.0414

5.8729

41.3000

0.7001 770.0356

5.8729;

subplot(1,2,1), plot(rez(:,1),rez(:,2))
subplot(1,2,2), plot(rez(:,1),rez(:,3))

% graficul conversiei
% graficul temperaturii