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This fibre is the most spread among the chemical fibres and it has reached the high maturity. PTT belongs to a class of polymers called aromatic polyesters. However, PTT Polymer is a unique product in that it behaves very differently than other polyesters. The fibre is got through poly condensation of PTA (purified terephthalic acid) and PDO (1, 3 propanediol), which is chemically obtained by the Shell Group and that is biochemically obtained by DuPont. The unique properties of PTT have been known for many years but the polymer has not been commercially available because of the high cost of production of the PDO raw material. Extensive research effort by Shell Chemicals has resulted in a cost-effective process to manufacture PDO. With this breakthrough in processing technology for PDO, PTT are now commercially available for use in carpet fibre, textile fibre, monofilament, film, non-woven fabric, and engineering thermoplastic applications. PTT is a futuristic synthetic fibre with its unique spring-like molecular structure possessing the favourable properties of both polyester and nylon, while having its own stretchiness. It is also readily compatible with natural and synthetic fibres thanks to its unique soft texture.
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nylon and comparable to Type 6, 6 nylon when subjected to a wide range of tests including high concentrations of ozone, nitrogen dioxide, and light and sun fading. PTT is oleophilic, and performs similarly to polyester PET and olefin, and it easily removes oily spots and soils (petroleum, animal, vegetable) using dry solvent spotters and cleaning additives (e.g., propylene glycol). PTTs hand, while a somewhat subjective evaluation, is achieved by the polymer itself, and is noticeably softer than polyester, and comparable to nylon fibre.
PTT Tensile strength (Cn/Dtex) Elongation at break (per cent) Initial youngs modulus (Cn/Dtex) Tensile recovery from 20 per cent elongation (per cent) Specific gravity Moisture regain (per cent) Boil shrinkage (per cent) Melting point ( C) Glass transition point ( C) Weathering resistance 3.4 3.7 36 42 23 88 1.34 0.4 14 230 51 Negligible loss of strength
Nylon 6,6 4.1 4.5 32 44 31 62 1.14 4.5 13 253 76 Moderate loss of strength, yellowing under some conditions Yellowing under some conditions
Yellowing resistance
Negligible yellowing
Negligible yellowing
Negligible yellowing
Nylon (staple)
Olefin (filament)
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Carpet fibre characteristics Resiliency determined by fibre structure and modifications Abrasion resistance determined by fibre and density of face fibre the more tightly packed the yarns, the more resistant to wear Soil and stain resistance/
Nylon Excellent
Excellent
Excellent
Excellent
Good to
Good to excellent
Excellent
clean ability determined excellent by colour, texture dyes, fibre structure and modifications Resistance to sunlight determined by fibre structure & modifications Poor-if protected from ultraviolet rays, degradation does not occur as rapidly Static determined by fibre structure and modifications Hand feel Builds up in low humidity unless modified Warm, soft
Loses strength and deteriorates unless chemically modified to resist sunlight damage Builds up in low humidity but at a lower level than nylon or polyester Waxy, soft
Excellent
Good-may weaken with prolonged exposure Builds up in low humidity unless modified Varies -finer deniers are soft and silky Excellent
Builds up in low humidity unless modified Varies from warm and soft to cold and coarse Fibre may be modified Burns slowly, melts in direct flame; self-extinguishing. Structure may alter what occurs. Celery-like odour
Resistance to mildew determined by fibre structure & modifications Flammability determined by fibre structure, modification, construction methods, dyes, padding and carpet installation methods
Poor if damp or soiled Burns slowly indirect flame; considered selfextinguishing. Burning hair odour
Excellent
Excellent
Melts at low Burns slowly, temperatures (170 C); melts; some are burns and emits heavy, sooty, waxy smoke. Paraffin wax odour. Pulling a heavy ojbect across the carpet surface can cause enough friction to melt the carpet fibres
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PET structure
PTT structure
PPT fibres can be used in apparel as well as home furnishing. In apparel it can be used in casual, swimwear, active wear and innerwear and on the other hand in home furnishing carpets, draperies, sheets and pillow cases, wall coverings and upholstery can be made by PTT fibres. However, PTT fibres are best to manufacture the carpets. Carpets made with PTT fibres offer a breakthrough in the combination of stain resistance and durability. They have nylon-like wear performance without the need for chemical stain treatments and complicated cleaning procedures. Most stains, including mustard, iodine and hot coffee, can be removed with hot water and are dry within a few hours. Moreover, PTT fibre's stain resistance offers an ease of maintenance and reduced need for replacement.
The mantra of Performance PLUS environmental benefits is evident for PTT fibre in carpet applications. In todays competitive environment, beauty is simply not enough. Designers, architects, and facility managers demand more in terms of performance, environment and value when it comes to products. Todays market demands beauty, performance and sustainable solutions. PTT fibre in commercial carpet applications provides what designers, architects and managers are looking for
By Vasant R Kothari, Assistant Professor, NIFT, Bangalore (Author can be contacted @ www.vasantkothari.com)
Conclusion
The PTT fibre is considered to be the most important fibre of the after-polyester period. It is the first significant new material in the textile and carpet industry for some time. Fabrics made with PTT fibres have great appeal in the fast-growing stretch market. It provides manufacturers with a wider range of options for new products than they have now. At this point, PTT does not hold a significant carpet market share; however, promotion by major industry players, such as Mohawk, Shaw and DuPont, may change that. As far as long-term performance is concerned, no other fibre can beat PPT.
HOME TEXTILE VIEWS / OCTOBER-DECEMBER 2011
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