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in Page 1

WORKSHEET - 1
1. Which of the following statement/s is/are true?
a) A solution is a homogeneous mixture of one or more components.
b) The major component of a solution is known as solvent. The minor component of
a solution is known as solute.
c) In syrup, sugar is the solute and water is the solvent.
d) In brine, salt is the solute and water is the solvent.
2. An example for a gas in liquid type of solution is
a) Soda water b) milk c) Alloy d) Air
3. An example for a liquid in gas type of solution is
a) Soda water b) milk c) Fog d) Smoke
4. (i) Which type of solution is milk?
(ii) Name a solid - solid type solution.
(iii) Which type of solution is smoke?


5. Solution-A: A solution which can dissolve some more solute at a given
temperature is known as an unsaturated solution.
Solution-B: A solution which cannot dissolve any more solute at a given
temperature is known as a saturated solution.
Solution-C: A solution which has excess of solute dissolved in it than can be
present in a saturated solution is known as a super saturated
solution.

6. If a saturated solution is heated, it
a) changes to unsaturated b) changes super saturated
c) remains same
d) till 50C, changes to un saturated and then super saturated
7. How can you obtain a saturated solution from an unsaturated solution?
a) By heating b) By cooling
c) By increasing the pressure d) By decreasing the pressure
(i) (ii) (iii)
a) Liquid in solid Atmosphere Gas in liquid
b) Liquid in gas Alloys Liquid in solid
c) Liquid in liquid Rubber Solid in gas
d) Gas in liquid Rubber Liquid in liquid

Solution A Solution - B Solution - C
a) Saturated Unsaturated Super saturated
b) Unsaturated Saturated Super saturated
c) Super saturated Unsaturated Saturated
d) Saturated Super saturated Unsaturated

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8. How can you obtain a saturated solution from a super saturated solution?
a) By heating b) By cooling
c) By disturbing d) By adding a crystal of the solute
9. What happens when some amount of solute is added to a saturated solution?
a) changes to unsaturated b) changes super saturated
c) remains same
d) till 50C, changes to un saturated and then super saturated
10. In which type of solution, a dynamic equilibrium exists between the solid solute and
dissolved solute?
a) Saturated b) Unsaturated
c) Super saturated d) None
11. Match the following :
Column - I Column - II
a) Soda water i) gas in gas
b) H
2
in platinum ii) liquid in liquid
c) Air iii) solid in solid
d) fog iv) gas in solid
e) milk v) gas in liquid
f) cheese vi) solid in liquid
g) smoke vii) solid in gas
h) ink viii) liquid in solid
i) alloy ix) liquid in gas
12. There are three types of solutions
Solution - A :- The density of it increases on addition of some solute.
Solution - B :- The density of it decreases on addition of some solute.
Solution - C :- The density remains unchanged on addition of some solute.
Identify which of the above three are saturated, unsaturated and supersaturated.
Q No: 1 2 3 4 5 6 7 8 9 10
All a c c b a b c,d c a
WORKSHEET - 2
1. 5g of a salt dissolved in 20g of water to form a saturated solution at 60
0
C. Calculate the
solubility of the salt at this temperature.
a) 100 b) 75 c) 50 d) 50
2. When 100g of a saturated solution is evaporated at 50
0
C, 50g of solid is left over. Find
the solubility of the substance at 50
0
C.
a) 100 b) 200 c) 300 d) 400
3. A hot solution contains 5g of a substance in 15g of water, at 35
0
C. What is the solubility
of the substance at this temperature?
a) 33.32 b) 66.66 c) 33.34 d) 16.67

www.olympiaus.in Page S

4. The solubility of salt at 30

0
C is 50. Calculate the weight of water required to prepare a
saturated solution containing 90g of salt.
a) 360g b) 180g c) 90g d) 45g
5. The solubility of a substance in water is 40. What is the maximum amount of solute
required to prepare a saturated solution with 50g of water?
a) 65g b) 50g c) 35g d) 20g
6. Solubility of a substance in a solvent is x. What is the minimum weight of solution
containing y g of solute?
a) b) c) d)
7. Solubility of a substance in a solvent is K. What is the minimum weight of the solvent
which can dissolve L g of solute, to give a saturated solution? [L-II]
a) b) c) d)
8. Solubility of a solute is 25. Minimum weight of solvent required to dissolve 10g of that
solute is _________.
a) 90g b) 65g c) 40g d) 15g
9. Solubility of a solid at 30
0
C is 30 and at 80
0
C is 50. If a saturated solution is made with
50g of solvent at 80
0
C and cooled to 30
0
C, the weight of solute that comes out of the
solution is _________.
a) 30g b) 20g c) 10g d) 5g
10. Solubility of the salt at 40
0
C is 40. The least weight of water which dissolves 10 grams of
substance is __________.
a) 25g b) 36g c) 47g d) 58g
11. 30 grams of saturated solution on evaporation gives a residue of 5 grams of solute.
Solubility of solute is ____________.
a) 40 b) 30 c) 20 d) 10
12. Solubility of a substance remains unchanged on heating or cooling. Plot its solubility
curve.



x(100 y)
gm
y
+


y(100 x)
gm
x
+


y(100 x)
gm
y
+


x(100 y)
gm
x
+


100 K
g
L



100 L
g
K



K
g
100 L

L
g
K 100

S
o
l
u
b
i
l
i
t
y
Temperature
a)
S
o
l
u
b
i
l
i
t
y
S
o
l
u
b
i
l
i
t
y
S
o
l
u
b
i
l
i
t
y
Temperature Temperature Temperature
b) c) d)

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13. On cooling, solubility of a substance decreases. Identify its solubility curve.

14. (i) Cooling favours the solubility of exothermic solutions. True or false?
We know that solubility of exothermic solutions decreases on increase of
temperature (heating). Therefore the given statement is true.
(ii) Heating favours the solubility of endothermic solutions. True or false?
We know that solubility increases with increase of temperature (heating). Therefore
the given statement is true.
(i) (ii)
a) T F
b) F T
c) T T
d) F F




WORKSHEET - 3
1. The graphs which indicate the effect of temperature on solubility of a solute
are called solubility curves.
a) Isothermic curves b) Isobaric curves c) solubility curve d) Isochoric curves
2. The solutions that are formed by the absorption of heat from the surroundings
are known as
a) Neutral solution b) Thermal solutions
c) Exothermic solutions d) Endothermic solutions
3. Which of the following forms endothermic solutions?
a)NaNO
3
b) NaOH c) Na
2
CO
3
d) Na
2
SO
4
.
4. The solutions that are formed by the evolution of heat to the surroundings are
known as
a) Neutral solution b) Thermal solutions
c) Exothermic solutions d) Endothermic solutions
5. Which of the following form exothermic solutions?
a)NaNO
3
b) NaOH c) Na
2
CO
3
d) Na
2
SO
4

a) b) c) d)
Q.No. 1 2 3 4 5 6 7 8 9 10
Ans
d a c b d b b c b a
Q.No. 11 12 13 14
Ans
c a c c
Key to Worksheet - 2

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6. (i) What is the nature of solution, if lattice energy is greater than hydration energy?
(ii) What is the nature of solution, if lattice energy is less than hydration energy?
(i) (ii)
a) Endothermic Endothermic
b) Exothermic Exothermic
c) Endothermic Exothermic
d) Exothermic Endothermic
7. Name some solutes whose solubility increases with increase in temperature.
a)NaNO
3
b) KNO
3
c) KCl d) NH
4
Cl.
8. Name some solutes whose solubility decreases with increase in temperature.
a) NaOH b) Na
2
CO
3
c) Na
2
SO
4
d) All
9. Name some solutes whose solubility fairy change or does not change with increase in
temperature.
a) NaOH b) Na
2
CO
3
c) NaCl

d)Li
2
SO
4

10. Solubility of a gas in liquid decreases with increase of temperature or
decrease of pressure. This is called
a) Boyles law b) Charles
c) Henrys law

d)Daltons law of solutions
11. Write the effect of temperature on the solubility of following solutions :
Solute A :- During its dissolution, it liberates heat to the surroundings.
Solute B :- During its dissolution, it absorbs heat from the surroundings.
Solute C :- During its dissolution, no heat exchange takes place with the
surroundings.
12. What are solubility curves and what is their utility ?
13. State Henry's law. To what kind of gases it is applicable.
14. What is the effect of temperature on the solubility of a gas in a liquid at
constant pressure ?
15. Solubility of a solid in a liquid decreases with increase of pressure. True /
False.
16. NaCl is soluble in water whereas naphthalene is not. Explain.
17. Why ethyl alcohol, Glucose being non-polar dissolve in water ?







Q.No. 1 2 3 4 5 6 7 8 9 10
Ans
c d a c b, c, d c All d c, d c
Key to Worksheet - 3

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WORKSHEET - 4
1. 10 grams of NaOH is dissolved in 100 grams of water at 25C to form a saturated
solution. Find the solubility and weight percentage of the solution.
Solubility Weight
a) 10 9.09
b) 20 18.18
c) 9.09 10
d) 18.18 20
2. A research student has only 300 g of valuable solvent and wishes to make solution of
10% by weight from solute A. How many grams of A is weighed out?
a) 30g b) 33.33g c) 70g d) 66.66g
3. A solution with weight percentage of sodium hydroxide of 6% is prepared by adding the
following mass of water (in grams) to 200 grams of that solution with a weight percent of
NaOH of 30%
a) 300 g b) 500 g c) 800 g d) 1000 g
4. If solubility of a solute is S, find its percentage by weight.
a) b) c) d)
5. If percentage by weight of a solute is its solubility, find the solubility of the solute.
a) 25 b) 50 c) 75 d) 100
6. If 50 ml of a liquid solute is dissolved in 500 ml of liquid solvent, then find its % by
volume (v/v).
a) 6.06 b) 7.07 c) 8.08 d) 9.09
7. Calculate the volume of solvent required to prepare 20 % by volume (v/v) solution by
using 70 ml of H
2
SO
4
.
a) 280 ml b) 560 ml c) 1120 ml d) 2240 ml
8. 10 g of a solute is dissolved in 90 g of solvent. If the density of solution is 2g/ml, find
the weight-volume percentage.
a) 5 g/ml b) 10 g/ml c) 15 g/ml d) 20 g/ml
9. Find the following in 15% (w/v) of solution if the density of solution is 1.06 g/ml.
a) Weight of solute b) Weight of solvent
Weight of solute Weight of solvent
a) 25 g 75 g
b) 50 g 50 g
c) 15 g 91 g
d) 20 g 90 g
10. An aqueous solution of glucose is 10% (w/v). The volume in which 1 g mole of it is
dissolved will be______. (Formula of glucose is C
6
H
12
O
6
)
a) 450 ml b) 900 ml c) 1800 ml d) 3600 ml
11. Calculate the mass percentage of K
2
CO
3
in a solution that is made by dissolving 15g of
K
2
CO
3
in 60g of H
2
O.
a) 10 b) 20 c) 30 d) 40
100S
100 S +
100 S
100S
+
2
100S
100 S +
2
(100 S)
100S
+

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12. How many grams of NaCl have to be dissolved in 54.0g of H

2
O to give a 10.0% weight
solution?
a) 3 g b) 6 g c) 9 g d) 18 g
13. If the solubility of a solute in a solution is 50, find the percentage by weight of the
solution.
a) 33.33 b) 66.66 c) 25 d) 75
14. If 2.2 g of oxalic acid is dissolved in 500 ml of solution (density = 1.1 g/ml), what is the
weight percent of oxalic acid in solution?
a) 0.1 b) 0.2 c) 0.3 d) 0.4
15. Calculate the masses of glucose and water required to prepare 180 g of 18% (w/w)
glucose solution.
Mass of water Mass of glucose
a) 147.6 g 32.4 g
b) 295.2 g 64.8 g
c) 442.8 g 97.2 g
d) 590.4 g 129.6 g




WORKSHEET - 5
1. 1.06 g of Na
2
CO
3
is present in 100 litres of solution. Find the molarity of the solution.
a) 10
2
M b) 10
4
M c) 10
1
M d) 10
3
M
2. Claculate the molarity of H
2
O in pure water.
a) 27.75 moles/lit b) 55.5 moles/lit c) 111 moles/lit d) 13.5moles/lit
3. Mass of a solution is m g. Its density is d g/ml. Find molarity if the amount of solute
present is p g. [Molecular weight = W].
a) b) c) d) moles/lit
4. Find the number of millimoles of KCl present in 3 litres of 2 molar solution.
a) 6 10
3
b) 0.6 10
3
c) 6 10
2
d) 6 10
4

5. 1.2 moles of CaCl
2
is dissolved in enough water to make 2 litres of solution. Calculate
the concentration of each of ions present in that solution.
a) 12 mole/lit b) 0.12 mole/lit c) 0.012 mole/lit d) 1.2 mole/lit
Q.No. 1 2 3 4 5 6 7 8 9 10
Ans
a b c a d d a d c c
Q.No. 11 12 13 14 15
Ans
b b a d a
Key to Worksheet - 4
Pd
moles/lit
mW
mW
moles/lit
Pb
Pb
1000moles/lit
mW

www.olympiaus.in Page 8

6. How many milligrams of barium and chloride ions are there in a millitre of 2M barium
chloride, BaCl
2
solution? (Atomic weight of Ba = 137.4 and Cl = 35.5)
a) 14.2 mg b) 142 mg c) 71 mg d) 7.1 mg
7. The number of sulphur atoms present in 100 ml of 0.1 M H
2
SO
4
is_________.
a) 1.505 10
23
b) 15.05 10
23
c) 15.05 10
24
d) 1.05 10
23

8. Find the number of molecules of NaOH present in 0.5 M, 500 ml solution.
a) 6.023 10
23
b) 6.023 10
24
c) 6.023 10
21
d) 6.023 10
26

9. A concentrated acids is 38% pure by weight in aqueous solution. The density of the
solution is 1.855 g/ml and molarity is 7.19 mol/litre. Identify the acid.
a) 90 grams b) 94.03 grams c) 92 grams d) 98.03 grams
10. Calculate molarity of solution of H
2
SO
4
(density of solution is 2g/ml) containing 27%
H
2
SO
4
by weight.
a) 42 M b) 04.2 M c) 5.5 M d) 55 M
11. The molarity of 4% (w/v) NaOH solution is___________
a) 2 M b) 0.2 M c) 1 M d) 0.1 M
12. Consider a solution of volume, V
1
whose molarity is M
1
, It is diluted by adding some
amount of water. The molarity of the solution after addition of water is M
2
(V
2
> V
1
;

M
2
<
M
1
). Calculate the volume or the amount of water added.
a) b) c) d)
13. Calculate the final concentration of NaCl after 1.5 litres of 0.100M NaCl solution is
diluted
a) to 3.5 litres with water b) with 3.5 litres of water
a) 0.214, 0.714 M b) 0.5M, 0.7 M
c) 0.414 M, 0.614 M d) 0.0314 M, 0.414 M
14. Find the molarity of a mixed solution formed by adding 250 ml of 0.2M NaOH solution
and 100 ml of 0.5M NaOH solution.
a) 0.845 M b) 0.585 M c) 0.285 M d) 0.485 M
15. 250 ml of 6M HCl, 650 ml of 3 M HCl were mixed together. The volume of water to be
added to make the solution 3 M is __________ml.
a) 150 ml b) 200 ml c) 125 ml d) 250 ml



1
1
2
M
V 1
M

2
1
1
M
V 1
M

1
2
2
M
V 1
M

2
1
M2
V 1
M

Q.No. 1 2 3 4 5 6 7 8 9 10
Ans
b b c a d b c a d c
Q.No. 11 12 13 14 15
Ans
c a a c d
Key to Worksheet - 5

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WORKSHEET - 6
1. The chloride of a metal (M) contains 65.5% of chlorine. 100ml of the vapour of the
chloride of the metal at S.T.P. weighs 0.72g. The molecular formula of the metal
chloride is:
a) MCl b) MCl
2
c) MCl
3
d) MCl
4

2. The oxide of an element possesses the formula M
2
O
3
. If the equivalent weight of the
metal is 9, then the atomic weight of the metal will be:
a) 9 b) 18 c) 27 d) none of these
3. If m
1
gram of a metal A displaces m
2
gram of another metal B from its salt solution and
if the equivalent weights are E
1
and E
2
respectively then, which of the following is true?
a) E
1
= b) E
1
= c) E
1
= d) E
1
=
4. One gram of hydrogen is found to combine with 80 g of bromine. One gram of calcium
(valency = 2) combines with 4 g of bromine. The equivalent weight of calcium is:
a) 10 b)

20 c) 30 d) 40
5. 1.520g of the hydroxide of a metal on ignition gave 0.995 g of oxide. The equivalent
weight of metal is:
a) 36.0 b) 27.0 c) 19.0 d) 9.0
6. One litre of hard water contains 12.00 mg Mg
2+
. Milli-equivalents of washing soda
required to remove its hardness is:
a) 1 b) 2 c) 3 d) 4
7. A metal oxide has the formula Z
2
O
3
. It can be reduced by hydrogen to give free metal and
water. 0.1596 g of the metal oxide requires 6 mg of hydrogen for complete reduction.
The atomic weight of the metal is:
a) 27.9 b) 34.3 c) 49.8 d) 55.8
8. In the reaction 2Na
2
S
2
O
3
+ I
2
Na
2
S
4
O
6
+ 2NaI.
The equivalent weight of Na
2
S
2
O
3
(mol. wt = M) is equal to:[At. wt. of iodine = 127]
a) M b) M/2 c) M/3 d) M/4
9. If the equivalent weight of a trivalent metal is 32.7, the molecular weight of its chloride
is:
a) 68.2 b) 103.7 c) 204.6 d) 232.7
10. When a metal is burnt, its weight is increased by 24 percent. The equivalent weight of
the metal will be:
a) 20 b) 24 c) 33.3 d) 76
11. The specific heat of a metal is 0.11 and its equivalent weight is 18.61. Its exact atomic
weight is:
a) 58.2 b) 29.1 c) 55.83 d) 27.91
12. The vapour density of a volatile chloride of a metal is 95 and the specific heat of the
metal is 0.13. The equivalent weight of the metal will be approximately:
a) 6 b) 12 c) 18 d) 24

1
2
2
m
E
m

2 2
1
m E
m

1 2
2
m m
E

1
2
2
m
E
m

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13. 0.84 g carbonate of a metal M gave on heating 0.40 g metal oxide. The specific heat of
the metal is 0.25. The atomic weight of the metal would be:
a) 12 b) 24 c) 36 d) 48
14. 1.5 g of a divalent metal displaced 4 g of copper (at. wt. = 64) from a solution of copper
sulphate. The atomic weight of the metal is:
a) 12 b) 24 c) 48 d) 56
15. 12g of an alkaline earth metal gave 14.8 g of its nitride. Atomic weight of that metal is:
a) 20 b) 12 c) 40 d) 14.8
16. 3g of an oxide of a metal is converted to chloride completely and it yielded 5 g of
chloride. The equivalent weight of the metal is:
a) 33.25 b) 28.52 c) 20.32 d) 18.5

Q No:1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
C c a b d a d a c c c b b b c a

WORKSHEET - 7
1. What is the normality of solution containing 35g of KOH dissolved in sufficient water to
make 400 ml solution?
a) 1.56 N b) 2.34 N c) 3.02 N d) 4.54 N
2. Calculate the normality of aqueous solution containing 31.5g of oxalic acid in 2.5 litres
solutions. [Mol. wt. of oxalic acid = 126]
a) 0.2 N b) 0.1 N c) 0.05 N d) 0.025 N
3. Which amongst the following has the highest normality?]
a) 8.0 g of KOH per 100 ml solution b) 6 g of NaOH per 100g of water
c) 1 N H
3
PO
4
d) 24.5 g of H
2
SO
4
in 1 litre solution
4. 0.1 N solution of a dibasic acid solution contains 6.3 g of the acid per 1000 ml or
solution. Calculate the equivalent weight of the acid.
a) 63 b) 54 c) 48 d) 36
5. Find the number of gram equivalents of solute present in 0.2 N, 250 ml solution.
a) 0.25 b) 0.05 c) 0.025 d) 0.015
6. Calculate the number of milli equivalents of solute present in 1500 ml of 0.2 N aqueous
urea solution.
a) 400 b) 350 c) 300 d) 250
7. How many grams of KMnO
4
would be required to prepare 2500 ml of 0.01 N solution,
based on the following reaction? [Mol. wt of KMnO
4
= 158]
a) 0.90 g b) 0.79 g c) 0.64 g d) 0.58 g
8. How many grams of a dibasic acid (Mol. wt. = 200) should be present in 100 ml of its
aqueous solution to give decinormal strength?
a) 2 g b) 1 g c) 0.5 g d) 0.25 g

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9. How many milligrams of aluminium and chloride ions are present in a millilitre of 2N
aluminium chloride, AlCl
3
solution?
Al
+3
Cl

a) 910
3
mg 106.510
3
mg
b) 1810
3
mg 7110
3
mg
c) 1810
3
mg 35.510
3
mg
d) 2710
3
mg 35.510
3
mg
10. Find the number of Al
+3
and ions present in 500 ml of 0.5 N Al
2
(SO
4
)
3
solution.
Al
+3
SO
4
2

a) 5.20210
22
7.22710
22

b) 4.81810
22
7.22710
22

c) 4.81810
22
5.23010
22

d) 2.32410
22
3.02310
22

11. How many number of nitrogen atoms are present in 100 ml of 0.1 N HNO
3
?
a) 12.04410
21
b) 6.02310
23
c) 6.02310
21
d) 3.01110
22

12. Find the number of molecules of Al(OH)
3
present in 0.5 N, 500 ml solution.
a) 5.02310
22
b) 4.81810
22
c) 3.62010
22
d) 2.31810
22

13. If a solution of H
2
SO
4
contains 3.0115 10
23
atoms of sulphur in 500 ml of solution, find
its normality?
a) 2.5 N b) 2 N c) 1 N d) 0.5 N
14. What is the molarity of 2N Na
2
SO
4
solution?
a) 2 M b) 1 M c) 0.5 M d) 0.25 M
15. Calculate the molarity and normality of a solution containing 0.5g of NaOH dissolved in
500 ml of the solution.
a) 0.025 M, 0.025 N b) 0.025 M, 0.05 N
c) 0.05 M, 0.075 N d) 0.025 M, 0.075 N
16. Express the concentration of a 5 percent phosphoric acid (w/v) solution having a
density of 1.027 g/ml in terms of molarity and normality.
Molarity Normality
a) 0.712 M 3.12 N
b) 0.635 M 2.34 N
c) 0.524 M 1.57 N
d) 0.460 M 0.85 N
17. The density of a solution containing 13% by mass of sulphuric acid is 1.09% g/ml.
Calculate the molarity and normality of the solution.
Molarity Normality
a) 1.326 M 3.10 N
b) 1.445 M 2.89 N
c) 2.132 M 1.52 N
d) 3.214 M 2.89 N

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18. What percent by weight of NaOH is present in a 4N NaOH solution having density of 1.15
g/ml?
a) 14.5 % b) 13.9% c) 12.2 % d) 1.6%
Q No:1.a 2.a 3.c 4.a 5.b 6.c 7.b 8.b 9.b 10.b 11.c 12.b 13.b
14.b 15.a 16.c 17.b 18.b
Worksheet - 8
1. How much MgCl
2
would be needed to make 250 ml of a solution having same
concentrations of Cl

as the one containing 3.78 g of NaCl per 100 ml?

a) 8.743 g b) 7.672 g c) 6.321 g d) 5.402 g
2. Upon heating a litre of N/2 HCl solution, 2.675 g of Hydrogen chloride is lost and the
volume of the solution shrinks to 750 ml. Calculate
(i) The normality of the resultant solution, and
(ii) The number of milli equivalents of HCl in 100 ml of the original solution.
(i) (ii)
a) 0.43 N 30 m.eq
b) 0.51 N 40 m.eq
c) 0.57 N 50 m.eq
d) 0.63 N 60 m.eq
3. How many millilitres of 0.2 N HCl solution will be required to react completely with 50
ml of 0.25 N NaOH?
a) 38.6 ml b) 43.5 ml c) 58.2 ml d) 62.5 ml
4. What is the strength in gram per litre of H
2
SO
4
solution of volume 12 ml of which
neutralised with 15 ml of 0.1 N NaOH solution?
a) 6.125 g/lit b) 5.435 g/lit

c) 4.822 g/lit d) 3.684 g/lit
5. Calculate the amount of KOH required to neutralise 15 Meq. of each of the following:
a) HCl b) KHSO
4
c) N
2
O
5
d) CO
2

a) 0.69 g b) 0.71 g c) 0.84 g d) 0.92 g
6. A standard solution of NaOH contains 45g of NaOH in 800 ml of solution. During
titration, 24.6 ml of the standard alkali solution is required to neutralise 36.4 ml of an
unknown solution of sulphuric acid.
i) Calculate the normality of the acid solution.
ii) What weight of sulphuric acid is present in 250 ml of the acid solution?
(i) (ii)
a) 0.636 N 8.61 g
b) 0.741 N 9.24 g
c) 0.828 N 10.01 g
d) 0.946 N 11.59 g
7. How much volume (in ml) of 0.2 N H
2
SO
4
can be made by diluting 20 ml of 0.5 N acid
with water?
a) 43 ml b) 50 ml c) 64 ml d) 70 ml
8. Calculate the normality of the resulting solution made by adding 2 drops (0.1 ml) of 0.1
N H
2
SO
4
in distilled water to make it 1 litre solution:
a) 10
3
N b) 10
4
N c) 10
5
N d) 10
6
N

www.olympiaus.in Page 1S

9. A piece of Al weighing 2.7 g is titrated with 75.0 ml of H

2
SO
4
(Density 1.18 g ml
1
and
24.7% H
2
SO
4
by weight). After the metal is completely dissolved, the solution is diluted
to 400 ml. Calculate the molarity of free H
2
SO
4
in solution.
a) 6.15 g b) 7.15 g c) 8.15 g d) 9.15 g
10. 200 ml of 0.1 M HCl and 150 ml of 0.3 M H
2
SO
4
solutions are mixed. Calculate the
normality of the resulting mixture.
a) 0.288 N b) 0.314 N c) 0.412 N d) 0.560 N
11. Hydrochloric acid solutions A and B have concentration of 0.5 N and 0.1 N respectively.
The volumes of solutions A and B required to make 2 litres of 0.2 N HCl are
a) 0.5 litre of A + 1.5 litres of B b) 1.5 litres of A + 0.5 litre of B
c) 1 litre of A + 1 litre of B d) 0.75 litre of A + 1.25 litres of B
12. 100 ml of 0.2 M HCl and 200 ml of 0.15 M H
2
SO
4
are mixed. Calculate the proton
concentration of the mixture.
[Note : The proton concentration of resulting solution is equal to the normality of the
resulting solution.]
a) 0.267 N b) 0.314 N c) 0.483 N d) 0.512 N
13. 100 ml of 0.2 N KOH solution is mixed with 100 ml of 0.1 M H
2
SO
4
solution. What is the
normality of resulting solution?
a) 3 N b) 2 N c) 1 N d) 0 N
14. 100 ml of 0.2 N NaOH solution is mixed with 100 ml of 0.1 N HCl solution. What is the
nature and normality of the resulting solution?
a) Acidic, 0.1 N b) Basic, 0.05 N c) Acidic, 0.025 N d) Basic, 0.20 N
15. What is the nature and normality of the resulting solution obtained by mixing?
i) 100 ml of 0.1 N HCl and 50 ml of 0.25 N NaOH
ii) 1 equivalent of 50 ml NaOH and 100 ml of 0.1 N HCl
(i) (ii)
a) Acidic, 0.0135 N Basic, 0.03 N
b) Basic, 0.0149 N Acidic, 0.04 N
c) Acidic, 0.0153 N Basic, 0.05 N
d) Basic, 0.0167 N Acidic, 0.06 N
Q No:1.b 2.c 3.d 4.a 5.c 6.d 7.b 8.c 9.b 10.b 11.a 12.a 13.d 14.b
15.d
WORKSHEET - 9
1. Which one of the following is most concentrated solution among the following for the
same solute?
a) 1M b) 1m c) 1 N d) All have same strength
2. 500 g of water and 0.46 g of ethanol are added to form a solution. Find its molality.
a) 0.02 moles/kg b) 0.2 moles/kg c) 0.01 moles/kg d) 0.1 moles/kg
3. 100 ml solution of Na
2
CO
3
is prepared by dissolving 8.653 g of salt in water. The density
of the solution is 1.0816 g/ml. What is the molality of the solution?
a) 0.9 moles/kg b) 0.41 moles/kg c) 0.82 moles/kg d) 0.4 moles/kg

www.olympiaus.in Page 14

4. The molality of 100 ml of solution of NaOH prepared by dissolving 0.4 g of it in water is

2 molal. Find the density of solution.
a) 0.027 g/ml b) 0.0135 g/ml c) 0.108 g/ml d) 0.054 g/ml
5. A solution of ethanol in water is 1.54 molal. How many grams of it are there in 2500 g of
the solvent? (Mol. wt. of ethanol = 46).
a) 177.1 g b) 88.5 g c) 35.42 g d) 24.27 g
6. 2.45 g of H
2
SO
4
is used to prepare 0.1 molal aqueous solution. Calculate the amount of
water.
a) 250 g b) 125 g c) 62.5 g d) 31. 25 g
7. Solubility of a substance is 100. If the molecular weight of the substance is 100, then,
find its molality.
a) 15 moles/kg b) 10 moles/kg c) 5 moles/kg d) 2.5 moles/kg
8. The molality of a solution is m moles/kg. If the solute is NaOH, how much amount of
NaOH is present in 100 g of solvent?
a) 1m g b) 2m g c) 4m g d) 8m g
9. Calculate the molality of 10 percent (by weight) solution of Ca(NO
3
)
2
.
a) 0.3385 mole/kg b) 0.677 mole/kg c) 0.169 mole/kg d) 1.3 mole/kg
10. What would be the molality of a solution made by mixing equal volumes of 30% by mass
of H
2
SO
4
(density 1.218 g cm
3
) and 70% by mass of H
2
SO
4
(density 1.610 g cm
3
)?
a) 22.8 moles/kg b) 5.7 moles/kg c) 2.5 moles/kg d) 11.4 moles/kg
11. The molality of a solution containing sulphuric acid is 1.52 molal. Find its solubility and
weight percentage.
Solubility Weight percentage
a) 29.997 16.586
b) 14.896 12.964
c) 7.4480 10.744
d) 3.7240 8.372
12. Calculate the molality of 1 litre solution of 93% (w/v) H
2
SO
4
. The density of solution is
1.84 g/ml.
a) 20.84 moles/kg b) 10.42 moles/kg c) 5.21 moles/kg d) 2.60 moles/kg
13. The molality of a solution of 90% (w/v) is 20.45, if the density of solution is
2 g/ml, the solute present in the solution is:
a) H
2
SO
4
b) Na
2
CO
3
c) HCl d) NaOH
14. The density of 3 M H
2
SO
4
solution is 1.84 g/ml. Find its molality.
a) 3.88 moles/kg b) 2.60 moles/kg c) 1.94 moles/kg d) 0.97 mole/kg
15. The density of 3M solution of sodium thio sulphate (Na
2
S
2
O
3
) is 1.25 g/ml. Calculate the
molality of Na
+
and ions respectively:
Na
+

a) 7.731moles/kg 3.865 moles/kg
b) 3.865 moles/kg 3.865 moles/kg
c) 3.865 moles/kg 7.731moles/kg
d) 1.9325 moles/kg 3.865 moles/kg

www.olympiaus.in Page 1S

16. 8.0575 10
2
kg of Glaubers salt ( Na
2
SO
4
.10H
2
O) is dissolved in water to obtain
1 litre of solution of density 1.0772 kg/m
3
. Calculate its molarity and molality.
Molarity Molality
a) 0.125 mole/lit 1.5 moles/kg
b) 0.5 mole/lit 1 mole/kg
c) 1 mole/lit 0.5 mole/kg
d) 0.25 mole/lit 0.25 mole/kg
17. x g of solute is mixed with a solvent to get y ml of solution. If molarity of the solution
is M and molality of solute is m, find the density of the solution.
a) b) c) d)
18. A 1000 ml solution contains 410.3 g of H
2
SO
4
at 20C. If the density of the solution is
1.243 g/ml, finds its molarity and molality?
Molarity Molality
a) 5.028 moles/lit 4.187 moles/kg
b) 2.09 moles/lit 2.40 moles/kg
c) 2.40 moles/lit 2.09 moles/kg
d) 4.187 moles/lit 5.028 moles/kg
Q No:1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
B a c d a a b c b d b b d c a d a d
WORKSHEET - 10
1. 180 g of water is taken in a beaker and 196 g of H
2
SO
4
is added to it. Find the mole fraction of H
2
SO
4
.
a) b) c) d)
2. A solution contains 25% water, 25% ethanol (C
2
H
5
OH) and 50% acetic acid (CH
3
COOH) by
mass. Calculate the mole fraction of each component:
Water Ethanol Acetic acid
a) 0.414 0.097 0.489
b) 0.502 0.196 0.301
c) 0.502 0.169 0.329
d) 0.414 0.147 0.439
3. A gaseous mixture contains equal weights of nitrogen and ethylene (C
2
H
4
) at certain temperature
and pressure. What is the ratio of the mole fractions of nitrogen and ethylene in the gas
mixture?
a) 1 : 4 b) 1 : 3 c) 1 : 2 d) 1 : 1
4. Mole fraction of NaCl in aqueous solution containing 5.85 g of it is 0.25. Find the
number of molecules of water present in the solution.
a) 2.769 10
23
b) 1.806 10
23
c) 0.95610
23
d) 0.36510
23

5. Mole fraction of urea is 0.25. Given solution contains 120 g of urea (Mol. wt = 60). The
weight of water in the solution is _________.
a) 108 g b) 120 g c) 148 g d) 180 g

mx My
my
+ y
mxy My +
my
mx My +
My
mx My +
1
3
1
4
1
5
1
6

www.olympiaus.in Page 16

6. The mole fraction of an acid of solubility 10 in its aqueous solution is 0.018. Calculate
the molecular weight.
a) 66 b) 78 c) 84 d) 99
7. The solubility of C
6
H
6
is 15. If the solvent is carbon tetrachloride (CCl
4
), find the
mole fraction of solute and solvent.
Solute Solvent
a) 0.23 0.77
b) 0.36 0.64
c) 0.42 0.58
d) 0.51 0.49
8. Calculate the mole fraction of ethanol and water in a sample of rectified spirit which
contains 95 percent of ethanol by weight.(Gram mol. wt. of ethanol = 46)
Ethanol Water
a) 0.88 0.12
b) 0.74 0.26
c) 0.63 0.37
d) 0.56 0.44
9. Molality of an aqueous solution is 0.45. Calculate the mole fraction of solute in that
solution.
a) 0.065 b) 0.008 c) 0.101 d) 1.20
10. Calculate the molality and mole fraction of the solute in aqueous solution containing
3.0 g of urea (mol. mass = 60) per 250 g of water.
Molality Mole fraction
a) 0.5 moles/kg 0.00634
b) 0.4 moles/kg 0.00531
c) 0.3 moles/kg 0.00428
d) 0.2 moles/kg 0.00361
11. Molality of an aqueous solution of glucose (C
6
H
12
O
6
) is 0.12 moles/kg. What are the mole
fractions of each component in the solution?
C
6
H
12
O
6
Water
a) 0.002 0.998
b) 0.105 0.895
c) 0.214 0.786
d) 0.355 0.645

www.olympiaus.in Page 17

12. 214.2 g of sugar syrup contains 34.2 g of sugar. Calculate.

i) molality of the solution and ii) mole fraction of sugar in the syrup.
Molality Mole fraction
a) 0.55 moles/kg 0.0099
b) 0.63 moles/kg 0.0084
c) 0.72 moles/kg 0.0073
d) 0.89 moles/kg 0.0056
Q No:1 2 3 4 5 6 7 8 9 10 11 12
D b d b a d a a b d a a
WORKSHEET 11
1. What is the volume (in ml) of 0.1 M potassium permanganate solution is required to
completely oxidize 100ml of 0.5M ferrous sulphate solution in acid medium?
(Mol. wt. of KMnO
4
is 158)
2 KMnO
4
+ 10FeSO
4
+ 8H
2
SO
4
5Fe
2
(SO
4
)
3
+ K
2
SO
4
+ 2MnSO
4
+ 8H
2
O
(5Fe
2+
+ + 8H
+
Mn
2+
+ 5Fe
3+
+ 4H
2
O)
a) 400 b) 300 c) 200 d) 100
2. 500ml of a solution contains 12.6 grams of oxalic acid (mol. wt. = 126). 10ml of this
solution is diluted to 100ml in a flask. What is the molarity of the resultant solution?
a) 0.2 M b) 0.1 M c) 0.02 M d) 0.01 M
3. An aqueous solution of glucose is 10%(w/v) in strength. The volume in which 1 gram
mole of it is dissolved will be:
a) 18 lt. b) 9 lt. c) 0.9 lt. d) 1.8 lt.
4. The molality of 4% (w/w) NaOH solution is:
a) 0.1 mole/kg b) 0.5 mole/kg c) 0.01 mole/kg d) 1.04 moles/kg
5. The concentration of an aqueous solution of 0.01M CH
3
OH solution is nearly equal to
which of the following?
a) 0.01% (w/v) CH
3
OH b) 0.01 m CH
3
OH
c) 0.01 N CH
3
OH d) 0.99M H
2
O
6. Zn reacts with CuSO
4
as follows: Zn + CuSO
4
ZnSO
4
+ Cu.
If excess of Zn is added to 100ml of 0.05M CuSO
4
, the amount of copper formed will be:
a) 0.6354 g b) 0.3175 g c) 0.177 g d) 6.354 g
7. The mole fraction of water in 20% aqueous solution of H
2
O
2
is:
a) 0.2 b) 0.4 c) 0.808 d) 0.117
8. If 20ml of 0.4M NaOH solution is completely neutralised by 40.0ml of a dibasic acid, the
molarity of the acid solution is
a) 0.1 M b) 0.2 M c) 0.3 M d) 0.4 M
9. The weight of H
2
C
2
O
4
.2H
2
O required to prepare 500ml of 0.2N solution is:
a)1.26 g b) 6.3 g c) 1.575 g d) 3.15 g
10. The molarity of a solution containing 1 gram of NaOH in 250ml of the solution is:
a) 0.1 M b) 0.2 M c) 0.05 M d) 0.15 M
11. The amount of anhydrous Na
2
CO
3
present in 250ml of 0.25M solution is:
a) 6.625 g b) 8 g c) 3.25 g d) 1 .025 g

www.olympiaus.in Page 18

12. 3 grams of a substance of mol. wt. 30 is dissolved in 250 grams of H

2
O. The molality of
the solution is
a) 1 m b) 0.4 m c) 0.3 m d) 0.2 m
13. The molecular weight of H
2
SO
4
is 98. The weight of acid present in 400ml of 0.125M
solution is
a) 2.45 g b) 3.92 g c) 4.9 g d) 9 g
14. 0.53 g of anhydrous sodium carbonate (M.W = 106) is dissolved in 100ml of solution.
Molarity of that solution is
a) 0.1 M b) 0.5 M c) 0.05 M d) 0.0 1 M
15. What volume of 0.8M solution contains 0.1 mole of the solute?
a) 100 ml b) 125 ml c) 500 ml d) 62.5 ml
16. A molal solution is one that contains one mole of solute in:
a) 1000 g of the solvent b) 199 ml of the solution
c) one litre of the solvent d) 22.4 litres of the solution
17. 25 ml of 3 M HNO
3
is mixed with 75ml of 4 M HNO
3
. If the volumes are additive, the
molarity of the final mixture would be
a) 3.25 M b) 4.0 M c) 3.75 M d) 3.50 M
18. How many grams of NaOH will be needed to prepare 250ml of 0.1 M solution?
a) 1 g b) 10 g c) 4 g d) 6 g
19. Molecular weight of tribasic acid is W. Its equivalent weight would be
a) W/2 b) W/3 c) W d) 3W
20. What volume of 0.8M solution contains 0.4 moles of solute?
a) 100 ml b) 125 ml c) 500 ml d) 6.25 ml
21. The molarity of 2N HCl is
a) 2 M b) l M c) 0.5 M d) 3 M
22. In which mode of expression does the concentration of a solution remain independent of
temperature?
a) Molarity b) Normality c) Formality d) Molality
23. How much water is to be added to dilute 10 ml of 10N HCl to make it decinormal?
a) 990 g b) 1010 g c) 100 g d) 1000 g
24. Equivalent weight of MnSO
4
is half of its molecular weight when it is converted to:
a) Mn
2
O
3
b) MnO
2
c) d)
25. A 0.6% (w/v) solution of urea (mol. wt. 60) would be isotonic with
a) 0.1 M glucose b) 0.1 M KCl c) 0.6% (w/v) NaCl d) 0.6% (w/v) glucose
Q No:1.d 2.c 3.d 4.d 5.c 6.b 7.c 8.a 9.b 10.a 11.a 12.b 13.c 14.c
15.b 16.a 17.c 18.a 19.b 20.c 21.a 22.d 23.a 24.b 25.a,b