TABLES DE THERMODYNAMIQUE

( 25C)

Etat

Gf

Hf

Compos

Physique

(kJ.mol-1)

(kJ.mol-1)

Ag
AgBr
AgCl
Ag2CO3
AgF
AgI
AgNO3
Ag2O
Ag2S
Ag2SO4

s
s
s
s
s
s
s
s
s
s

0
-96.94
-109.50
-12.22
-184.89
-66.32
-29.58
-10.84
-39.62
-618.40

0
-100.42
-126.78
-81.17
-202.92
-61.92
-120.50
-30.54
-31.78
-715.88

25.52
52.38
50.79
111.63
51.92
54.39
93.22
66.78
75.31
131.46

42.68
107.11
96.23
167.36
83.68
115.48
141.00
121.75
143.51
200.41

Al
AlBr3
AlCl3
AlF3
AlI3
Al2O3
Al(OH)3
Al2(SO4)3

s
s
s
s
s
s
s
s

0
-504.42
-630.15
-1410.13
-305.10
-1582.36
-1147.17
-3108.34

0
-527.18
-705.34
-1489.50
-309.20
-1675.70
-1284.49
-3440.90

24.35
101.67
91.38
75.10
98.91
78.70
93.14
259.41

28.33
180.25
110.67
66.53
189.54
51.04
71.13
239.32

Ba
BaBr2
BaCl2
BaCO3
BaF2
BaI2
BaO
BaSO4

s
s
s
s
s
s
s
s

0
-717.35
-809.60
-1102.65
-1151.73
-599.65
-523.71
-1352.69

0
-755.21
-859.39
-1216.29
-1203.74
-604.59
-553.54
-1465.24

26.36
74.52
75.31
88.03
78.45
80.37
45.27
101.75

67.78
148.53
123.64
112.13
96.23
167.36
70.29
132.21

Br2

71.55

152.21

C
C 2H 2
C 2H 4
C 2H 6
C 3H 8

s (gr)
g
g
g
g

0
+209.19
+68.10
-32.93
-23.47

0
+226.70
+52.26
-84.70
-103.85

8.49
44.06
43.72
52.93
73.89

5.73
200.79
219.45
229.49
269.91

CO
CO2

g
g

-137.28
-396.35

-110.50
-395.50

29.29
37.20

197.90
213.64

Ca
CaBr2
CaCl2
CaCO3
CaF2
CaI2
Ca(NO3)2
CaO

s
s
s
s
s
s
s
s

0
-664.96
-755.84
-1128.84
-1168.93
-531.83
-741.49
-604.17

0
-682.83
-800.82
-1206.87
-1221.31
-535.55
-936.80
-635.55

26.28
68.20
72.84
82.01
71.13
75.31
149.37
42.68

41.63
133.89
113.80
92.88
68.83
145.27
193.22
39.75

Cp

(J.mol-1.K-1) (J.mol-1.K-1)

Ca(OH)2
CaSO4

s
s

-898.60
-1320.22

-986.21
-1432.60

87.53
99.66

83.39
106.69

Cd
CdCl2
CdO
CdS
CdSO4

s
s
s
s
s

0
-344.22
-226.06
-145.10
-822.99

0
-391.62
-255.64
-149.37
-933.45

25.90
76.57
42.97
55.10
100.42

51.46
115.48
54.81
69.04
123.01

Cl2

33.97

222.97

Co
CoCl2
CoSO4

s
s
s

0
-269.66
-760.82

0
-312.54
-867.76

24.81
78.49
138.28

30.04
109.20
113.30

Cr
CrCl3
Cr2O3
Cr2(SO4)3

s
s
s
s

0
-482.16
-1048.01
-280.54

0
-552.29
-1129.68
-609.61

23.35
90.12
104.52
302.55

23.77
123.01
81.17
269.87

Cs
CsBr
CsCl
CsF
CsI

s
s
s
s
s

0
-380.53
-414.59
-525.59
-331.79

0
-394.55
-442.83
-554.67
-336.81

32.01
51.76
52.47
51.97
51.55

84.35
113.39
101.17
88.28
125.52

Cu
CuBr
CuCl
CuCl2
CuI
Cu2O
CuO
Cu(OH)2
Cu2S
CuS
CuSO4

s
s
s
s
s
s
s
s
s
s
s

0
-105.19
-120.83
-161.67
-69.33
-147.53
-127.19
-372.67
-86.06
-48.91
-660.82

0
-107.95
-138.07
-205.85
-67.78
-170.29
-155.85
-450.37
-79.50
-48.53
-769.98

24.52
54.77
48.70
72.68
54.18
65.31
42.22
95.19
81.59
47.66
98.78

33.35
96.23
87.03
108.07
96.65
92.93
42.59
108.37
120.92
66.53
109.24

F2

31.46

202.92

Fe
FeCl2
FeCl3
FeO
Fe2O3
Fe3O4
Fe(OH)2
Fe(OH)3
FeS
FeS2
FeSO4
Fe2(SO4)3

s
s
s
s
s
s
s
s
s
s
s
s

0
-303.47
-334.01
-251.50
-740.99
-1015.50
-492.08
-705.63
-97.86
-166.06
-825.04
-2271.45

0
-342.25
-399.40
-272.04
-825.50
-1118.38
-574.04
-832.61
-95.39
-177.40
-928.85
-2582.99

24.27
76.32
96.65
49.66
104.77
148.57
97.03
101.50
54.64
62.09
100.54
263.47

27.15
120.08
142.34
60.75
87.45
146.44
87.86
104.60
67.36
52.93
120.96
307.52

H2
H3BO3
HBr
HCOOH
HCl
HF

g
s
g
l
g
g

0
-969.14
-53.43
-359.49
-95.27
-273.22

0
-1094.53
-36.40
-422.79
-92.30
-271.12

28.87
81.34
29.12
99.16
29.12
29.16

130.58
88.70
198.57
128.99
186.69
173.64

HI
HNO3
H 2O
H 2O
H 2O 2
H3PO4
H 2S
H2SO4

g
g
l
g
l
s
g
l

+1.59
-74.01
-237.18
-228.58
-120.50
-1106.96
-36.20
-690.07

+26.48
-134.31
-285.80
-241.80
-187.86
-1261.48
-20.60
-814.00

29.12
53.51
75.40
34.23
89.33
106.23
33.97
138.95

206.31
266.35
69.96
188.74
109.62
110.54
205.69
156.9

Hg
HgBr2
Hg2Br2
HgCl2
Hg2Cl2
HgF2
Hg2F2
HgI2
Hg2I2
HgO
HgS

l
s
s
s
s
s
s
s
s
s
s

0
-152.17
-178.70
-184.05
-210.41
-374.09
-427.34
-99.04
-111.09
-58.53
-50.29

0
-169.45
-204.18
-230.12
-264.85
-422.58
-485.34
-105.44
-119.08
-90.79
-58.16

27.87
75.31
106.52
73.93
101.96
74.85
100.29
77.40
105.86
44.89
46.40

76.02
170.33
218.74
144.52
192.46
116.32
160.67
170.71
241.29
70.29
81.59

I2
I2

s
g

0
+19.37

0
+62.43

54.43
36.86

116.15
260.58

K
KBr
KCN
K2CO3
KCl
KClO4
KF
K3AlF6
KI
KNO3
KOH
K2SO4

s
s
s
s
s
s
s
s
s
s
s
s

0
-380.45
-102.05
-1064.87
-408.78
-300.37
-537.69
-3163.31
-323.05
-392.54
-378.99
-1315.91

0
-393.80
-113.47
-1150.18
-436.68
-430.12
-567.35
-3326.28
-327.90
-492.46
-424.68
-1433.86

29.29
52.3
66.36
114.22
51.71
112.38
50.29
221.08
53.01
96.27
65.61
130.00

64.68
95.94
127.78
155.52
82.55
151.04
66.61
284.51
106.40
132.88
79.29
175.73

Li
LiBr
Li2CO3
LiCl
LiF
LiI
Li2O
LiOH

s
s
s
s
s
s
s
s

0
-340.91
-1132.02
-384.05
-584.67
-269.66
-562.12
-438.69

0
-350.20
-1215.87
-408.27
-612.96
-270.08
-598.73
-484.67

24.18
49.20
95.40
48.41
41.92
50.29
53.47
49.75

29.08
74.06
90.17
59.29
35.65
85.77
37.91
42.68

Mg
MgBr2
MgCO3
MgCl2
MgF2
Mg(NO3)2
MgO
Mg(OH)2
MgS
MgSO4

s
s
s
s
s
s
s
s
s
s

0
-499.23
-1012.65
-591.87
-1070.23
-588.61
-568.98
-833.70
-340.74
-1170.68

0
-518.82
-1096.21
-641.41
-1123.40
-789.94
-601.24
-924.66
-347.27
-1284.91

24.89
73.81
75.56
71.17
63.64
141.92
37.07
77.66
41.84
95.60

32.68
119.24
65.69
89.54
57.24
164.01
26.94
63.18
42.68
91.63

Mn

26.32

32.01

MnBr2
MnCO3
MnCl2
MnF2
MnI2
MnO
MnO2
Mn2O3
Mn3O4
MnS
MnSO4

s
s
s
s
s
s
s
s
s
s
s

-371.16
-817.60
-441.20
-752.41
-243.43
-362.67
-465.26
-879.02
-1281.60
-218.49
-957.34

-384.93
-894.96
-482.00
-794.96
-242.67
-384.93
-520.07
-956.88
-1386.58
-214.22
-1065.25

75.31
81.55
72.97
67.99
75.35
44.77
54.22
98.74
148.07
49.96
100.42

138.07
85.77
118.20
92.26
150.62
59.83
53.14
110.46
153.97
78.24
112.13

N2
NH3
N2H4
NH4Cl
NH4I
NO
N2O
NO2
N2O4

g
g
g
s
s
g
g
g
g

0
-16.57
+158.53
-203.22
-112.05
+86.69
+104.14
+51.84
+98.28

0
-46.10
+95.19
-314.55
-202.09
+90.37
+82.01
+33.05
+9.67

29.29
35.15
51.80
86.65
81.67
29.83
38.83
36.65
77.61

191.50
192.51
240.16
94.98
112.97
210.62
219.83
239.74
304.30

Na
NaBr
NaCl
NaCN
Na2CO3
NaHCO3
NaF
Na3AlF6
NaI
NaNO3
Na2O
NaOH
Na2S
Na2SO4

s
s
s
s
s
s
s
s
s
s
s
s
s
s

0
-349.36
-384.22
-80.54
-1048.22
-849.56
-543.42
-3140.76
-284.64
-365.68
-379.28
-381.96
-361.54
-1269.51

0
-361.41
-411.20
-90.71
-1130.77
-947.26
-573.63
-3305.36
-287.86
-466.52
-417.98
-428.02
-372.38
-1387.21

27.99
51.88
50.79
68.62
111.34
87.78
47.15
219.53
52.47
93.05
68.91
59.66
79.45
128.37

51.17
86.82
72.13
118.49
138.78
102.09
51.30
238.49
98.32
116.32
75.06
64.43
97.91
149.62

Ni
NiCl2
NiO
NiS
NiSO4

s
s
s
s
s

0
-259.16
-212.46
-90.25
-93.99

0
-305.43
-240.58
-92.88
-198.74

25.82
71.55
44.31
54.68
135.98

29.87
97.70
38.07
52.93
133.89

O2
O3

g
g

0
+163.18

0
+142.67

29.37
38.91

205.06
238.82

P
PCl3
PCl5

s (rouge)
g
g

0
-267.78
-305.43

0
-287.02
-374.89

21.38
71.88
111.63

22.80
311.67
352.71

Pb
PbBr2
PbCl2
PbF2
PbI2
PbO
PbO2
Pb3O4
PbS
PbSO4

s
s
s
s
s
s
s
s
s
s

0
-259.95
-315.39
-630.82
-173.43
-188.87
-250.35
-616.14
-98.78
-813.24

0
-276.44
-360.66
-676.97
-175.14
-219.28
-277.40
-733.50
-100.42
-920.06

26.44
80.54
73.14
74.14
81.17
46.02
62.89
146.98
49.50
104.31

64.81
161.75
135.98
112.97
175.18
65.27
76.57
210.87
91.21
148.53

S
SO2
SO3
Sb
SbBr3
SbCl3
SbI3
Sb2O3
Sb2O5

s
g
g
s
s
s
s
s
s

0
-302.97
-373.61
0
-226.06
-324.47
-94.98
-626.60
-829.27

0
-296.80
-395.70
0
-259.83
-382.00
-96.23
-708.77
-971.94

31.92
39.92
50.75
25.02
108.53
106.86
97.57
101.25
117.61

22.76
248.53
256.23
45.52
179.91
187.02
215.48
123.01
125.10

Si
SiO2

s
s

0
-855.29

0
-909.06

20.00
44.93

18.83
41.84

Sn
SnCl2
SnCl4
SnO
SnO2
SnS
SnS2

s
s
l
s
s
s
s

0
-281.92
-440.16
-256.69
-519.82
-106.44
-159.03

0
-325.10
-511.28
-285.77
-580.74
-108.37
-167.36

26.99
79.33
150.62
44.31
52.59
49.25
70.12

51.55
129.70
258.57
56.48
52.30
76.99
87.45

Zn
ZnBr2
ZnCl2
ZnCO3
ZnF2
ZnI2
ZnO
ZnS
ZnSO4

s
s
s
s
s
s
s
s
s

0
-310.62
-369.70
-731.28
-713.46
-210.20
-318.11
-196.94
-872.62

0
-327.61
-416.31
-812.53
-764.42
-209.20
-348.11
-201.67
-978.64

25.40
65.69
67.53
80.08
65.69
65.69
40.25
57.74
114.35

41.63
136.82
108.37
82.42
73.64
161.08
43.51
46.02
128.03

TABLE THERMODYNAMIQUE
POUR QUELQUES IONS

Ion

Gf
(kJ.mol-1)

Hf
(kJ.mol-1)

ClFFe2+
Fe3+
H+
H 3O +
OHSn2+
Sn4+

-131.25
-278.82
-84.94
-10.54
0
-237.19
-157.28
-27.20
2.51

-167.15
-332.63
-87.86
-47.70
0
-285.85
-230.00
-8.79
30.54

Cp
(J.mol-1.K-1)

S
(J.mol-1.K-1)
55.23
-9.62
-113.39
-293.30
0
69.96
-10.54

ENERGIES DE LIAISON
A) Liaisons simples (kJ.mol-1)

H-H
H-F
H-Cl
H-Br
H-I
H-C
H-N
H-O

:
:
:
:
:
:
:
:

435.97
563.17
431.79
366.10
298.74
414.22
389.11
464.22

H-S
C-C
C-Cl
C-Br
C-O
C-N
N-N
N-Cl

:
:
:
:
:
:
:
:

338.90
347.27
326.35
276.14
351.46
292.88
158.99
200.83

:
:
:

878.64
418.4
945.58

O-O
S-S
F-F
Cl-Cl
Br-Br
I-I
I-Cl
I-Br

B) Liaisons multiples (kJ.mol-1)

C=C
CC
C=O

:
:
:

615.05
811.70
711.28

O=O

497.00

CN
N=N
NN

CHALEURS DE COMBUSTION (kJ.mol-1)

CO (g)
H2 (g)
CH4 (g)
C2H4 (g)
C2H6 (g)
C3H8 (g)

-283.01
-285.85
-890.36
-1410.97
-1559.88
-2221.66

C (graphite)
C (diamant)
CH3OH (g)
CH3CH2OH (g)
CH3COOH (g)
CH3COCH3 (g)

-393.51
-395.39
-763.96
-1409.25
-919.73
-1821.38

:
:
:
:
:
:
:
:

138.07
213.38
153.13
242.67
192.88
151.04
210.46
177.82