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1.Whichstatementiscorrectabout elementsinthePeriodicTable?
A:InGroupI,thereactivitydecreasesasproton numberincreases. B:InGroupVII,themeltingpointincreasesas protonnumberincreases. C:InGroupVIII,theelementsbecomedarkeras protonnumberincreases. D:InGroupII,thenumberofoutershell electronsincreasesasprotonnumber increases.
ThoughtprocessforQn 1
A:InGroupI,thereactivitydecreasesasproton Asprotonnumberincreases=Downthegroup, ReactivityofGroupImetalsincreases. numberincreases. B:InGroupVII,themeltingpointincreasesas Asprotonnumberincreases=Downthegroup, MeltingpointofGroupVIIhalogensincreases. protonnumberincreases. C:InGroupVIII,theelementsbecomedarkeras Asprotonnumberincreases=Downthegroup, Colour ofGroupVIIInoblegasesremainscolourless. protonnumberincreases. D:InGroupII,thenumberofoutershell Asprotonnumberincreases=Downthegroup, Numberofoutershell electronsinGroupIIremainsthesame electronsincreasesasprotonnumber (2). increases.
ThoughtprocessforQn 2
A:Asolutionofpotassiumchlorideisformed. B:Chlorineandiodideionscombinetogetherto Chlorineandiodideionsdonotcombinetogetheratall. formacompound. Yes,andbecauseiodineisbrownhere,acolour changefrom C: Thechlorinedisplacesiodideionstoform colourless tobrownisobserved. iodine. D:Thepotassiumiodideisdecomposed. Nothingdecomposesduringdisplacementreaction.
Thoughtprocess: 1) Identifythehalogenwhichwillbedisplacingthehalidefromitssolution.In thiscase,itischlorinetryingtodisplaceiodinefromitshalidesolution. 2) Sincechlorineismorereactivethaniodine,displacementreactionwill occurandiodinewillbeformed(brownsolution) Potassiumchlorideisalsocolourless,soitdoesntaccountforcolour change.
3.Whichlistcontainselementswhichallexistas diatomicmoleculesatroomconditions?
A:chlorine,neon,oxygen B:fluorine,hydrogen,neon C:helium,hydrogen,iodine D:hydrogen,bromine,chlorine Thoughtprocess: Noblegasescanonlyexistassingleatomsor monatomic.Usethisknowledgetoeliminateoptions. Halogensandgasessuchashydrogen,oxygenand nitrogenexistasdiatomicmolecules.
5.Lithiumandcaesium arethe1st and5th elementsinGroupIofthePT.Whichofthe followingiscorrect? A:CshasalowermeltingpointthanLi. B:Cshasmoreelectronsinitsoutershellthan Li. C:Csisametal,Liisanonmetal. D:CsreactslessrapidlywithwaterthandoesLi.
ThoughtprocessforQn 5
A:CshasalowermeltingpointthanLi. Downthegroup,meltingpointdecreases. B:Cshasmoreelectronsinitsoutershellthan AllGroupImetalshave1valenceelectron. Li. AllGroupIelementsaremetals. C:Csisametal,Liisanonmetal. D:CsreactslessrapidlywithwaterthandoesLi. Downthegroup,reactivityincreases.Csisexpectedtobemore
reactivethanLi.
ThoughtprocessforQn 6
A:ItformstheionSa. Yup,itgainsoneelectrontofillitsvalenceshell. B:Itismonoatomic. becauseitisnotstableonitsown. Itcannotbemonoatomic
Itisnotlikelytoconductelectricitybecauseitisexpectedtobe C:Itconductselectricity. anonmetal.
7.FluorineistheelementatthetopofGroupVII inthePT.Whichstatementisnottrue?
DownGroupVII,reactivitydecreases.Fluorineismore A:Fluorineislessreactivethanchlorine. reactivethanchlorine.
Allhalogensexistasdiatomicmolecules(F2,Cl2 B:Fluorineexistsasdiatomicmolecules. ,Br2,etc) C:Fluorineformsnegativeionsinits Yup,fluorineneedstogain(one)electrontofillitsvalenceshell definitelynegativeion. compounds. D:Fluorinedisplacesbrominefromaqueous Yup,fluorineismorereactivethanbromine.Soitcan potassiumbromide. displacebromidefrompotassiumbromideinorderto
formbromine.
ThoughtprocessforQn 7
DownGroupVII,reactivitydecreases.Fluorineismore A:Fluorineislessreactivethanchlorine. reactivethanchlorine.
Allhalogensexistasdiatomicmolecules(F2,Cl2 B:Fluorineexistsasdiatomicmolecules. ,Br2,etc) C:Fluorineformsnegativeionsinits Yup,fluorineneedstogain(one)electrontofillitsvalenceshell definitelynegativeion. compounds. D:Fluorinedisplacesbrominefromaqueous Yup,fluorineismorereactivethanbromine.Soitcan potassiumbromide. displacebromidefrompotassiumbromideinorderto
formbromine.
8.Whichelementismostlikelyan alkalimetal?
Element Melting Density Numberofcompounds point (g/cm3) formedwithchlorine (oC)
A B C D
220 113
0.002 3 2.1 3 1 2
9.Whichelectronarrangementisthatofa gaseouselementthatfillslightbulbs?
A:2 B:2.6 C:2.8.3 D:2.8.8 Thoughtprocess: Keyword:fillslightbulbs Thinkofnoblegases
10.Astatine(At)hasaprotonnumber85. WhichislikelytobeapropertyofAt?
Nope,sinceAtisanonmetal(ofGroupVII). A:Itisaverygoodelectricalconductor. B:Itdisplacesiodinefromanaqueoussolution Nope,AtislessreactivethanI.SoAtcannotdisplaceI. ofiodideions. C:ItisdisplacedfromanaqueoussolutionofAt Yup,BrismorereactivethanAt.SoBrcandisplaceAt. ionsbybromine. D:Itsoxideisbasic. Atisanonmetal.Nonmetalsformacidic oxides.
ThoughtprocessforQn 10
Nope,sinceAtisanonmetal(ofGroupVII). A:Itisaverygoodelectricalconductor. B:Itdisplacesiodinefromanaqueoussolution Nope,AtislessreactivethanI.SoAtcannotdisplaceI. ofiodideions. C:ItisdisplacedfromanaqueoussolutionofAt Yup,BrismorereactivethanAt.SoBrcandisplaceAt. ionsbybromine. D:Itsoxideisbasic. Atisanonmetal.Nonmetalsformacidic oxides.
SectionBQ1
Term Alkalimetals Halogens Noblegases Transition elements First example Sodium Fluorine Helium Iron Second example Potassium Chlorine Neon Zinc
Note:ThequestionaskedforNAMES.Donotwritethechemicalsymbols.
Q2
Element chlorine bromine iodine astatine Molecular formula Cl2 Br2 I2 Melting point(oC) 101 7 113 Boilingpoint (oC) 35 59 184
2.
(a)(i)Whichelementinthetableisliquidatrtp? Bromine[1].
2.
(a)(ii)howmanyoutershellelectronsdoes astatinehave? 7/seven[1]
2.
(a)(iii)Predictthemolecularformulaofastatine. At2[1]
2.
(a)(iv)Predictthephysicalstateandcolour of astatineatrtp. Solid[1] Black[1]
2.(b)(i)Whathappenswhenaqueouschlorineis shakenwithaqueoussolutionsofsodiumsalts.
Sodiumsalt Observation Namesof products
Sodium bromide
Sodium iodide
2.(b)(ii)Chemicalequationforthereactionof aqueouschlorinewithaqueoussodium bromide. Aqueouschlorine=Cl2 Aqueoussodiumbromide=NaBr Cl2 +NaBr NaCl +Br2 Balanced? Cl2 +2NaBr 2NaCl+Br2
[1]
3.AmetallicelementZhasthe followingproperties:
Soft,withsilveryappearance Lessdensethanwater Meltingpointlessthan100oC FormsachloridewithformulaZCl OxideofZreactswithwatertoformasoluble hydroxide
3.(a)SuggestwhichGroupofthePT metalZbelongsto.
GroupI[1] Inromannumeral,otherwise,wrong.
3.(c)Writetheequation,includingstate symbols,forthereactionthattakesplace.
Generalequation? Alkalimetal+water metalhydroxide+ hydrogengas Z+H2O ZOH+H2 Z(s) +H2O(l) ZOH(aq) +H2(g) Balanced? 2Z(s) +2H2O(l) 2ZOH(aq) +H2(g)