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a. When a Group A metal and a nonmetal react, the metal cation and a nonmetal anion. Mg + Cl2 Mg + O2 MgCl2 MgO
Which of the following oxides may produce an acid when dissolved in water? CO2 NO2 Fe2O3
product is a compound that is a combination of a 5. Metal oxide + nonmetal oxide salt Metallic oxide may also react with nonmetal oxides to form a K2O + SO3 K2SO4
CaO + CO2
CaCO3
b. When a transition metal and a nonmetal react, there may be one or more possible products. Fe + S 2. Nonmetal + nonmetal Fe + S Fe2S3 FeS
When a nonmetal and nonmetal react by combination, more than one product is often possible. 2C + O2 C + O2 S + O2 2CO
Using the previous examples as your guidelines, complete the following combination reactions. 1. Al + O2 2. Cu + S 3. SO3 + H2O
CO2 SO2
2S + 3O2
2SO3
Some NONMETAL OXIDES react with water to produce an ACID. SO2 + H2O H2SO3
Some METALLIC OXIDES react with water to form a BASE. CaO + H2O Ca(OH)2
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Al2(SO4)3
Oxides of metals beyond Hg in the electromotive series can be decomposed by HEATING to produce a metal and oxygen gas. Ag2O 4Ag + O2 Al2O3 no reaction Fe2O3 no reaction 4. Nitrates
The nitrates of Group I metals decompose into nitrites and oxygen. 2KNO3
heat
heat
heat 2KNO2 + O2
heat
The nitrates of other metals will decompose into nitrogen dioxide, oxygen, and metal oxide. 2Pb(NO3)2 5. Carbonates
However, oxides of the metals above Hg in the activity series may be decomposed by electrolysis, thus,
Except for Group I carbonates, all carbonates lose carbon dioxide to form a metallic oxide. MgCO3
All hydroxides except those of Group IA will lose water when heated forming the metal oxide. Mg(OH)2
heat MgO + H2O heat NaOH no reaction heat 2Al(OH)3 Al2O3 + 3H2O
3. Sulfates With the exception of the Group IA and Group IIA sulfates, the sulfates of all other metals are decomposed by heated to form a metal oxide and sulfur trioxide.
All chlorates decompose by heating to form the chloride of the metal and oxygen gas. KClO3
heat KCl + O2
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DOUBLE-REPLACEMENT REACTIONS 1. One product is slightly soluble and precipitates in the solution.
When a metal is above the hydrogen in the activity series is reacted with an acid, hydrogen is liberated and salt is formed. Zn + HCl Cu + H2SO4 ZnCl2 + H2
a. All salts of sodium, potassium, and ammonium are soluble in water. NaCl, Na2SO4, Na2CO3 ------ soluble
no reaction
b. Nitrates, chlorates and acetates of all metals are soluble in water. KNO3, Mg(ClO3)2, NaC2H3O2 ----- soluble
2. A metal + a salt
Each metal in the activity series displaces any metal below it from a salt in a solution. Cu + AgNO3 Cu + FeSO4
c. Chlorides, bromides and iodides of all metals EXCEPT lead, silver, and mercury (I) are soluble in water. (PbCl2, PbBr2 and PbI2 are soluble in hot water) MgI2--- soluble
Cu(NO3)2 + 2Ag
no reaction
AgCl--- insoluble d. Sulfates of all metals EXCEPT lead, mercury (I), barium and calcium are soluble in water. Na2SO4 ----- soluble CaSO4---- insoluble
Cl2 + 2NaI
2NaCl + I2
e. Carbonates, phosphates, borates, sulfites, chromates and arsenates of all metals except sodium, potassium, and ammonium are insoluble in water. Na2CO3 ----- soluble
MgCO3----- insoluble
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f.
potassium and ammonium are soluble in water. All other CaS ---- soluble
FeS---- insoluble g. The hydroxides of sodium, potassium, ammonium, hydroxides of all other metals are insoluble. MgO--- insoluble NaOH --- soluble
Potassium (K) Barium (Ba) Strontium (Sr) Calcium (Ca) Sodium (Na)
INCREASING ACTIVITY
2. One product is a gas that bubbles out in of the mixture. 3. One product is a molecular compound such as water.
Chromium (Cr) Iron (Fe) Cadmium (Cd) Cobalt (Co) Nickel (Ni) Tin (Sn) Lead (Pb)
BaCO3 + 2KCl
no reaction
Hydrogen (H)
Mercury II (Hg2+)
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