Final Examination of Microanalysis

For
th
4- year students of Special Chemistry
Time: 0.5 Hour
Name:
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Answer the following questions:
A- Put () or (X) for the following statements. Only four
1- Silver salt method is used to determine the M.Wt. of halogen containing carboxylic acid.

2- NaOI can oxidize formaldehyde.

3- Kjeldhal methode can be used for determine nitrogen content of diazo compounds.

4- Sodium hydroxide is favourable in determining M.Wt. of carboxylic acid by silver salt methode. (

5- sod. thiosulphate is used in determining formaldhyde percent in formaline.

------------------------------------------------------------------------------------------------------------------------------B- 1.9 gm of organic aromatic amine will be acetylated by acetic anhydride-pyridine mixture. The sample
flask required 67.7 ml of NaOH 1N, but the blank flask required 87.6 ml NaOH 1N.
Calculate the number of amino groups in this compound
Note : M.Wt. of the compound is 94 g/mole
------------------------------------------------------------------------------------------------------------------------------C- Give the equation for the following: Only four
1- Determining Nitrogen content in organic compounds.
2- Determining Chlorine content in organic compounds.
3- Determining Carbon content in organic compounds.
4- Determining the M.Wt. of amino acid.
5- Determining the purity of aniline sulphate.
------------------------------------------------------------------------------------------------------------------------------D- Calculate the molecular formula of an organic dibasic acid which gave the next results on analyses:
a) Combustion of 0.249 gm dicarboxylic acid gave 0.528 gm CO2 and 0.081 gm H2O
b) Ignition of 1.9 gm of silver salt gave 1.08 gm of silver.

GOOD LUCK