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M1.

(a)

(i)

test tube / boiling tube for 1 mark


1

(ii)

Na2CO3 NaCl each for 1 mark


2

(b)

(i)

flask measuring cylinder each for 1 mark


2

(ii)

used smaller pieces gains 1 mark but larger surface area for reaction gains 2 marks
2

(c)

(i)

steeper line straight line each for 1 mark


2

(ii)

reaction occurs when particles collide higher temperature, higher speed of particles so harder collisions more frequent collisions any three for 1 mark each
3

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M2.

(a)

2 2 multiples of allowed for 1 mark


1

(b)

(i)

2. 8. 1 and 2. 8. 7 gains 3 marks 1 mark for 2 electrons in each inner shell 1 mark for 8 electrons in each second shell 1 mark for 1 electron in sodium outer shell and 7 in chlorine outer shell
3

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(ii)

sodium atom loses; electron; chlorine atom gains; electron for 1 mark each inversion = 2 marks lose negative charge = 1 mark
4

(c)

(i)

KCl (accept 2KCl) for 1 mark


1

(ii)

both have on electron in outer shell/same number of electrons/ lose same number of electrons in compound formation/ both lose one electron for 1 mark
1

(d)

0 amps; the ions; cannot move in the solid solid Na chloride does not conduct for 1 mark each
3

(e)

(i)

water (H2O) for 1 mark


1

(ii)

(1) chlorine; (2) hydrogen for 1 mark


1

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M3.

(a)

(i)

(s) (aq) (1) 2 or 3 correct 1 mark 1 correct 0 marks

(g)

(ii)

calcium chloride
1

(b)

(i)

points deduct 1 mark for each error to a maximum of 2 marks


2

line accept a single line best fit curve accept reasonable attempt at curve
1

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(ii)

increase temperature or heat accept increase surface area or increase concentration or description
1

(iii)

75% or not pure 1 mark only 60 cm3 (instead of 80 cm3 of gas) or 100 1 mark
3

[10]

M4.

(a)

(i)

H2O must be formula


1

(ii)

catalyst
1

(b)

(i)

correct plotting
2

1 mark deducted per error to a maximum of 2 do not accept a complete dot-to-dot line do not accept a bar chart if the (0,0) point is missing and line to one minute missing then maximum mark is 2 best fit single line if curve correct but no obvious points award 3marks
1

(ii)

4.5 5 no units required


1

(iii)

all hydrogen peroxide had reacted accept all hydrogen peroxide had decomposed or been used up accept no hydrogen peroxide (particles) left
1

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(c)

(i)

remains lower than previous line do not accept bar chart


1

line levels off lower than 60cm3 correct points but no line drawn then maximum 1 mark
1

(ii)

decrease of (hydrogen peroxide) concentration accept concentration is less accept fewer collisions (of particles) do not accept weaker solutions or dilute solutions
1

[10]

M5.

(a)

(i) calcium carbonate calcium oxide + carbon dioxide

accept CaO3CaO+CO2
1

(ii)

(thermal) decomposition accept endothermic accept reversible


1

(b)

(i)

neutralisation accept exothermic


1

(ii)

sulphuric (acid) H2SO4


2

(c)

(i)

to speed up the reaction accept to increase the rate of reaction or to increase the number or rate of collisions do not accept dissolves copper oxide faster
1

(ii)

all acid reacts accept there will be no acid left or acid used up
1

acid is neutralised (for 2 marks) do not accept to form a concentrated or saturated solution
1

(excess) copper oxide collects in filter paper accept larger particles (of copper oxide) cannot pass through filter paper
1

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copper sulphate solution passes through the filter paper accept dissolved copper sulphate passes through filter paper or smaller particles (of copper sulphate) in solution (liquid) pass through filter paper accept (black) solid collects in filter paper and filtrate or soluble solid or (blue) solution (liquid) passes through filter paper for 1 mark only
1

[10]

M6.

(a)

(i)

column
1

(ii)

mass spectrometer
1

(b)

(i)

165 if answer is not correct then evidence of correct working gains one mark. e.g. (10 12) + 15 + 14 + 16
2

(ii)

10.37% accept 10 / 10.4 / 10.37............... if answer is not correct then evidence of correct working gains one mark. e.g. minimum evidence would be 14/135
2

(c)

any two from: faster more accurate detects smaller amounts


2

(d)

to avoid bias accept to check / compare the result


1

to improve reliability
1

[10]

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