Ol FT I Jeea Paper 2 PDF

AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/13
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1

ANSWERS, HINTS & SOLUTIONS
FULL TEST I
(Paper-2)

Q. No. PHYSICS CHEMISTRY MATHEMATICS
1.
A B C
2.
B B B
3.
D B A
4.
D B C
5.
A, D

A, C A, C
6.
A, B, C, D

A, B, C A, C
7.
B, C A, B, D A, C
8.
A, C A, B, D C, D
9.
A, B, C
B, C
A, C, D
1.
(A) (p, q, r, s )
(B) (q, r)
(C) (q, r)
(D) (p, q, r, s)
(A) (r, s)
(B) (p, r)
(C) (r, t)
(D) (q)
(A) (s, t)
(B) (p, q)
(C) (r)
(D) (p, q, r, s, t)
2.
(A) (r)
(B) (p)
(C) (q)
(D) (s)

(A) (q, r, t)
(B) (s, t)
(C) (s, t)
(D) (p, r, t)
(A) (q)
(B) (r)
(C) (q)
(D) (p, q, r, s, t)
1.
8 5 4
2.
4 2 8
3.
9 2 3
4.
5 5 5
5.
3 8 3
6.
1 8 5
7.
5 6 3
8.
8 7 3

A
L
L

I
N
D
I
A

T
E
S
T

S
E
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I
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S

FIITJEE JEE(Advanced)-2013
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4

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4
3

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7
5

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1
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9

i
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5
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R
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3
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2
0
1
2


2
P Ph hy ys si ic cs s PART I

SECTION A

1. By conservation of momentum
J = mV + 2 mV
V= J/3m.

2. 0 + 2 1 + 3 1 = V
B

V
B
= 5 volt

4. S <
2
1
gt
2

S < 2g. (due to Lenzs Law).

6. The molar heat capacity has the general definition

1 Q
C
n T

where n = number of moles, Q = heat absorbed by the gas and T = rise in temperature of gas.
It is possible to obtain almost any set of values for Q and T by proper selection of a process.

7.
1
2 10
2usin
2
T
g 10

= = = 1 sec.

30 30
30
30

8. M' g T M' a = (i)
T = Ma (ii)
M' g a(M M') = +

M' g
a
(M M')
=
+

masin mgcos =
a gcot =
T
R
Mg
M

M' g
gcot
(M M')
=
+

cot M cot M' M' + =

Mcot
M'
(1 cot )
=

T = M a
= M. g cot

Mg
T
tan
=
.
masin
ma
mgsin
mgcos

+ macos


3
9.
R
F 2 2iBa = .

2iBa
2iBa

SECTION C

1. P = v
2

2
mdv
.v v
dt
=

0
0
2v t
v 0
dv
dt
v m
=

ln2 .t
m
=

mln2
t =

4 2
t 0.693
0.693
=
t = 8 seconds.

2. After 5 s, speed of detector = 50 10 5 = 0
and that of source = 0 + 10 5 = 50 m/s
and the source has fallen a distance
2
1
10 (5) 125
2
= = m
and the detector has rises a distance
2
1
50 5 10(5) 125
2
= = m
So,
300 0
f ' 130
300 50
| |
=
|
\ .
= 156 Hz.
Ground
O
v=0
50 m/s
S

3.
2
GM
g
R
=

2
G.2m
g'
4R
=

g
g'
2
=
F mg' sin =

mg
F .sin2
2
=
mg
2R
mgsin
2R
mgcos

As is much small

mg
ma .2
2
=
a g. =

x
a g.
2R
=

4

g
2R
= f

2R
T 2
g
=

3
2 6400 10
T 2 3.14
10

=
= 2 3 800 1.41
T = 6768 s.

4. AB = v dt sin (i)
(along the circular arc)
OA =
AN
sin

ds = r d
given vdt sin = OA d
2a 3
d
O
B
N
A

AN
vdt sin .d
sin
=

a
vdt sin d
sin
=

2
d v
sin
dt a
=

d
5
dt
= rad/s.

5. We have,
10.2 = W + K
max, 1
(i)
and 10.2 Z
2
= W + K
max, 2
(ii)
Also
de Broglie
h h
2mK
= =

1 2
2 1
2 1
K
2.3 K 5.25 K
K
= = =
(iii)
Also 10.2 Z
2
= energy corresponding to longest wavelength of the Lyman series = 3 13.6
Z = 2.
From equations (i), (ii) and (iii)
W = 3 eV.

6. Velocity of efflux v 2gy =
Range
2h
x 2gy
g
=
The velocity of the block must be
dx
dt
| |
|
\ .
.
V
A
x
a
y
h

b
dx 2h 1 dy
V 2g
dt g dt
2 y
= =

b
h dy
V .
dt
y
= (i)

5
Using equation of continuity

Ady
a 2gy
dt
= (ii)
equation (i) and (ii)

b
h a
V 2gy
y A
=

b
a
V 2gh
A
=

1
20
20
= = 1 ms
1
.
7. If there were no hole

0
2
GM
g
R
=
decrease in g due to hole (absent mass)

( )
1
2 2
GM/ 8 GM
g
2R
R
2
= =
effective g = g
0
g
1

2
GM
2R
=
= 5.5 m/s
2
.

8.
q q
dq .Rd .d
2 R 2
= =

dq qd
di
T 2 2
= =

2
q
di .d
4
d
Rd

2
0
3
di(Rsin )
dB
2R

=

2
0
2
0
sin q
dB d
2R
4
| |
=
|
\ .

0
q
B
16 R

=

= Ba
2

2 0
q
a .
16 R

=

2
0
q a
16R

=

d
| |
dt
=

2
0
qa
| |
16R
= .
= 8 volt

8
i
1
= = 8 A.

6
C Ch he em mi is st tr ry y PART II

SECTION A
1. W
solute
= 3 gms, W
solvent
= 50 gm = 75 25

OH
3 x
W
40 56
= + .
( )
+
= =
3 x
40 56
m 5 1000
47

X = 9

2. Major product is formed via E
2
.
H anti to halogen will be eliminated.

3. n
Hx
= n
NaOH
= 0.25 V
NaOH
, pH = pK
a
= 5 (acid buffer)

a
1 1
pH 7 pK logC 9
2 2
= + + =
1
logC 1 C 10
= =

NaOH
NaOH
0.25V
C V 40 ml
60 V
= =
+

n
Hx
= 10 mm = 0.82 gm

0.82
% 100 80%
1.025
= =

4. Time required for equifractional change in a first order reaction is constant.

SECTION C

1.
C
H
N H
C
H
O
P
Q
2.
Co
Cl
NH
3
H N
3
Cl
(Fac) (Mer)
+
Cl
NH
3
H N
3
Co
Cl
Cl
NH
3
H N
3
NH
3 Cl
Co
Cl
Cl
H N
3
Cl
NH
3
H N
3

3.
( )
( )
2 4 7 2 3 3
4
5 3
4
Na B O H O 2Na B OH 2H BO
1mol 2 mol
NaOH H BO NaB OH
2 mol 2 mol
( + +

( +


7
4. A = 2y
1/3
nm. M = 6.023 y 4 amu
Density = m/a
3
=
27
27
6.023 4 1.66 10
kg / m
8y 10

40
5 kg / m
8
= =

5. Two double bonds capable exhibiting geometrical and one chiral carbon molecule
asymmetric.
2
3
= 8

6.
Pvm
w 58.33 gm
RT
= =

58.33
% 100 77%
75
= =

7.
B O B
O
O
O
O


8
M Ma at th he em ma at ti ic cs s PART III

SECTION A

1. PQ is a focal chord
2
1 a 2a
Q ,
t t
t
| | (
=
|
(
\ .

Normal drawn at P(t) meets the curve at Q
2
t,
t
(
(

Normal drawn at
1
Q
t
| |
|
\ .
meets the parabola again at R
1
2t
t
(
+
(

2
1 1
R a 2t , 2a 2t
t t
(
| | | |
+ + (
| |
\ . \ .

Equation of tangent at R is
2
1 1
y 2t x a 2t
t t
| | (
+ = + +
|
(
\ .
.. (1)
Equation of focal chord PQ is
( ) ( )
2
t 1 y 2t x a = .. (2)
T is the point of intersection of line (1) and (2)

2
2
a 1 2a 1
T 4t , 4t
3 3 t
t
( | | | |
+
|
| (
\ .
\ .

Area of TQR =
3
2
8a 1
t
3 t
(
+
(

2. Let a point (3 + 1, + 2, 2 + 3) of the first line also lies on the second line. Then
3 1 3 2 1 2 3 2
1 2 3
+ + +
= = = 1
Hence the point of intersection P of the two lines is (4, 3, 5). Equation of plane perpendicular to
OP where OP is (0, 0, 0) and passing through P is 4x + 3y + 5z = 50

3. For non triangle solution
a b c
b c a 0
c a b
= =
a + b + c = 0 1 is a root of ax
2
+ bx + c = 0

4. Clearly we have

xy 2
xdy ydx xdy ydx
e x
+
=

xy
y
d(xy)e d
x
| |
=
|
\ .

xy
y
e c
x

+ =

5. Let the roots of az
3
+ bz
2
+ cz + d = 0, z
1
= x
1
, z
2
, z
3
= x
2
iy
2

z
1
+ z
2
+ z
3
=
b
a

ab > 0
Also z
1
z
2
z
3
= ( )
2 2
1 2 2
d
x x y
a
+ =
ad > 0


9
6. On solving we have
1
2
= and
2
3
4
=
3
2
=
New roots are and
2
which are roots of x
3
1 = 0 or x
2
+ x + 1 = 0

7. Redefining the function, we get
2
x 4x 8
; x 1
5 5 5
f(x)
2 x ; x [1, 2)
x 2 ; x 2
+ <

We have R.H.L at x = 1 is =
h 0
lim2 (1 h) 1
+ =
L.H.L at x = 1 is =
( ) ( )
2
h 0
1 h 4 1 h 8
lim 1
5 5 5

+ =
f(x) is continuous at x = 1
Now
2x 4
; x 1
5 5
f '(x)
1 ; 1 x 2
1 ; x 2
<
=

<

R.H.D at x = 1 1
L.H.D at x = 1
2
5

Not differentiable at x = 1
Not differentiable at x = 2

8. Let a
G
, b
G
, c
G
lie in the xy plane
Let
a i =
G
,
1 3

b i j
2 2
= +
G
and
1 3

c i j
2 2
=
G

1 3 1 3

p q r a b c i i j i j
2 2 2 2
| | (
+ + = + + = + + +
| (
\ .
G
G G G G G

= ( )
2
2 3
2 2 4
| |
+
|
\ .
=
2 2 2
+ +
= ( ) ( )
( )
2 2 2 1 1
1 1 4 3
2 2
+ + + + =
p q r + +
G G G
can take a value equal to 3 and 2.

9. z
2
+ az + a
2
= 0
z = a, a
2
(where is non real root of unity)
locus of z is a pair of straight lines and arg (z) = arg(a) + arg() or arg(a) + arg(
2
)
arg(z) =
3
2
also, |z| = |a||| or |a| |
2
| |z| = |a|.


10
SECTION B

1. Clearly lines are 2x + y + 2 = 0 and x + 2y + 1 = 0 and third line is bx + y + 5 = 0
For four circles three lines must not be concurrent b 5
For two circles exactly two lines should be parallel
1
b
2
= and 2
For no circle three lines must be concurrent b = 5
For infinite circles two lines must be identical b

2. (A) Solving
2
2K K
y 0
3
= > and
2
4K 2K
x 0
3
= >
1
K , 2
2
| |
|
\ .

(B) Given
( )
1
g(x) ln cos x
= ; As
1
0 cos x x [ 1, 1]

So domain of g(x) = [1, 1]. Hence number of integers are two (i.e. 1 and 0)
(C) Clearly, domain of expression = {1, 1}. As x > 0 given
So x = 1
Hence value of expression
( )
2010
1
1 sin x 1
+ =
(D) Here
x a
f(x)
x b
+
=
+
.. (1)
and
1
a bx
f (x)
x 1
.. (2)
Given
1
f(x) f (x)
=
x a a bx
x b x 1
+
=
+

( ) ( ) ( )
2 2
1 b x b 1 x x 1 b 0 + + + = x D
f

Hence b = 1 and a R

SECTION C

1. Using AM GM inequality
(a + b)
2
+ (a + b + 4c)
2
= (a + b)
2
+ (a + 2c + b + 2c)
2

( ) ( )
2 2
2 ab 2 2ac 2 2bc + +
= 4ab 8ac 8bc 16c ab + + +

( ) ( )
( ) ( )
2 2
a b a b 4c 4ab 8ac 8bc 16c ab
a b c a b c
abc abc
+ + + + + + +
+ + + +
=
( )
4 8 8 16 a a b b
a b c c
c b a 2 2 2 2
ab
( (
+ + + + + + + + +
( (

2 2
5 5
2 2 4
1 a b c
8 5 5 100
2a b c 2
| (
(
( =
(
(

\

2. Putting X = x + 1 and Z = z + 1
f(X) + f(Z) = f(X + Z)

( )
h 0 h h 0
f(X h) f(X) f(X) f(h) f(X) f(h) f(0)
f ' X lim lim lim
h h h
+ +
= = =
= f(0) = 4 f(X) = 4 f(X) = 4X + c
f(x) = 4x f(2) = 8

3. Let f() = (tan tan
i
) ( )
( ) i
tan tan

We have
( )
/ 2
f

Again ( )
1
f 0 > , ( )
3
f 0 < and
( )
/ 2
f

There will be 3 such values of


11
4. Let the equation be K(x )(x ) = 0
Sum of coefficient = K( 1)( 1) is prime
K is 1 and 1 is 1
One root is 2 and 1 is 2
Hence roots are 2 and 3.

5. Let
3
t x = in I
2

We have
1 1
2
t 1 t
0 0
1 1 1 1
I dt dt
3 3
e (2 t) e (1 t)
= =
+

1
t
1
2 1
2
0
I 1 e 1
I dt I 3
3e (1 t) 3e eI
= = =
+

6. Let 3, 4 and r be radii of the circles inscribed into the s ACD, BCD and ABC respectively, we
get
r AB c
3 AC b
= =
3c
b
r
=
Similarly ABC and BCD are similar, we get
r c
4 a
=
4c
a
r
=
Now as
2 2 2
c a b = +

2 2
2
2 2
9c 16c
c
r r
= + r = 5

7. Putting x = 2,
1
2
and 1 successively

1
f(2) f 3
2
| |
+ =
|
\ .
.. (1)

( )
1 3
f f 1
2 2
| |
+ =
|
\ .
.. (2)
and f(1) + f(2) = 0 ..... (3)
Solving, we get
3
f(2)
4
=

8. On solving we have
4 2
A cos 1 cos 1 = + + =
2
2
1 7
cos
2 4
| |
+
|
\ .

7
A , 2
4
(

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