INTERMEDIATE 1

ST
YEAR CHEM ISTRY
M ODEL QUESTION PAPER ( EFFECTIVE FROM IPE M ARCH 2013)
TIM E : 3 HOURS] [ M AX. M ARKS : 60
SECTION-A 10x2=20
NOTE : Answer a l l t he quest i ons
1. Calculat e t he R M S speed of nit rogen molecules at 27C ?
2. What is di sproport i onat i on react i on? Gi ve example.
3. Calcul at e t he pH of 0.05M Ba(OH), solut i on.
4. Wri t e t he bi ol ogi cal i mpor t ance of magnesi um and calci um
5. Gi ve t he r eact i ons t hat t akes pl ace at anode and cat hode i n Cast ner-Kel l ner pr ocess.
6. Gr aphit e i s a good conduct or of el ect ri cit y, Why?
7. What is al l ot r opy ? Name t wo cryst alli ne al lot r opes of carbon.
8. Def i ne t he t er ms C O D and B O D?
9. What ar e t he har mf ul ef f ect s of aci d r ai ns?
10. G i ve t he st ruct ur al f or mul ae of t he f ol l owi ng compounds
(a)2,3- di met hyl but ane (b) 2-met hyl but -1-ene

SECTION-B 6x4=24
NOTE: Answer any Si x of t he f oll owi ng quest ions.
11. Wr i t e any f ou r post ulat es of ki net ic mol ecular t heor y of gases.
12. Balance t he f ollowing r edox equat ion in acidic medium by ion-elect r on met hod
M nO, + C,C, - M n + CO,
13. St at e Hess s l aw of const ant heat summat ion. Expl ai n wi t h one exampl e.
14. Deri ve t he r el at ion bet ween Kp and Kc f or t he equi li br ium r eact ion
N,g, + 3H,g, -2 NH,g,
15. Expl ai n el ect r ol yt ic met hod of prepar at ion of hydr ogen peroxide.
16. Expl ai n t he st ruct ur e of di borane on t he basi s of VBT
17. Expl ai n (a) posi t i on Isomer ism and (b) f unct i onal group Isomer i sm wi t h one exampl e for
each of t hem.
18. Expl ai n (a) Wur t z r eact ion and (b) Fri edel- Cr af t s al kyl at i on w it h one example f or each
of t hem.

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SECTION-C 2x8=16
NOTE : Answer any Tw o of t he foll owi ng
19. What ar e Quant um Numbers? Expl ai n t he signi f i cance of t he f our quant um numbers
associ at ed wi t h an el ect r on.
20. Def i ne f i r st and second i oni sat ion pot ent i al s. Why t he second i onisat ion pot ent i al of an
el ement i s al ways gr eat er t han i t s f i r st ioni sat i on pot ent i al ? Expl ai n any f our f act ors
t hat af f ect t he ionisat ion pot ent ial of an element .
21. (a) Expl ai n spd hybridizat ion wit h one exampl e.
(b) Expl ai n t he mol ecular or bi t al t heory of oxygen mol ecule.Cal cul at e i t s bond or der
and explai n i t s magnet i c pr opert y.

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