Nne teml-fpw Ah-bpsS ipo-I-c-W-{]-{In-bbpw Xmsg sImSp-n-cn-p-p.

temlw Ti Ni Ge Cn

{]{Inb

hm-B tamUvkv {]{Inb {]{Inb

Ce-Ivt{Sm-en-nIv dnss^-\nMv

tkm dnss^-\nMv

enIz-j

temlhpw AXns ipo-I-c-W-{]-{In-bbpw tNs-gp-Xp-I. 2 kvtIm; 4 an\nv] Scoring Key

Scoring Indicators Stage Score Total Time Score (Minutes)

T i Ni Ge Cu -

Van-Arkel process Monds process Zone refining Electrolytic refining

.1
32

00

ar

ks

.in

Chapter : 11. COORDINATION COMPOUNDS

C.O. Qn. (1)

: 68

A and B are two isomeric co-ordination comounds with molecular formula COCl3 . 6H2O. A gives 2 moles of AgCl and B gives 3 moles of AgCl with AgNO3 solution. a) b) c) Write the structural formula of A and B. Give the IUPAC, names of A and B What tye of isomers are A and B.

b) c)

A bpsSbpw B bpsSbpw IUPAC \ma- Fgp-Xp-I.

A bpw B bpw GXp Xc-n-ep sFtkm-sa-dp-I-fm-Wv ?

00

ar

a)

A bpsSbpw B bpsSbpw LS\ kp{X-hmIyw Fgp-Xp-I.

ks

[3 score; 5 minutes] COCl3 . 6H2O Xm-{X-hm-Iy-ap tImUn-t\-j tImu-ns sFtkm-sa-dp-I-fmWv A bpw B bpw. A[n-I-tXm-Xn AgNO3 emb\n tNm A bn \nv 2 tam AgCl Dw B bn \nv 3 tam AgCl Dw e`n-p-p.

Scoring Key
Scoring Indicators

.1

.in
1 1 1

[3 kvtIm; 5 an\nv]
Stage Score Total Time Score (Minutes)

a) b) c)

A is penta aquacholore cobalt (|||) chloride B is hexaqua cobalt (|||) chloride Hydrate isomerism

A is [Co (H2O)5 Cl] Cl2 . H2O and B is [Co (H2O)6 ] Cl3

C.O. : 71 Qn. (2) With the help of valence bond theory answer the following questions related to the complexes [Fe (CN)6]4, [Fe (CN)6]3 and [Co F6]3 a) b) c) Which among these from outer orbital complex? Predict the magnetic properties. Predict the hybirdisation state of central metal ions. [5 1 2 score; 10 minutes]

33

hmekvt_mv knmw D]-tbm-Knv [Fe (CN)6]4, [Fe (CN)6]3 , [Co F6]3XpS-nb tImwkp-Isf kw_-n-p Xmsg--d-bp tNmZy-v D-c-sa-gp-Xp-I. a) b) c) Ch-bn Hu Hm_n-n tImwIvkv GXv? Ch-bpsS amK-\-nIv KpW- hni-Z-am-pI. tI{-sa- B-ns ssl{_n-ssU-tk-j hni-Zo-I-cn-p-I. [5 1 2 kvtIm; 10 an\nv] Scoring Key
Scoring Indicators Stage Score Total Time Score (Minutes)

a) b)

[Co F6]3 because F is a weak ligand. [Fe (CN)6]4 digamatic due to absence of unpaired electron. [Fe (CN)6]3 and [CO F6]3 are paramagnetic due to the presence of unpaired electron.

1 3

c)

d2sp3, d2sp3, sp3d2

.in
1 12

5 12

10

C.O. : 73 Qn. (2) A list of co-ordination compounds are given below.

Which type of isomerism do these compounds exhibit ?

00

[Co (NH3)6] [Cr (CN)6] and [Pt (NH3)2 Cl2]

[Cr (H2O)6] Cl3, [Co (NH3)5 Br] SO4, [Co (NH3)5 NO2]2+, [Cr (H2O)6] Cl3,

ar

ks w w w .1
(2 1 2 score; 5 minutes] [2 1 2 kvtIm; 5 an\nv]
Stage Score
1 1 1 1 1 2 2 2 2 2

XmsgXn-cn-p tImUn-t\-j tImu-p-I ImWn-p sFtkm-sa-dnkw hni-Z-amp-I. [Cr (H2O)6] Cl3, [Co (NH3)5 Br] SO4, [Co (NH3)5 NO2]2+, [Cr (H2O)6] Cl3, [Co (NH3)6] [Cr (CN)6] and [Pt (NH3)2 Cl2] Scoring Key
Scoring Indicators Total Time Score (Minutes)

[Co (NH3)5 Br] SO4 - Ionisation isomerism. [Co (NH3)6] [Cr (CN)6]- Co-ordination isomerism. [Co (NH3)5 NO2] - Linkage isomerism. [Cr (H2O)6] Cl3 - Hydrate isomerism [Pt (NH3)2 Cl2] - Geometric isomerism.
2

2 12

34

Chapter : 12. STERO CHEMISTRY

C.O. Qn. (1)

: 80, 81

Identify correct and wrong statements from the following. Justify your answer. a) b) c) Meso comounds are optically inactive. Diasteromers have same physical properties. Racemic mixture is opitcally inactive due to internal compensation.

[3 score; 3 minutes] Xmsg ]d-bp {]m-h-\-I-fn icnbpw sXpw Is-p-I. \n-fpsS D-c- km[q-Icn-p-I. a) b) c) aotkm kwbp-- H]vn-en C\m-Ivo-hm-Wv. Ubm-o-cntbm-ta-gvkn\v Htc `uXnI kz`m-h-am-Wv.

CtS-W tImw]tk-jaqew dk-anIv anIvk-N H]vn-en C\m-IvSohv BWv.

ar m 00
1 1 1

ks

Scoring Key
Scoring Indicators

.in
[3 kvtIm; 3 an\nv]
Stage Score Total Time Score (Minutes)

a) b) c)

True Wrong external compensation

Wrong. Racemic mixture is optically inactive due to

.1

A compound C4H8 has two isomers having different spatial configurations and phsical properties. a) b) c) Name the type of stereoisomerism exhibited by these compounds. Draw the spatial formulae of these compounds and give their IUPAC names. Which compound has higher boiling point. Justify. [4 score; 10 minutes] C4H8 F kwbp--ns cv sFtkm-a-dp-Iv hyXy-kvX-amb tIm^n-K-td-j-\pw, `uXnI kz`m-h-hp-am-Wv. a) b) c) Cu kwbp-- ImWn-p ocntbm sFtkm-sa-dn-k-ns t]cv Fgp-Xp-I. Cu kwbp---fpsS kvt]jy t^maqe hcv IUPAC \maw Fg-XpI? GXv kwbp--n-\mWv IqSnb Xnf-\ne DXv? km[q-I-cn-pI. [4 kvtIm; 3 an\nv]

C.O. : 76 Qn. (2)

35

Scoring Key
Scoring Indicators Stage Score Total Time Score (Minutes)

a)

Geometrical isomerism H H C H3 C C CH3 Cis- 2-butene H3 C H C C A e tras - 2 - butenc CH3

b)

c)

Cis isomer. High dipolemoment due to unsymmetric structure.

A compound CH3 CH (OH) COOH can exhibit steroisomerism. a) b) c)

How many steromerisomers are possible for this compound.

An eqimolar mixture of these isomers is found to be optically inactive. Substantiate.

ar

ks
[3 score; 4 minutes] [3 kvtIm; 4 an\nv]
Stage Score Total Time Score (Minutes)

Name the type of steroisomerism exhibited by this compound.

a) b) c)

Cu kwbpw ImWn-p ocntbm sFtkm-sa-dn-k-ns t]cv Fgp-XpI? Cu sFtkm-sa-dp-I-fpsS CIzn-tam-fm an{inXw H]vn- BIvn-hnn ImWn-p-n-. hni-Z-am--pI.

Scoring Indicators

a) b) c)

Optical isomerism 2 stereoisomers (dextro form and laevo form) Due to external compensation.

Scoring Key

.1

Cu kwbp-Xn\v F{X ocntbm sFtkm-sa-dp-I km[y-amWv?

00

CH3 CH (OH) COOH F kwbpw ocntbm sFtkm-sa-dnkw {]I-Sn-n-p-p.

.in
1 1 1 3 4

C.O. : 76, 80 Qn. (3)

C.O. : 82 Qn. (3) O CH3 C CH2 CH2 CH3 H2 / Ni A O CH3 C CH2 CH2 CH3 N2 / Ni
chiral catalyst

36

a) b)

It was observed that the product A was optically inactive. Justify. Predict whether B is optically active or not. Give reason. [32 score; 4 minutes] O

CH3 C CH2 CH2 CH3 H2 / Ni A O CH3 C CH2 CH2 CH3 N2 / Ni

chiral catalyst

a) b)

A F kwbpw H]vn-eo C\m-IvSohv BWv. km[q-I-cn-p-I. B F kwbpw H]vn-eo BIvSohv BtWm Atbm Fv {]h-Nn-pI. ImcWw Fgp-Xp-I. [3 kvtIm; 4 an\nv]

Scoring Indicators

.in ks ar
H H OH H (III) 1 2

Scoring Key

Stage Score

Total Time Score (Minutes)

a) b)

Racemic mixture is formed. B is optically active asymmetric synthesis.

Stero isomers of lactic acid are given. COOH H OH

00

C.O. : 81 Qn. (5)

m w .1
COOH COOH OH

HO

HO

HO

COOH (I) a) b)

COOH (II)

COOH

Identify optically active and inactive compounds. Which of these compounds can be used to prepare racemic mixture ? [4 score; 5 minutes]

37

emIvSnIv Bkn-Uns ocntbm sFtkm-a-dp-I Xmsg Xn-cn-p-p. COOH H OH HO COOH H H COOH OH

HO

OH

HO

COOH (I) a) b)

COOH (II)

COOH (III)

H]vn-en BIvSohpw C\m-IvSohpw Bb kwbp-- Xncn--dn-bp-I. GsXms kwbp---fmWv dk-anIvan{inXw Xm-dm-m D]-tbm-Kn-p-I ? [3 kvtIm; 4 an\nv]
Total Time Score (Minutes)

Scoring Key
Scoring Indicators

ks ar m w w w .1 00
38

a) b)

I and II are optically active. III is optically inactive. Equal proportion of I and II form racemic mixture.

.in
2 1

Stage Score

Chapter : 13. ORGANIC COMPOUNDS WITH FUNCTIONAL GROUP

CONTAINING OXYGEN - I

C.O. Qn. (1) a) b) a) b)

: 84

Draw the structure of all isomeric alcohols of the molecular formula C4H10O. Give the IUPAC names of the above alcohols. [4 score; 6 minutes] C4H10O F Xm-{Xm-hm-Iy-ap Fm sFtkm-sa-dnIv B-tlm-fp-Ifp-tSbpw LS\ hc-bvp-I.

Scoring Indicators

ks ar m w w w .1 00
39

Scoring Key

.in
2 2

apI-fn hc B-tlm-fp-I-fpsS IUPAC \maw Fgp-Xp-I.

[4 kvtIm; 6 an\nv]
Total Time Score (Minutes)

Stage Score

a) c)

Structural formulae of four isomeric alcohols. ( 1 2 4) IUPAC names ( 1 2 4)

C.O. : 88. 89 Qn. (2) Give short notes on. a) Williamsons ether synthesis b) Reimer - Tiemann Reaction c) Kobles Reaction

[4 1 2 score; 10 minutes]

Xmsg--d-bp--h-bpsS eLp-hn-h-cWw Xbm-dm-p-I. a) b) a) hneyw-kkv CuY kn-kn-kv. doa--So-am dobm-Ivj tIm_vkv dobm-Ivj [4 1 2 kvtIm; 6 an\nv] Scoring Key
Scoring Indicators Stage Score Total Time Score (Minutes)

a)

Equation or explanantion of each

(1 1 2 3 )

Chapter : 14. ORGANIC COMPUNDS WITH

THE FUNCTIONAL GROUPS CONTAINING OXYGEN - II

C.O. Qn. (1)

: 92

The following reagents are available in laboratory. HCHO, CH3CHO, CH3 CO CH3, CH3 Mg Br and distilled water. a) b) c) Give reaction for the preparation of a primary alchohol, secondary alcohol and teritary alcohol. Which of above reagents give iodo form test ? HCHO is allowed to react with NaOH. Predict the product and name the reaction.

b) c)

GsXms cmk-h-kvXp- Ab-tUmt^mw sSv \Ip-p ?

00

HCHO, NaOH Dw Bbn {]hn-m GXv Dw e`n-pw. {]h-\-ns t]cv Fgp-Xp-I. [4 kvtIm; 6 an\nv]
Stage Score Total Time Score (Minutes)

Scoring Indicators

b) c)

C.O. : 92, 93 Qn. (2) How will you bring about the following conversions. a) Propanone to propane b) Toluene to Benzoic acid c) Ethanal to But - 2 - enal [4 score; 10 minutes] Xmsg--d-bp cmk-a-- Fs\ km[y-ammw? a) b) s{]m-t\m s{]mt sSmfp-hn s_tkm-bnIv BknUv

a)

HC HO + CH3 Mg Br Primary alcohol CH3 CHO + CH3 Mg Br Secondary alcohol CH3 CHO + CH3 Mg Br Teritory alcohol CH3 CHO and CH3 CO CH3 give ido form test. HCOONa and CH3OH. Cannizzaro reactions.

.1

Scoring Key

m
40

ar

-em_n Xmsg-]-d-bp cmk-h-kvXp- e`y-am-Wv. HCHO, CH3CHO, CH3 CO CH3, CH3 Mg Br, UnnUv hm. a) 1o B-tlm, 2o B-tlm, 3o B-tlm Fnh Xbm-dm-p {]h-\- Fgp-Xp-I.

ks

.in

[4 score; 6 minutes]

a)

FY-\m _yqv 2 Cu\m [4 kvtIm; 6 an\nv]

Scoring Key
Scoring Indicators Stage Score Total Time Score (Minutes)

a) b) c)

Reduction of C = 0 to CH2 group. Oxidation, acidification Aldol condensation, elimination of water.

1 1 12 1 12 4 6

C.O. : 94, 95 Qn. (2) Follwing are a group of compounds showing acidic behaviour. OH HCOOH, a) , CH3 COOH, CH3 CH2 COOH.

b) c)

doesnot contain carboxylic group, still it is acidic. Why? Arrange them in the increasing order of acidity.

b) a)

F-kw-bp--n Imt_m-Ivkn-enIv {Kqv Cs-nepw AXv Akn-UnIv BWv. Fp-sImv? Cu kwbp--sf Akn-Un-nbpsS Btcm-lW{Ia-n Fgp-Xp-I. [4 kvtIm; 6 an\nv]

Scoring Key
Scoring Indicators Stage Score
1 2

a)

Cu kwbp---fpsS IUPAC \maw Fgp-Xp-I. OH

HCOOH,

, CH3 COOH, CH3 CH2 COOH.

.1

[5 score; 8 minutes] Akn-Un-Ivkz-`m-h-ap Hcp Iqw kwbp-- Xmsg sImSp-n-cn-p-p. OH

00

ar

ks
Total Time Score (Minutes)

Give the IUPAC names of these compounds. OH

a) b) c)

IUPAC names (4

) 4 6

Explanation based on resonance stabilisation of pheonoxide ion 1 12 Correct sequence OH<CH3CH2COOH<CH3COOH<HCOOH 1 1 2

41

.in