412C (awad I.

Said)

Dyes Azo
A) Acidic azo dyes
1- Methyl orange
HO3S N2Cl N(CH3)2 + Methyl Orange HO3S N=N N(CH3)2

2- Acid black H.A.

OH OH NH2 NH2 N=N NO2

O2N

N2Cl HO3S

+ HO3S SO3H N2Cl SO3H

OH N=N

NH2 N=N NO2

HO3S Acid black H.A.

SO3H

3- Orang II
OH HO3S N2CL
+

NaOH NaO3S N=N

NaO Orang II

4- Orang I

NaO3S

N=N

ONa

Orang I

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412C (awad I. Said)

B) Basic azoic dyes

1- Bismark Brown
H 2N

ClN2

H2N H 2N N2Cl + 2 NH2

N=N

H2N

N=N

NH2

m-phenylenediamine

Bismark brown

2- Ghryosidine
H2N N2Cl + H2N

NH2

N=N

NH2

m-phenylenediamine

Ghryosidine

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C) Direct azo dyes

1-Congo Red
NH2

ClN2

N2CL

+ 2

SO3H

NH2

H2N

N=N

N=N

HO3S

Congo Red

SO3H

2- Direct Blue

412C (awad I. Said)

NaO3S

NH2 OH HO

H2N

SO3Na

N=N NaO3S H3CO Direct Blue

N=N SO3Na OCH3

C)Ingrain azo dyes

1- Para Red
NaO OH O2N N2Cl
+

NaOH

O2N

N=N

Para Red

2- Phenyl azo -Naphthol

NaO OH N2Cl
+

NaOH

N=N