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PAPER 2 PERLIS 08 Section B

Bahagian B

[20 marks]
[20 markah]

Answer any one question from this section.

Jawab mana-mana satu soalan daripada bahagian ini.

(a)

The following information is about two solution of ethanoic acid.

Maklumat berikut adalah tentang dua larutan asid etanoik.

Solution A
Larutan A

Ethanoic acid dissolve in water.

: Asid etanoik dilarutkan dalam air

Solution B : Ethanoic acid dissolve in propanone

Larutan B : Asid etanoik dilarutkan dalam propanon

Explain why dry blue litmus paper turns red in solution A and remain blue in solution B.
Terangkan mengapa kertas litmus biru bertukar merah dalam larutan A dan kekal biru dalam larutan B.

[4 marks] (b) In a titration, 22.00 cm3 of 0.1 mol dm-3 sulphuric acid is required to neutralise 25.00 cm3 of sodium hydroxide.

Dalam satu pentitratan 22.00 cm3 asid sulfuric 0.1 mol dm-3 diperlukan untuk menuetralkan 25 cm3 larutan natrium hidroksida.

(i) Write the chemical equation of the reaction.

Tulis persamaan kimia bagi tindak balas ini.

(ii)

Calculate the concentration of sodium hydroxide used in this experiment.

Hitung kepekatan larutan natrium hidroksida yang digunakan dalam eksperimen ini.

[6 marks] (c) Describe the chemical tests that can be used to verify the cation and anion in magnesium nitrate.
Huraikan ujian-ujian kimia yang boleh digunakan untuk mengenal kation dan anion dalam magnesium nitrat.

[10 marks]

2 ANSWER FOR PERLIS NO7 SECTION B Question 7. (a) Answer Ethanoic acid ionizes in water produce H + ions The present of H+ ions shows the acidity Ethanoic acid in propanone, cannot ionize to form H+ ions//exist as molecules No H+ ions cannot shows the acidity (b)(i) H2SO4 + 2 NaOH Na2SO4 + 2 H2O Correct formula of reactant Correct formula of product Balance The no. of mol of H2SO4 =22x0.1/1000//0.0022 Mol of NaOH = 0.0044 Molarity of NaOH= 0.0044x 1000/25// = 0.176 mol dm -3 @ 0.1 x 22 = Mb x 25 (c ) 2 [1] [1] [1] [1] To identify Mg 2+ ion -Magnesium nitrate solution is poured into a test tube -NaOH solution is added until excess -white precipitate insoluble in excess and -test with NH3 solution -same step and same result will obtained when test with NH3 solution NO3- ion -Magnesium nitrate solution is poured into a test tube -dilute sulfuric acid is added -followed by iron(II) sulphate solution -shake the test tube -concentrated sulphuric acid is added slowly/through the wall of the test tube -brown ring formed Total marks 1 Marks [1] [1] [1] [1] [1] [1] [1] [1] [1] [1]

[1] [1] [1] [1] [1] [1] [20]

JOHOR 2009 P2

Table 3 shows pH values of different concentration of hydrochloric acid, HCl solutions. Jadual 3 menunjukkan nilai-nilai pH bagi larutan asid hidroklorik, HCl yang berbeza kepekatan. 4 Type of solution Jenis larutan Concentration Kepekatan pH value Nilai pH Solution I Larutan I 0.1 mol dm-3 1 Table 3 (a) (i) Which of the solutions in Table 3 has the highest concentration of hydrogen ions? Larutan yang manakah dalam Jadual 3 mempunyai kepekatan ion hidrogen yang paling tinggi? .......................................................................................................... (ii) Calculate the number of hydrogen ions in 25 cm3 of Solution II. [Avogadro Constant = 6 x 1023 mol-1 ] Hitungkan bilangan ion hidrogen dalam 25 cm3 Larutan II. [Nombor Avogadro = 6 x 1023 mol -1 ] Solution II Larutan II 0.01 mol dm-3 2 Solution III Larutan III 0.001 mol dm-3 3

(iii)

Name an indicator that can be used to measure the pH values of the solutions I, II and III. Namakan satu penunjuk yang boleh digunakan untuk mengukur nilai pH larutan-larutan I, II dan III. ... kah]

(b)

Solution I is used to neutralise 25 cm3 of 0.1 mol dm-3 of sodium hydroxide, NaOH solution. Larutan I digunakan untuk meneutralkan 25 cm3 larutan natrium hidroksida, NaOH 0.1 mol dm-3. (i) Calculate the number of moles of sodium hydroxide, NaOH in the solution. Hitungkan bilangan mol natrium hidroksida, NaOH dalam larutan.

(ii)

Calculate the volume of Solution I used to neutralise sodium hydroxide, NaOH solution in cm3. Hitungkan isipadu Larutan I yang digunakan untuk meneutralkan larutan natrium hidroksida, NaOH dalam cm3. [3 Draw an apparatus set-up for the titration of sodium hydroxide solution with solution I. Lukis susunan radas untuk pentitratan larutan natrium hidroksida

(iii)

ANSWER JOHOR 2009 P2 Question No. 3 (a) (i) Solution I // I (ii) Explanation Mark 1 Mark

Number of mole = 25 x 0.01 = 0.00025 1000 = 0.00025 // 2.5 x 10-4 mol Number of H+ = 0.00025 x 6.02 x 1023 = 1.5 x 1020

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(iii) (b) (i)

Universal indicator // pH paper // pH meter. Number of mole of NaOH = 25 x 0.1 1000 = 0.0025 mol HCl + NaOH NaCl + H2O From the equation, 1 mol of NaOH react with 1 mol of HCl 0.0025 mol of NaOH react with 0.0025 mol of HCl// No. of mole of HCl = 0.0025 mol Volume of HCl = 0.0025 x 1000 0.1 = 25 cm
3

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(ii)

(iii)

Correct diagram of apparatus set-up. Correct label.

Hydrochloric acid / HCl// Solution I

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Sodium hydroxide / NaOH solution